Conforms to ANSI Z400.5-2004 Standard (United States, Canada, Mexico).
Material Safety Data Sheet
55000 Adhesive
1. Product and company identification
55000 Adhesive
Product name :
NK
Synonym :
Rubber/ Solvent Solution.
Material uses :
Fenner Dunlop
Supplier/Manufacturer :
146 South Westwood
P. O. Box 441
Toledo, OH 43697
Tel : (419) 534 5300 ext. 324
Fax : (419) 531-6284
Email : Dan.hoca@fennerdunlop.com
55000
Code :
KMK Regulatory Services inc.
MSDS authored by :
CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887
In case of emergency :
Liquid.
Product type :
2. Hazards identification
Emergency overview
Black.
Color :
Liquid.
Physical state :
Solvent. [Slight]
Odor :
WARNING!
Signal word :
FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSES
Hazard statements :
RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION. MAY BE HARMFUL IF ABSORBED
THROUGH SKIN. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS
AND CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN
DAMAGE. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE
CANCER. BIRTH DEFECT HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE
BIRTH DEFECTS.
: Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions
Precautions
before use. Do not breathe vapor or mist. Do not ingest. Do not get in eyes or on skin
or clothing. Avoid exposure during pregnancy. Use only with adequate ventilation.
Keep container tightly closed and sealed until ready for use. Wash thoroughly after
handling.
: This material is considered hazardous by the OSHA Hazard Communication Standard
OSHA/HCS status
(29 CFR 1910.1200).
: Dermal contact. Eye contact. Inhalation. Ingestion.
Routes of entry
Potential acute health effects
: Harmful by inhalation. Irritating to respiratory system. May cause sensitization by
Inhalation
inhalation.
: Toxic if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.
Ingestion
: Irritating to skin. May cause sensitization by skin contact. May be harmful if absorbed
Skin
through skin.
: Irritating to eyes.
Eyes
Potential chronic health effects
: Contains material that can cause target organ damage. Once sensitized, a severe
Chronic effects
allergic reaction may occur when subsequently exposed to very low levels.
: Contains material which can cause cancer. Risk of cancer depends on duration and
Carcinogenicity
level of exposure.
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
1/13
www.kmkregservices.com
55000 Adhesive
2. Hazards identification
No known significant effects or critical hazards.
Mutagenicity :
Contains material which can cause birth defects.
Teratogenicity :
No known significant effects or critical hazards.
Developmental effects :
No known significant effects or critical hazards.
Fertility effects :
Contains material which may cause damage to the following organs: blood, kidneys,
Target organs :
lungs, liver, mucous membranes, spleen, peripheral nervous system, cardiovascular
system, upper respiratory tract, skin, eyes, central nervous system (CNS).
Over-exposure signs/symptoms
: Adverse symptoms may include the following:
Inhalation
respiratory tract irritation
coughing
wheezing and breathing difficulties
asthma
: Adverse symptoms may include the following:
Ingestion
nausea or vomiting
: Adverse symptoms may include the following:
Skin
irritation
redness
: Adverse symptoms may include the following:
Eyes
pain or irritation
watering
redness
: Pre-existing respiratory and skin disorders and disorders involving any other target
Medical conditions
organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to
aggravated by over-
this product.
