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MSDS Material Safety Data Sheet
CAS

108-05-4 023-00-0 51000-52-3 3724-65-0

File Name: 108-05-4_023-00-0_51000-52-3_3724-65.asp

Safety data sheet


Page: 1/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 24.10.2007 Version: 1.1
Product: Luviset* CAN
(30060969/SDS_COS_EU/EN)
Date of print 04.02.2008




1. Substance/preparation and company identification

Luviset* CAN
Use: Polymer, cosmetic ingredient


Company:
BASF SE
67056 Ludwigshafen
GERMANY
Care Chemicals
Telephone: +49 621 60-28444
Telefax number: +49 621 60-28189
E-mail address: EM-Masterdata@basf.com

Emergency information:
Telephone: +49 180 2273-112
Telefax number: +49 621 60-92664



2. Hazard identification
The product is under certain conditions capable of dust explosion.



3. Composition/information on ingredients

Chemical nature

INCI Name: VA/Crotonates/Vinyl Neodecanoate Copolymer

copolymer

vinyl acetate
Page: 2/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 24.10.2007 Version: 1.1
Product: Luviset* CAN
(30060969/SDS_COS_EU/EN)
Date of print 04.02.2008


CAS Number: 108-05-4
EC-Number: 203-545-4
INDEX-Number: 607-023-00-0
vinyl neodecanoate
CAS Number: 51000-52-3
EC-Number: 256-905-8
crotonic acid
CAS Number: 3724-65-0
EC-Number: 223-077-4


4. First-aid measures

General advice:
Take off immediately all contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:
Rinse mouth and then drink plenty of water.



5. Fire-fighting measures

Suitable extinguishing media:
water, dry powder

Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.



6. Accidental release measures

Personal precautions:
Use breathing apparatus if exposed to vapours/dust/aerosol.

Environmental precautions:
Do not empty into drains.
Page: 3/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 24.10.2007 Version: 1.1
Product: Luviset* CAN
(30060969/SDS_COS_EU/EN)
Date of print 04.02.2008


Methods for cleaning up or taking up:
For small amounts: Sweep/shovel up.
For large amounts: Sweep/shovel up.
Dispose of absorbed material in accordance with regulations.



7. Handling and storage

Handling
Avoid dust formation.

Protection against fire and explosion:
Take precautionary measures against static discharges.

Storage
Further information on storage conditions: Keep container tightly closed and dry; store in a cool
place.


8. Exposure controls and personal protection

Components with workplace control parameters

Product contains residual monomer(s). The substance mentioned is contained only in traces in the
product.

108-05-4: vinyl acetate



Personal protective equipment
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice.
Page: 4/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 24.10.2007 Version: 1.1
Product: Luviset* CAN
(30060969/SDS_COS_EU/EN)
Date of print 04.02.2008



9. Physical and chemical properties

Form: powder
Colour: white
Odour: odourless

melting range: 40 - 50 癈

Minimum ignition energy: > 4 J

Bulk density: approx. 750 kg/m3

Solubility in water:
< 1 mg/l
(23 癈)



10. Stability and reactivity
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.

Hazardous reactions:
Dust explosion hazard.


Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.


11. Toxicological information

Acute toxicity

Assessment of acute toxicity:
Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact.

LD50 rat (oral): > 34.6 g/kg
The product has not been tested. The statement has been derived from products of a similar
structure and composition.

LD50 rat (dermal): > 10.200 mg/kg
The product has not been tested. The statement has been derived from products of a similar
structure and composition.

Irritation

Assessment of irritating effects:
Not irritating to the skin. Not irritating to the eyes.

Primary skin irritation rabbit: non-irritant (Draize test)
Page: 5/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 24.10.2007 Version: 1.1
Product: Luviset* CAN
(30060969/SDS_COS_EU/EN)
Date of print 04.02.2008


The product has not been tested. The statement has been derived from products of a similar
structure and composition.

Primary irritations of the mucous membrane rabbit: non-irritant (Draize test)
The product has not been tested. The statement has been derived from products of a similar
structure and composition.

Sensitization

Assessment of sensitization:
Skin sensitizing effects were not observed in animal studies.

Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)

Genetic toxicity

Assessment of mutagenicity:
The substance was not mutagenic in bacteria.


12. Ecological information

Ecotoxicity

Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition
of the degradation activity of activated sludge is not anticipated when introduced to biological
treatment plants in appropriate low concentrations. The product has not been tested. The statement
has been derived from products of a similar structure and composition.

Toxicity to fish:
LC50 (96 h) > 10,000 mg/l, Leuciscus idus (DIN 38412 Part 15, static)
The details of the toxic effect relate to the nominal concentration.

Microorganisms/Effect on activated sludge:
EC20 (0.5 h) approx. 160 mg/l, activated sludge (OECD Guideline 209, aerobic)

Persistence and degradability

Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria). Poorly biodegradable. The product has not been
tested. The statement has been derived from products of a similar structure and composition.

Elimination information:
< 20 % BOD of COD (28 d) (OECD Guideline 301 F) (aerobic, activated sludge)

Bioaccumulation potential

Bioaccumulation potential:
Based on its structural properties, the polymer is not biologically available. Accumulation in
organisms is not to be expected.
Page: 6/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 24.10.2007 Version: 1.1
Product: Luviset* CAN
(30060969/SDS_COS_EU/EN)
Date of print 04.02.2008



13. Disposal considerations

Observe national and local legal requirements.



14. Transport information

Land transport

ADR
Not classified as a dangerous good under transport regulations

RID
Not classified as a dangerous good under transport regulations


Inland waterway transport
ADNR
Not classified as a dangerous good under transport regulations



Sea transport
IMDG
Not classified as a dangerous good under transport regulations



Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations


15. Regulatory information

Regulations of the European union (Labelling) / National legislation/Regulations

The product does not require a hazard warning label in accordance with EC Directives.

Other regulations


16. Other information


Vertical lines in the left hand margin indicate an amendment from the previous version.
Page: 7/7
BASF Safety data sheet according to Regulation (EC) No.1907/2006
Date / Revised: 24.10.2007 Version: 1.1
Product: Luviset* CAN
(30060969/SDS_COS_EU/EN)
Date of print 04.02.2008


The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.

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