MATERIAL SAFETY DATA SHEET
T1V1
FILE NO.:
MSDS DATE: 11/30/2009
Product: T1 MSDS No.: T1113009
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: T1 Threadlocker
T1ML10, T1ML50, T1ML250
PRODUCT CODES:
SmartAdhesives LLC
COMPANY NAME:
San Francisco, CA 94129
ADDRESS:
Chemtrec: 1-800-424-9300
EMERGENCY PHONE:
Anaerobic adhesive and sealant; Industrial use
PRODUCT USE:
11-30-2009
ISSUE DATE:
SECTION 2: INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENT: C.A.S. No. % by Wt.
Ethoxylated Bisphenol A Dimethacrylate 41673-38-1 50-65%
Dibutyl Phthalate 84-74-2 30-40%
Ethylene Dimethacrylate 97-90-5 1-10%
SECTION 3: HAZARDS IDENTIFICATION
Normal physical form - liquid
EMERGENCY OVERVIEW:
IMMEDIATE HEALTH AND ENVIRONMENTAL HAZARDS
Causes eye, skin and respiratory tract irritation. May cause skin sensitization.
Hazardous polymerization may occur.
POTENTIAL HEALTH EFFECTS
Eye irritant.
EYE CONTACT:
Skin irritant. May cause skin sensitization.
SKIN CONTACT:
irritating to the mucous membranes and upper respiratory tract.
INHALATION:
Not expected to be ingested under normal conditions of use. May be harmful if
INGESTION:
swallowed.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
Eye, skin and respiratory disorders.
Acute Toxicity: Symptoms of overexposure include dizziness, headache or nausea.
CARCINOGENICITY
Ethoxylated Bisphenol A Dimethacrylate OSHA: NO NO NO
NTP: IARC:
Dibutyl Phthalate OSHA: NO NO NO
NTP: IARC:
Ethylene Dimethacrylate OSHA: NO NO NO
NTP: IARC:
SECTION 4: FIRST AID MEASURES
PAGE 1 OF 5
Product: T1 Revision Date: 11/30/2009
MATERIAL SAFETY DATA SHEET
Immediately flush eyes with plenty of water for at least 15 minutes. Seek medical
EYES:
advice immediately.
Immediately remove product from skin with dry cloth or towel. Wash skin with soap
SKIN:
and plenty of warm water. If symptoms occur, seek medical advice. Wash
contaminated clothing prior to reuse.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting
INGESTION:
occurs, the head should be kept low so that vomit does not enter the lungs. Get
medical attention immediately. Never give anything by mouth to an unconscious
person.
Move to fresh air. If symptoms persist, seek medical advice.
INHALATION:
SECTION 5: FIRE FIGHTING MEASURES
not determined
FLAMMABLE LIMITS UPPER:
not determined
(% BY VOLUME) LOWER:
200癋 (93癈) (closed cup)
FLASH POINT:
not determined
AUTOIGNITION TEMP:
NFPA HAZARD CLASSIFICATION
HEALTH: 2 1 REACTIVITY: 1
FLAMMABILITY:
HMIS HAZARD CLASSIFICATION
FLAMMABILITY: 1 PHYSICAL HAZARD: 1 PROTECTION: none
HEALTH: *2
Use foam, dry chemical powder, water fog or carbon dioxide.
EXTINGUISHING MEDIA:
SPECIAL FIRE FIGHTING PROCEDURES:
Wear positive pressure, self-contained breathing apparatus and full protective clothing.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or
oxidizers may cause polymerization reaction, generating heat and/or pressure. Closed
containers my rupture or explode during rapid polymerization.
