SAFETY DATA SHEET 10.10.2008
1. IDENTIFICATION OF THE PRODUCT
IDENTIFICATION OF THE PRODUCER
Trade Name: French - gel white
Characteristic: UV Gel. Cosmetics.
Importer/Distributor: La Femme Cosmetics Sp. z o.o.
ul. Chyloska 210
81-007 Gdynia, Polska
Tel: +48 (58) 774 40 00
Fax: +48 (58) 661 40 29
Date of issue: 10.10.2008
2. HAZARD IDENTIFICATION
Product is classified as hazardous.
Product classification: Xi; R37; R43; R52/53
Fire menace:
- product is hardly non-inflammable liquid
- product emits toxic gases during the fire
Health menace:
- product is irritant
- product is irritating to respiratory system
- product is sensitizing
- product may cause sensitization by skin contact
Ecological menace:
- product is classified as dangerous for an environment
- product is harmful to aquatic organisms
- product may cause long-term adverse effects in the aquatic environment.
- to proceed compliance with the instruction or safety data sheet
- avoid dumping into environment
3. COMPOSITION / INFORMATION ON INGREDIENTS
Classified according to European directives (67/548/EC and 1999/45/EC) on classification of hazardous
substances and preparations.
10% ?20% Ethylene glycol dimethacrylate
Index No: 607-114-00-5 CAS No: 97-90-5 EC No: 202-617-2
Xi: 37; R43
3%?% 1-Hydroxycyclohexyl phenyl ketone
Index number: - CAS No: 947-19-3 EC No: 213-426-9
Xi: R36
0%?% Benzophenone
Index No: - CAS No: 119-61-9 EC No: 204-337-6
N: R50/53
Meaning of symbols and risk phrases ?see Section 16.
4. FIRST AID MEASURES
Inhalation:
- injured person transport to well-ventilated room
- get medical attention
Eye contact:
- wash out with plenty of water for least 10-15 minutes with the eyelid held wide open; avoid strong stream
of water, which can cause cornea injury
- does not use any liquids or ointment before getting medical attention
- remove any contact lenses
- get medical attention
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Skin contact:
- remove contaminated clothing
- wash off with plenty of water and soap
- do not use any solvents or diluents
- get medical attention
Ingestion:
- consumption is unlikely because of the form of product ?aerosol
- rinse mouth with plenty of water
- do not serve anything to drink
- do not evoke vomiting
- get medical attention
5. FIRE FIGHTING MEASURES
Fire menace:
- product is hardly non-inflammable liquid
- product emits toxic gases during the fire
Suitable extinguishing media:
- carbon dioxide (CO2)
- fire extinguishing powder
- alcohol resistant foam
- water- diffuse stream
Not suitable extinguishing media:
- water-strong stream
Cool down intact containers with water to prevent bursting and if possible remove from fire
Hazardous combustion products:
- carbon oxide and dioxide
- toxic gas and smoke
Recommended protective equipment:
- self-contained breathing apparatus and chemical protection suits
6. ACCIDENTAL RELEASE MEASURES
General recommendations:
- inform appropriate service
- remove from dangerous area people not taking part in liquidating damage
Personal precautions:
- self-contained breathing apparatus
- avoid gas and steam inhaling
- avoid contact with skin and eyes
- chemical protection gloves and suits
- wear tightly goggles or face shield
Particular recommendations:
- remove all fire source
- do not smoke
Environmental precautions:
- bank leak with incombustible, absorptive material (sand, infusorial earth), and gather in closed, meant
container; polluted area flush with water
- liquidate leak
- remove all fire source
- prevent discharge to water source and drain
- contact with local authority if discharge to water source or drain
Methods for cleaning up:
- small leak bank leak with incombustible, absorptive material (sand, infusorial earth), and gather in closed,
meant container; polluted area flush with water
- ventilate polluted compartment
- after sweep up area may be flushed with water
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7. HANDLING AND STORAGE
Handling:
- product vapour with air is flammable and explosive mixture, prevent high product vapour concentration in
air
- during handling ventilate compartment; prevent product aerosol formation
- handle in accordance with good occupational hygiene and safety practices
- avoid inhalation
- product can accumulate electrostatic charge ?fire hazard
- product can not contact with hot surface, flame and fire source
- do not smoke
- avoid contact with skin and eyes
- avoid inhalation
- avoid prolonged and repeated exposure
Storage instructions:
- overt container keep in vertical position
- do not smoke in store
- keep container tightly closed
- keep away from sunlight
- keep away from flame, sparks and heat sources
Requirements concerning storage space:
- cool, dry and well ventilated
Containers:
- storage only in original containers
- keep containers tightly closed and well labeled
- protect container from damage
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Personal protection:
- after handling wash whole body
- polluted clothes lounder befor following use
Skin protection:
- protective suit
Hand protection:
- wear protective gloves resistant to organic solvent (neoprene, PCV, nitril rubber)
Eye protection:
- wear protective goggles
Respiratory equipment:
- in case of normal use is not required (well ventilated compartment)
- in case of long-lasting exposing use self-contained respiratory equipment
General:
- requisite eye-washing stand
- avoid contact with skin and eyes
Exposure Limits:
--
9. PHYSICAL AND CHEMICAL PROPERTIES
physical state: labile liquid
color: white
odour: like acrylate
pH: -
boiling point: -
melting point: -
autoignition point: -
>100oC
ignition point:
explosion limits(vol%):
- lower: -
- upper: -
flammability does not cause hazard
explosive properties does not cause explosive menace
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oxidizing properties: -
vapor pressure: <0,01 mmHg (20oC)
density: 1,15 g/cm3 (20oC)
vapor density: -
solubility in water not miscible
solubility in organic solvent: miscible with most organic solvents
partition coefficient(n-octanol/water): -
10. STABILITY AND REACTIVITY
Stability:
- stable at normal conditions
Conditions to avoid
- sunlight and ultraviolet radiation (product may polymerize)
- heat (above 40 oC - product may polymerize)
- heat above 40 oC may cause disruption of packing
Materials to avoid:
- polymerization initiators (peroxides, strong oxidants, cooper, cooper alloy, carbon steel, rust and
strong bases)
Dangerous decomposition products:
- carbon oxides
- toxic gas and smoke
11. TOXICOGICAL INFORMATION
Health menace:
- product is irritant
- product is irritating to respiratory system
- product is sensitizing
- product may cause sensitization by skin contact
Toxicological information:
Acrylate:
Oral toxicity LD50 (rat): 1000 mg/kg
Inhalation LC50 (rat): 3800 ppm/m3
Dermal LD50 (rabbit, ): >2000 mg/kg
Other information:
skin: may cause irritation
eyes : may cause irritation to eyes , redness, lacrimation (high concentration)
inhalation: vapour may be irritant; may cause central nervous system- stupefaction
consumption: may be irritant to mucous membranes in digestive system, stomachache, nausea,
vomiting, diarrhea
12. ECOLOGICAL INFORMATION
Ecological menace:
- product is classified as dangerous for an environment
- product is harmful to aquatic organisms
- product may cause long-term adverse effects in the aquatic environment.
- to proceed compliance with the instruction or safety data sheet
- avoid dumping into environment
Ecotoxicity:
- no data available
Product mobility, bioconcentration and biodegradation:
- no data available
13. DISPOSAL CONSIDERATIONS
Discards procedure:
- product is classified as dangerous for an environment
- handle contaminated packing in the same way as the substance itself
- do not purge into savage system
- do not store at waste dump
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- neutralizing ?thermal utilization (chemicals incineration furnace)
Content of package:
- type of discard: other discards
- discard code: 07 06 99
Package:
- type of discard: plastic package
- discard code: 15 01 02
- type of discard: metal package
- discard code: 15 01 04
14. TRANSPORT INFORMATION
Transport information:
Product does not cause transport menace
15. REGULATORY INFORMATION
Markings according to EU guidelines:
The product has been classified and marked in accordance with EU Directives.
Product contains:
Ethylene glycol dimethacrylate
Hazard symbol:
Xi Irritant
Risk phrases:
R37 Irritating to respiratory system
R43 May cause sensitization by skin contact
R52/53 Harmful to aquatic organisms; May cause long-term adverse effects in the
aquatic environment.
Safety phrases:
S24/25 Avoid contact with skin and eyes
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
In case of retail trade use additional safety phrase: "S2 Keep out of reach of children" and "S45 In case
of accident or if you feel unwell, seek medical advice immediately (show the label where possible)".
This data sheet is particularly in accordance with the European directives 1999/45/CE and 2001/59/
CE; it is written according to the directive 2001/58/CE.
16. OTHER INFORMATIONS
Meaning of symbols and risk phrases:
Xi Irritant
N Dangerous for the environment
R36 Irritating to eyes
R37 Irritating to respiratory system
R43 May cause sensitization by skin contact
R52/53 Harmful to aquatic organisms; May cause long-term adverse effects in the
aquatic environment.
The information above is based on a current available data concerning the product, but also on the
experience and knowledge in this field of the producer. They are neither a quality description of the product
nor a guarantee of particular features. They are to be treated as aid to safety in transport, storage and
usage of the product. This does not free the user from the responsibility of improper usage of the
information above and also of improper compliance with the law norms in the field.
Safety Data Sheet made by: CHEM-NET S.C. 91-716 L骴, Nowopolska 9A; biuro@chem-net.info
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