MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 1
L275-1
Product Code:
CLEAR CRACKLE LACQUER 1 GAL
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
(SEE TOP OF PAGE)
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT/EXPOSURE LIMITS CAS#
---------------------------------------------------------------------------
ISOBUTYL ACETATE 110-19-0
OSHA: PEL 150ppm-TWA
ACGIH TLV 150ppm-TWA
PAINT ADDITIVE MIXTURE
PMA ACGIH TLV 100PPM
TERT BUTYL ACETATE 540-88-5
ETHYL ACETATE 141-78-6
ETHYL ACETATE 400ppm TWA, OSHA & ACGIH '
TOLUENE 108-88-3
OSHA PEL: 200ppm
ACGIH TLV 50ppm
NITROCELLULOSE MIX2
AQUEOUS ISOPROPANOL: OSHA PEL 400 ppm
VM&P NAPTHA 68410-96-8
OSHA: NONE
NIOSH: 350 MILLIGRAMS PER CUBIC METER-TWA
NIOSH: 1800 MILLIGRAMS PER CUBIC METER-CEILING
METHYL ISOBUTYL KETONE 108-10-1
OSHA: 100 PPM PEL-TWA
NIOSH: 50 PPM PEL-TWA
NIOSH: 500 PPM IDLH
ISOPROPANOL 67-63-0
400ppm TWA8 ACGIH, 983 mg/m3 TWA8 ACGIH
980mg/m3 TWA8 OSHA, 500ppM STEL OSHA
1,2,4-TRIMETHYLBENZENE 95-63-6
TERTIARY BUTANOL 75-65-0
3. HAZARDS IDENTIFICATION
Flammable in a liquid state
High vapor concentrations may cause mild eye and skin irritation.
POTENTIAL HEALTH EFFECTS
SKIN:
Widespread contact with skin for several hours can cause harmful amounts of material to be absorbed.
INGESTION:
Excessive inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness, fatigue,
nausea, headache, possible unconsciousness and even asphyxiation.
INHALATION:
High vapor concentrations or prolonged breathing of lower concentrations may result in damage to the
liver, kidneys, lungs and blood forming organs.
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 2
L275-1
Product Code:
CLEAR CRACKLE LACQUER 1 GAL
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
4. FIRST AID MEASURES
EYES:
Flush with luke warm water for a minimum of 15 minutes. Seek medical attention immediately.
SKIN:
Remove contaminated clothing, wash area immediately with soap and water. See physician if irritation
persists.
INGESTION:
Rinse mouth immediately. Drink 1 or 2 glasses of water to dilute. Do NOT induce vomiting. Contact
physician or poison control center immediately.
INHALATION:
Remove exposed individual to fresh air and assist breathing if necessary. Seek immediate medical
attention.
5. FIRE FIGHTING MEASURES
FLAMMABLE CLASSIFICATION: CLASS 1B FLAMMABLE
LOWEST FLASH POINT: 24F
METHOD: TCC
DOT: FLAMMABLE LIQUID
FLAMMABLE LIMITS:
LOWER FLAMMABLE LIMIT: 1.2
UPPER FLAMMABLE LIMIT: 11
EXTINGUISHING MEDIA: Alcohol Foam, CO2, Dry Chemical.
The National Fire Protection Association Class B extinguisher is designed to extinguish NFPA
Class 1B flammable liquid fires.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Closed containers may explode when exposed to extreme heat. Do not apply to hot surfaces. Never
use welding or cutting torch on or near container (even empty) because product (even residue) may
ignite explosively. Liquid and vapor states of this substance are dangerous fire hazards and
moderate explosion hazards when exposed to heat or flame.
FIREFIGHTING INSTRUCTIONS:
Clear fire area of unprotected personnel. Do not enter confined space without helmet, face shield, bunker
coat, gloves, rubber boots and a positive pressure NIOSH-approved self-contained breathing
apparatus. A water stream can scatter flames. A spray of water may be used to cool closed
containers to prevent pressure buildup and possible autoignition or explosion when exposed to
extreme heat. If water is used, fog nozzles are preferable.
