Material Safety Data Sheet
This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200
This product is CORROSIVE under the PESTICIDE PRODUCTS HCS CLASS: Corrosive liquid.
ACT Regulations. This product is Disinfectant Drug and is
therefore not regulated under WHMIS. Although the product
label is not regulated under WHMIS, this Material Safety Data
Sheet must be presented and maintained as a part of WHMIS
Compliance.
WHMIS (Pictograms) WHMIS (Classification) HCS
Section 1. Chemical Product and Company Identification
Product Name/ Stix Code
76
Trade name
Not applicable.
CAS #
Toilet Bowl/Porcelain/Shower Tile Cleaner
Synonym
Validation Date 3/2/2007
Not available.
Chemical Family
3/24/2007
Print Date
Chemical Formula Not applicable.
Chemtrec (800) 424-9300
In Case of
Manufacturer/ Supplier Betco Corporation Emergency
1001 Brown Avenue
Toledo, Oh 43607
(419) 241-2156
TSCA Inventory: All components listed or are exempt from listing.
TSCA
Protective Clothing
DSL/ NDSL All components listed unless noted elsewhere on this MSDS
Section 2. Composition and Information on Ingredients
Name CAS # Exposure Limits
% by LC50/LD50
Weight
Water 7732-18-5 70 - 85 Not available. Not available.
TWA: 1 mg/m 3
Phosphoric Acid 7664-38-2 20 Not available.
OSHA (United States).
TWA: 1 mg/m 3
STEL: 3 mg/m 3
Nonionic Surfactant 9016-45-9 0.69 Not available. Not available.
Benzaldehyde 100-52-7 0.06 Not available. Not available.
Quaternary Ammonium Chloride 68424-85-1 0.05 Not available. Not available.
Section 3. Hazards Identification
Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage
Potential Acute Health
particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may
Effects
produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract,
characterized by coughing, choking, or shortness of breath. Severe over-exposure can result
in death.
Potential Chronic Health Prolonged exposure may result in skin burns and ulcerations. Severe over-exposure can
produce lung damage, choking, unconsciousness or death.
Effects
Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Carcinogenic Effects
Section 4. First Aid Measures
Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove
Eye Contact
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison
control center or doctor immediately for treatment advice.
Remove contaminated clothing and shoes. Rinse skin with plenty of water for 15 to 20
Skin Contact
minutes. Call a poison control center or doctor for further treatment advice.
Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give
Inhalation
artificial respiration., preferably mouth to mouth if possible. Call a poison control center or
doctor for further treatment advice.
Call a poison control center immediately for treatment advice. Have person sip a glass of
Ingestion
water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison
control center or doctor. Do not give anything by mouth to an unconscious person
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric
lavage.
Section 5. Fire Fighting Measures
Not available.
Products of Combustion
N/A
Fire Fighting Media
and Instructions
N/A
Special Remarks on Fire
Hazards
N/A
Special Remarks on
Explosion Hazards
Section 6. Accidental Release Measures
Chemical anti-splash goggles.
Small Spill and Leak
Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill and Leak
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be
Personal Protection in
sufficient; consult a specialist BEFORE handling this product.
Case of a Large Spill
Section 7. Handling and Storage
Keep locked up. Keep container dry. Keep away from heat. Keep away from sources of
Precautions
ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground
all equipment containing material. DO NOT ingest. Do not breathe gas, fumes, vapor or
spray. Never add water to this product. Wear suitable protective clothing. If ingested, seek
medical advice immediately and show the container or the label.
Strong alkalis and oxidizers, reactive metals.
Incompatibility
Corrosive materials should be stored in a separate safety storage cabinet or room. Keep out
Storage
of the reach of children. Not for use or storage in or around the home.
Section 8. Exposure Controls/Personal Protection
Good general ventilation should be sufficient to control airborne levels.
Engineering Controls
Personal Protection
Eyes Splash goggles.
Body
Respiratory Not applicable.
Hands Gloves (impervious).
Protective Clothing
(Pictograms)
Phosphoric Acid
Exposure Limits
TWA: 1 (mg/m 3)
TWA: 1 (mg/m 3) from OSHA (PEL)
STEL: 3 (mg/m 3)
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Liquid.
Physical State and Pleasant. (Slight.)
Odor
Appearance
Taste Not available.
