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First Aid Measures Fire Fighting Measures Manufacturer/Responsible Party
Personal Protection Physical -Chemical Properites Accidental Release Measures
Handling/Storage Chemical Ingredients HAZCOM Label
Product Identification
Product ID: PAINT THINNER
MSDS Date: 03/31/1989 Tech Review: 12/06/1998
FSC: 8010 NIIN: 00-254-4218 LIIN: MSDS Number: 086321
Submitter: G AW
Status Cd: C
MFN: 01
Article: N
Kit Part: N
Manufacturer-Responsible Party
Company Name: ASHLAND CHEMICAL COMPANY
Address: N/K
Box: 2219
City: COLUMBUS State: OH ZIP: 43216-2219 Country: US
Info Phone Num: 614-790-3333/800-325-3751
Emergency Phone Num: 800-274-5236 0R 800-ASHLAND
Resp. Party Other MSDS Num.:
Preparer's Name: N/K
Chemtrec Ind/Phone:
Proprietary Ind: N
Review Ind: Y
Published: Y
CAGE: 34897
Special Project Cd: N
Contractor Identification
Company Name: ASHLAND CHEMICAL CO
Address:
Box: 2219
City: COLUMBUS State: OH ZIP: 43216 Country: US
Phone: 614-790-3333
Contract Num:
CAGE: 34897
Company Name: CSD INC. (OBSOLETE ADDRESS; USE 4N760)
Address: 420 SEABOARD DRIVE
Box:
City: MATTHEWS State: NC ZIP: 28105-5073 Country: US
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Phone: 704-821-9822
Contract Num:
CAGE: 5W216
Item Description Information
Item Name: THINNER,PAINT PRODUCTS
Item Manager: GSA
Specification Num: NK
Type/Grade/Class: NK
Unit of Issue: DR Quantitative Expression: 00000000055GL
UI Container Qty: NK
Type of Container:
CHEMICAL INGREDIENTS
Ingred Name: NORMAL BUTANOL (SARA 313) *
CAS: 71-36-3 Cd: M
RTECS #: EO1400000 Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
% High Vol: Cd:
% Text: 21
Environmental Wt:
Other REC Limits: NONE SPECIFIED
OSHA PEL: 100 PPM Cd: M
OSHA STEL: Cd:
ACGIH TLV: S, C 50 PPM; 9293 Cd: M
ACGIH STEL: N/P Cd:
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
Ozone Depleting Chemical: N
Ingred Name: * SKIN ABSORPTION MAY POTENTIALLY CONTRIBUTE TO OVERALL EXPOSURE
TO MAT'L. APPROPRIATE MEASURES SHOULD BE TAKEN TO **
CAS: Cd: X
RTECS #: 9999999ZZ Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
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% High Vol: Cd:
% Text: N/K
Environmental Wt:
Other REC Limits: NONE SPECIFIED
OSHA PEL: N/K Cd: M
OSHA STEL: Cd:
ACGIH TLV: N/K Cd: M
ACGIH STEL: N/P Cd:
EPA Rpt Qty:
DOT Rpt Qty:
Ozone Depleting Chemical:
Ingred Name: ** PREVENT ABSORPTION SO THAT THE TLV IS NOT INVALIDATED.
CAS: Cd: X
RTECS #: 9999999ZZ Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
% High Vol: Cd:
% Text: N/K
Environmental Wt:
Other REC Limits: NONE SPECIFIED
OSHA PEL: N/K Cd: M
OSHA STEL: Cd:
ACGIH TLV: N/K Cd: M
ACGIH STEL: N/P Cd:
EPA Rpt Qty:
DOT Rpt Qty:
Ozone Depleting Chemical:
Ingred Name: ALIPHATIC PETROLEUM DISTILLATES *
CAS: 8030-30-6 Cd: M
RTECS #: DE3030000 Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
% High Vol: Cd:
% Text: 60
Environmental Wt:
Other REC Limits: NONE SPECIFIED
OSHA PEL: 300 PPM Cd: M
OSHA STEL: Cd:
ACGIH TLV: 300 PPM Cd: M
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ACGIH STEL: N/P Cd:
EPA Rpt Qty:
DOT Rpt Qty:
Ozone Depleting Chemical: N
Ingred Name: *** NISOH RECOMMENDS A LIMIT OF 350 MG/CUM-8 HR TWA, 1800 MG/CUM AS
DETERMINED BY A 15 MINUTE SAMPLE.