exposure
See toxicological information (section 11)
3. Composition/information on ingredients
United States
Name CAS number %
Toluene 108-88-3 30 - 60
Methyl ethyl ketone 78-93-3 10 - 30
Solvent naphtha (petroleum), light arom. 64742-95-6 5 - 10
1,2,4-Trimethylbenzene 95-63-6 5 - 10
Resorcinol 108-46-3 1-5
Methenamine 100-97-0 1-5
Trilead dioxide phosphonate 12141-20-7 1-5
Selenium 7782-49-2 1-5
Carbon black 1333-86-4 1-5
Mesitylene 108-67-8 1-5
Naphtha (petroleum), hydrotreated heavy 64742-48-9 1-5
Epichlorhydrin 106-89-8 0.1 - 1
Canada
Name CAS number %
Toluene 108-88-3 30 - 60
Methyl ethyl ketone 78-93-3 10 - 30
Solvent naphtha (petroleum), light arom. 64742-95-6 5 - 10
1,2,4-Trimethylbenzene 95-63-6 5 - 10
Resorcinol 108-46-3 1-5
Methenamine 100-97-0 1-5
Trilead dioxide phosphonate 12141-20-7 1-5
Selenium 7782-49-2 1-5
Carbon black 1333-86-4 1-5
Mesitylene 108-67-8 1-5
Naphtha (petroleum), hydrotreated heavy 64742-48-9 1-5
Epichlorhydrin 106-89-8 0.1 - 1
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
2/13
www.kmkregservices.com
55000 Adhesive
3. Composition/information on ingredients
Mexico Classification
Name CAS number UN number % IDLH H F R Special
Toluene 108-88-3 UN1294 30 - 60 500 ppm 2 3 1
Methyl ethyl ketone 78-93-3 UN1193 10 - 30 3000 ppm 2 3 0
Solvent naphtha (petroleum), light 64742-95-6 UN1268 5 - 10 - 1 1 0
arom.
1,2,4-Trimethylbenzene 95-63-6 UN1993 5 - 10 - 2 2 0
Resorcinol 108-46-3 UN2876 1-5 - 2 1 0
Methenamine 100-97-0 UN1328 1-5 - 2 3 0
Carbon black 1333-86-4 Not regulated. 1-5 1750 mg/m? 2 0 0
Trilead dioxide phosphonate 12141-20-7 Not regulated. 1-5 100 mg/m? 0 0 0
Selenium 7782-49-2 Not regulated. 1-5 1 mg/m? 0 0 0
Mesitylene 108-67-8 UN2325 1-5 - 0 2 0
Naphtha (petroleum), hydrotreated 64742-48-9 UN1268 1-5 - 0 1 0
heavy
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in
this section.
4. First aid measures
: Immediately flush eyes with plenty of water for at least 20 minutes, occasionally lifting
Eye contact
the upper and lower eyelids. Get medical attention.
: In case of contact, immediately flush skin with plenty of water for at least 20 minutes.
Skin contact
Get medical attention.
: Move exposed person to fresh air. If not breathing, if breathing is irregular or if
Inhalation
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Call medical doctor or poison control center immediately.
: Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
Ingestion
personnel. Never give anything by mouth to an unconscious person. Call medical
doctor or poison control center immediately.
: No action shall be taken involving any personal risk or without suitable training. If it is
Protection of first-aiders
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
: Contact poison treatment specialist immediately if large quantities have been ingested or
Notes to physician
inhaled.
5. Fire-fighting measures
: Flammable liquid.
Flammability of the product
Extinguishing media
: Use dry chemical, CO2, water spray (fog) or foam.
Suitable
: Do not use water jet.
Not suitable
: This material is harmful to aquatic organisms. Fire water contaminated with this material
Special exposure hazards
must be contained and prevented from being discharged to any waterway, sewer or
drain.
: Decomposition products may include the following materials:
Hazardous decomposition
carbon dioxide
products
carbon monoxide
nitrogen oxides
phosphorus oxides
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
Special protective
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
3/13
www.kmkregservices.com
55000 Adhesive
6. Accidental release measures
: Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not
Personal precautions
breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Put on appropriate personal protective equipment (see section
8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
Environmental precautions
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods for cleaning up
: Stop leak if without risk. Prevent entry into sewers, water courses, basements or
Spill
confined areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see section 13). Use spark-proof tools and explosion-proof equipment.
Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilled product. Note: see section 1 for emergency
contact information and section 13 for waste disposal.
7. Handling and storage
: Put on appropriate personal protective equipment (see section 8). Persons with a history
Handling
of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory
disease should not be employed in any process in which this product is used. Avoid
exposure during pregnancy. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.
Take precautionary measures against electrostatic discharges. To avoid fire or
explosion, dissipate static electricity during transfer by grounding and bonding containers
and equipment before transferring material. Empty containers retain product residue
and can be hazardous. Do not reuse container.
