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MATERIAL SAFETY DATA SHEET
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
PRODUCT NAME: P-29
CHEMICAL NAME: Solvent-Borne Vinyl-Based Filler
MANUFACTURER: CASS POLYMERS OF MICHIGAN, INC.
815 WEST SHEPHERD STREET
CHARLOTTE MI 48813 USA
INFORMATION PHONE: (248) 588-2270
EMERGENCY PHONE: (703) 527-3887(Call Collect)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Materials Information System (United States)
Health 2*
Flammability 1
Physical Hazard 0
Hazard Codes: *=Chronic Hazard 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard, 4=Severe Hazard
Material Composition
Component CAS.NO EINECS/ELINCS No. Percent
Not Available 10% - 15%
2-Butaendioic Acid-Polymer with Chloroethane and Ethenyl Acetate 9005-09-8
Magnesium Silicate 14807-96-6 238-877-9 50% - 60%
Methyl Isobutyl Ketone 108-10-1 203-550-1 15% - 20%
Methyl Ethyl Ketone 78-93-3 201-159-0 5% - 10%
Ethylene Glycol Monomethyl Ether 110-80-5 203-804-1 2% - 4%
DibutylPhthalate* 87-74-2 201-557-4 1% - 3%
* This Material Presents a Chronic Health Hazard. See section 8-EXPOSURE CONTROLS/PERSONAL PROTECTION, and section
11-TOXICOLOGICAL INFORMATION for complete hazard/exposure limit information.
NOTE: Hazardous Materials are required to be listed if present in concentrations of 1.0% or higher. Materials posing a possible
Chronic Health Risk are required to be listed at concentrations of 0.1% or higher. All materials listed in section 2 are not necessarily
hazardous. See section 8-EXPOSURE CONTROLS/PERSONAL PROTECTION, and section 11-TOXICOLOGICAL
INFORMATION for further hazard/exposure limit information.
3. HAZARDS IDENTIFICATION
EC Classification(s): T-Toxic, F-Flammable, N-Harmful to the Environment
Risk Phrase(s): R11: Highly Flammable
R36/37/38: Irritating to the eyes, respiratory system and skin
R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation
R53: May cause long term adverse effects in the aquatic environment
R62: Possible Risk of Impaired Fertility
R67: Vapors may cause drowsiness and dizziness
(See Section 15-REGULATORY INFORMATION for complete risk phrases.)
ROUTES OF EXPOSURE
Eye Contact
Skin Contact
Ingestion
Inhalation
EXPOSURE STANDARDS
Exposure standards available for individual components only See section 8-EXPOSURE CONTROLS/PERSONAL
PROTECTION, and section 11-TOXICOLOGICAL INFORMATION for complete hazard/exposure limit information.
Maintain air contaminant concentrations in the workplace at the lowest feasible levels.
IMMEDIATE HEALTH HAZARDS
Skin irritant.
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Eye irritant.
Respiratory tract irritant.
May cause skin sensitization.
TARGET ORGANS ACUTE AND CHRONIC EFFECTS
Skin, Eyes, Kidneys, Liver, Lungs, Testes, Central Nervous System.
SIGNS AND SYMPTOMS OF EXPOSURE (Acute effects)
Contact with eyes may cause irritation and discomfort. Contact with skin causes irritation, redness and discomfort which is
transient. Inhalation of mists may cause irritation in the respiratory tract. Inhalation of vapors may cause irritation in the
respiratory tract. Coughing and chest pain may result.
CHRONIC EXPOSURE HAZARDS (Possible Longer Term Effects)
Repeated and/or prolonged exposure may cause allergic reaction/sensitization. Repeated and/or prolonged exposures may
result in: Impaired fertility, birth defects, developmental abnormalities in the unborn child.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Skin disorders, Respiratory Disorderes and Allergies
CARCINOGENS UNDER OSHA, ACGIH, NTP, IARC, OTHER
This product contains no carcinogens in concentrations of 0.1 percent or greater. Other chronic health risks exist with
components of this product. See section 8 and section 11 for further information.
4. FIRST AID MEASURES
Never give fluids or induce vomiting if patient is unconscious or is having convulsions.
