M283-0028 ALMOND 122 VINYL MARKER
MATERIAL SAFETY DATA SHEET
RPM Wood Finishes Group
3194 Hickory Boulevard
Hudson, North Carolina 28638
828-728-8266
EMERGENCY PHONE (CHEM TREC): . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-800-424-9300
FOR ALL INTERNATIONAL TRANSPORTATION ACCIDENTS. . . . . . . . . . . . . . . . .1-703-527-3887 (collect)
Health: 2 Flammability: 0 Reactivity 0
PRODUCT NAME: M283-0028 ALMOND 122 VINYL MARKER
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 11/04/01
SUPERCEDES: 11/04/01
MSDS NO. RPMFILSTIK
II. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME % CAS # PEL
titanium dioxide 21-30 13463-67-7 total dust: 15 mg/m3 TWA
Methyl Ethyl Ketone 11-20 78-93-3 200 ppm TWA; 590 mg/m3 TWA
methyl isobutyl ketone 11-20 108-10-1 100 ppm TWA; 410 mg/m3 TWA
cyclohexanone 1-10 108-94-1 50 ppm TWA; 200 mg/m3 TWA
aliphatic hydrocarbons 1-10 8052-41-3 500 ppm TWA; 2900 mg/m3 TWA
PM acetate 1-10 108-65-6 No PEL established
VINYL CHLORIDE-VINYL ACETATE-VINYL ALCOHOL 1-10 25086-48-0 No PEL established
TERPOLYMER
acrylic resin 1-10 25086-15-1 No PEL established
acetone 1-10 67-64-1 1000 ppm TWA; 2400 mg/m3 TWA
toluene 1-10 108-88-3 200 ppm TWA; C 300 ppm
aluminum oxide 1-10 1344-28-1 total dust: 15 mg/m3 TWA; respirable
fraction: 5 mg/m3 TWA
carbon black <1 1333-86-4 3.5 mg/m3 TWA
III. HAZARDS IDENTIFICATION
Ingestion.Skin contact.Eye contact.
Routes of Entry:
Respiratory disease including asthma and bronchitis. Skin disease including eczema
Medical Conditions Aggravated:
and sensitization. Liver disease. Kidney disease. Eye disease.
Immediate (Acute) Health Effects
May cause skin irritation.
Skin Contact:
Can cause minor irritation, tearing and reddening.
Eye Contact:
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Mildly irritating to mouth, throat, and stomach. Can cause abdominal discomfort.
Ingestion:
Target Organ Acute Toxicity:
Titanium dioxide respiratory system (in animals: lung tumors)
2-Butanone CNS, eyes, skin, respiratory system
Hexone eyes, skin, CNS, respiratory system, liver, kidneys
Cyclohexanone eyes, skin, CNS, respiratory system, liver, kidneys
Stoddard solvent skin, eyes, CNS, respiratory system, kidneys
Acetone respiratory system, skin, eyes, CNS
Toluene CNS, liver, kidneys, skin, eyes, respiratory system
alpha-Alumina respiratory system, skin, eyes
Carbon black respiratory system, eyes, lymphatic cancer
Long-Term (Chronic) Health Effects:
Contains a substance that is a probable cancer hazard based on human studies.
Carcinogenicity
ACGIH. IARC. NIOSH. NTP. OSHA.
Possible reproductive hazard.
Reproductive and Developmental
Toxicity:
No data available to indicate product or any components present at greater than 0.1%
Mutagenicity:
is mutagenic or genotoxic.
Respiratory Tract. Skin. Nervous System. Liver. Kidneys. Eyes.
Target Organ Chronic Toxicity
No additional health information available.
Supplemental Health Hazard
Information:
IV. FIRST AID
Immediately flush with plenty of water. After initial flushing, remove any contact
Eyes:
lenses and continue flushing for at least 15 minutes. Have eyes examined and tested
by medical personnel.
Wash with soap and water. Get medical attention if irritation develops or persists.
Skin Contact:
No hazard expected under normal industrial use. If a large quantity is swallowed, seek
Ingestion:
medical attention. Do not induce vomiting.
Treat according to symptoms present.
Notes to MD:
V. FIRE FIGHTING MEASURES
Flammability Summary:
None Known.
Fire Hazards:
Hazardous Combustion Products: Hydrogen chloride methyl methacrylate
Carbon dioxide, Carbon monoxide
VI. ACCIDENTAL RELEASE MEASURES
Spill Mitigation Procedures
None Known.
General Methods:
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VII. HANDLING AND STORAGE
Wash thoroughly after handling.
Handling:
Store in a cool dry place. Isolate from incompatible materials.
Storage:
VIII. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
Check ventilation codes.
Engineering Controls:
Protective Equipment
No respiratory protection required under normal conditions of use.
