DENTSPLY/International
DENTSPLY/Caulk
Safety Data Sheet 566898
1. Identification
Product Name MSDS Code Number
Temporary Bridge Resin Liquid 566898
Trade Name & Synonyms Date of Last Revision
Temporary Bridge Resin Liquid 12/01/09
Manufacturer: Address
DENTSPLY Caulk 38 West Clarke Avenue
Milford DE 19963-1805
http://www.caulk.com
http://www.dentsply.com
Grades or Minor Variant Identities Information Telephone Number
Not Applicable
(302) 422-4511 (8:00 AM ?4:30 PM Eastern Time)
Product Use (for Canada) Emergency Telephone Number
(302) 422-4511 (8:00 AM ?4:30 PM Eastern Time)
Denture Acrylic Resin
2. Hazard(s) Identification
Danger WARNING
Highly Flammable MAY CAUSE AN ALLERGIC SKIN REACTION
Liquid and Vapour
3. Composition/Information on Ingredients
Hazardous Components C.A.S. Number Exposure Limits %
Methyl methacrylate 80-62-6 50 ppm > than 85
Ethylene Glycol dimethacrylate 97-90-5 Not Established < than 5
4. First Aid Measures
Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Effects
Eye Flush eyes with plenty of water for at least 15 minutes, occasionally lifting Get medical aid immediately. None known
the upper and lower eyelids. If symptoms persist consult physician
Skin Flush skin with plenty of soap and water for at least 15 minutes. Remove Get medical aid. Allergic reaction possible
contaminated clothing and shoes. Wash clothing before reuse.
Inhalation Move to fresh air immediately. If breathing is difficult give oxygen. If not Get medical aid immediately. Allergic reaction possible
breathing, give artificial respiration. Do not use mouth to mouth
resuscitation. Instead apply artificial respiration using oxygen and a
suitable mechanical device such as a bag and a mask.
Consult physician if symptoms persist
Ingestion If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Get medical aid. Allergic reaction possible
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting.
Other Not Applicable Not Applicable Not Applicable
Note to Physicians (Treating, Testing and Monitoring): Treat symptomatically.
5. Fire Fighting Measures
Flashpoint Method: Flammable (Explosive) Limits in Air Autoignition Temperature: N. A. Other: Not
LEL: 2.1% UEL: 12.5% 435 C (815 F)
13 C (55 F) TOC Applicable
Flame Propagation or Burning Rate (for Solids) Not Known Properties Contributing to Fire Intensity: Not Flammability Classification:
known NFPA Flammability = 3
Extinguishing Media: Water spray, alcohol resistant foam, carbon dioxide, dry chemical. Extinguishing Media to Avoid: Water with full jet.
Protection and Procedures for Firefighters: As in any fire, firefighters should wear self-contained respiratory protective devices. Formation of toxic, irritating gases is
possible from the decomposition of the polymer.
Unusual Fire and Explosion Hazards: Dusts may be combustible when exposed to heat, flame, or oxidizing agents. Although the polymer dust is not easily ignited, the
explosive limits of the polymer dust suspended in air are approximately those of coal dust therefore, fire fighters should avoid extinguishing methods which generate
dust clouds. Formation of toxic, irritating gases is possible from the decomposition of the polymer. In routine use this product does not present an explosion hazard.
6. Accidental Release Measures
Containment Techniques: Absorb spill with inert material (such as vermiculite, activated carbon absorbent, sand or earth), then place in the container. Do not flush into
sewer.
Spill/Leak Clean-up Procedures and Equipment: Wear protective clothing and scoop up bulk material and place in a labeled plastic or
metal container. Avoid gross skin contact to minimize the possibility of contact dermatitis to susceptible persons. Polymer particles are slippery when spilled on hard
floor so sweep immediately and wash area with water to avoid accidental falls. Keep exposure to airborne particles to a minimum when cleaning by using proper
ventilation as discussed in section 8.
Evacuation Procedures: Not Applicable Special Instructions: Not Applicable Reporting Requirements: Not Applicable
7. Handling and Storage
Handling Practices and Warnings: Avoid inhalation and contact with eyes. Product is intended for dental use only. Handling of this product should be by trained dental
healthcare professionals only. Observe normal care for working with chemicals.
Storage Practices and Warnings: Store in a cool, dry, well ventilated area. Store only in the original package. Keep package tightly sealed to prevent water absorption
and contamination. Keep out of direct sunlight. Store away from food and beverages.
