#826
MATERIAL SAFETY DATA SHEET
NFPA RATING: Health = 3 Flammability = 2 Reactivity = 0
HMIS RATING: Health = /3 Flammability = 2 Reactivity = 0
SECTION I ?IDENTITY AND MANUFACTURER'S INFORMATION (1125B)
Manufacturer's Name: HILLYARD INDUSTRIES Product Name: ARSENAL STRIPPER
Address: 302 North Fourth Street Date Prepared: April 28, 2008
St. Joseph, MO 64501 Prepared by: Regulatory Affairs Department
Emergency Telephone No.: (800) 424-9300 (Only in the event of chemical emergency involving a spill, leak, fire, exposure or
accident involving chemicals.) Other information calls: (816) 233-1321 (Ext. 8285)
http://www.hillyard.com
SECTION II ?INGREDIENTS/IDENTITY INFORMATION
Components
(Specific Chemical Identity: ACGIH OTHER LIMITS
Common Name(s) CAS# OSHA PEL TLV RECOMMENDED %
2-Butyl cellosolve (2-Butoxyethanol) (1)* 111-76-2 50 ppm 20 ppm N.A. 50-55
Benzyl Alcohol (2) 100-51-6 none none 10 ppm from AIHA 27-32
WEEL (1994).
Ethanolamine (3) 141-43-5 3 ppm 3 ppm N.A. 14-19
Water 7732-18-5 none none N.A. ---
(1) Regulated by OSHA, FL, IL, LA, MA, NJ, PA, RI.
(2) Contains trace amounts of Benzaldyde (CAS #100-52-7) possible Teratogene by NTP. It is present in the formula at less than
0.05%.
(3) Regulated by OSHA, CT, FL, IL, LA, MA, NJ, PA, RI.
*This product contains the following chemicals subject to the reporting requirements of SARA Title III, Sec. 313, and 40 CFR Part
372: 2-Butoxyethanol.
VOC (Concentrate) = 82%; VOC (dilution 1:10) = 7.45%
SECTION III ?PHYSICAL / CHEMICAL CHARACTERISTICS
250篎 Specific Gravity (H2O = 1): 25篊 = 0.96 & 39篊 = 0.96
Boiling Point:
0.49 98.8%
Vapor Pressure (mm Hg.): Percent Volatile by Volume (%):
3.6 Evaporation Rate (ethyl ether = 1): slower than 1
Vapor Density (AIR = 1):
Appreciable Clear, colorless liquid; solvent odor
Solubility in Water: Appearance and Odor:
11.6
pH (concentrate) =
SECTION IV ?FIRE AND EXPLOSION HAZARD DATA
Flash point: 162篎 (Tag Closed Cup) Flammable Limits: LEL = Not established UEL = Not established
Carbon dioxide, dry chemical or foam (water spray to cool closed containers)
Extinguishing Media:
Special Fire Fighting Procedures: Self-contained breathing apparatus and protective clothing should be worn in fighting
fires involving chemicals.
Unusual Fire and Explosion Hazards: None known to Hillyard.
SECTION V ?PHYSICAL HAZARDS
Stable
Stability: Conditions to Avoid: Heat, sparks and open flame
Incompatibility (Materials to Avoid): Keep away from strong oxidizers such as permanganate or strong oxides.
As with any organic material, combustion
Hazardous Decomposition Products or Byproducts:
will produce carbon dioxide and carbon monoxide.
will not occur N/A
Hazardous Polymerization: Conditions to Avoid:
SECTION VI -- HEALTH HAZARD DATA
Routes of entry: Inhalation? Yes Skin? Yes Ingestion? Yes
HEALTH HAZARDS (1. Acute and 2. Chronic)
1. Corrosive to all body tissue with which it comes in contact. Chronic local effects may consist of multiple areas of
superficial destruction of the skin or dermatitis. Estimated LD50: less than 1.75 g/kg. Acute Inhalation 1 hour exposure
study showed no mortality of 1:3 dilution at 11.1 mg./L. 2. None known to Hillyard.
page 2 of #826 Arsenal Stripper
SECTION VI -- HEALTH HAZARD DATA continued
Chemical listed as Carcinogen or Potential Carcinogen:
National Toxicology Program = No No OSHA = No
I.A.R.C. Monographs =
Signs and Symptoms of Exposure: Butyl cellosolve is readily absorbed through the skin in toxic amounts. Inhalation of high
concentrations of vapors results in respiratory and eye irritation, narcosis, headache, nausea, dizziness, hematuria and damage to
liver and kidneys.
