Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
TATTOO 1/7
Version 4 / GB Revision Date: 28.09.2007
102000000877 Print Date: 14.07.2008
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name TATTOO
Product code (UVP) 05934524
Usage Fungicide
Company Bayer CropScience Limited
230 Cambridge Science Park
Milton Road
Cambridge
Cambridgeshire CB4 0WB
Great Britain
Telephone +44(0)1223 226500
Telefax +44(0)1223 426240
Responsible Department Email: ukinfo@bayercropscience.com
Emergency telephone number 0800-220876 (UK 24 hr)
+44(0)1603-242424 (Overseas 24 hr)
2. HAZARDS IDENTIFICATION
Risk advice to man and the environment
May cause sensitization by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Suspension concentrate (=flowable concentrate)(SC)
20.00% Propamocarb Hydrochloride (248 g/l), 24.32% Mancozeb (302 g/l )
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Mancozeb 8018-01-7 Xi R37, R43 24.32
Propamocarb hydrochloride 25606-41-1 Xi R43 20.00
247-125-9
Copper(II)-sulphate 7758-99-8 Xn, N R22, R36/38, > 0.25 - < 2.50
pentahydrate R50/53
Lignosulfonic acid, sodium 68512-34-5 Xi R36 > 1.00 - < 20.00
salt, sulfomethylated
Methenamine 100-97-0 F, Xn R11, R42/43 > 0.10 - < 1.00
202-905-8
For the full text of the R phrases mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
TATTOO 2/7
Version 4 / GB Revision Date: 28.09.2007
102000000877 Print Date: 14.07.2008
General advice
Remove contaminated clothing immediately and dispose of safely.
Inhalation
When inhaled remove to fresh air and seek medical aid. Place and transport victim in stable
position (lying sideways).
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Ingestion
Do NOT induce vomiting. Rinse out mouth and give water in small sips to drink. Ingest
activated charcoal. Call a physician or poison control center immediately.
Notes to Physician
Symptoms
eye and mucous membrane irritation, Erythema, Nausea, Vomiting, Allergic reactions,
gastrointestinal discomfort, More severe effects if alcohol is consumed.
Risks
More severe effects if alcohol is consumed.
Treatment
Treat symptomatically.
Follow-up measures: Strict abstinence from alcohol for 1 to 2 weeks, due to antabuse effect.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media which should not be used for safety reasons
High volume water jet
Specific hazards during fire fighting
Dangerous gases are evolved in the event of a fire.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
Further information
Cool closed containers/ tanks exposed to fire with water spray.
Do not allow run-off from fire fighting to enter drains or water courses.
Extinguishing measures to suit surroundings.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Use personal protective equipment.
Environmental Precautions
Do not allow to get into surface water, drains and ground water.
If spillage enters drains leading to sewage works inform local water company immediately.
If spillage enters rivers or watercourses, inform the Environment Agency (emergency
telephone number 0800 807060).
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
TATTOO 3/7
Version 4 / GB Revision Date: 28.09.2007
102000000877 Print Date: 14.07.2008
Methods for Cleaning Up
Keep in suitable, closed containers for disposal.
Clean floors and contaminated objects with plenty of water.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Additional Advice
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Ensure adequate ventilation.
Advice on protection against fire and explosion
No special precautions required.
Storage
Requirements for storage areas and containers
Store in original container.
Keep away from direct sunlight.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage period 24 Months
Storage temperature 0 - 30 癈
Suitable materials
HDPE (high density polyethylene)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment)
Regulations 2004). Engineering controls should be used in preference to personal
protective equipment wherever practicable. Refer also to COSHH Essentials.
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases
the following recommendations would apply.
Respiratory Protection No personal respiratory protective equipment normally required.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
TATTOO 4/7
Version 4 / GB Revision Date: 28.09.2007
102000000877 Print Date: 14.07.2008
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
Skin and body protection Wear standard coverall and type 3 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
Hygiene measures
Keep away from food, drink and animal feedingstuffs.
Remove soiled clothing immediately and clean thoroughly before using again.
Avoid contact with skin, eyes and clothing.
Wash hands immediately after work, if necessary take a shower.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form liquid, suspension
Colour light brown
Odour weak, characteristic
Safety data
pH 4.7 - 6.5 at 1 % (23 癈)
Boiling point/ range approx. 100 癈
Flash point not applicable
Autoignition Temperature The product is not self-ignitable.
Density approx. 1.248 g/cm?at 20 癈
Water solubility dispersible
Viscosity, dynamic 160 - 260 mPa.s at 20 癈
Velocity gradient 100 /s
Explosivity Not explosive
10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.
Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
TATTOO 5/7
Version 4 / GB Revision Date: 28.09.2007
102000000877 Print Date: 14.07.2008
Acute Oral Toxicity LD50 (rat) > 5,000 mg/kg
Acute Dermal Toxicity LD50 (rat) > 4,000 mg/kg
Skin Irritation Slight irritant effect - does not require labelling. (rabbit)
Eye Irritation Slight irritant effect - does not require labelling. (rabbit)
Sensitization sensitizing (guinea pig)
OECD Test Guideline 406, Buehler test
May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 13.1 mg/l
static test Exposure time: 96 h
Toxicity to daphnia EC50 (Daphnia) 3.5 mg/l
static test Exposure time: 48 h
Toxicity to algae IC50 (Algae) 0.211 mg/l
Exposure time: 96 h
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations and, if necessary, after consultation with the site
operator and/or with the responsible authority, the product may be taken to a waste disposal
site or incineration plant.
Advice may be obtained from the local waste regulation authority (part of the Environment
Agency in the UK).
Contaminated packaging
Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using an integrated pressure
rinsing device, or, by manually rinsing three times.
Add washings to sprayer at time of filling.
Dispose of empty and cleaned packaging safely.
Large containers (> 25 l or > 25 kg) should not be rinsed or re-used for any other purpose.
Return large containers to supplier.
Follow advice on product label and/or leaflet.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-Number 3082
Labels 9
Packaging group III
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
TATTOO 6/7
Version 4 / GB Revision Date: 28.09.2007
102000000877 Print Date: 14.07.2008
Hazard no. 90
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(MANCOZEB SOLUTION)
IMDG
UN-Number 3082
Labels 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(MANCOZEB SOLUTION)
IATA
UN-Number 3082
Labels 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(MANCOZEB SOLUTION )
UK 'Carriage' Regulations
UN-Number 3082
Labels 9
Packaging group III
Hazard no. 90
Emergency action code 3Z
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(MANCOZEB SOLUTION)
15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information
and Packaging for Supply) Regulations 2002: CHIP 3 and any subsequent amendments.
Classification:
Hazard warning labelling compulsory
Hazardous components which must be listed on the label:
?Propamocarb hydrochloride
?Mancozeb
Symbol(s)
Xi Irritant
N Dangerous for the environment
R-phrase(s)
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Bayer CropScience
SAFETY DATA SHEET according to Regulation (EU) No. 1907/2006
TATTOO 7/7
Version 4 / GB Revision Date: 28.09.2007
102000000877 Print Date: 14.07.2008
S-phrase(s)
S24 Avoid contact with skin.
S35 This material and its container must be disposed of in a safe way.
S37 Wear suitable gloves.
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 3:
R11 Highly flammable.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R36/38 Irritating to eyes and skin.
R37 Irritating to respiratory system.
R42/43 May cause sensitization by inhalation and skin contact.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or
policy in force or arising from any risk assessment involving the substance or product should take
precedence over any of the guidance contained in this safety data sheet where there is a
difference in the information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take
account of information or advice contained in this safety data sheet.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
|