Safety Data Sheet according to 91/155/EEC
European Nail Factory
Revision date : 18.01.2006 Revision no. : 1,00
PRIMER
00642-0026
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation
PRIMER
Use of the substance/preparation
Cosmetic
1.2 Company/undertaking identification
European Nail Factory
In der Salzheck 7
D-56332 Dieblich
Telephone : ++49 (0) 26 07-96 60-0
Telefax : ++49 (0) 26 07-96 60-29
Contact person :
www.europeannailfactory.com
Internet:
Inquiry office :
Emergency telephone :++49 (0) 2607 / 96600 European Nail Factory GmbH, available during open hours
2. Composition/information on ingredients
( preparation )
Chemical characterization
Mixture of organic solvents
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
201-204-4 79-41-4 2-methylpropenoic acid, methacrylic acid 50 - 55 % Xn, C R21/22-35
204-658-1 123-86-4 n-butyl acetate 20 - 25 % R10-66-67
202-615-1 97-88-1 n-butyl methacrylate 10 - 15 % Xi R10-36/37/38-43
200-578-6 64-17-5 Ethanol 5 - 10 % F R11
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Symbols : Corrosive
R-phrases :
Harmful in contact with skin and if swallowed.
Causes severe burns.
May cause sensitization by skin contact.
Vapours may cause drowsiness and dizziness.
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
Call a physician immediately.
After inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.
In the event of persistent symptoms receive medical treatment.
GB - EN Page 1 of 7
Safety Data Sheet according to 91/155/EEC
European Nail Factory
Revision date : 18.01.2006 Revision no. : 1,00
PRIMER
00642-0026
After contact with skin
Wash off immediately with soap and plenty of water.
Consult a doctor if skin irritation persists.
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Seek medical treatment by eye specialist.
After ingestion
Do not induce vomiting.
Rinse out mouth and give plenty of water to drink.
Never give anything by mouth to an unconscious person.
Summon a doctor immediately.
5. Fire-fighting measures
Suitable extinguishing media
Foam, carbon dioxide (CO2), dry chemical, water-spray.
Extinguishing media which must not be used for safety reasons
Full water jet
Special exposure hazards arriving from substance or preparation itself, combustion products,
resulting gases
Fire may produce:
Carbon monoxide and carbon dioxide.
Special protective equipment for fire-fighters
In case of fire, wear suitable respiratory equipment with positive air supply.
Protective suit
Additional information
Cool containers at risk with water spray jet.
Backfire at a long distance is possible.
Heating will cause pressure rise with risk of bursting.
Fire residues and contaminated firefighting water must be disposed of in accordance with the local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective clothing.
Ensure adequate ventilation.
Keep away sources of ignition.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
7. Handling and storage
7.1 Handling
Advice on safe handling
GB - EN Page 2 of 7
Safety Data Sheet according to 91/155/EEC
European Nail Factory
Revision date : 18.01.2006 Revision no. : 1,00
PRIMER
00642-0026
Keep container tightly closed.
Handle and open container with care.
Avoid contact with skin, eyes and clothing.
Ensure adequate ventilation, especially in confined areas.
Advice on protection against fire and explosion
Keep away from heat and sources of ignition.
7.2 Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry, cool and well-ventilated place.
Protect from light. Keep away from heat.
Keep at temperatures above 15癈.
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
8A
Storageclass (VCI) :
8. Exposure controls/personal protection
8.1 Exposure limit values
Exposure limits (EH40)
CAS No. Substance ml/m? mg/m? F/ml Category Origin
123-86-4 Butyl acetate 150 724 TWA (8 h) WEL
Butyl acetate 200 966 STEL (15 min) WEL
64-17-5 Ethanol 1000 1920 TWA (8 h) WEL
Ethanol - - STEL (15 min) WEL
79-41-4 Methacrylic acid 20 72 TWA (8 h) WEL
Methacrylic acid 40 143 STEL (15 min) WEL
8.2 Exposure controls
Occupational exposure controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes and clothing.
Do not inhale vapours.
When using, do not eat, drink or smoke.
Remove and wash contaminated clothes before re-use.
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A).
Hand protection
Splash protection:
Protective gloves resistant to chemicals made off butyl, Minimum coat thickness 0,7 mm, Permeation
resistance (wear duration) > 60 minutes, i.e. protective glove made by www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN
374 carried out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
Eye protection
Tightly fitting goggles
Eye wash bottle with pure water.
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Safety Data Sheet according to 91/155/EEC
European Nail Factory
Revision date : 18.01.2006 Revision no. : 1,00
PRIMER
00642-0026
Skin protection
Long sleeved clothing.
9. Physical and chemical properties
9.1 General information
Physical state : Liquid
Colour : Clear, Colourless
Odour : Pungent
9.2 Important health, safety and environmental information
Test method
2,0 - 2,2
pH-Value :
Changes in the physical state
Melting point : 15,8 癈
Boiling point : 161 癈
Flash point : 65 癈
Flammability
n. d.
Lower explosion limits :
n. d.