6. ACCIDENTAL RELEASE MEASURES
Stay upwind and away from spill or leak unless wearing appropriate protective equipment.
Stop and/or contain discharge if it may be done safely. Keep all sources of ignition away.
Ventilate area of spill. Use non-sparking tools for clean up. Cover with inert material to reduce
fumes. Keep out of drains, sewer or waterways.
If large spill occurs, alert spill response teams. Contact fire authorities. Notify local health
and pollution control agencies.
7. HANDLING AND STORAGE
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 3
L275-1
Product Code:
CLEAR CRACKLE LACQUER 1 GAL
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
HANDLING:
Bond and ground metal containers when transferring liquid. Avoid free fall of liquid in excess of a few
inches. Personnel should avoid inhalation of vapors. Personal contact with the product should be
avoided. Should contact be made, remove saturated clothing and flush affected skin areas with
water. Containers of this material may be hazardous when emptied. Since emptied containers retain
product residues (vapor, liquid and/or solid), all hazard precautions given in this sheet must be
observed.
STORAGE:
Keep product containers cool, dry and away from sources of ignition. Use and store this product with
adequate ventilation. DO NOT SMOKE in or near storage areas
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION:
PRIMARY ROUTES OF ENTRY: inhalation, skin contact, eyes, ingestion.
Use local exhaust as required to control vapor concentrations. Avoid prolonged or repeated
breathing of vapors. If exposure exceeds TLV, use NIOSH-approved respirator to prevent
overexposure.
SKIN PROTECTION:
Required for prolonged or repeated contact. Wear resistant gloves such as natural rubber, neoprene, buna
N or nitrile. An apron should be worn to avoid skin contact.
EYE PROTECTION:
Wear splashproof goggles and face shield if there is a likelihood of contact with eyes.
HYGIENIC PRACTICES:
Wash hands thoroughly before eating or using restroom. Remove contaminated clothing immediately and do
not wear again until it has been properly laundered.
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: 171F
MELTING POINT: N/A
VAPOR PRESSURE: N/A
VAPOR DENSITY: Heavier Than Air
SOLUBILITY IN WATER: N/A
SPECIFIC GRAVITY: .9
COATING VOC LB/GL: 6.3136 lb/gl
COATING VOC GM/LTR: 757 g/l
MATERIAL VOC LB/GL: 5.1448 lb/gl
MATERIAL VOC GM/LTR: 616 g/l
% VOLATILE BY VOLUME: 92.277%
EVAPORATION RATE: Faster than Butyl Acetate.
WEIGHT PER GALLON: 7.494 lb/gl
PH: N/A
ODOR: N/A
APPEARANCE: Colored Liquid
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY:
Stable Conditions To Avoid: high heat, sparks, flames.
INCOMPATIBILITY
Materials to Avoid: Strong oxidizing agents, strong alkalines, strong mineral acids
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 4
L275-1
Product Code:
CLEAR CRACKLE LACQUER 1 GAL
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
HAZARDOUS DECOMPOSITION PRODUCTS:
Oxidation may produce carbon and nitrogen oxides.
HAZARDOUS POLYMERIZATION:
Will not occur.
11. TOXICOLOGICAL INFORMATION
CANCER INFORMATION:
This product contains no reported carcinogens or suspected carcinogens.
TERATOLOGY (BIRTH DEFECT) INFORMATION:
This product contains no reported or suspected teratogens.
REPRODUCTION INFORMATION:
Toluene is a chemical known to the state of California to cause birth defect or other reproductive harm.
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:
Uncontrolled release of the product may result in contamination of air, ground, waterways and/or sewers.
13. DISPOSAL CONSIDERATIONS
Do not flush to sewer, watershed or waterway. Dispose of product in accordance with
applicable local, county, state and federal regulations.