: Store in accordance with local regulations. Store in a segregated and approved area.
Storage
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
8. Exposure controls/personal protection
United States
Ingredient Exposure limits
Toluene NIOSH REL (United States, 6/2008).
STEL: 560 mg/m?15 minute(s).
STEL: 150 ppm 15 minute(s).
TWA: 375 mg/m?10 hour(s).
TWA: 100 ppm 10 hour(s).
OSHA PEL Z2 (United States, 11/2006).
AMP: 500 ppm 10 minute(s).
CEIL: 300 ppm
TWA: 200 ppm 8 hour(s).
ACGIH TLV (United States, 1/2009).
TWA: 20 ppm 8 hour(s).
Methyl ethyl ketone ACGIH TLV (United States, 1/2009).
STEL: 885 mg/m?15 minute(s).
STEL: 300 ppm 15 minute(s).
TWA: 590 mg/m?8 hour(s).
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
4/13
www.kmkregservices.com
55000 Adhesive
8. Exposure controls/personal protection
TWA: 200 ppm 8 hour(s).
NIOSH REL (United States, 6/2008).
STEL: 885 mg/m?15 minute(s).
STEL: 300 ppm 15 minute(s).
TWA: 590 mg/m?10 hour(s).
TWA: 200 ppm 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 590 mg/m?8 hour(s).
TWA: 200 ppm 8 hour(s).
Solvent naphtha (petroleum), light arom. Manufacturer (United States).
TWA: 40 ppm 8 hour(s).
1,2,4-Trimethylbenzene ACGIH TLV (United States, 1/2009).
TWA: 123 mg/m?8 hour(s).
TWA: 25 ppm 8 hour(s).
NIOSH REL (United States, 6/2008).
TWA: 125 mg/m?10 hour(s).
TWA: 25 ppm 10 hour(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 25 ppm 8 hour(s).
TWA: 125 mg/m?8 hour(s).
Resorcinol ACGIH TLV (United States, 1/2009).
STEL: 90 mg/m?15 minute(s).
STEL: 20 ppm 15 minute(s).
TWA: 45 mg/m?8 hour(s).
TWA: 10 ppm 8 hour(s).
NIOSH REL (United States, 6/2008).
STEL: 90 mg/m?15 minute(s).
STEL: 20 ppm 15 minute(s).
TWA: 45 mg/m?10 hour(s).
TWA: 10 ppm 10 hour(s).
OSHA PEL 1989 (United States, 3/1989).
STEL: 90 mg/m?15 minute(s).
STEL: 20 ppm 15 minute(s).
TWA: 45 mg/m?8 hour(s).
TWA: 10 ppm 8 hour(s).
Trilead dioxide phosphonate ACGIH TLV (United States, 1/2009).
TWA: 0.05 mg/m? (Pb) 8 hour(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ug/m? (Pb) 8 hour(s).
Selenium ACGIH TLV (United States, 1/2009).
TWA: 0.2 mg/m? (Se) 8 hour(s).
NIOSH REL (United States, 6/2008).
TWA: 0.2 mg/m? (Se) 10 hour(s).
Carbon black ACGIH TLV (United States, 1/2009).
TWA: 3.5 mg/m?8 hour(s).
NIOSH REL (United States, 6/2008).
TWA: 3.5 mg/m?10 hour(s).
TWA: 0.1 mg of PAHs/cm?10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 3.5 mg/m?8 hour(s).
Mesitylene ACGIH TLV (United States, 1/2009).
TWA: 123 mg/m?8 hour(s).
TWA: 25 ppm 8 hour(s).
NIOSH REL (United States, 6/2008).
TWA: 125 mg/m?10 hour(s).
TWA: 25 ppm 10 hour(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 25 ppm 8 hour(s).
TWA: 125 mg/m?8 hour(s).
Naphtha (petroleum), hydrotreated heavy ACGIH TLV (United States).
TWA: 300 ppm 8 hour(s).
Epichlorhydrin ACGIH TLV (United States, 1/2009). Absorbed through skin.
TWA: 1.9 mg/m?8 hour(s).