Ignition temperature :
Density (at 20 癈) : 1,015 g/cm?br>
Miscible
Water solubility :
at (20 癈)
log Po/w = 0,97 (25癈)
Partition coefficient :
1,4 mPa穝
Viscosity / dynamic :
at (20 癈)
10. Stability and reactivity
Conditions to avoid
To avoid thermal decomposition, do not overheat.
Violent polymerisation possible.
Materials to avoid
Strong oxidizing agents, reducing agents.
Hazardous decomposition products
Carbon monoxide and carbon dioxide.
Additional information
No decomposition if stored and applied as directed.
11. Toxicological information
Acute toxicity
LD50/oral/rat: 2200 mg/kg
LD50/dermal/rabbit: 500 mg/kg
LC50/inhalativ/rat: 7100 mg/m?4 h
Empirical data on effects on humans
Causes severe burns.
May cause sensitization by skin contact.
Vapours may cause drowsiness and dizziness.
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Safety Data Sheet according to 91/155/EEC
European Nail Factory
Revision date : 18.01.2006 Revision no. : 1,00
PRIMER
00642-0026
Liver and renal damage is possible.
12. Ecological information
Additional information
Do not flush into surface water or sanitary sewer system.
Slightly water hazardous.
A pH-change becomes possible in waters.
13. Disposal considerations
Advice on disposal
Can be landfilled after chemical and physical treatment, when in compliance with local regulations.
Where possible recycling is preferred to disposal.
Waste disposal number of waste from residues/unused products :
070604 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats,
grease, soaps, detergents, disinfectants and cosmetics; other organic solvents, washing
liquids and mother liquors
Classified as hazardous waste.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be
taken for reuse.
Packaging that cannot be cleaned should be disposed of like the product.
14. Transport information
Land transport (ADR/RID)
ADR/RID class : 8
Hazard-no. : 80
UN number : 1760
Hazard label : 8
ADR/RID packing group : II
Description of the goods
Corrosive liquid, n.o.s. (2-methylpropenoic acid, methacrylic acid, n-butyl methacrylate)
Remarks (land transport)
LQ 22: combination packaging: 1 l / 30 kg (total gross mass); trays: 0,5 l / 20 kg (total gross mass).
Inland waterways transport
Marine transport
8
IMDG code :
UN number : 1760
Marine pollutant : No
EmS : F-A; S-B
IMDG packing group : II
Hazard label : 8
Description of the goods
CORROSIVE LIQUID, N.O.S. (methacrylic acid, butyl methacrylate)
Remarks (marine transport)
Limited quantities (chapter 3.4): combination packaging: 1 l / 30 kg (total gross mass); trays: 1 l / 20 kg
(total gross mass)
GB - EN Page 5 of 7
Safety Data Sheet according to 91/155/EEC
European Nail Factory
Revision date : 18.01.2006 Revision no. : 1,00
PRIMER
00642-0026
Air transport
ICAO/IATA-DGR : 8
UN/ID number : 1760
Hazard label : 8
808
IATA-packing instructions - Passenger :
IATA-max. quantity - Passenger : 1L
IATA-packing instructions - Cargo : 812
IATA-max. quantity - Cargo : 30 L
ICAO packing group : II
Description of the goods
CORROSIVE LIQUID, N.O.S. (methacrylic acid, butyl methacrylate)
15. Regulatory information
15.1 Labelling
Indication of danger : C - Corrosive
Labelling according to EC-guidelines : According to the EC hazardous substance regulations in compliance with
the EC cosmetic product regulations this product must not be labelled as a
hazardous substance.
According to ruling EC Directives the product must be labelled as
hazardous substance as follows:
Hazardous component(s) to be indicated on label
2-methylpropenoic acid, methacrylic acid
n-butyl methacrylate
R phrases :
35 Causes severe burns.
43 May cause sensitization by skin contact.
67 Vapours may cause drowsiness and dizziness.
21/22 Harmful in contact with skin and if swallowed.
S phrases :
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
15.2 National regulations
Employment restrictions : Observe employment restrictions for young people.; Observe
employment restrictions for child bearing mothers and nursing.
Water contaminating class : 1 - slightly water contaminating
1999/13/EC (VOC) : 100 %
16. Other information
List of relevant R phrases
10 Flammable.
11 Highly flammable.
35 Causes severe burns.
43 May cause sensitization by skin contact.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
21/22 Harmful in contact with skin and if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
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Safety Data Sheet according to 91/155/EEC
European Nail Factory
Revision date : 18.01.2006 Revision no. : 1,00
PRIMER
00642-0026
36/37/38 Irritating to eyes, respiratory system and skin.
Other data
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the
product (in this sense consult information on use and on product), but to liberation of major amounts in
case of accidents and irregularities.
The information describes exclusively the safety requirements for the product (s) and is based on the
present level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal
warranty regulations.
"(n.a. = not applicable; n.d. = not determined)"
(The data for the hazardous ingredients were taken respectively from the last version of the
sub-contractor's safety data sheet.)
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