Inhalation
Move effected persons to fresh air; if effects continue, consult a physician.
Skin Contact
Continued and thorough washing in flowing water for at least 15 minutes is imperative while removing contaminated clothing.
Prompt medical consultation is essential. Wash clothing before reuse. Destroy contaminated leather items.
Eye Contact
Wash immediately and continuously with flowing water for at least 15 minutes. Remove contact lenses after the first 5
minutes and continue washing. Obtain prompt medical consultation, preferably from an ophthalmologist.
Ingestion
If swallowed, call a physician immediately. Remove stomach contents by gastric suction or induce vomiting only as directed
by a physician or medical personnel. Do not give anything by mouth to an unconscious person.
Note to Physician
No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the
patient.
5. FIRE FIGHTING PRECAUTIONS
Extinguishing Media
Water fog or fine spray. Carbon dioxide. Alcohol resistant foam. Dry chemical fire extinguishers. Flash Point is 61篎 (16篊).
Hazardous Combustion Products
May generate toxic or irritating combustion products. Sudden reaction and fire may occur if product is mixed with an
oxidizing agent.
Protection of Firefighters
Wear positive-pressure self-contained breathing apparatus and protective fire fighting clothing (includes fire fighting helmet,
coat, trousers, boots and gloves.)
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Wear adequate personal protective equipment, see Section 8, EXPOSURE CONTROLS/PERSONAL PROTECTION.
Methods of Cleaning Up
Ventilate area and remove or turn off all sources of ignition.
Large spills: Contain with dike. Pump into suitable and properly labeled containers.
Small spills: Dilute with water and recover or use non-combustible absorbent material/sand and shovel into appropriate
containers.
7. HANDLING AND STORAGE
STORAGE
Keep away from oxidizers. Keep in cool, dry, ventilated storage areas and in closed containers.
HANDLING
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Avoid prolonged exposure. Do not get on skin, in eyes or on clothing. Do not breathe vapors. Handle in well-ventilated
workspace. When handling, do not eat, drink, or smoke. After handling, wash exposed skin thoroughly before eating,
drinking, smoking or using the toilet.
OTHER PRECAUTIONS
Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by
government regulations (e.g. OSHA).
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Hazardous Component Control Parameters ?br>
Component CAS. No. EINECS Percent Exposure Limits Source
205 mg/m3 TWA ACGIH
Methyl Isobutyl Ketone 108-10-1 203-550-1 15% - 20%
307 mg/m3 STEL ACGIH
200 ppm TWA- skin OSHA
Ethylene Glycol Monomethyl Ether 110-80-5 203-804-1 2% - 4%
5ppm TWA- skin ACGIH
300 ppm- STEL ACGIH
200 ppm- TWA ACGIH
Methyl Ethyl Ketone 78-93-3 201-159-0 5% - 10%
590 mg/m3 8 hr PEL OSHA
5 mg/m3 TWA ACGIH
DibutylPhthalate* 87-74-2 201-557-4 1% - 3%
5 mg/m3 8 hr PEL OSHA
10 mg/m3
Nuisance Dust from Sanding ACGIH
-No Further Data Available-
EYE PROTECTION
Chemical safety glasses. A full-face shield and vapor respirator is recommended for operations involving spraying this
material.
HAND PROTECTION
Neoprene rubber gloves. Impermeable gloves. Nitrile rubber gloves. The breakthrough time of the selected
glove(s) must be greater than the intended use period. The selection of a specific glove for a particular application and
duration of use in a workplace should also take into account all requisite workplace factors such as, but not limited to: Other
chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), as well as the
instructions/specifications provided by the glove supplier.
RESPIRATORY PROTECTION
A cartridge mask National Institute for Occupational Safety and Health (NIOSH) approved for organic vapors is appropriate
for use with this material. Maintain adequate workplace ventilation at levels below designated occupational guidelines.
PROTECTIVE CLOTHING
Long sleeved clothing. Impermeable (non-absorbant) work clothing.
ENGINEERING CONTROLS
No specific controls needed.