8. Exposure Control / Personal Protection
Occupational Exposure Limits: Not Applicable
Engineering Controls: Not Applicable
Individual Protection Personal Protective Equipment for Personal Protective Equipment for Emergencies
Measures
Normal Use
Eye/Face Wear appropriate protective eyeglasses or For emergency or higher risk of exposure, wear chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
safety glasses to prevent exposure during
normal use. EN166.
Skin During normal use, disposable gloves are For emergency or higher risk of exposure, wear protective gloves to prevent skin exposure
recommended to prevent skin exposure. and wear a lab coat to prevent contamination of your clothing. Wash contaminated clothing
before reuse.
Inhalation During normal use with local exhaust, use For emergency or higher risk of exposure, (for example when obvious dust cloud is
of a dust mask will provide additional observed), follow the OSHA respirator regulations found in 29CFR 1910.134 or European
protection. Standard EN149. Always use a NIOSH or European Standard EN149 approved respirator
when necessary.
Body Protection Protective work clothing Not Applicable
9. Physical and Chemical Characteristics
Appearance: Clear liquid. Odor: Characteristic methacrylate ester odor
Normal Physical State: Liquid Melting Point: Not Applicable
Specific Gravity: 1.0 g/cm3 pH: Not Applicable Vapor Pressure (mm Hg): Not Established
Evaporation Rate (Butyl Acetate =1): Not Applicable Decomposition Temperature: 200癈 (392癋)
Other: Not Applicable
10. Stability and Reactivity Data
Incompatibility (Materials to Avoid): Visible light, high temperatures, strong acids, strong oxidizing agents.
Hazardous Products Produced During Decomposition: Methacrylates, acrylates, carbon dioxide, carbon monoxide, peroxides and irritating gases.
Hazardous Polymerization: May Occur May Not Occur Conditions to Avoid: High Temperatures, ignition sources.
Stability? Stable Unstable Conditions to Avoid: High Temperatures, ignition sources.
11.Toxicological Information
Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic Effects, Reproductive Effects, or Structure Activity Data:
Product may be an irritant to the skin in susceptible persons. On the eye the product has an irritating effect. Certain susceptible persons may be sensitized or allergic to
acrylates and methacrylates.
Emergency Overview: Liquid and vapor are flammable. Heating, sunlight or contact with incompatible materials may cause explosive
polymerization. May form explosive peroxides. Liquid is not known to cause significant health problems, however can be harmful if swallowed or
inhaled (affects central nervous system). Causes irritation to skin eyes and respiratory tract. May cause allergic skin reaction! May be harmful if
absorbed through skin. Warning target Organs: Kidneys, central nervous system, liver, and skin.
Routes of Single, Severity (Mild, Acute and Chronic Health Effect(s)
Exposure Signs and Symptoms Repeated, or Moderate, Severe) Target
Lifetime Organ(s)
Exposure
Eye Flush eyes with plenty of water for at least Get medical aid None known Irritation and possible corneal damage Yes
15 minutes, occasionally lifting the upper immediately.
and lower eyelids. If symptoms persist
consult physician
Skin Flush skin with plenty of soap and water for Get medical Allergic reaction Irritation or possible allergic response. Yes
at least 15 minutes. Remove contaminated aid. possible Severe allergic response may result
clothing and shoes. Wash clothing before in breathing difficulties.
reuse.
Inhalation Move to fresh air immediately. If breathing Get medical aid Allergic reaction Chronic inhalation may cause effects similar Yes
is difficult give oxygen. If not breathing, immediately. possible to those of acute inhalation. Causes
give artificial respiration. Do not use mouth respiratory tract irritation. May cause motor
to mouth resuscitation. Instead apply in coordination and speech abnormalities.
artificial respiration using oxygen and a
suitable mechanical device such as a bag
and a mask.
Consult physician if symptoms persist
Ingestion If conscious and alert, rinse mouth and Get medical Allergic reaction Not Applicable No
drink 2-4 cupfuls of milk or water. Never aid. possible
give anything by mouth to an unconscious
person. Do NOT induce vomiting.
Other: Not Applicable Not Applicable Not Applicable Not Applicable Not
Central Applicable
nervous
system
Medical Conditions Aggravated by Exposure Open sores and wounds of the skin. Individuals with known sensitivity to methacrylates, acrylates, or urethane
dimethacrylate resin used in Dental restorative products.