TWA: 0.5 ppm 8 hour(s).
OSHA PEL (United States, 11/2006). Absorbed through skin.
TWA: 19 mg/m?8 hour(s).
TWA: 5 ppm 8 hour(s).
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
5/13
www.kmkregservices.com
55000 Adhesive
8. Exposure controls/personal protection
Canada
TWA (8 hours) STEL (15 mins) Ceiling
Occupational exposure limits
Ingredient List name ppm mg/m?Other ppm mg/m?Other ppm mg/m?Other Notations
Toluene US ACGIH 1/2009 20 - - - - - - - -
AB 6/2008 50 188 - - - - - - - [1]
BC 6/2008 20 - - - - - - - -
ON 6/2008 50 - - - - - - - -
QC 6/2008 50 188 - - - - - - - [1]
Methyl ethyl ketone US ACGIH 1/2009 200 590 - 300 885 - - - -
AB 6/2008 200 590 - 300 885 - - - -
BC 6/2008 50 - - 100 - - - - -
ON 6/2008 200 590 - 300 885 - - - -
QC 6/2008 50 150 - 100 300 - - - -
1,2,4-Trimethylbenzene US ACGIH 1/2009 25 123 - - - - - - -
AB 6/2008 25 123 - - - - - - -
BC 6/2008 25 - - - - - - - -
ON 6/2008 25 123 - - - - - - -
QC 6/2008 25 123 - - - - - - -
Resorcinol US ACGIH 1/2009 10 45 - 20 90 - - - -
AB 6/2008 10 45 - 20 90 - - - -
BC 6/2008 10 - - 20 - - - - -
ON 6/2008 10 45 - 20 90 - - - -
QC 6/2008 10 45 - 20 90 - - - -
Methenamine ON 6/2008 - - - 0.35 2 - - - -
Trilead dioxide phosphonate, Pb US ACGIH 1/2009 - 0.05 - - - - - - -
AB 6/2008 - 0.05 - - - - - - -
BC 6/2008 - 0.05 - - - - - - -
QC 6/2008 - 0.05 - - - - - - -
Selenium, Se US ACGIH 1/2009 - 0.2 - - - - - - -
AB 6/2008 - 0.2 - - - - - - -
BC 6/2008 - 0.1 - - - - - - -
ON 6/2008 - 0.2 - - - - - - -
QC 6/2008 - 0.2 - - - - - - -
Carbon black US ACGIH 1/2009 - 3.5 - - - - - - -
AB 6/2008 - 3.5 - - - - - - -
BC 6/2008 - 3.5 - - - - - - -
ON 6/2008 - 3.5 - - - - - - -
QC 6/2008 - 3.5 - - - - - - -
Mesitylene US ACGIH 1/2009 25 123 - - - - - - -
AB 6/2008 25 123 - - - - - - -
BC 6/2008 25 - - - - - - - -
ON 6/2008 25 123 - - - - - - -
QC 6/2008 25 123 - - - - - - -
Naphtha (petroleum), hydrotreated US ACGIH 300 - - - - - - - -
heavy
Epichlorhydrin US ACGIH 1/2009 0.5 1.9 - - - - - - - [1]
AB 6/2008 0.5 1.9 - - - - - - - [1]
BC 6/2008 0.1 - - - - - - - - [1]
ON 6/2008 0.5 - - - - - - - - [1]
QC 6/2008 2 7.6 - - - - - - - [1]
[1]Absorbed through skin.
Mexico
Ingredient Exposure limits
Toluene NOM-010-STPS (Mexico, 9/2000). Absorbed through skin.
LMPE-PPT: 188 mg/m?8 hour(s).
LMPE-PPT: 50 ppm 8 hour(s).
Methyl ethyl ketone NOM-010-STPS (Mexico, 9/2000).
LMPE-CT: 885 mg/m?15 minute(s).
LMPE-CT: 300 ppm 15 minute(s).
LMPE-PPT: 590 mg/m?8 hour(s).
LMPE-PPT: 200 ppm 8 hour(s).
1,2,4-Trimethylbenzene NOM-010-STPS (Mexico, 9/2000).