14. TRANSPORT INFORMATION
DOT NUMBER: UN1263
15. REGULATORY INFORMATION
HMIS HAZARD INDEX: 4=SEVERE, 3=SERIOUS, 2=MODERATE, 1=SLIGHT, 0=LEAST
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY: 0
PERSONAL PROTECTION: I
SECTION 313:
This product contains the following toxic chemicals subject to the reporting requirements of section 313
of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372 (Chemicals
listed below constitute the specific percentage of product by weight. Chemicals that do not have
a listed percentage comprise less than 1% of total product weight):
% BY WT
* TOLUENE 108-88-3 7
* METHYL ISOBUTYL KETONE 108-10-1 3
* 1,2,4-TRIMETHYLBENZENE 95-63-6
* TERTIARY BUTANOL 75-65-0
16. DISCLAIMER:
The following supersedes any provision contained in the forms, letters and papers of your
company. This product is designed and intended for professional application only. All products
should be thoroughly tested under application conditions prior to use. The information contained
herein is believed to be reliable. HOWEVER, GEMINI MAKES NO WARRANTY CONCERNING THIS PRODUCT,
WHETHER EXPRESS OR IMPLIED. INCLUDING THE WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE.
UNDER NO CIRCUMSTANCES SHALL GEMINI BE LIABLE FOR SPECIAL, INCIDENTAL,CONSEQUENTIAL,OR ANY OTHER
DAMAGES FROM ALLEGED NEGLIGENCE, BREACH OF WARRENTY, STRICT LIABILITY, OR ANY OTHER LEGAL THEORY,
ARISING OUT OF THE USE OR HANDLING OF THIS PRODUCT. THE SOLE REMEDY OF THE BUYER AND THE SOLE
LIABILITY OF GEMINI FOR ANY CLAIMS SHALL BE LIMITED TO THE BUYER'S PURCHASE PRICE OF THE PRODUCT
WHICH IS THE SUBJECT OF THE CLAIM OR THE AMOUNT ACTUALLY PAID FOR SUCH PRODUCT, WHICHEVER IS
LESS.
TECHNICAL ADVICE FURNISHED BY GEMINI SHALL NOT CONSTITUTE AN EXPRESS WARRANTY, WHICH IS EXPRESSLY
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 5
L275-1
Product Code:
CLEAR CRACKLE LACQUER 1 GAL
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
DISCLAIMED. ALL TECHNICAL ADVICE GIVEN IS ACCEPTED AT THE RISK OF THE BUYER.
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 1
L275-5
Product Code:
CLEAR CRACKLE LACQUER (5 GAL)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
(SEE TOP OF PAGE)
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT/EXPOSURE LIMITS CAS#
---------------------------------------------------------------------------
ISOBUTYL ACETATE 110-19-0
OSHA: PEL 150ppm-TWA
ACGIH TLV 150ppm-TWA
PAINT ADDITIVE MIXTURE
PMA ACGIH TLV 100PPM
TERT BUTYL ACETATE 540-88-5
ETHYL ACETATE 141-78-6
ETHYL ACETATE 400ppm TWA, OSHA & ACGIH '
TOLUENE 108-88-3
OSHA PEL: 200ppm
ACGIH TLV 50ppm
NITROCELLULOSE MIX2
AQUEOUS ISOPROPANOL: OSHA PEL 400 ppm
VM&P NAPTHA 68410-96-8
OSHA: NONE
NIOSH: 350 MILLIGRAMS PER CUBIC METER-TWA
NIOSH: 1800 MILLIGRAMS PER CUBIC METER-CEILING
METHYL ISOBUTYL KETONE 108-10-1
OSHA: 100 PPM PEL-TWA
NIOSH: 50 PPM PEL-TWA
NIOSH: 500 PPM IDLH
ISOPROPANOL 67-63-0
400ppm TWA8 ACGIH, 983 mg/m3 TWA8 ACGIH
980mg/m3 TWA8 OSHA, 500ppM STEL OSHA
1,2,4-TRIMETHYLBENZENE 95-63-6
TERTIARY BUTANOL 75-65-0
3. HAZARDS IDENTIFICATION
Flammable in a liquid state
High vapor concentrations may cause mild eye and skin irritation.