Carcinogenicity NTP?: Not listed IARC monographs?: Not listed OSHA regulated?: No. All components of this product are in compliance with the
inventory listing Requirements of the U. S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Potential Environmental Effects Do not allow to enter sewers/ surface or ground water.
NFPA Hazard Classification Ratings (Scale 0-4) Health =2, Fire =3, Reactivity=2 Specific Hazard = None
12.Ecological Information
Danger
Hazardous to aquatic life
Toxicity Data, Environmental Fate, Physical/Chemical Data, or other Data Supporting Environmental Hazard Statements: Water Hazard class1 (Self-assessment):
CAS# 80-62-6 Methyl Methacrylate: is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under
the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
13.Disposal Considerations
Regulations: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Dispose of material as solid waste in a closed
container. Dispose of in accordance with Federal, State and Local regulations.
Properties (Physical/Chemical) Affecting Disposal: Dispose of material as solid waste in a closed container.
RCRA P-Series: None Listed, RCRA U-Series CAS#80-62-6: Waste Number U162 (Ignitable Waste)
14.Transport Information
Flammable Liquid
Regulated for Shipping: Yes DOT Shipping Name: Methyl Methacrylate Monomer, Stabilized Solution Packing Group: II
Do Changes in Quantities, packaging, or shipment DOT Hazard Class: 3 UN Number: UN1247
method change product classification? Yes
DOT Labels Required (49CFR172.101): Yes Other: Not Applicable
15.Regulatory Information
This product has been classified in accordance with the hazard criteria of the Globally Harmonized System of Classification and
Labeling of Chemicals and the SDS contains all of the information required by the Canadian Controlled Products Regulations.
U.S. Federal Regulations: CERCLA 103 Reportable Quantity: CAS# 80-62-6: RQ is 1000 lb. final RQ; 454 kg final RQ.
Report spills required under federal, state and local regulations
Section 313 Toxic Chemicals: This product contains the following chemicals subject to Annual Release Reporting Requirements:
CAS# 80-62-6 Methyl Methacrylate which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA Codes: CAS# 80-62-6 Methyl Methacrylate: acute, chronic, flammable, reactive.
Section 302 Extremely Hazardous Substances (TPQ): None
Clean Air Act: CAS# 80-62-6 Methyl Methacrylate: is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 ozone depletors. This
material does not contain any Class 2 depletors.
Clean Water Act: CAS# 80-62-6 Methyl Methacrylate: is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority
Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA: OSHA does not consider CAS# 80-62-6 Methyl Methacrylate highly hazardous.
RCRA U-Series Hazardous Waste Code for CAS# 80-62-6 Methyl Methacrylate: U162
EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory.
State CAS# 80-62-6 Methyl Methacrylate can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota and
Massachusetts.
U.S. State Regulations California Proposition 65: This product does not contain any chemicals, which are on the California Proposition 65 list.
International Regulations: Canadian Environmental Protection Act:
This product is a medical device and not subject to chemical notification requirements.
WGK (Water Danger/Protection) Pure Methyl Methacrylate, CAS # 80-62-6: 1
Canada ?DSL/NDSL CAS # 80-62-6 is listed on Canada's DSL List.
Canada ?WHMIS This product has a WHNIS Classification of B2, D2B.
European Community Labeling: in accordance with EC Directives: Hazard Symbol for pure Methyl Methacrylate XI F
Risk Phrases: R11 Highly Flammable, R37/38 Irritating to respiratory system and skin. R43 May cause sensitization by skin contact.
Safety Phrases: S24 Avoid contact with skin. S37 Wear suitable gloves. S46 If swallowed, seek medical advice immediately.
European Inventory of New and Existing Chemicals Substances (EINECS):
This product is a medical device and not subject to chemical notification requirements.
Other: N. A.
16.Other Information
To the best of our knowledge this product does not contain gluten, wheat grains, flaxseed, natural rubber, or natural latex. All components are synthetically produced;
none are derived from animal products.
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific products features and shall not establish a legally
valid contractual relationship.
The attached safety data sheet covers the dangers and measures to be taken when large quantities of material are released, for example due to accidents during
transport or storage by the dealer. For quantities of material typically used in clinical practice, information necessary for safe use and storage of the product is given in
the DFU.
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