LMPE-CT: 170 mg/m?15 minute(s).
LMPE-CT: 35 ppm 15 minute(s).
LMPE-PPT: 125 mg/m?8 hour(s).
LMPE-PPT: 25 ppm 8 hour(s).
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
6/13
www.kmkregservices.com
55000 Adhesive
8. Exposure controls/personal protection
Resorcinol NOM-010-STPS (Mexico, 9/2000).
LMPE-CT: 90 mg/m?15 minute(s).
LMPE-CT: 20 ppm 15 minute(s).
LMPE-PPT: 45 mg/m?8 hour(s).
LMPE-PPT: 10 ppm 8 hour(s).
Trilead dioxide phosphonate NOM-010-STPS (Mexico, 9/2000).
LMPE-PPT: 0.15 mg/m? (as Pb) 8 hour(s). Form: powder and smoke
Selenium ACGIH TLV (United States, 1/2009).
TWA: 0.2 mg/m? (Se) 8 hour(s).
Carbon black NOM-010-STPS (Mexico, 9/2000).
LMPE-CT: 7 mg/m?15 minute(s). Form: smoke
LMPE-PPT: 3.5 mg/m?8 hour(s). Form: smoke
Mesitylene NOM-010-STPS (Mexico, 9/2000).
LMPE-CT: 170 mg/m?15 minute(s).
LMPE-CT: 35 ppm 15 minute(s).
LMPE-PPT: 125 mg/m?8 hour(s).
LMPE-PPT: 25 ppm 8 hour(s).
Naphtha (petroleum), hydrotreated heavy ACGIH TLV (United States).
TWA: 300 ppm 8 hour(s).
Consult local authorities for acceptable exposure limits.
: Personal, workplace atmosphere or biological monitoring may be required to determine
Recommended monitoring
the effectiveness of the ventilation or other control measures and/or the necessity to use
procedures
respiratory protective equipment.
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
Engineering measures
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor
or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.
: Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
: Respirator selection must be based on known or anticipated exposure levels, the
Respiratory
hazards of the product and the safe working limits of the selected respirator.
Recommended: Wear an appropriate NIOSH approved respirator if concentration levels
exceed the safe exposure limits.
: Use gloves appropriate for work or task being performed. Recommended: Natural
Hands
rubber (latex).
: Safety eyewear should be used when there is a likelihood of exposure. Recommended:
Eyes
Safety glasses with side shields.
: Personal protective equipment for the body should be selected based on the task being
Skin
performed and the risks involved and should be approved by a specialist before handling
this product. Recommended: Lab coat.
: Emissions from ventilation or work process equipment should be checked to ensure they
Environmental exposure
comply with the requirements of environmental protection legislation. In some cases,
controls
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
9. Physical and chemical properties
Liquid.
Physical state :
Closed cup: -4癈 (24.8癋) [Pensky-Martens.]
Flash point :
Black.
Color :
Solvent. [Slight]
Odor :
0.97 g/cm3
Specific gravity :
2.5 [Air = 1]
Vapor density :
73 to 78% (v/v)
Volatility :
2.8 (butyl acetate = 1)
Evaporation rate :
Insoluble in the following materials: cold water and hot water.
Solubility :
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
7/13
www.kmkregservices.com
55000 Adhesive
10. Stability and reactivity
: The product is stable.
Chemical stability
: Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
Conditions to avoid
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas. Avoid exposure - obtain special
instructions before use. Avoid exposure during pregnancy. Do not swallow.
: Reactive or incompatible with the following materials: oxidizing materials and acids.
Materials to avoid
: Under normal conditions of storage and use, hazardous decomposition products should
Hazardous decomposition
not be produced.
products
: Under normal conditions of storage and use, hazardous reactions will not occur.
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous polymerization will not occur.
Hazardous polymerization
11. Toxicological information
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Toluene LC50 Inhalation Vapor Rat 49 g/m3 4 hours
LD50 Oral Rat 636 mg/kg -
Methyl ethyl ketone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
Solvent naphtha (petroleum), light LD50 Oral Rat 8400 mg/kg -
arom.
