PACKAGING SERVICE CO., INC. DATE: 10/01/02
PRODUCT IDENTITY: CROWN DENATURED ALCOHOL PAGE 1 OF 7
NEW MSDS DATE: 10/01/2002
MATERIAL SAFETY DATA SHEET
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD)
IMPORTANT: Read this MSDS before handling & disposing of this product.
Pass this information on to employees, customers, & users of this product.
SECTION 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY
PRODUCT IDENTITY: CROWN DENATURED ALCOHOL
COMPANY IDENTITY: PACKAGING SERVICE CO., INC.
COMPANY ADDRESS: 1904 MYKAWA ROAD / P O Box 875
COMPANY CITY: PEARLAND, TX 77581
COMPANY PHONE: 1-281-485-1458
CHEMTREC PHONE: 1-800-424-9300
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
CONTAINS: 65-75% METHANOL (67-56-1)[200-659-6],
20-30% ETHANOL (64-17-5)[200-578-6],
< 10% ISOPROPANOL (67-63-0)[200-661-7],
< 10% METHYL ISOBUTYL KETONE (108-10-1)[203-550-1]
Number in parentheses is CAS #, number in brackets is European EC #.
SECTION 3. HAZARDS IDENTIFICATION
RISK STATEMENTS:
R11 Highly Flammable.
R41 Risk of serious damage to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R39/25 Toxic: danger of very serious irreversible effects if swallowed.
SAFETY STATEMENTS:
S7 Keep container tightly closed.
S9 Keep container in a well-ventilated place.
S16 Keep away from sources of ignition. No smoking.
S24 Avoid contact with skin.
S45 In case of accident, or if you feel unwell, seek medical advice
immediately. (Show the label where possible).
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PACKAGING SERVICE CO., INC. DATE: 10/01/02
PRODUCT IDENTITY: CROWN DENATURED ALCOHOL PAGE 2 OF 7
NEW MSDS DATE: 10/01/2002
SECTION 4. FIRST AID MEASURES
EYE CONTACT:
For eyes, flush with plenty of water for 15 minutes & get medical attention.
SKIN CONTACT:
In case of contact with skin immediately remove contaminated clothing.
Wash thoroughly with soap & water. Wash contaminated clothing before reuse.
INHALATION:
After high vapor exposure, remove to fresh air. If breathing is difficult,
give oxygen. If breathing has stopped give artificial respiration.
SWALLOWING:
Induce vomiting promptly using physician's instructions or by having patient
stick finger down throat. After vomiting has been induced, give two
teaspoonfuls of baking soda in a glass of water. CALL A PHYSICIAN. Never give
anything by mouth to an unconscious person. Have patient lie down & keep warm.
Cover eyes to exclude light.
DNAL01.
SECTION 5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
NFPA Class B extinguishers (Carbon Dioxide or foam) for Class I B liquid
fires.
SPECIAL FIRE FIGHTING PROCEDURES
Water spray may be ineffective on fire but can protect fire-fighters
& cool closed containers. Use fog nozzles if water is used.
Do not enter confined fire-space without full bunker gear.
(Helmet with face shield, bunker coats, gloves & rubber boots).
Use NIOSH approved positive-pressure self-contained breathing apparatus.
UNUSUAL EXPLOSION AND FIRE PROCEDURES
HIGHLY FLAMMABLE!! VAPORS CAN CAUSE FLASH FIRE
Keep container tightly closed.
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Closed containers may explode if exposed to extreme heat.
Applying to hot surfaces requires special precautions.
Empty container very hazardous! Continue all label precautions!
SECTION 6. ACCIDENTAL RELEASE MEASURES
CONTAINMENT TECHNIQUES
Stop spill at source. Dike area & contain.
CLEAN-UP PROCEDURES:
Clean up remainder with absorbent materials. Mop up & dispose of. Persons
without proper protection should be kept from area until cleaned up.
PACKAGING SERVICE CO., INC. DATE: 10/01/02
PRODUCT IDENTITY: CROWN DENATURED ALCOHOL PAGE 3 OF 7
NEW MSDS DATE: 10/01/2002
SECTION 7. HANDLING AND STORAGE
HANDLING:
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Use only with adequate ventilation. Avoid breathing of vapor or spray mist.
Avoid contact with skin & eyes.
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier.
Wear gloves, apron & footwear impervious to this material. Wash clothing
before reuse.
Avoid free fall of liquid. Ground containers when transferring. Do not flame
cut, saw, drill, braze, or weld. Empty container very hazardous! Continue
all label precautions!
STORAGE:
Do not store above 49 C/120 F. Store large amounts in structures made for
OSHA Class I B liquids
Keep container tightly closed
& upright when not in use to prevent leakage.
OSHA Class I B liquids
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION:
EXPOSURE CONTROLS:
Ventilate to keep vapors of this material below 110 ppm.