WORK AND HYGIENIC PRACTICES
Provide readily accessible eye wash stations and safety showers. Wash at the end of each work shift and before eating,
smoking or using the toilet.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Paste-like material
Color: White, Grey, Black or Tan
Odor: Solvent Odor
Specific gravity: 1.2 ?1.4
Vapor pressure: Not Determined
Boiling point/range: Not Determined
Freezing point/range: Not Determined
Water solubility: Liquid Components Readily Soluble in Water
pH: Not Determined
Flash point: 61篎 (16篊)
Auto-ignition temp: Not Determined
Flammability-LFL: 1.2% by volume at 200篎 (93.3篊)
Flammability- 8.0% by volume at 200篎 (93.3篊)
Volatile Organic Compounds: 33% (473g/L)
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
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Stable
CONDITIONS TO AVOID (if unstable)
Not applicable
INCOMPATIBILITY (Materials to Avoid)
Oxidizing Agents (i.e. perchlorates, nitrates etc.). Sodium or Calcium Hypochlorite. Reaction with peroxides
may result in violent decomposition of peroxide possibly creating an explosion.
HAZARDOUS DECOMPOSITION PRODUCTS (from burning, heating, or reaction with other materials).
Carbon Monoxide in a fire. Carbon Dioxide in a fire. Irritating and toxic fumes at elevated temperatures.
HAZARDOUS POLYMERIZATION
Will not occur
CONDITIONS TO AVOID (if polymerization may occur)
Not applicable
11. TOXICOLOGICAL INFORMATION
Acute toxicity
This finished product has not been tested to determine individual toxicological/ecological limits. Individual components of
this mixture have been independently tested by the raw material manufacturers and any known results have been presented
below. The results for the individual components may not be representative of the toxicity of this finished product.
Ingredient Name CAS No. % Test Result Route Species
LD50 8000mg/kg Oral Rat
4250 mg/m3
LC50 Inhalation Rat
DibutylPhthalate* 87-74-2 1% - 3%
LD50 3050 礚/kg Interaperitoneal Rat
LD50 >20mL/kg Dermal Rabbit
LD50 2737 mg/kg Oral Rat
23,500 mg/m3
5% -10% LC50 Inhalation Rat
Methyl Ethyl Ketone 78-93-3
LD50 6484 mg/kg Dermal Rabbit
-No Further Data Available-
Ingestion
This material should be considered toxic by ingestion.
Skin Contact
Widespread skin contact is not likely to cause immediate toxic effects. Prolonged skin contact may cause impared fertility or
reproductive harm.
Irritation
Skin
Skin contact has caused allergic skin reactions in certain sensitized individuals.
Eyes
Irritation with local redness. Mechanical irritation possible due to solid filler materials.
Inhalation
May cause respiratory irritation upon exposure to vapors.
Chronic Exposure
Carcinogen
This material does not contain any known or suspected carcinogens in concentrations above 0.1%.
Mutagen
This material contains DIBUTYL PHTHALATE (CAS# 84-74-2), a substance that has caused DNA and other cell damage to
human tissues in laboratory tests.
Reproductive Hazard
This material contains DIBUTYL PHTHALATE (CAS# 84-74-2), a substance that has caused reproductive problems and
birth defects in laboratory animals.
12. ECOLOGICAL INFORMATION
Persistence/degradability
This material contains components that show little or no evidence of biodegradability. Caution should be taken to prevent
release to the environment. See Section 13 for disposal information.
Ecotoxicity Data:
Chemical Name CAS No. % Test Concentration Result Species
15% - 20% LC50 780 mg/L LC50 Fathead Minnow
Methyl isobutyl ketone 108-10-1
5% - 10% LC50 3130 mg/L LC50 Fathead Minnow
Methyl Ethyl Ketone 78-93-3
DIBUTYL PHTHAlATE 84-74-2 1% - 3% LC50 0.92 mg/L 96 hr Fathead Minnow
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EC50 3.4 mg.L 48 hr Daphnid
-No Further Data Available-
Individual components of this mixture have been independently tested by the raw material suppliers and any known results have been
presented above. The results for the individual components may not be representative of the ecological toxicity of this finished
product. This finished product has not been tested to determine individual toxicological/ecological limits Caution should be taken to
prevent release to the environment. See Section 13 for further information.
