Safety data sheet Verst鋜ker RE - englisch, Stand 30.09.2005, Seite 1 von 6
Safety Data Sheet ( 91/155/EEC) revised 30.09.2005
Verst鋜ker RE
1.identification 2.composition 3.hazards 4.first-aid 5.fire 6.release 7.handling 8.protection
9.properties 10.stability 11.toxicology 12.ecology 13.disposal 14.transport 15.regulations 16.other
1. Identification and company
Trade name Verst鋜ker RE
ContiTech Transportbandsysteme GmbH
Company Breslauerstr. 14, D-37154 Northeim
Tel.05551-702207 Fax. 05551-702504
Dr. Ziebarth, Fon.05551-702378 Fax.05551-702505
information by
E-mail: meinolf.ziebarth@tbs.contitech.de
Emergency phone Werksfeuerwehr 0049-(0)5551-702300
2. Composition / information on ingredients
Chemical characterization:
Polyisocyanat in ethylacetate
Hazardous components:
CAS-Nr. 141-78-6 108-90-7 2422-91-5
EINECS-Nr. 205-500-4 203-628-5 219-351-8
name ethylacetate chlorobenzene Triphenylmethane-4,4',4''triisocyanate
content, approx. 50-100% < 2,5% 25-50%
symbols F, Xi Xn, N Xn
R-phrases 11,36,66,67 10, 20, 51/53 42
additional information:
3. Hazards identification
Hazard designation:
F highly inflammable
Xn harmful
Information pertaining to particular dangers for man and environment :
R 11 Highly flammable.
R 36 Irritating to eyes.
R 42 May cause sensitization by inhalation.
R 67 Vapours may cause drowsiness and dizziness
Contains isocyanates. See information supplied by the manufacturer
4. First-aid measures
After inhalation: Remove to fresh air .
After skin contact: Remove contaminated clothing immediately.Wash with soap and water.
Safety data sheet Verst鋜ker RE - englisch, Stand 30.09.2005 , Seite 2 von 6
After eye contact: Rinse with plenty of fresh water. Consult an ophthalmologist.
After swallowing: Do not induce vomiting. Seek medical advice, show this document.
5. Fire-fighting measures
Suitable extinguishing media: CO2, chemical foam or powder, water mist.
Extinguishing media which must not be used for safety reasons: Water jet
Special exposure hazards arising from the substance or preparation itself: none
Combustion products in the event of fire: CO, NOx, HCN, vapours of isocyanates
Special protective equipment for firefighters: In the event of fire, use self-contained breathing
protection apparatus
Further information: Dispose of fire debris and contaminated fire fighting water in accordance
with official regulations.Collect contaminated fire fighting water separately. It must not enter
drains.
6. Accidental release measures
Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Use breathing protection against the effects of fumes/dust/aerosol.
Wear protective clothing.
Measures for environmental protection:
Prevent material from reaching sewage system, holes and cellars.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,
sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
Send for recovery or disposal in suitable containers.
7. Handling and storage
Handling:
Precautions for safe handling: Stop any vapours at the source of emission. Measures to
prevent fire and explosion: Avoid electrical discharges, do not smoke.
Storage:
Design for storage rooms or vessels: store in the original packaging hermetically closed.
Shelter heat, sparks and all ignition sources.
Incompatible materials: none
Further information to the conditions of storage: Class of storage: A1 ( VbF )
8. Exposure controls / personal protection
Further Information to the system design:
Use ventilation to avoid the inhalation of vapours. see P.7.
Safety data sheet Verst鋜ker RE - englisch, Stand 30.09.2005 , Seite 3 von 6
Ingredients with occupational exposure limits (OEL):
CAS-Nr. Bezeichnung Type of OEL Value Unit
400 ml/m3
141-78-6 ethylacetate TLV
1500 mg/m3
10 ml/m3
108-90-7 chlorobenzene TLV
47 mg/m3
Personal protection:
General protective and hygienic measures: Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of
the work.
Breathing equipment: In case of brief exposure or low pollution (exceeding of TLV) use breathing
filter apparatus (Filter A). In case of intensive or longer exposure use breathing apparatus that is
independent of circulating air.
Protection of hands: Solvent resistant gloves
Eye protection: Tightly sealed safety glasses.