If over TLV, in accordance with 29 CFR 1910.134,
use NIOSH approved positive-pressure self-contained breathing apparatus.
Consult Safety Equipment Supplier. Use explosion-proof equipment.
VENTILATION:
LOCAL EXHAUST : Necessary
MECHANICAL (GENERAL) : Acceptable
SPECIAL : None
OTHER : None
PERSONAL PROTECTIONS:
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier.
Wear gloves, apron & footwear impervious to this material. Wash clothing
before reuse.
WORK & HYGIENIC PRACTICES:
Provide readily accessible eye wash stations & safety showers.
Wash at end of each workshift & before eating, smoking or using the toilet.
Promptly remove clothing that becomes contaminated. Destroy contaminated
leather articles. Launder or discard contaminated clothing.
PACKAGING SERVICE CO., INC. DATE: 10/01/02
PRODUCT IDENTITY: CROWN DENATURED ALCOHOL PAGE 4 OF 7
NEW MSDS DATE: 10/01/2002
SECTION 9. PHYSICAL DATA
APPEARANCE: Liquid, Water-White
ODOR: Ketone
BOILING RANGE: 63 66 83 C / 147 152 182 F
AUTO IGNITION TEMPERATURE: 371 C / 700 F (Lowest Component)
LOWER FLAMMABLE LIMIT IN AIR (% by vol): 6.4
FLASH POINT (TEST METHOD): 4 C / 40 F (TCC)
FLAMMABILITY CLASSIFICATION: Class I B
GRAVITY @ 60 F:
API: 47.0
SPECIFIC GRAVITY (Water=1): .793
POUNDS/GALLON: 6.603
VOC'S (>0.44 Lbs/Sq In): 100.2 Vol. % / 794.1 g/L / 6.614 Lbs/Gal
TOTAL VOC'S (TVOC): 100.1 Vol. % / 792.7 g/L / 6.603 Lbs/Gal
NONEXEMPT VOC'S (CVOC): 100.1 Vol. % / 792.7 g/L / 6.603 Lbs/Gal
HAZARDOUS AIR POLLUTANTS (HAPS): 73.0 Wt. % / 578.6 g/L / 4.819 Lbs/Gal
VAPOR PRESSURE (mm of Hg)@20 C 86.1
NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C) 86.1
VAPOR DENSITY (air=1): 1.2
WATER ABSORPTION: Complete
REFRACTIVE INDEX: 1.338
SECTION 10. STABILITY & REACTIVITY
STABILITY:
Stable
CONDITIONS TO AVOID:
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
MATERIALS TO AVOID:
Isolate from strong oxidizers such as permanganates, chromates & peroxides.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide, Carbon Dioxide from burning.
HAZARDOUS POLYMERIZATION:
Will not occur.
SECTION 11. TOXICOLOGICAL INFORMATION
MATERIAL CAS # TWA (OSHA) TLV (ACGIH) HAP
Methanol 67-56-1 200 ppm S 200 ppm S Yes
Ethanol 64-17-5 1000 ppm 1000 ppm A4 No
Isopropanol 67-63-0 400 ppm 200 ppm A4 No
Methyl Isobutyl Ketone 108-10-1 100 ppm 50 ppm Yes
Each component showing `Yes' under "HAP" is an EPA Hazardous Air Pollutant.
PACKAGING SERVICE CO., INC. DATE: 10/01/02
PRODUCT IDENTITY: CROWN DENATURED ALCOHOL PAGE 5 OF 7
NEW MSDS DATE: 10/01/2002
SECTION 11. TOXICOLOGICAL INFORMATION (CONTINUED)
MATERIAL CAS # CEILING STEL (OSHA/ACGIH)
Methanol 67-56-1 None Known 250 ppm
Isopropanol 67-63-0 None Known 400 ppm
Methyl Isobutyl Ketone 108-10-1 None Known 75 ppm
ACUTE HAZARDS
EYE & SKIN CONTACT:
Primary irritation to skin, defatting, dermatitis.
Primary irritation to eyes, redness, tearing, blurred vision.
Liquid can cause eye irritation. Wash thoroughly after handling.
INHALATION:
Anesthetic. Irritates respiratory tract. Acute overexposure
can cause serious nervous system depression. Vapor harmful.
Breathing vapor can cause irritation.
Acute overexposure can cause damage to kidneys, blood, nerves, liver & lungs.
Repeated exposure over TLV can cause blindness.
SWALLOWING:
Can be fatal or cause blindness if swallowed. Cannot be made non-poisonous.
POISON! Can cause irreversible nervous system damage & death.
Harmful or fatal if swallowed.
Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.
SUBCHRONIC HAZARDS/CONDITIONS AGGREVATED
CONDITIONS AGGREVATED:
Chronic overexposure can cause damage to kidneys, blood, nerves, liver
& lungs.