POTENTIAL HEALTH EFFECTS
SKIN:
Widespread contact with skin for several hours can cause harmful amounts of material to be absorbed.
INGESTION:
Excessive inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness, fatigue,
nausea, headache, possible unconsciousness and even asphyxiation.
INHALATION:
High vapor concentrations or prolonged breathing of lower concentrations may result in damage to the
liver, kidneys, lungs and blood forming organs.
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 2
L275-5
Product Code:
CLEAR CRACKLE LACQUER (5 GAL)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
4. FIRST AID MEASURES
EYES:
Flush with luke warm water for a minimum of 15 minutes. Seek medical attention immediately.
SKIN:
Remove contaminated clothing, wash area immediately with soap and water. See physician if irritation
persists.
INGESTION:
Rinse mouth immediately. Drink 1 or 2 glasses of water to dilute. Do NOT induce vomiting. Contact
physician or poison control center immediately.
INHALATION:
Remove exposed individual to fresh air and assist breathing if necessary. Seek immediate medical
attention.
5. FIRE FIGHTING MEASURES
FLAMMABLE CLASSIFICATION: CLASS 1B FLAMMABLE
LOWEST FLASH POINT: 24F
METHOD: TCC
DOT: FLAMMABLE LIQUID
FLAMMABLE LIMITS:
LOWER FLAMMABLE LIMIT: 1.2
UPPER FLAMMABLE LIMIT: 11
EXTINGUISHING MEDIA: Alcohol Foam, CO2, Dry Chemical.
The National Fire Protection Association Class B extinguisher is designed to extinguish NFPA
Class 1B flammable liquid fires.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Closed containers may explode when exposed to extreme heat. Do not apply to hot surfaces. Never
use welding or cutting torch on or near container (even empty) because product (even residue) may
ignite explosively. Liquid and vapor states of this substance are dangerous fire hazards and
moderate explosion hazards when exposed to heat or flame.
FIREFIGHTING INSTRUCTIONS:
Clear fire area of unprotected personnel. Do not enter confined space without helmet, face shield, bunker
coat, gloves, rubber boots and a positive pressure NIOSH-approved self-contained breathing
apparatus. A water stream can scatter flames. A spray of water may be used to cool closed
containers to prevent pressure buildup and possible autoignition or explosion when exposed to
extreme heat. If water is used, fog nozzles are preferable.
6. ACCIDENTAL RELEASE MEASURES
Stay upwind and away from spill or leak unless wearing appropriate protective equipment.
Stop and/or contain discharge if it may be done safely. Keep all sources of ignition away.
Ventilate area of spill. Use non-sparking tools for clean up. Cover with inert material to reduce
fumes. Keep out of drains, sewer or waterways.
If large spill occurs, alert spill response teams. Contact fire authorities. Notify local health
and pollution control agencies.
7. HANDLING AND STORAGE
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 3
L275-5
Product Code:
CLEAR CRACKLE LACQUER (5 GAL)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
HANDLING:
Bond and ground metal containers when transferring liquid. Avoid free fall of liquid in excess of a few
inches. Personnel should avoid inhalation of vapors. Personal contact with the product should be
avoided. Should contact be made, remove saturated clothing and flush affected skin areas with
water. Containers of this material may be hazardous when emptied. Since emptied containers retain
product residues (vapor, liquid and/or solid), all hazard precautions given in this sheet must be
observed.
STORAGE:
Keep product containers cool, dry and away from sources of ignition. Use and store this product with
adequate ventilation. DO NOT SMOKE in or near storage areas
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION:
PRIMARY ROUTES OF ENTRY: inhalation, skin contact, eyes, ingestion.