HAZARDOUS DECOMPOSITION PRODUCTS:
see Section 10
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES:
No action shall be taken involving any personal risk or without suitable training. Evacuate
untrained and unprotected people from release areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through spilled material. Avoid
breathing vapor or mist. Ventilate area. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see section 8). Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
For small spills, absorb with inert material (sand, silica gel, universal binder) and dispose
in appropriate waste disposal container. For larger spills, first extinguish all sources of
ignition. Material is combustible. Make sure to first stop spill or leak at source before
clean-up. Dike if necessary. Absorb with inert material and place in appropriate waste
disposal container. Spilled or release material may polymerize and release heat and/or
gases. Dispose of all material in accordance with Federal, State, and local regulations.
SECTION 7: HANDLING AND STORAGE
PAGE 2 OF 5
Product: T1 Revision Date: 11/30/2009
MATERIAL SAFETY DATA SHEET
Eating, drinking and smoking should be prohibited in areas where this material is
HANDLING:
handled, stored and processed. Workers should wash hands and face with soap and
water before eating, drinking and smoking.
Avoid contact with eyes and skin. Material is a potential skin sensitizer. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Keep in the original
container or an approved alternative made from a compatible material. Prevent
contaminating product with foreign material.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
STORAGE:
area, away from sources of heat and ignition, and water. Prevent moisture contact and
contaminating product with foreign material. Store in accordance with local regulations.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Use local exhaust ventilation, sufficient in pattern and volume, to maintain vapor
VENTILATION :
concentration below established TLV requirements.
Use NIOSH approved respirator if there is a potential to exceed exposure limits.
RESPIRATORY PROTECTION:
Avoid contact with eyes. Use safety glasses with side shields or indirect vented goggles.
EYE PROTECTION:
Avoid contact with skin. Use nitrile, PVA, or butyl rubber gloves.
SKIN PROTECTION:
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
Facilities storing or utilizing this material should be equipped with eye wash fountains and
safety shower.
Remove contaminated clothing and launder before next use. Wash thoroughly after
WORK HYGIENIC PRACTICES:
handling.
EXPOSURE GUIDELINES:
Organization Type Limit
3
Dibutyl phthalate ACGIH (TLV) TWA 5 mg/m
3
OSHA (PEL) TWA 5 mg/m
ACGIH: American Conference of Governmental Industrial Hygienists
OSHA: Occupational Safety and Health Administration
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
blue liquid not available
COLOR & APPEARANCE: VAPOR PRESSURE (mmHg):
slight not available
ODOR THRESHOLD: VAPOR DENSITY (AIR=1):
liquid 1.06
PHYSICAL FORM: SPECIFIC GRAVITY (H2O=1):
not available
FLAMMABLE LIMITS EVAPORATION RATE:
not available
LEL:
not available
UEL:
not available slight
BOILING POINT: SOLUBILITY IN WATER:
not available
AUTOIGNITION TEMP: 140 ?10 cP
VISCOSITY:
VOLATILE ORGANIC COMPOUNDS (VOC)
200癋 (93癈)
FLASH POINT:
(Pensky-Martens Closed Cup ASTM D 93) NA
VOC:
NA
VOC less H2O & Exempt Solvent:
not available
pH AS SUPPLIED:
SECTION 10: STABILITY AND REACTIVITY
Stable under recommended storage conditions. Hazardous polymerization may occur
STABILITY:
under the conditions listed below.
PAGE 3 OF 5
Product: T1 Revision Date: 11/30/2009
MATERIAL SAFETY DATA SHEET
MATERIALS AND CONDITIONS TO AVOID (STABILITY):
Product will be unstable at high temperatures, fire conditions, or depletion of inhibitor.
Avoid direct sunlight, oxidizing agents, inert gas blanketing, and freezing conditions.
Acids, bases, chlorines, free radical initiators, inert gases, nitrates, oxidizing agents,
oxygen scavengers, and reducing agents.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
Carbon oxides. Nitrogen oxides. Sulfur oxides. May emit other toxic fumes under fire
conditions.
HAZARDOUS POLYMERIZATION: Hazardous polymerization may occur in the event of accidental impurities, exposure to
radiation or oxidizers, lack of inhibitor, high temperatures, or when exposed to direct
sunlight or heat.
