REFRIGERANT 116
MATERIAL SAFETY DATA SHEET 12/18/99
MSDS PROVIDED BY:
STOODY INDUSTRIAL AND WELDING SUPPLY, INC.
3316 National Ave., San Diego, Ca. 92113
Phone: (619) 234-6750
MILITARY EMERGENCY RESPONSE NUMBER 1-800-851-8061
E I DUPONT FREON PROD -- FREON 116 REFRIGERANT-NITROUS OXIDE BLEND 90-10 -
HEXAFLUOROETHANE,TECHNICAL
MATERIAL SAFETY DATA SHEET
NSN: 6830001817754
Manufacturer's CAGE: 5P414
Part No. Indicator: B
Part Number/Trade Name: FREON 116 REFRIGERANT/NITROUS OXIDE BLEND 90/10
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General Information
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Item Name: HEXAFLUOROETHANE,TECHNICAL
Company's Name: E I DUPONT DE NEMOURS & CO, FREON PROD
Company's Street: 1007 MARKET ST
Company's City: WILMINGTON
Company's State: DE
Company's Country: US
Company's Zip Code: 19899
Company's Emerg Ph #: 800-441-3637/800-424-9300(CHEMTREC)
Company's Info Ph #: 302-999-4946
Record No. For Safety Entry: 003
Tot Safety Entries This Stk#: 003
Status: FE
Date MSDS Prepared: 16OCT96
Safety Data Review Date: 04NOV97
Supply Item Manager: CX
MSDS Preparer's Name: UNKNOWN
MSDS Serial Number: CFMPR
Specification Number: NONE
Spec Type, Grade, Class: NONE
Hazard Characteristic Code: G3
Unit Of Issue: LB
Unit Of Issue Container Qty: 95 LBS
Type Of Container: CYLINDER
Net Unit Weight: 95 LBS
NRC/State License Number: NOT RELEVANT
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Ingredients/Identity Information
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Proprietary: NO
Ingredient: HEXAFLUOROETHANE
Ingredient Sequence Number: 01
Percent: 90
NIOSH (RTECS) Number: KI4110000
CAS Number: 76-16-4
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: TWA 1000 PPM (MFR)
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Proprietary: NO
Ingredient: NITROUS OXIDE
Ingredient Sequence Number: 02
Percent: 10
NIOSH (RTECS) Number: QX1350000
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 1 OF 4
REFRIGERANT 116 MSDS
CAS Number: 10024-97-2
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: 50 PPM; 9596
Other Recommended Limit: NONE RECOMMENDED
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Physical/Chemical Characteristics
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Appearance And Odor: CLEAR, COLORLESS GAS - SLIGHT ETHEREAL ODOR
Boiling Point: -144F,-98C
Melting Point: UNKNOWN
Vapor Pressure (MM Hg/70 F): 43221 @70F
Vapor Density (Air=1): 3.9
Specific Gravity: 1.587 @ -100F
Decomposition Temperature: UNKNOWN
Evaporation Rate And Ref: NOT RELEVANT
Solubility In Water: UNKNOWN
Percent Volatiles By Volume: 100
Viscosity: NOT RELEVANT
Radioactivity: NOT RELEVANT
Corrosion Rate (IPY): UNKNOWN
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Fire and Explosion Hazard Data
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Flash Point: NONE
Lower Explosive Limit: NOT RELEVANT
Upper Explosive Limit: NOT RELEVANT
Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR
SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CYLINDERS.
Special Fire Fighting Proc: WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE
PRESSURE MODE. STOP GAS FLOW IF POSSIBLE
Unusual Fire And Expl Hazrds: CYLINDERS MAY RUPTURE.
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Reactivity Data
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Stability: YES
Cond To Avoid (Stability): HIGH TEMPERATURES, OPEN FLAMES
Materials To Avoid: ALKALI OR ALKALINE EARTH METALS, POWDERED ALUMINUM,
ZINC, BERYLLIUM (BE), AMMONIA, CARBON MONOXIDE, HYDROGEN, PHOSPHINE
Hazardous Decomp Products: MAY FORM HYDROGEN FLUORIDE, POSSIBLY CARBONYL
FLUORIDE AND NITROGEN OXIDES.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
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Health Hazard Data
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LD50-LC50 Mixture: LD50(ORAL,RAT)>15000MG/KG(NITROUS OXIDE)
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: NO
Route Of Entry - Ingestion: NO
Health Haz Acute And Chronic: TARGET ORGANS:EYE, SKIN, CNS, RESPIRATORY
TRACT, HEART. ACUTE- OVEREXPOSURE BY INHALATION TO VERY HIGH CONCENTRATIONS
MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS/DEATH. DELIBERATE
INHALATION MAY CAUSE DEATH WITHOUT WARNING. LIQUID CONTACT CAN CAUSE EYE
AND SKIN FROSTBITE. INGESTION IS NOT LIKELY (GAS). CHRONIC- UNK
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NONE
Signs/Symptoms Of Overexp: HEADACHE, WEAKNESS, NAUSEA, DIZZINESS,
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 2 OF 4
REFRIGERANT 116 MSDS
CONFUSION, INCOORDINATION, LUNG IRRITATION, COUGH, DISCOMFORT, SHORTNESS OF
BREATH, IRREGULAR PULSE, FROSTBITE, ASPHYXIATION, HEART IRREGULARITIES,
UNCONSCIOUSNESS, DEATH, BLINDNESS
Med Cond Aggravated By Exp: INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE
CENTRAL NERVOUS SYSTEM OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED
SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.
Emergency/First Aid Proc: GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.
EYES:IMMEDIATELY FLUSH WITH WARM WATER FOR 15 MINUTES. CALL PHYSICIAN.