Use local exhaust as required to control vapor concentrations. Avoid prolonged or repeated
breathing of vapors. If exposure exceeds TLV, use NIOSH-approved respirator to prevent
overexposure.
SKIN PROTECTION:
Required for prolonged or repeated contact. Wear resistant gloves such as natural rubber, neoprene, buna
N or nitrile. An apron should be worn to avoid skin contact.
EYE PROTECTION:
Wear splashproof goggles and face shield if there is a likelihood of contact with eyes.
HYGIENIC PRACTICES:
Wash hands thoroughly before eating or using restroom. Remove contaminated clothing immediately and do
not wear again until it has been properly laundered.
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: 171F
MELTING POINT: N/A
VAPOR PRESSURE: N/A
VAPOR DENSITY: Heavier Than Air
SOLUBILITY IN WATER: N/A
SPECIFIC GRAVITY: .9
COATING VOC LB/GL: 6.3136 lb/gl
COATING VOC GM/LTR: 757 g/l
MATERIAL VOC LB/GL: 5.1448 lb/gl
MATERIAL VOC GM/LTR: 616 g/l
% VOLATILE BY VOLUME: 92.277%
EVAPORATION RATE: Faster than Butyl Acetate.
WEIGHT PER GALLON: 7.494 lb/gl
PH: N/A
ODOR: N/A
APPEARANCE: Colored Liquid
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY:
Stable Conditions To Avoid: high heat, sparks, flames.
INCOMPATIBILITY
Materials to Avoid: Strong oxidizing agents, strong alkalines, strong mineral acids
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 4
L275-5
Product Code:
CLEAR CRACKLE LACQUER (5 GAL)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
HAZARDOUS DECOMPOSITION PRODUCTS:
Oxidation may produce carbon and nitrogen oxides.
HAZARDOUS POLYMERIZATION:
Will not occur.
11. TOXICOLOGICAL INFORMATION
CANCER INFORMATION:
This product contains no reported carcinogens or suspected carcinogens.
TERATOLOGY (BIRTH DEFECT) INFORMATION:
This product contains no reported or suspected teratogens.
REPRODUCTION INFORMATION:
Toluene is a chemical known to the state of California to cause birth defect or other reproductive harm.
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:
Uncontrolled release of the product may result in contamination of air, ground, waterways and/or sewers.
13. DISPOSAL CONSIDERATIONS
Do not flush to sewer, watershed or waterway. Dispose of product in accordance with
applicable local, county, state and federal regulations.
14. TRANSPORT INFORMATION
DOT NUMBER: UN1263
15. REGULATORY INFORMATION
HMIS HAZARD INDEX: 4=SEVERE, 3=SERIOUS, 2=MODERATE, 1=SLIGHT, 0=LEAST
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY: 0
PERSONAL PROTECTION: I
SECTION 313:
This product contains the following toxic chemicals subject to the reporting requirements of section 313
of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372 (Chemicals
listed below constitute the specific percentage of product by weight. Chemicals that do not have
a listed percentage comprise less than 1% of total product weight):
% BY WT
* TOLUENE 108-88-3 7
* METHYL ISOBUTYL KETONE 108-10-1 3
* 1,2,4-TRIMETHYLBENZENE 95-63-6
* TERTIARY BUTANOL 75-65-0
16. DISCLAIMER:
The following supersedes any provision contained in the forms, letters and papers of your
company. This product is designed and intended for professional application only. All products
should be thoroughly tested under application conditions prior to use. The information contained
herein is believed to be reliable. HOWEVER, GEMINI MAKES NO WARRANTY CONCERNING THIS PRODUCT,
WHETHER EXPRESS OR IMPLIED. INCLUDING THE WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE.