1,2,4-Trimethylbenzene LC50 Inhalation Vapor Rat 18000 mg/m3 4 hours
LD50 Oral Rat 5 g/kg -
Resorcinol LD50 Dermal Rabbit 3360 mg/kg -
LD50 Oral Rat 301 mg/kg -
Selenium LD50 Oral Rat 6700 mg/kg -
Carbon black LD50 Dermal Rabbit >3 g/kg -
LD50 Oral Rat >15400 mg/kg -
Mesitylene LC50 Inhalation Vapor Rat 24000 mg/m3 4 hours
LD50 Oral Rat 5000 mg/kg -
Epichlorhydrin LD50 Dermal Rabbit 515 mg/kg -
LD50 Oral Rat 90 mg/kg -
Chronic toxicity
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
Toluene A4 3 - - - -
Resorcinol A4 3 - - - -
Trilead dioxide phosphonate A3 - - - Possible -
Selenium - 3 - - - -
Carbon black A4 2B - + - -
Epichlorhydrin A3 2A - + Possible -
12. Ecological information
: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
Environmental effects
environment.
Aquatic ecotoxicity
Product/ingredient name Result Species Exposure
Toluene Acute EC50 6000 ug/L Fresh water Daphnia - Daphnia magna - Juvenile 48 hours
(Fledgling, Hatchling, Weanling)
Acute LC50 15.5 ppm Marine water Crustaceans - Palaemonetes pugio - 48 hours
Adult
Acute LC50 5500 ug/L Fresh water Fish - Oncorhynchus kisutch - FRY - 1 g 96 hours
Chronic NOEC 28000 ug/L Fresh water Daphnia - Daphnia magna - <=24 hours 48 hours
Methyl ethyl ketone Acute LC50 >520000 ug/L Fresh water Daphnia - Daphnia magna - <=24 hours 48 hours
Acute LC50 >400 ppm Marine water Fish - Cyprinodon variegatus - Juvenile 96 hours
(Fledgling, Hatchling, Weanling) - 8 to 15
mm
Chronic NOEC <70000 ug/L Fresh water Daphnia - Daphnia magna - <=24 hours 48 hours
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
8/13
www.kmkregservices.com
55000 Adhesive
12. Ecological information
Chronic NOEC 400 ppm Marine water Fish - Cyprinodon variegatus - Juvenile 96 hours
(Fledgling, Hatchling, Weanling) - 8 to 15
mm
1,2,4-Trimethylbenzene Acute LC50 17000 ug/L Marine water Crustaceans - Cancer magister - Zoea 48 hours
Acute LC50 7720 to 8280 ug/L Fresh water Fish - Pimephales promelas - 34 days 96 hours
Resorcinol Acute LC50 78000 to 106500 ug/L Marine water Crustaceans - Palaemonetes pugio 48 hours
Acute LC50 >100000 ug/L Fresh water Daphnia - Daphnia pulicaria 48 hours
Acute LC50 40000 ug/L Fresh water Fish - Pimephales promelas - Juvenile 96 hours
(Fledgling, Hatchling, Weanling) - 0.2 to
0.5 g
Methenamine Acute EC50 36000000 to 43390000 ug/L Fresh Daphnia - Daphnia magna - 1 to 3 days 48 hours
water
Acute LC50 >10000000 ug/L Marine water Fish - Alburnus alburnus - 8 cm 96 hours
Selenium Acute LC50 430 to 570 ug/L Fresh water Daphnia - Daphnia magna - <=24 hours 48 hours
Acute LC50 1000 to 1200 ug/L Fresh water Fish - Pimephales promelas - FRY - 25 to 96 hours
35 days - 17 mm - 0.03 g
Chronic NOEC 220 ug/L Fresh water Daphnia - Daphnia magna - <=24 hours 48 hours
Chronic NOEC 2 ppm Marine water Fish - Cyprinodon variegatus - Juvenile 96 hours
(Fledgling, Hatchling, Weanling) - 8 to 15
mm
Mesitylene Acute LC50 13000 ug/L Marine water Crustaceans - Cancer magister - Zoea 48 hours
Acute LC50 12520 to 15050 ug/L Fresh water Fish - Carassius auratus - 1 to 1.5 years - 96 hours
13 to 20 cm - 20 to 80 g
Epichlorhydrin Acute LC50 21000 to 22800 ug/L Fresh water Daphnia - Daphnia magna - Neonate 48 hours
Acute LC50 10600 to 12300 ug/L Fresh water Fish - Pimephales promelas - Juvenile 96 hours
(Fledgling, Hatchling, Weanling) - 30 to 35
days - 14.9 mm - 76.8 mg
: No known significant effects or critical hazards.