Medical Conditions Generally Aggravated by Exposure: Repeated overexposure may result in damage to the blood.
Emergency and First Aid Procedures: Inhalation: If the victim is not breathing, perform mouth-to-mouth resuscitation with
proper PPE. Remove person to fresh air. If breathing difficulty persists or occurs later, call physician. Skin and eye contact: Check
for and remove any contact lenses. Immediately flush with plenty of water for 15 minutes. Get prompt medical attention. Remove
and wash all contaminated clothing before reuse. Ingestion: DO NOT induce vomiting. Immediately give large amounts of water
and CALL A PHYSICIAN, hospital emergency room or poison control center.
SECTION VII 璓RECAUTIONS FOR SAFE HANDLING AND USE
Steps To Be Taken In Case Material Is Released Or Spilled: Absorb large spills with floor dry material (see disposal below).
Small spills: Flush with water and pick up with mop or wet vacuum.
Waste Disposal Method: Dispose of in accordance with state or local regulations. Do not dispose of in storm drains or streams;
monoethanolamine is toxic to fish.
Precautions To Be Taken In Handling And Storing: Keep container closed when not in use. Since empty packages retain product
residue, follow label warning even after package is empty. Do not store above 120篎. Spray mist may produce respiratory irritation
or damage and increase susceptibility to respiratory illness. USE WITH ADEQUATE VENTILATION. Avoid breathing vapors or
spray mist. Open windows and doors, use exhaust fans or other means to insure fresh air entry during application and drying. Refer
to OSHA Standard 29 CFR 1910.94 for technical guidelines on keeping air contamination below acceptable exposure limits. Do not
get on skin, in eyes or on clothing.
SECTION VIII ?CONTROL MEASURES
Respiratory Protection (Specify Type): Wear appropriate, properly fitted respirator (NIOSH or MSHA approved unless air
monitoring demonstrates vapor or mist levels are below applicable limits.
Ventilation: at least 10 air changes per hour recommended
recommended recommended Special = N/A N/A
Local Exhaust = Mechanical (General) = Other =
Protective Gloves: impervious rubber gloves Eye Protection: chemical safety goggles
Other Protective Clothing or Equipment: protective clothing such as uniforms, coveralls
Work / Hygienic Practices: Wash contaminated clothing before reuse (including shoes).
SECTION IX ?TRANSPORTATION INFORMATION
DOT SHIPPING DESCRIPTION ON BILL OF LADING:
(1/2 gallon, 1, 5 and 55 gallon packages) = Compound, cleaning, liquid, (Monoethanolamine), 8, NA 1760, PG II
Package Marking = Compound, cleaning liquid (Monoethanolamine), NA 1760
Package Label = Corrosive Hazard Class = 8 Package Group = II
EPA Hazardous waste number/code: not listed
Hazardous waste characteristics: Ignitability = not applicable; Corrosivity = not applicable; Reactivity = not applicable
DISCLAIMER OF WARRANTIES
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS
FOR A PARTICULAR PURPOSE, OR OF ANY NATURE ARE MADE WITH RESPECT TO THE PRODUCT(S) OR
INFORMATION CONTAINED IN THIS MATERIAL SAFETY DATA SHEET.
The information and recommendations contained in this Material Safety Data Sheet are supplied pursuant to 29 CFR
1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. All information contained herein
is presented in good faith and is believed to be appropriate and accurate.
THE BUYER OR USER ASSUMES ALL RISKS ASSOCIATED WITH THE USE, MISUSE OR DISPOSAL OF THIS
PRODUCT. THE BUYER OR USER IS RESPONSIBLE TO COMPLY WITH ALL FEDERAL, STATE OR LOCAL
REGULATIONS CONCERNING THE USE, MISUSE OR DISPOSAL OF THESE PRODUCTS.
|