UNDER NO CIRCUMSTANCES SHALL GEMINI BE LIABLE FOR SPECIAL, INCIDENTAL,CONSEQUENTIAL,OR ANY OTHER
DAMAGES FROM ALLEGED NEGLIGENCE, BREACH OF WARRENTY, STRICT LIABILITY, OR ANY OTHER LEGAL THEORY,
ARISING OUT OF THE USE OR HANDLING OF THIS PRODUCT. THE SOLE REMEDY OF THE BUYER AND THE SOLE
LIABILITY OF GEMINI FOR ANY CLAIMS SHALL BE LIMITED TO THE BUYER'S PURCHASE PRICE OF THE PRODUCT
WHICH IS THE SUBJECT OF THE CLAIM OR THE AMOUNT ACTUALLY PAID FOR SUCH PRODUCT, WHICHEVER IS
LESS.
TECHNICAL ADVICE FURNISHED BY GEMINI SHALL NOT CONSTITUTE AN EXPRESS WARRANTY, WHICH IS EXPRESSLY
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 5
L275-5
Product Code:
CLEAR CRACKLE LACQUER (5 GAL)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
DISCLAIMED. ALL TECHNICAL ADVICE GIVEN IS ACCEPTED AT THE RISK OF THE BUYER.
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 1
L275-Q
Product Code:
CLEAR CRACKLE LACQUER (QT)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
(SEE TOP OF PAGE)
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT/EXPOSURE LIMITS CAS#
---------------------------------------------------------------------------
ISOBUTYL ACETATE 110-19-0
OSHA: PEL 150ppm-TWA
ACGIH TLV 150ppm-TWA
PAINT ADDITIVE MIXTURE
PMA ACGIH TLV 100PPM
TERT BUTYL ACETATE 540-88-5
ETHYL ACETATE 141-78-6
ETHYL ACETATE 400ppm TWA, OSHA & ACGIH '
TOLUENE 108-88-3
OSHA PEL: 200ppm
ACGIH TLV 50ppm
NITROCELLULOSE MIX2
AQUEOUS ISOPROPANOL: OSHA PEL 400 ppm
VM&P NAPTHA 68410-96-8
OSHA: NONE
NIOSH: 350 MILLIGRAMS PER CUBIC METER-TWA
NIOSH: 1800 MILLIGRAMS PER CUBIC METER-CEILING
METHYL ISOBUTYL KETONE 108-10-1
OSHA: 100 PPM PEL-TWA
NIOSH: 50 PPM PEL-TWA
NIOSH: 500 PPM IDLH
ISOPROPANOL 67-63-0
400ppm TWA8 ACGIH, 983 mg/m3 TWA8 ACGIH
980mg/m3 TWA8 OSHA, 500ppM STEL OSHA
1,2,4-TRIMETHYLBENZENE 95-63-6
TERTIARY BUTANOL 75-65-0
3. HAZARDS IDENTIFICATION
Flammable in a liquid state
High vapor concentrations may cause mild eye and skin irritation.
POTENTIAL HEALTH EFFECTS
SKIN:
Widespread contact with skin for several hours can cause harmful amounts of material to be absorbed.
INGESTION:
Excessive inhalation of vapors can cause nasal and respiratory irritation, dizziness, weakness, fatigue,
nausea, headache, possible unconsciousness and even asphyxiation.
INHALATION:
High vapor concentrations or prolonged breathing of lower concentrations may result in damage to the
liver, kidneys, lungs and blood forming organs.
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 2
L275-Q
Product Code:
CLEAR CRACKLE LACQUER (QT)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
4. FIRST AID MEASURES
EYES:
Flush with luke warm water for a minimum of 15 minutes. Seek medical attention immediately.
SKIN:
Remove contaminated clothing, wash area immediately with soap and water. See physician if irritation
persists.
INGESTION:
Rinse mouth immediately. Drink 1 or 2 glasses of water to dilute. Do NOT induce vomiting. Contact
physician or poison control center immediately.
INHALATION:
Remove exposed individual to fresh air and assist breathing if necessary. Seek immediate medical
attention.