Not applicable.
Molecular Weight
Clear Pink (Light.)
Color
1.5 to 2 [Acidic.]
pH
88癈 (190.4癋)
Boiling/Condensation
Point
Not available.
Melting/Freezing Point
Not available.
Critical Temperature
Not available.
Instability Temperature
1.12 (Water = 1)
Specific Gravity
<20 mm of Hg (@ 20癈)
Vapor Pressure
>1 (Air = 1)
Vapor Density
Not available.
Volatility
Not available.
VOC
<1 compared to Water
Evaporation Rate
See solubility in water.
Dispersion Properties
Easily soluble in cold water.
Solubility
May be combustible at high temperature.
The Product is:
Not available.
Auto-ignition
Temperature
Not available.
Flash Points
Not available.
Flammable Limits
Fire Hazards in Presence No specific information is available in our database regarding the flammability of this product
in presence of various materials.
of Various Substances
Not applicable
Explosion Hazards in
Presence of Various
Substances
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Strong alkalis and oxidizers, reactive metals.
Incompatibility with
Various Substances
Hazardous Decomposition Will not occur.
Products
Section 11. Toxicological Information
Absorbed through skin. Eye contact. Inhalation. Ingestion.
Routes of Entry
Acute oral toxicity (LD50): 4610 mg/kg [Rat]. (Nonionic Surfactant).
Toxicity to Animals
Acute Effects on Humans
Eyes Severe eye irritant. Liquid or mist may burn or injure the eyes.
Skin Severe skin irritant. Prolonged or repeated contact can cause chemical burns or dermatitis.
Inhalation May be irritating to mucous membranes of the nose, throat, and lungs.
Ingestion May be irritating to the mouth and throat. Large doses can cause nausea and vomiting.
Prolonged exposure may result in skin burns and ulcerations. Severe over-exposure can
Chronic Effects on
produce lung damage, choking, unconsciousness or death.
Humans
No additional remark.
Special Remarks on
Toxicity to Animals
No additional remark.
Special Remarks on
Chronic Effects on
Humans
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term
Products of
degradation products may arise.
Biodegradation
Toxicity of the Products of Not available.
Biodegradation
No additional remark.
Special Remarks on the
Products of
Biodegradation
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control
Waste Information
regulations.
Not available.
Waste Stream
Section 14. Transport Information
DOT (U.S.A)
(Pictograms)
CORROSIVE
8
Class 8: Corrosive material
TDG Classification
8
PIN UN, Proper Shipping 1760 Corrosive liquid n.o.s. PG II
Name, PG
Maritime Transportation Not available.
Not available.
Special Provisions for
Transport
Section 15. Other Regulatory Information and Pictograms
This product is CORROSIVE under the PESTICIDE PRODUCTS
WHMIS (Classification)
ACT Regulations. This product is Disinfectant Drug and is therefore
not regulated under WHMIS. Although the product label is not
regulated under WHMIS, this Material Safety Data Sheet must be
presented and maintained as a part of WHMIS Compliance.
No products were found.
Regulatory Lists
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Regulations
HCS CLASS: Corrosive liquid.
Other Classifications HCS (U.S.A.)
California prop. 65: This product contains the following ingredients for
USA Regulatory
which the State of California has found to cause reproductive harm
Lists
(female) which would require a warning under the statute: Ethylene Oxide
<1 ppm
California prop. 65: This product contains the following ingredients for
which the State of California has found to cause cancer which would
require a warning under the statute: Ethylene Oxide <1 ppm
Massachusetts RTK: Ethylene Oxide
SARA 311/312 MSDS distribution - chemical inventory - hazard
identification: Phosphoric Acid
SARA 313 toxic chemical notification and release reporting: Phosphoric
Acid
R35- Causes severe burns.
DSD (EEC)
International No products were found.
Regulations Lists
Hazardous Material 3 National Fire
Health
Flammability
0
Information System 0 Protection
Flammability
3 0
(U.S.A.) Instability
Health
0 Association
Physical Hazard
(U.S.A.)
The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard
MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product.
Section 16. Other Information
Validated by CRushton on 3/2/2007. Verified by CRushton.
Printed 3/24/2007.
Information Contact Betco Corporation
1001 Brown Avenue
Toledo, Ohio 43607
(419) 241-2156
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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