MP-90060 MATERIAL SAFETY DATA SHEET Page 1 of 10
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MSDS PREPARED BY: Environmental Health Dept.-Grace Construction Products
W.R.Grace & Co.-Conn. W. R. Grace & Co. of Canada Ltd.
62 Whittemore Ave. 294 Clements Rd. West
Cambridge, MA 02140 Ajax, Ontario, L1S 3C6
Telephone Number for Information and Emergency Response
In USA: (617) 876-1400 In Canada: (905) 683-8561
MSDS Number: MP-90060 000001 Cancels MSDS # MP-90030 Date: 09/16/1996
Trade Names and Synonyms : POWER BRITE and SPEED E
(SEE SECTION 16 FOR ADDITIONAL
PRODUCT IDENTIFICATION)
Chemical Names and Family : Acid Cleaner
Product Use: Concrete & Masonry Cleaning Agent
Formula: MIXTURE-NA
CAS# (Chemical Abstract Service) : MIXTURE-NA
SECTION 2 - HAZARDOUS INGREDIENT AND MAJOR COMPONENT INFORMATION
(See Section 11 for Complete Chemical Names)
EXPOSURE LIMITS (See Section 8 for Canadian Limits)
Max. % Exposure Limits
INGREDIENT: By Wt. . OSHA ACGIH OTHER
BENZALDEHYDE 0.30 None Established None Established None Established
CAS# 00100-52-7
ETHYL. GLYC. MONOBUT. ETHE 4.00 25 ppm - TWA 25 ppm - TWA NIOSH REL 5 ppm
CAS# 00111-76-2 (121 mg/m3) (120 mg/m3) (24 mg/m3)
(SKIN) (SKIN) (SKIN)
HYDROCHLORIC(MURIA.)ACID 97.00 5ppm 5ppm ---
CAS# 07647-01-0 (Ceiling Limit) (Ceiling Limit)
MP-90060 MATERIAL SAFETY DATA SHEET Page 2 of 10
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview:
Warning Statements:
DANGER! CAUSES EYE AND SKIN BURNS.
HARMFUL IF SWALLOWED.
... Contains one or more of the following ingredients: Hydrochloric
(Muriatic) acid CAS# 7647-01-0, Ethylene glycol monobutyl ether
CAS# 111-76-2, Alkylaryl sulfonate isopropylamine salt CAS#
9106-45-9, Alkyl ether sulfate sodium salt CAS# 73665-22-2,
Benzaldehyde CAS# 100-52-7, and Water CAS# 7732-18-5.
... Eye contact will cause irritation and burns.
... Skin contact will cause irritation and burns. May cause
dermatitis. Ethylene glycols contained in this product can be
absorbed through the skin in harmful amounts. Excessive exposure
may cause hemolysis which impairs the bloods ability to transport
oxygen.
... Inhalation of mist may cause irritation or burns to the upper
respiratory tract. High exposures can cause lung irritation
pulmonary edema and can cause death.
... Ingestion causes irritation and burns to the gastro-intestinal
tract. Fluid in the lungs from vomiting can cause asphyxiation.
Ingestion can cause death.
... Read and understand all Health and Safety information on the
product Label and Material Safety Data Sheet before use.
2926f
NPCA-HMIS Hazard Index : o Health: 3
o Flammability: 0
o Reactivity: 0
o Personal Protection: H
(See Section 8)
Potential Health Effects
Routes of Exposure:
Inhalation:
Inhalation of vapor or mist can cause irritation or burns to the upper
respiratory tract. Intense coughing, throat irritation, sneezing and
labored breathing may occur. Following high exposures lung irrita-
tion, pulmonary edema and death can occur.
Ethylene Glycol Monobutyl Ether is contained in these products at a
maximum of 4%. Ethylene Glycols have been shown to cause harm to the
developing fetus in laboratory animals. Liver, kidney, lung and
blood damage have also been reported. Similar effects are suspected
in humans.
Skin and Eye:
EYE and SKIN contact causes irritation and burns. Vapor can cause
irritation or corneal burns, conjunctivitis and loss of sight. May
cause dermatitis. Ethylene Glycols can be absorbed through the skin
in harmful amounts. Excessive exposure may cause hemolysis which
impairs the bloods ability to transport oxygen.
Ingestion:
Causes irritation and burns to the gastro-intestinal tract. May
perforate stomach or esophagus in extreme cases. May cause
asphyxiation from pulmonary edema (fluid in the lungs). Ingestion
can cause death.
MP-90060 MATERIAL SAFETY DATA SHEET Page 3 of 10
Carcinogenicity Information :
Not Applicable
SECTION 4 - FIRST AID MEASURES
EYE: In case of contact immediately flush eyes with plenty of
water for at least 15 minutes. Do not rub eyes. Get
immediate medical attention.
SKIN: Wash skin with soap and water. If irritation develops
and persists, call a physician. Wash contaminated
clothes before reuse.
INHALATION: If irritation due to inhalation develops, get fresh air.