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:
Dibutyl Phthalate
Acute oral LD50: >8,000 mg/kg (rat)
Acute dermal LD50: >20 mL/kg (rabbit)
3
Acute inhalation LC50: >4,250 mg/m (rat)
Toxicity: Investigated as a tumorigen, mutagen, and reproductive effector.
Reproductive Toxicity:
Women working where phthalates were used had higher incidence of miscarriages,
menstrual disorders, and reduced gestation periods.
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:
Dibutyl Phthalate
When release into the soil, this material may biodegrade to a moderate extent and may leach into
groundwater. When release into water, this material is expected to readily biodegrade and have a
half-life between 10-30 days. This material is not expected to significantly bioaccumulate. When
released into the air, this material may be removed from the atmosphere to a moderate extent by
dry deposition.
96 Hr LC50 fathead minnow: 0.85 mg/L (flow-through);
96 Hr LC50 rainbow trout: 1.24 mg/L (flow-through);
96 Hr LC50 bluegill: 0.42 mg/L (flow-through)
Dangerous to the environment. Very toxic to aquatic organisms.
SECTION 13: DISPOSAL CONSIDERATIONS
Disposal of this product, solutions and any by-products should at all times comply with
WASTE DISPOSAL METHOD:
Federal, State and local regulations. Any material should be disposed of in a RCRA
approved waste facility or RCRA approved incinerator. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
Dibutyl phthalate: U069.
RCRA HAZARD CLASS:
SECTION 14: TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (49 CFR)
PROPER SHIPPING NAME: Environmentally Hazardous Substances, N.O.S. (Dibutyl Phthalate)
9
HAZARD CLASS:
UN 3082
ID NUMBER:
III
PACKING GROUP:
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA)
PROPER SHIPPING NAME: Environmentally Hazardous Substances, N.O.S. (Dibutyl Phthalate)
PAGE 4 OF 5
Product: T1 Revision Date: 11/30/2009
MATERIAL SAFETY DATA SHEET
9
HAZARD CLASS:
UN 3082
ID NUMBER:
III
PACKING GROUP:
WATER TRANSPORTATION (IMO/IMDG)
PROPER SHIPPING NAME: Environmentally Hazardous Substances, N.O.S. (Dibutyl Phthalate)
9
HAZARD CLASS:
UN 3082
ID NUMBER:
III
PACKING GROUP:
none
MARINE POLLUTANT:
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA (Toxic Substance Control Act)
All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
311/312 HAZARD CATEGORIES:
Chronic: Yes Reactivity: Yes Acute: Yes
SECTION 313: (Toxic chemicals subject to reporting requirements of that section and 40 CFR part 372 (EPCRA))
Dibutyl Phthalate 30%-40% (% by weight) CAS 84-74-2
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION, AND LIABILITY ACT):
Dibutyl Phthalate: reportable quantity is 10 lbs.
STATE REGULATIONS
Dibutyl Phthalate: developmental toxicity, female reproductivity, male reproductivity.
California Prop. 65:
SECTION 16: OTHER INFORMATION
OTHER INFORMATION:
HMIS Rating
Health *2
Flammability 1
Physical Hazard 1
NFPA Rating
Health 2
Flammability 1
Reactivity 1
PREPARATION INFORMATION:
DISCLAIMER: The material in this Material Safety Data Sheet (MSDS) is, to the best of our knowledge, accurate as of the
date issued. However, neither SmartAdhesives nor any of its subsidiaries or agents assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. Compliance with all applicable federal, state, and local laws and regulations remains the
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that may exist. Given the quantity of
variables that affect use and application of our products, many of which are within the user's control and unique to each
user's knowledge, SMARTADHESIVES MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING BUT NOT
LIMITED TO ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR
COURSE OF PERFORMANCE OR USAGE OF TRADE.
PAGE 5 OF 5
|