CAS: Cd: X
RTECS #: 9999999ZZ Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
% High Vol: Cd:
% Text: N/K
Environmental Wt:
Other REC Limits: NONE SPECIFIED
OSHA PEL: N/K Cd: M
OSHA STEL: Cd:
ACGIH TLV: N/K Cd: M
ACGIH STEL: N/P Cd:
EPA Rpt Qty:
DOT Rpt Qty:
Ozone Depleting Chemical:
Ingred Name: ISOBUTYL ISOBUTYRATE ****
CAS: 97-85-8 Cd: M
RTECS #: NQ5250000 Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
% High Vol: Cd:
% Text: 1-10
Environmental Wt:
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED Cd: M
OSHA STEL: Cd:
ACGIH TLV: NOT ESTABLISHED Cd: M
ACGIH STEL: N/P Cd:
EPA Rpt Qty:
DOT Rpt Qty:
Ozone Depleting Chemical: N
Ingred Name: TOLUENE (SARA III)
CAS: 108-88-3 Cd: M
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RTECS #: XS5250000 Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
% High Vol: Cd:
% Text: 9
Environmental Wt:
Other REC Limits: NONE SPECIFIED
OSHA PEL: 200 PPM/150 STEL Cd: M
OSHA STEL: Cd:
ACGIH TLV: 50 PPM; 9293 Cd: M
ACGIH STEL: N/P Cd:
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
Ozone Depleting Chemical: N
Ingred Name: **** NIOSH RECOMMENDS A LIMIT OF 100 PPM 8-HOUR TWA; 200 PPM 10 MINUTE
CEILING.
CAS: Cd: X
RTECS #: 9999999ZZ Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
% High Vol: Cd:
% Text: N/K
Environmental Wt:
Other REC Limits: NONE SPECIFIED
OSHA PEL: N/K Cd: M
OSHA STEL: Cd:
ACGIH TLV: N/K Cd: M
ACGIH STEL: N/P Cd:
EPA Rpt Qty:
DOT Rpt Qty:
Ozone Depleting Chemical:
Hazards Identification
LD50 LC50 Mixture : N/K
Route of Entry Inds -
Inhalation: YES
Skin: YES
Ingestion: NO
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Carcinogenicity Inds -
NTP: N/P
IARC: N/P
OSHA: N/P
Health Hazards Acute and Chronic
EYES: CAUSES IRRITATION, SKIN: PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE
IRRITATION, BREATHING: EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL, AND
RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS, DEATH. SWALLOWING: CCAN
CAUSE GASTROINTESTINA IRRITATION.
Explanation of Carcinogenicity
N/K
Signs and Symptions of Overexposure
EYES: REDNESS, TEARING. SKIN: (CNS) DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE
AND POSSIBLE UNCONSCIOUSNESS AND EVEN DEATH. SWALLOWING: NAUSEA, VOMITING,
DIARRHEA.
Medical Cond Aggravated by Exposure
N/K
First Aid Measures
First Aid
SKIN: WASH W/SOAP & WATER. REMOVE CONTAM CLOTH. EYES: FLUSH W/LRG AMTS WATER,
LIFTING EYELIDS OCCASIONALLY. GET MED ATTN. SWALLOWED: DON'T INDUCE VOMITING,
KEEP WARM, QUIET & GET MED ATTN. ASPIRATION (MAT'L INTO LUNGS -VOMIITING) CAN CAUSE
CH EM PNEUMONITI (CAN BE FATAL). BREATHED: REMOVE TO FRESH AIR. IF BREATH DIFFICULT,
ADMIN OXYGEN. IF BREATH STOPPED, GIVE AFTIF RESP. KEEP WARM, QUIET, CALL DR.
Accidental Release Measures
Spill Release Procedures
SMALL: ABSORB LIQ ON PAPER, VERMIC, FLOOR ABSORB, ETC. LARGE: ELIMINATE IGNIT
SOURCES. EVACUATE UNPROTECTED. STOP SPILL, DIKE. PUMP LIQ TO SALVAGE TANK,
REMAINING LIQ MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, ETC &p;
SHOVEL INTO CNTNRS.
Neutralizing Agent
N/K
Disposal Considerations
Waste Disposal Methods
SMALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE & LOCAL REGULATIONS.
LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE & LOCAL REGULATIONS.
Handling and Storage
Handling and Storage Precautions
CNTNRS OF MATERIAL MAY BE HAZARDOUS WHEN EMPTIED (EMPTIED CNTNRS RETAIN
PRODUCT RESIDUES--VAPOR/LIQUID/SOLID). ALL HZD PRECAUTIONS MUST BE OBSERVED.