If symptoms persist, consult a physician.
INGESTION: If swallowed do not induce vomiting. Give large
quantities of water for dilution effect. Rinse mouth
with water. Call physician immediately. Never give
anything by mouth to an unconscious person.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: Not Determined Flammable Limits:
Method Used: Unknown LEL NA UEL NA
N.F.P.A. Rating: H-3 F-0 R-0
Extinguishing Media
Water fog, foam or CO 2, dry chemical
Special Fire Fighting Procedures
Wear positive pressure self contained breathing apparatus with full
face piece and protective clothing. Do not use direct stream of
water which may splatter this material. Cool containers with
water spray. Prevent runoff from fire control or dilution from
entering streams or drinking water supplies.
Unusual Fire and Explosion Hazards
Product will react with metals (ex.: aluminum, zinc, tin, etc.) to
release explosive flammable hydrogen gas. Heat can cause evolution
of gaseous hydrogen.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
U.S. RELEASES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
CORROSIVE MATERIAL. Evacuate unprotected personnel from area.
Maintain adequate ventilation. Use proper Safety Equipment.
Contain spill, place into drums for proper disposal. Flush
remaining area with water and neutralize with Soda Ash or
Lime and dispose of properly. Avoid direct discharge to sewers
and surface waters.
CANADIAN RELEASES
Prevent product from entering drinking water supplies or streams.
Observe precautions above, collect liquid or solidify liquid with
an inert, noncombustible material and remove for disposal. Dispose
of all waste in accordance with applicable government regulations.
MP-90060 MATERIAL SAFETY DATA SHEET Page 4 of 10
SECTION 7 - HANDLING AND STORAGE INFORMATION
Precautionary Measures:
... Avoid contact with eyes, skin and clothing.
... Wash thoroughly after handling.
... Avoid breathing vapor or mist.
... Keep containers closed when not in use.
... FOR PROFESSIONAL USE ONLY. KEEP OUT OF CHILDREN'S REACH.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION/CANADIAN EXPOSURE LIMITS
Ventilation:
Local Exhaust: Use If Available.
Mechanical: Not Generally Available
Special: Not Generally Required
Other: Not Generally Required
Respiratory Protection :
Respirators are not generally required. However, if specific use
causes irritation or exposures above the limits specified in
Section 9 of this MSDS, a NIOSH approved (Type Acid Gas respirator
TC-23C-XXX) with a prefilter for mist is recommended.
Skin Protection:
Gloves resistant to acids should be worn whenever handling this
product.
Eye Protection:
Goggles should be worn if splashing is likely.
Other Protective Clothing or Equipment :
See Work Hygienic Practices.
Work/Hygienic Practices :
Personal Protective Equipment (PPE) specified above is appropriate
for typical production operations and exposures. For any unusual
situations such as spill clean-up, contact your supervisor or
Health and Safety Coordinator to determine additional PPE require-
ments and Safety procedures.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION/CANADIAN EXPOSURE LIMITS (Cont'd)
Provincial Exposure Limits
Ingredients ACGIH ALBERTA B.C. ONTARIO QUEBEC
BENZALDEHYDE: --- --- --- --- ---
CAS# 100-52-7
ETHYLENE GLYCOL
MONOBUTYL ETHER: 25 ppm TWA 25 ppm TWA 25 ppm TWA 25 ppm TWA 25 ppm TWA
CAS# 111-76-2 (SKIN) (SKIN) (SKIN) (SKIN) (SKIN)
HYDROCHLORIC
(MURIATIC) ACID: 5 ppm 5 ppm 5 ppm 5 ppm 5 ppm
CAS# 7647-01-0 (Ceiling Limit) (Ceiling Limit) (Ceiling Limit) (Ceiling Limit) (Ceiling Limit)
1494f
MP-90060 MATERIAL SAFETY DATA SHEET Page 5 of 10
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: Not Determined Specific Gravity(H2O=1) 1.136
Vapor Pressure (mm Hg.) Not Determined % Volatiles 100%
Vapor Density(AIR = 1) Not Determined Evaporation Rate >1
(Butyl Acetate = 1)
Solubility in Water: 100% pH <2
Bulk Density (#/cu. ft) : Not Applicable
Appearance and Odor: Green or Maroon Liquid. Sharp
penetrating odor.
Odor Threshold:
Approximately 5ppm for HCl
MP-90060 MATERIAL SAFETY DATA SHEET Page 6 of 10
SECTION 10 - STABILITY AND REACTIVITY
Stable under normal conditions (yes or no): YES
Conditions or Materials to avoid (which may react or cause instability):
Most metals, alkalis, metallic oxides, amines, strong oxidizers
and other organics.
Hazardous Decomposition or Byproducts:
Flammable Hydrogen Chloride vapors are released in increasing
amounts at higher temperatures. Will release hydrogen when in
contact with some metals.
Hazardous Polymerization :
Will not occur.