Respiratory Tract:
No special requirements under normal industrial use.
Eyes:
Not normally considered a skin hazard. Where use can result in skin contact, practice
Skin:
good personal hygiene. Wash hands and other exposed areas with mild soap and water
before eating, drinking, and when leaving work.
IX. PHYSICAL DATA
Physical State: Colored Solid
Odor: None to very faint
Solids Vol % 100
Solids Wt % 100
Material VOC lbs/gal: 0
Material VOC gms/l: 0
Weight per gallon: 9.8703
X. STABILITY AND REACTIVITY
Stable under normal conditions.
Stability Information:
Contamination.High temperatures.
Conditions to Avoid:
Hazardous Polymerization will not occur.
Hazordous Polymerization:
XI. TOXICOLOGICAL INFORMATION
Chemical Name CAS Number LD50/LC50
2-Butanone 78-93-3 Inhalation LC50 Rat : 23500 mg/m3/8H; Inhalation LC50 Mouse : 32
gm/m3/4H; Oral LD50 Rat : 2737 mg/kg; Oral LD50 Mouse : 4050 mg/kg;
Dermal LD50 Rabbit : 6480 mg/kg
2-Pentanone, 4-methyl- 108-10-1 Inhalation LC50 Mouse : 23300 mg/m3; Oral LD50 Rat : 2080 mg/kg; Oral
LD50 Mouse : 2671 mg/kg; Dermal LD50 Rabbit : >20 mL/kg
Cyclohexanone 108-94-1 Inhalation LC50 Rat : 8000 ppm/4H; Oral LD50 Rat : 1620 uL/kg; Oral
LD50 Mouse : 1400 mg/kg; Dermal LD50 Rabbit : 1 mL/kg
Acetic acid, 2-methoxy-1-methylethyl 108-65-6 Oral LD50 Rat : 8532 mg/kg; Dermal LD50 Rabbit : >5 gm/kg
ester
Acetone 67-64-1 Inhalation LC50 Rat : 50100 mg/m3/8H; Inhalation LC50 Mouse : 44
gm/m3/4H; Oral LD50 Rat : 5800 mg/kg; Oral LD50 Mouse : 3 gm/kg
Toluene 108-88-3 Inhalation LC50 Rat : 49 gm/m3/4H; Inhalation LC50 Mouse : 400 ppm/24H;
Oral LD50 Rat : 636 mg/kg; Dermal LD50 Rabbit : 14100 uL/kg
Carbon black 1333-86-4 Oral LD50 Rat : >15400 mg/kg; Dermal LD50 Rabbit : >3 gm/kg
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XII. ECOLOGICAL INFORMATION
None Known
Ecological Values:
XIII. DISPOSAL CONSIDERATIONS
Dispose of in a landfill. Disposal is not likely to be regulated.
Disposal Methods:
Components Subject to USEPA Land Disposal Restrictions:
Methyl ethyl ketone 78-93-3 19.48 %
Methyl isobutyl ketone 108-10-1 12.91 %
Cyclohexanone 108-94-1 8.64 %
Acetone 67-64-1 2.72 %
Toluene 108-88-3 2.00 %
XIV. TRANSPORTATION INFORMATION
Non-regulated
DOT
XV. REGULATORY INFORMATION
Toxic Substances Control Act (TSCA): This substance is listed on the TSCA Inventory of Existing Chemical
Substances.
Chemical Name Regulation CASRN %
Methyl ethyl ketone SARA 313 Reportable: 78-93-3 19.48
Methylisobutyl ketone SARA 313 Reportable: 108-10-1 12.91
Toluene SARA 313 Reportable: 108-88-3 2.00
Aluminum oxide SARA 313 Reportable: 1344-28-1 1.36
m-Xylene SARA 313 Reportable: 108-38-3 0.00
o-Xylene SARA 313 Reportable: 95-47-6 0.00
Ethyl benzene SARA 313 Reportable: 100-41-4 0.00
p-Xylene SARA 313 Reportable: 106-42-3 0.00
Carbon Black 1333-86-4 0.02
California Proposition 65 Cancer List:
Toluene 108-88-3 2.00
California Proposition 65
Developmental Toxicity:
13463-67-7 28.07
titanium dioxide New Jersey Right To Know:
78-93-3 19.48
Methyl Ethyl Ketone New Jersey Right To Know:
108-10-1 12.91
methyl isobutyl ketone New Jersey Right To Know:
108-94-1 8.64
cyclohexanone New Jersey Right To Know:
8052-41-3 4.54
aliphatic hydrocarbons New Jersey Right To Know:
XVI. ADDITIONAL INFORMATION
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION
Other Information:
CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY
FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A
PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES
OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA
OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS
AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND
INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION
OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE
ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
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MSDS glossary.
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