Other adverse effects
13. Disposal considerations
: The generation of waste should be avoided or minimized wherever possible. This
Waste disposal
material and its container must be disposed of in a safe way. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers. Empty
containers or liners may retain some product residues. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.
14 . Transport information
Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
UN1133 ADHESIVES (Containing a 3 II -
DOT Classification
flammable liquid)
UN1133 ADHESIVES (Containing a 3 II -
TDG Classification
flammable liquid)
UN1133 ADHESIVES (Containing a 3 II -
Mexico
flammable liquid)
Classification
UN1133 ADHESIVES (Containing a 3 II -
IMDG Class
flammable liquid)
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
9/13
www.kmkregservices.com
55000 Adhesive
14 . Transport information
UN1133 ADHESIVES (Containing a 3 II -
IATA-DGR Class
flammable liquid)
PG* : Packing group AERG : 128
Exemption to the above classification may apply.
15 . Regulatory information
United States
: Flammable liquid
HCS Classification
Toxic material
Irritating material
Sensitizing material
Carcinogen
Target organ effects
: United States inventory (TSCA 8b): All components are listed or exempted.
U.S. Federal regulations
TSCA 8(d) H and S data reporting: Trilead dioxide phosphonate: 2008
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Toluene; Methyl ethyl ketone; 1,2,4-
Trimethylbenzene; Resorcinol; Selenium; Methenamine; Carbon black; Mesitylene
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Toluene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard;
Methyl ethyl ketone: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)
health hazard; 1,2,4-Trimethylbenzene: Fire hazard, Delayed (chronic) health hazard;
Resorcinol: Immediate (acute) health hazard, Delayed (chronic) health hazard;
Selenium: Immediate (acute) health hazard, Delayed (chronic) health hazard;
Methenamine: Fire hazard, Immediate (acute) health hazard; Carbon black: Immediate
(acute) health hazard, Delayed (chronic) health hazard; Mesitylene: Fire hazard,
Immediate (acute) health hazard
Clean Water Act (CWA) 307: Toluene; Trilead dioxide phosphonate; Selenium
Clean Water Act (CWA) 311: Toluene; Resorcinol
Clean Air Act (CAA) 112 accidental release prevention: Epichlorhydrin
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: Epichlorhydrin
: Listed
Clean Air Act Section
112(b) Hazardous Air
Pollutants (HAPs)
: Not listed
Clean Air Act Section 602
Class I Substances
: Not listed
Clean Air Act Section 602
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Listed
DEA List II Chemicals
(Essential Chemicals)
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
10/13
www.kmkregservices.com
55000 Adhesive
15 . Regulatory information
SARA 313
Product name CAS number Concentration
: Toluene 108-88-3 30 - 60
Form R - Reporting
Methyl ethyl ketone 78-93-3 10 - 30
requirements
1,2,4-Trimethylbenzene 95-63-6 5 - 10
Trilead dioxide phosphonate 12141-20-7 1-5
Selenium 7782-49-2 1-5
Epichlorhydrin 106-89-8 0.1 - 1
: Toluene 108-88-3 30 - 60
Supplier notification
Methyl ethyl ketone 78-93-3 10 - 30
1,2,4-Trimethylbenzene 95-63-6 5 - 10
Trilead dioxide phosphonate 12141-20-7 1-5
Selenium 7782-49-2 1-5
Epichlorhydrin 106-89-8 0.1 - 1
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
: Connecticut Carcinogen Reporting: None of the components are listed.