Conditions to Avoid:
Elevated temperatures will increase vapor pressure causing containers
to rupture.
MP-90060 MATERIAL SAFETY DATA SHEET Page 7 of 10
SECTION 11 - TOXICOLOGICAL INFORMATION
INGREDIENT TOXICITY DATA: LD 50 & LC50
(Chemical Name,
CAS#, & Common Name) (See Section 2 for Exposure Limits)
Benzaldehyde LD 50 oral rat 1300 mg/kg
CAS# 100-52-7
Ethylene Glycol LD 50 oral rat 530 mg/kg
Monobutyl Ether LD 50 dermal rabbit 450 mg/kg
CAS# 111-76-2 LD 50 Inhal. rat 450ppm/4hr
Hydrochloric(Muriatic)Acid LD 50 oral rabbit 900 mg/kg
CAS# 7647-01-0 LC 50 inhal. rat 3124 ppm/lhr.
LD 50 dermal rabbit 490 mg/kg
1493f
MP-90060 MATERIAL SAFETY DATA SHEET Page 8 of 10
SECTION 12 - ECOLOGICAL INFORMATION
None Available At This Time
SECTION 13 - DISPOSAL CONSIDERATIONS
U.S. DISPOSAL
WASTE DISPOSAL METHOD:
Dispose of at approved Waste Treatment Facility. If approved,
neutralize material and flush to sewer. If product is not neutralized
this material will have a pH less than 2 which the EPA defines as
hazardous waste with an EPA waste Number D002. If pH is adjusted to
neutral according to EPA CFR 261.3, the material is not considered a
hazardous waste. DO NOT pressurize, cut, weld, braze, solder, drill,
grind or expose empty containers to heat, flame, sparks or other
sources of ignition.
Consult all regulations (federal, state, provincial, local etc.)or
a qualified waste disposal firm when characterizing waste for disposal.
Dispose of waste in accordance with all applicable regulations.
CANADIAN DISPOSAL
Consult all regulations (federal, state, provincial, local etc.)or
a qualified waste disposal firm when characterizing waste for disposal.
Dispose of waste in accordance with all applicable regulations.
SECTION 14 - TRANSPORT INFORMATION
Transportation Hazard Classification
United States DOT . Canadian Regulations
PROPER SHIPPING: TDG CLASS:
NAME
HAZARD CLASS: Corr.Liq.Acid,Inorganic,
IDENTIFICATION #: N.O.S.(Contains Hydro-
LABEL(s) REQUIRED: chloric Acid)8,UN3264,II
Surface Freight Classification: Not Applicable
MP-90060 MATERIAL SAFETY DATA SHEET Page 9 of 10
(Not Meant To Be All Inclusive
SECTION 15 - REGULATORY INFORMATION Selected Regulations Represented)
SARA Title III Reporting Information
Tier I & II Hazard Categories: DELAYED (CHRONIC) HEALTH
IMMEDIATE (ACUTE) HEALTH
Contains Extremely Hazardous-SARA III Section 302 Ingredient: NO
Comments:
Contains Toxic Chemical Release-SARA III Section 313 Ingredient: YES
Comments: Contains: Hydrochloric (Muriatic) Acid max. 97%
(35% wt. in H 2O): REPORTABLE
Glycol Ethers Max 4% REPORTABLE
Other Government Reporting Requirements:
CHEMICAL INVENTORY CERTIFICATION:
All ingredients contained in this product are included on the US EPA
Toxic Substances Control Act (TSCA) inventory or exempt from listing
on the TSCA inventory.
All ingredients contained in this product comply with the requirements
of the Canadian Environmental Protection Act (CEPA) and are listed
on the DSL or NDSL lists.
CERCLA/SARA SECTION 304 HAZARDOUS SUBSTANCE: Hydrochloric acid
is listed as a reportable substance with a Reportable Quantity of
5000 lbs.
CALIFORNIA PROPOSITION 65 INFORMATION: This product is subject
to labeling requirements under the California Proposition 65 law.
2927f
Non-Hazardous Ingredient Disclosure:
Water CAS# 07732-18-5
MP-90060 MATERIAL SAFETY DATA SHEET Page 10 of 10
SECTION 16 - OTHER INFORMATION
The information contained in this Material Safety Data Sheet is applicable to
the following products:
POWER BRITE and SPEED E
"THE DATA INCLUDED HEREIN ARE PRESENTED IN ACCORDANCE WITH VARIOUS ENVIRONMENT, HEALTH
AND SAFETY REGULATIONS. IT IS THE RESPONSIBILITY OF A RECIPIENT OF THIS DATA TO REMAIN
CURRENTLY INFORMED ON CHEMICAL HAZARD INFORMATION, TO DESIGN AND UPDATE ITS OWN PROGRAM
AND TO COMPLY WITH ALL NATIONAL, FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS
APPLICABLE TO SAFETY, OCCUPATIONAL HEALTH, RIGHT-TO-KNOW AND ENVIRONMENTAL PROTECTION."
|