INHALED:MOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED. SKIN:TREAT FOR
POSSIBLE FROSTBITE USING WARM WATER (105F), THEN FLUSH SKIN WITH PLENTY OF
WATER. ORAL:UNLIKELY TO OCCUR. NOTE TO PHYSICIAN:CATECHOLAMINE DRUGS SHOULD
BE USED WITH SPECIAL CAUTION ONLY IN EMERGENCY LIFE SUPPORT.
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Precautions for Safe Handling and Use
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Steps If Matl Released/Spill: WEAR PROTECTIVE EQUIPMENTS. REMOVE OPEN
FLAMES. VENTILATE AREA ESPECIALLY LOW OR ENCLOSED PLACES WHERE HEAVY VAPORS
MIGHT COLLECT. WEAR SELF CONTAINED BREATHING APPARATUS.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Method: RECLAIM BY DISTILLATION, INCINERATE OR REMOVE TO A
PERMITTED WASTE FACILITY. COMPLY WITH LOCAL, STATE AND FEDERAL REGULATIONS.
Precautions-Handling/Storing: STORE IN COOL, VENTILATED, DRY AREA AWAY
FROM OPEN FLAMES AND INCOMPATIBLE MATERIALS. AVOID TEMPERATURES ABOVE 125 F
(52C).
Other Precautions: AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH
AFTEER HANDLING AND BEFORE EATING OR DRINKING. USE WITH ADEQUATE
VENTILATION. KEEP OUT OF REACH OF CHILDREN.
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Control Measures
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Respiratory Protection: NOT NORMALLY REQUIRED. WEAR NIOSH-APPROVED SELF-
CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR
SUPPLIED-AIR RESPIRATOR IF A LARGE RELEASE OCCURS.
Ventilation: MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO
MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves: LINED BUTYL WHEN HANDLING LIQUID
Eye Protection: CHEMICAL SPLASH GOGGLES WHEN HANDLE LIQ.
Other Protective Equipment: EYEBATH, SAFETY SHOWER, PROTECTIVE CLOTHING
Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Suppl. Safety & Health Data: FORMULA CHANGED. FOR PREVIOUS FORMULATION,
SEE PNI A, SAME NSN. LC50 FOR FREON 116 >800,000 PPM IN RATS (INHALATION 4-
HOUR).
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Transportation Data
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Trans Data Review Date: 97308
DOT PSN Code: DQQ
DOT Proper Shipping Name: COMPRESSED GASES, N.O.S.
DOT Class: 2.2
DOT ID Number: UN1956
DOT Label: NONFLAMMABLE GAS
DOT/DoD Exemption Number: NOT RELEVANT
IMO PSN Code: EQH
IMO Proper Shipping Name: COMPRESSED GAS, N.O.S. o
IMO Regulations Page Number: 2124
IMO UN Number: 1956
IMO UN Class: 2(2.2)
IMO Subsidiary Risk Label: -
IATA PSN Code: HDO
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 3 OF 4
REFRIGERANT 116 MSDS
IATA UN ID Number: 1956
IATA Proper Shipping Name: COMPRESSED GAS, N.O.S. *
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
AFI PSN Code: HDO
AFI Symbols: *
AFI Prop. Shipping Name: COMPRESSED GAS, N.O.S.
AFI Class: 2.2
AFI ID Number: UN1956
AFI Special Prov: P5
AFI Basic Pac Ref: A6.3, A6.5,A6.6
N.O.S. Shipping Name: CONTAINS HEXAFLUOROETHANE (FREON 116) AND NITROUS
OXIDE.
Additional Trans Data: PROPER SHIPPING NAME, UN ID NUMBER, HAZARD CLASS,
PER MSDS.
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Disposal Data
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Label Data
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Label Required: YES
Technical Review Date: 04NOV97
MFR Label Number: UNKNOWN
Label Status: F
Common Name: FREON 116 REFRIGERANT/NITROUS OXIDE BLEND 90/10
Signal Word: WARNING!
Acute Health Hazard-Moderate: X
Contact Hazard-Moderate: X
Fire Hazard-None: X
Reactivity Hazard-None: X
Special Hazard Precautions: TARGET ORGANS:EYE, SKIN, CNS, RESPIRATORY
TRACT, HEART. ACUTE- INHALATION TO HIGH CONCENTRATIONS MAY CAUSE HEART
IRREGULARITIES, UNCONSCIOUSNESS/DEATH. LIQUID CONTACT CAN CAUSE EYE/SKIN
FROSTBITE. INGESTION IS NOT LIKELY. CHRONIC- UNKNOWN. STORE IN COOL,
VENTILATED AREA AWAY FROM OPEN FLAMES & INCOMPATIBLES. IF LEAKING,
FLUSH WITH WARM WATER FOR 15 MINUTES. CALL PHYSICIAN. INHALED:MOVE TO FRESH
AIR. PROVIDE OXYGEN/CPR IF NEEDED. SKIN:TREAT FOR POSSIBLE FROSTBITE USING
WARM WATER (105F), THEN FLUSH SKIN WITH PLENTY OF WATER. ORAL:UNLIKELY TO
OCCUR.
Label Name: E I DUPONT DE NEMOURS & CO, FREON PROD
Label Street: 1007 MARKET ST
Label City: WILMINGTON
Label State: DE
Label Zip Code: 19899
Label Country: US
Label Emergency Number: 800-441-3637/800-424-9300(CHEMTREC)
SIWS PROVIDES MSDS AS A COURTISY. TO ENSURE ACCURATE AND CURRENT DATA, OBTAIN AND USE ONLY MSDS FROM MANUFACTURER. PAGE 4 OF 4
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