5. FIRE FIGHTING MEASURES
FLAMMABLE CLASSIFICATION: CLASS 1B FLAMMABLE
LOWEST FLASH POINT: 24F
METHOD: TCC
DOT: FLAMMABLE LIQUID
FLAMMABLE LIMITS:
LOWER FLAMMABLE LIMIT: 1.2
UPPER FLAMMABLE LIMIT: 11
EXTINGUISHING MEDIA: Alcohol Foam, CO2, Dry Chemical.
The National Fire Protection Association Class B extinguisher is designed to extinguish NFPA
Class 1B flammable liquid fires.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Closed containers may explode when exposed to extreme heat. Do not apply to hot surfaces. Never
use welding or cutting torch on or near container (even empty) because product (even residue) may
ignite explosively. Liquid and vapor states of this substance are dangerous fire hazards and
moderate explosion hazards when exposed to heat or flame.
FIREFIGHTING INSTRUCTIONS:
Clear fire area of unprotected personnel. Do not enter confined space without helmet, face shield, bunker
coat, gloves, rubber boots and a positive pressure NIOSH-approved self-contained breathing
apparatus. A water stream can scatter flames. A spray of water may be used to cool closed
containers to prevent pressure buildup and possible autoignition or explosion when exposed to
extreme heat. If water is used, fog nozzles are preferable.
6. ACCIDENTAL RELEASE MEASURES
Stay upwind and away from spill or leak unless wearing appropriate protective equipment.
Stop and/or contain discharge if it may be done safely. Keep all sources of ignition away.
Ventilate area of spill. Use non-sparking tools for clean up. Cover with inert material to reduce
fumes. Keep out of drains, sewer or waterways.
If large spill occurs, alert spill response teams. Contact fire authorities. Notify local health
and pollution control agencies.
7. HANDLING AND STORAGE
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 3
L275-Q
Product Code:
CLEAR CRACKLE LACQUER (QT)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
HANDLING:
Bond and ground metal containers when transferring liquid. Avoid free fall of liquid in excess of a few
inches. Personnel should avoid inhalation of vapors. Personal contact with the product should be
avoided. Should contact be made, remove saturated clothing and flush affected skin areas with
water. Containers of this material may be hazardous when emptied. Since emptied containers retain
product residues (vapor, liquid and/or solid), all hazard precautions given in this sheet must be
observed.
STORAGE:
Keep product containers cool, dry and away from sources of ignition. Use and store this product with
adequate ventilation. DO NOT SMOKE in or near storage areas
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
RESPIRATORY PROTECTION:
PRIMARY ROUTES OF ENTRY: inhalation, skin contact, eyes, ingestion.
Use local exhaust as required to control vapor concentrations. Avoid prolonged or repeated
breathing of vapors. If exposure exceeds TLV, use NIOSH-approved respirator to prevent
overexposure.
SKIN PROTECTION:
Required for prolonged or repeated contact. Wear resistant gloves such as natural rubber, neoprene, buna
N or nitrile. An apron should be worn to avoid skin contact.
EYE PROTECTION:
Wear splashproof goggles and face shield if there is a likelihood of contact with eyes.
HYGIENIC PRACTICES:
Wash hands thoroughly before eating or using restroom. Remove contaminated clothing immediately and do
not wear again until it has been properly laundered.
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: 171F
MELTING POINT: N/A
VAPOR PRESSURE: N/A
VAPOR DENSITY: Heavier Than Air
SOLUBILITY IN WATER: N/A
SPECIFIC GRAVITY: .9
COATING VOC LB/GL: 6.3136 lb/gl
COATING VOC GM/LTR: 757 g/l
MATERIAL VOC LB/GL: 5.1448 lb/gl
MATERIAL VOC GM/LTR: 616 g/l
% VOLATILE BY VOLUME: 92.277%
EVAPORATION RATE: Faster than Butyl Acetate.
WEIGHT PER GALLON: 7.494 lb/gl
PH: N/A
ODOR: N/A
APPEARANCE: Colored Liquid
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY:
Stable Conditions To Avoid: high heat, sparks, flames.