13. DISPOSAL CONSIDERATIONS
Disposal
The generation of waste should be avoided or minimized wherever possible. Preferred method of disposal includes
incineration under controlled conditions in accordance with all local and national laws and regulations. Untreated material is
not suitable for disposal. Waste, even small quantities, should never be poured down drains, sewers or watercourses. Waste
must be disposed of in accordance with federal, state and local environmental control regulations.
Contaminated packaging
Empty containers can only be disposed of when the remaining product adhering to the container walls has been removed.
Hazard warning labels should be removed from the container only after it has been properly emptied.
14. TRANSPORT INFORMATION
Land/Air/Sea/Rail
Proper Shipping Name: Resin Solution
UN Number: UN-1866
Hazard Class: 3
Packing Group: III
15. REGULATORY INFORMATION
US FEDERAL REGULATIONS
TOXIC SUBSTANCES CONTROL ACT (TSCA)-
All components are included in the EPA Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
TOXIC SUBSTANCE CONTROL ACT (TSCA) 12(b) COMPONENT(S)
DIBUTYL PHTHALATE (CAS#84-74-8), 2%
OSHA Hazard Communication Standard (29CFR1910.1200) hazard class(es)
Irritant. Sensitizer. Possible Risk of Impaired Fertility.
EPA SARA Title III Section 312 (40CFR370) hazard class
Immediate Health Hazard. Delayed Health Hazard.
EPA SARA Title III Section 313 (40CFR372) toxic chemicals above "de minimis" level are
DIBUTYL PHTHALATE (CAS#84-74-8), 2%
2-Ethoxyethanol (CAS# 110-80-5), 3%
Methyl isobutyl ketone (CAS#108-10-1), 20%
Methyl ethyl ketone (CAS# 78-93-3), 9%
STATE REGULATIONS
PROPOSITION 65 SUBSTANCES (component(s) known to the State of California to cause cancer and/or reproductive toxicity
and subject to warning and discharge requirements under the "Safe Drinking Water and Toxic Enforcement Act of 1986")
DIBUTYL PHTHALATE (CAS#84-74-8), 2% - Reproductive Hazard
2-Ethoxyethanol (CAS# 110-80-5), 3% - Reproductive Hazard
CANADIAN REGULATIONS
DSL
Included on Inventory.
WHMIS HAZARD CLASSIFICATION
D2B- Toxic Material Causing Other Toxic Effects
WHMIS INGREDIENT DISCLOSURE LIST
DIBUTYL PHTHALATE CAS#84-74-2, 2%
WHMIS TRADE SECRET REGISTRY NUMBER(S)
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
None
WHMIS SYMBOL(S):
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EUROPEAN ECONOMIC COMMUNITY (EEC)
EINECS Status:
All components of this product are included in the European Inventory of Existing Chemical Substances (EINECS) in
Compliance with Council Directive 67/548/EEC and its amendments. CHIP3 Regulations have been applied and meets all
requirements
F N T
EU Labeling Classification: T-Toxic; N-Harmful to the Environment; F-Flammable
Risk Phrases: R11: Highly Flammable
R36/37/38: Irritating to the eyes, respiratory system and skin
R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation
R53: May cause long term adverse effects in the aquatic environment
R62: Possible Risk of Impaired Fertility
R67: Vapors may cause drowsiness and dizziness
Safety Phrases: S53: Avoid exposure - obtain special instructions before use
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S61: Avoid release to the environment. Refer to special instructions/Safety data sheets
16. OTHER INFORMATION
Definitions:
ACGIH: American Conference of Government Industrial Hygenists
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
TLV: Threshold Limit Value
TWA: Time-Weighted Average
LD50: Lethal Dose (50%)-The minimum dose required for lethal effects in 50% of a given population of test specimens.
LC50: Lethal Concentration (50%)- The minimum concentration required for lethal effects in 50% of a given population of
test specimens
NIOSH: National Institute for Occupational Safety and Health
WHMIS: Workplace Hazardous Material Information System
DSL: Domestic Substances List
To the best of our knowledge, the information contained herein is accurate. Final determination of the suitability of any material is the
sole responsibility of the users. All materials may present unknown hazards and should be used with caution. Although certain hazards
are described herein, we cannot guarantee that these are the only hazards which exist.
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