9. Physical and chemical properties
value / range unit method
Physical state liquid
Odour typically solvent
colour violet
pH-value not possible
Melting point/range not determined 癈
Boiling point/range 75 癈
flash point -4 癈
Flammability highly inflammable
Ignition temperature ca. 460 癈
Autoflammability no
explosion limits lower: 2,1 Vol%
upper: 11,5 Vol%
Vapour pressure (20癈) ca. 100 mbar
density (20癈) 0,99 g/cm3
Water solubility (20癈) 50 (solvent) g/dm3
viscosity (20癈) 11 s DIN 53211/4
solvent content (VOC) 73 % weight
solid content 27 % weight
10. Stability and reactivity
Conditions to avoid: humidity
Materials to avoid: water, alcohols, amines, acids and bases. Reacts with these to gaseous CO2
which may cause pressure in closed containers and the risk of bursting.
Hazardous decomposition products: not known
Safety data sheet Verst鋜ker RE - englisch, Stand 30.09.2005 , Seite 4 von 6
11. Toxicological information
Toxicological characteristics: special informations don't exist for this preparation. Acute toxicity of
ingredients:
108-90-7 chlorobenzene oral LD50: 2910 mg/kg (rat)
Experiences: not available
general remarks: the mixture has not been tested explicitely.
skin contact: not irritant
eye contact : irritant
sensitization: repeated inhalation of aerosols may cause sensitization.
Additional toxicological information: The product shows the following dangers according to the
calculation method of the General EC Classification Guidelines for Preparations as issued in the
latest version: Harmful
12. Ecological information
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or
sewage system.
13. Disposal considerations
Product recommendation: Hazardous waste ! Must be handed over to an authorized collector
responsible for proper disposal of hazardous waste. Unused product can be recycled by the
manufacturer.
European waste catalogue: 08 04 06 adhesives and sealants sludges free of halogenated solvents
Uncleaned packaging recommendation:
Dried bottles may be recycled.
14. Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/ domestic)
ADR/RID/GGVS/GGVE-Klasse 3, flammable liquid
Item 3b
Hazard No. 33
UN-No. 1173
label 3
Designation of goods: Ethylacetat, solution
ADR 2001 - classification:
Remarks
ADR-Code F1, Packing group II
Maritime transport IMDG/GGVSea:
GGVSee/IMDG-class 3.2
UN-Nr.: 1173
packing group II
EmS 3-07
MFAG 330
Marine pollutant NO
Correct technical name: Ethyl acetate, solution
Remarks: Suitable UN approved container necessary.
Safety data sheet Verst鋜ker RE - englisch, Stand 30.09.2005 , Seite 5 von 6
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA-class 3
UN/ID-Nr. 1173
PG II
Correct technical name Ethyl acetate, solution
Remarks: Suitable UN approved container necessary.
15. Regulatory information
Code letter and hazard designation of product:
Xn Harmful
F Highly flammable
ingredients relevant for labelling :
Triphenylmethane-4,4',4''triisocyanate
Risk phrases:
11 Highly flammable.
36 Irritating to eyes.
42 May cause sensitization by inhalation.
67 Vapours may cause drowsiness and dizziness
Safety phrases:
16 Keep away from sources of ignition - No smoking.
23 Do not breathe gas/fumes/vapour/spray.
25 Avoid contact with eyes.
33 Take precautionary measures against static discharges.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
60 This material and its container must be disposed of as hazardous waste.
special designation of certain preparations:
Contains isocyanates. See information supplied by the manufacturer
National regulations (Germany)
see german edition, not relevant for others
16. Other information
Further information
The information of this MSDS is based on the present state of our knowledge and on current EC and
national laws. It is meant as a description of the safety requirements of our product, but it is not to be
considered as a guarantee of properties. Verst鋜ker RE is added to different rubber solutions and
CONTI SECUR for curing, see separate safety data sheets.
Contact : Dr. Ziebarth Phone: 0049-(0)5551-702378 Fax 0049-(0)5551-702505 E-mail:
meinolf.ziebarth@tbs.contitech.de
1.identification 2.composition 3.hazards 4.first-aid 5.fire 6.release 7.handling 8.protection
Safety data sheet Verst鋜ker RE - englisch, Stand 30.09.2005 , Seite 6 von 6
9.properties 10.stability 11.toxicology 12.ecology 13.disposal 14.transport 15.regulations 16.other
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