INCOMPATIBILITY
Materials to Avoid: Strong oxidizing agents, strong alkalines, strong mineral acids
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 4
L275-Q
Product Code:
CLEAR CRACKLE LACQUER (QT)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
HAZARDOUS DECOMPOSITION PRODUCTS:
Oxidation may produce carbon and nitrogen oxides.
HAZARDOUS POLYMERIZATION:
Will not occur.
11. TOXICOLOGICAL INFORMATION
CANCER INFORMATION:
This product contains no reported carcinogens or suspected carcinogens.
TERATOLOGY (BIRTH DEFECT) INFORMATION:
This product contains no reported or suspected teratogens.
REPRODUCTION INFORMATION:
Toluene is a chemical known to the state of California to cause birth defect or other reproductive harm.
12. ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:
Uncontrolled release of the product may result in contamination of air, ground, waterways and/or sewers.
13. DISPOSAL CONSIDERATIONS
Do not flush to sewer, watershed or waterway. Dispose of product in accordance with
applicable local, county, state and federal regulations.
14. TRANSPORT INFORMATION
DOT NUMBER: UN1263
15. REGULATORY INFORMATION
HMIS HAZARD INDEX: 4=SEVERE, 3=SERIOUS, 2=MODERATE, 1=SLIGHT, 0=LEAST
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY: 0
PERSONAL PROTECTION: I
SECTION 313:
This product contains the following toxic chemicals subject to the reporting requirements of section 313
of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372 (Chemicals
listed below constitute the specific percentage of product by weight. Chemicals that do not have
a listed percentage comprise less than 1% of total product weight):
% BY WT
* TOLUENE 108-88-3 7
* METHYL ISOBUTYL KETONE 108-10-1 3
* 1,2,4-TRIMETHYLBENZENE 95-63-6
* TERTIARY BUTANOL 75-65-0
16. DISCLAIMER:
The following supersedes any provision contained in the forms, letters and papers of your
company. This product is designed and intended for professional application only. All products
should be thoroughly tested under application conditions prior to use. The information contained
herein is believed to be reliable. HOWEVER, GEMINI MAKES NO WARRANTY CONCERNING THIS PRODUCT,
WHETHER EXPRESS OR IMPLIED. INCLUDING THE WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE.
UNDER NO CIRCUMSTANCES SHALL GEMINI BE LIABLE FOR SPECIAL, INCIDENTAL,CONSEQUENTIAL,OR ANY OTHER
DAMAGES FROM ALLEGED NEGLIGENCE, BREACH OF WARRENTY, STRICT LIABILITY, OR ANY OTHER LEGAL THEORY,
ARISING OUT OF THE USE OR HANDLING OF THIS PRODUCT. THE SOLE REMEDY OF THE BUYER AND THE SOLE
LIABILITY OF GEMINI FOR ANY CLAIMS SHALL BE LIMITED TO THE BUYER'S PURCHASE PRICE OF THE PRODUCT
WHICH IS THE SUBJECT OF THE CLAIM OR THE AMOUNT ACTUALLY PAID FOR SUCH PRODUCT, WHICHEVER IS
LESS.
TECHNICAL ADVICE FURNISHED BY GEMINI SHALL NOT CONSTITUTE AN EXPRESS WARRANTY, WHICH IS EXPRESSLY
MATERIAL SAFETY DATA SHEET
Date Printed: 6/22/2010 Page: 5
L275-Q
Product Code:
CLEAR CRACKLE LACQUER (QT)
Product Name:
GEMINI INDUSTRIES, INC., 2300 HOLLOWAY DRIVE, EL RENO, OK 73036
24-Hour Emergency (Spill, Leak, Exposure or Accident): INFOTRAC 800-535-5053 Outside USA, Call Collect 1-352-323-3500
24-Hour Emergency HAZMAT Response and MSDS help: EMI 800-510-8510
DISCLAIMED. ALL TECHNICAL ADVICE GIVEN IS ACCEPTED AT THE RISK OF THE BUYER.
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