Persons with severe skin, liver or kidney problems should avoid use.
CHRONIC HAZARDS
CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS:
This product has no carcinogens listed by IARC, NTP, NIOSH, OSHA or ACGIH, as
of this date, greater or equal to 0.1%.
Absorption thru skin may be harmful. Studies with laboratory animals indicate
this product can cause damage to fetus.
PACKAGING SERVICE CO., INC. DATE: 10/01/02
PRODUCT IDENTITY: CROWN DENATURED ALCOHOL PAGE 6 OF 7
NEW MSDS DATE: 10/01/2002
SECTION 12. ECOLOGICAL INFORMATION
MAMMALIAN INFORMATION:
MATERIAL CAS # LOWEST KNOWN LETHAL DOSE DATA
LOWEST KNOWN LD50 (ORAL)
Methanol 67-56-1 1000.0 mg/kg(Man)
LOWEST KNOWN LC50 (VAPORS)
Isopropanol 67-63-0 16000 ppm (Rats)
LOWEST KNOWN LD50 (SKIN)
Isopropanol 67-63-0 16400.0 mg/kg (Rabbits)
AQUATIC ANIMAL INFORMATION:
The most sensitive known marine group to any component of this product is:
Chub 250 ppm or mg/L (24 hour exposure).
Keep out of sewers and natural water supplies.
MOBILITY:
This material is a mobile liquid.
DEGRADABILITY:
This product is biodegradable.
ACCUMULATION:
This product does not accumulate or biomagnify in the environment.
SECTION 13. DISPOSAL CONSIDERATIONS
Recycle / dispose of observing national, regional, state, provincial and local
health, safety & pollution laws. If questions exist, contact the appropriate
agencies.
SECTION 14. TRANSPORT INFORMATION
DOT SHIPPING NAME: Alcohols,n.o.s.,3, UN1987, PG II
DRUM LABEL: (FLAMMABLE LIQUID)
IATA / ICAO: Alcohols,Flammable,Toxic,n.o.s.
(Methanol,Ethanol),3 (6.1),UN1986,PG-II
DRUM LABEL: (FLAMMABLE LIQUID & TOXIC)
IMO / IMDG: Alcohols,Flammable,Toxic,n.o.s.
(Methanol,Ethanol),3 (6.1),UN1986,PG-II
DRUM LABEL: (FLAMMABLE LIQUID & TOXIC)
EMERGENCY RESPONSE GUIDEBOOK NUMBER: 131
PACKAGING SERVICE CO., INC. DATE: 10/01/02
PRODUCT IDENTITY: CROWN DENATURED ALCOHOL PAGE 7 OF 7
NEW MSDS DATE: 10/01/2002
SECTION 15. REGULATORY INFORMATION
EPA REGULATIONS:
SARA SECTION 311/312 HAZARDS: Acute Health, Fire
All components of this product are on the TSCA list.
SARA Title III Section 313 Supplier Notification
This product contains the indicated <*> toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning & Community
Right-To-Know Act of 1986 & of 40 CFR 372. This information must be
included in all MSDSs that are copied and distributed for this material.
SARA TITLE III INGREDIENTS CAS# WT. % (REG. SECTION) RQ(LBS)
*Methanol 67-56-1 <80 (311,312,313,RCRA) 5000
*Methyl Isobutyl Ketone 108-10-1 < 1 (311,312,313,RCRA) 5000
IF > 6874 POUNDS OF THIS PRODUCT IS IN ONE CONTAINER THE "RQ" OF METHANOL IS
EXCEEDED.
INTERNATIONAL REGULATIONS:
The components of this product are listed on the chemical inventories of the
following countries:
Australia, Canada, Europe (EINECS), Japan, Korea, United Kingdom.
SECTION 16. OTHER INFORMATION
HAZARD RATINGS:
HEALTH (NFPA) : 1
HEALTH (HMIS) : 3
FLAMMABILITY : 3
REACTIVITY : 0
This information is intended solely for the use of individuals trained in the NFPA
& HMIS hazard rating systems.
EMPLOYEE TRAINING:
Employees should be made aware of all hazards of this material (as stated
in this MSDS) before handling it.
NOTICE
The supplier disclaims all expressed or implied warranties of merchantability or
fitness for a specific use, with respect to the product or the information
provided herein, except for conformation to contracted specifications. All
information appearing herein is based upon data obtained from manufacturers and/or
recognized technical sources. While the information is believed to be accurate,
we make no representations as to its accuracy or sufficiency. Conditions of use
are beyond our control, and therefore users are responsible for verifying the data
under their own operating conditions to determine whether the product is suitable
for their particular purposes and they assume all risks of their use, handling,
and disposal of the product. Users also assume all risks in regards to the
publication or use of, or reliance upon, information contained herein. This
information relates only to the product designated herein, and does not relate to
its use in combination with any other material or process.
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