State regulations
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components are
listed.
Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: Toluene; Methyl
ethyl ketone; 1,2,4-Trimethylbenzene; Resorcinol; Selenium; Carbon black; Mesitylene
Michigan Critical Material: None of the components are listed.
Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: The following components are listed: Toluene;
Methyl ethyl ketone; 1,2,4-Trimethylbenzene; Resorcinol; Methenamine; Trilead dioxide
phosphonate; Selenium; Carbon black; Mesitylene; Epichlorhydrin
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: The following components are listed:
Toluene; Methyl ethyl ketone; Resorcinol; Selenium; Epichlorhydrin
New York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: The following components are listed:
Toluene; Methyl ethyl ketone; 1,2,4-Trimethylbenzene; Resorcinol; Trilead dioxide
phosphonate; Selenium; Carbon black; Mesitylene; Epichlorhydrin
Rhode Island Hazardous Substances: None of the components are listed.
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
Toluene No. Yes. No. 7000 g/day
(ingestion)
13000 g/day
(inhalation)
Trilead dioxide phosphonate Yes. No. No. No.
Carbon black Yes. No. No. No.
Epichlorhydrin Yes. Yes. Yes. No.
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
11/13
www.kmkregservices.com
55000 Adhesive
15 . Regulatory information
Canada
: Class B-2: Flammable liquid
WHMIS (Canada)
Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
: CEPA Toxic substances: None of the components are listed.
Canadian lists
Canadian ARET: None of the components are listed.
Canadian NPRI: The following components are listed: Toluene; Methyl ethyl ketone;
Solvent naphtha (petroleum), light arom.; 1,2,4-Trimethylbenzene; Trilead dioxide
phosphonate; Selenium; Mesitylene; Naphtha (petroleum), hydrotreated heavy
Alberta Designated Substances: None of the components are listed.
Ontario Designated Substances: None of the components are listed.
Quebec Designated Substances: None of the components are listed.
: All components are listed or exempted.
Canada inventory
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
Mexico
Classification :
Flammability
3
2 0
Health Instability
Special
International regulations
: Australia inventory (AICS): All components are listed or exempted.
International lists
China inventory (IECSC): All components are listed or exempted.
Japan inventory: Not determined.
Korea inventory: All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
: Not listed
Chemical Weapons
Convention List Schedule I
Chemicals
: Not listed
Chemical Weapons
Convention List Schedule
II Chemicals
: Not listed
Chemical Weapons
Convention List Schedule
III Chemicals
16 . Other information
United States
: FLAMMABLE LIQUID AND VAPOR. HARMFUL IF INHALED. CAUSES
Label requirements
RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION. MAY BE HARMFUL IF ABSORBED
THROUGH SKIN. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS
AND CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN
DAMAGE. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE
CANCER. BIRTH DEFECT HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE
BIRTH DEFECTS.
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
12/13
www.kmkregservices.com
55000 Adhesive
16 . Other information
Hazardous Material :
Information System (U.S.A.)
* 2
Health
3
Flammability
0
Physical hazards
Caution: HMIS?ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS?ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS?ratings are to be used with a fully implemented
HMIS?program. HMIS?is a registered mark of the National Paint & Coatings Association (NPCA). HMIS?br>
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection :
Association (U.S.A.)
Flammability
3
2 0
Health Instability
Special
Canada
WHMIS (Canada) :
: 11/15/2009
Date of issue
: 11/30/2006
Date of previous issue
:2
Version
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
www.askdrluc.com www.kmkregservices.com www.ghssmart.com
www.askdrluc.com www.kmkregservices.com www.ghssmart.com
www.askdrluc.com www.kmkregservices.com www.ghssmart.com
Dr. Luc S間uin, PhD chemist, 25 years as Global - Multilingual authoring services Optimizing your company's GHS
a professional in regulatory compliance for all regulatory documents deployment
13/13
KMK Regulatory Services Inc. Tel : +1-888-GHS-7769 (447-7769)/+1-450-GHS-7767 (447-7767); Services R間lementaires KMK Inc.
www.kmkregservices.com
|