Other Precautions
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N/K
Fire Fighting Measures
Flash Point Method: TCC
Flash Point: Flash Point Text: 20 TO 99F
Autoignition Temp: Autoignition Temp Text: N/K
Lower Limits: .9%
Upper Limits: N/K
Extinguishing Media
REGULAR FOAM OR WATER FOG OR CARBON DIOXIDE OR DRY CHEMICAL
Fire Fighting Procedures
WEAR SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN THE
POSITIVE PRESSURE DEMAD MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard
VAPOR (HEAVIER THAN AIR) MAY TRAVEL ALONG GROUND/MOVED BY VENT-IGNITED AT
DISTANT POINT. GROUND/BOND 5 (& LARGER) GAL PAILS WHEN MAT'L TRANSFERED.
Personal Protection
Respiratory Protection
IF TLV'S EXCEEDED A NIOSH/MSHA AIR SUPPLIED RSPRTR IN ABSENCE OF ENVIRONMNTL
CONTROL. OSHA REGS OK OTHER NIOSH/MSHA RSPRTRS (NEG PRESSURE TYPE) UNDER
SPECIFIED COND (SEE SFTY EQUIP SUPPLR). IMPLEMENT ENGINEER/ADMIN CONTROLS TO
REDUUCE EXPOS.
Ventilation
PROVIDE SUFFICIENT MECHANICAL (GENERAL/LOCAL EXHAUST) VENT TO MAINTAIN
EXPOSURE BELOW TLV(S).
Protective Gloves
RESISTANT GLOVES SUCH AS NITRILE RUBBER.
Eye Protection
CHEM SPLSH GOGGLES, SFTY GLASSES
Other Protective Equipment
TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND
BOOTS.
Work Hygienic Practices
LAUNDER CONTAM CLOTHING BEFORE REUSE. REMOVE CONTAM SHOES PROMPTLY. DISCARD
SHOES SATURATED W/PRODUCT.
Supplemental Safety and Health
N/K
Physical/Chemical Properties
HCC: F2
NRC/State Lic Num: N/K
Net Prop Wt for Ammo: N/K
Boiling Pt: B.P. Text: 232F,111C*
Melt/Freeze Pt: M.P/F.P Text: N/K
Decomp Temp: Decomp Text: N/K
Vapor Pres: 22 @ 68 F Vapor Density: > AIR
Volatile Org Content %:
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Spec Gravity: LESS THAN WATER
VOC Pounds/Gallon:
pH: N/K
VOC Grams/Liter:
Viscosity: N/K
Evaporation Rate & Reference: SLOWER THAN ETHER.
Solubility in Water: N/K *@ 760 MM HG
Appearance and Odor: N/K
Percent Volatiles by Volume: 100.00
Corrosion Rate: N/K
Stability and Reactivity Data
Stability Indicator/Materials to Avoid: YES AVOID CONTACT WITH OXIDIZING AGENTS.
Stability Condition to Avoid: N/K
Hazardous Decomposition Products: MAY FORM TOXIC MATERIALS: CARBON DIOXIDE, CARBON
MONOXIDE, VARIOUS HYDROCARBONS, ETC. FEB2092
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization: N/K
Toxicological Information
Toxicological Information: N/P
Ecological Information
Ecological: N/P
MSDS Transport Information
Transport Information: N/P
Regulatory Information
SARA Title III Information: N/P
Federal Regulatory Information: N/P
State Regulatory Information: N/P
Other Information
Other Information: N/P
HMIS Transportation Information
Responsible Party CAGE: 34897
Trans ID Num: 61599
Product ID: PAINT, THINNER
MSDS Prepared Date: 03/31/1989
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Review Date: 02/18/1992
MFN: 1
Submitter: G AW
Status Cd: C
Article w/o MSDS : N
Tech Entry NOS Shipping Nm: N/K
Radioactivity: N/K
Form:
Net Explosive Weight: N/K
Coast Guard Ammo Cd: N/K
Magnetism: N/P
Net Unit Weight: N/K
AF MMAC Cd: NK
DOD Exemption Num: N/K
Limited Qty Ind:
Multiple Kit Num: 0
Kit Ind: N
Kit Part Ind: N
Review Ind: Y
Unit of Issue: DR
Container Qty: NK
Type of Container:
Additional Data: N/K
Detail DOT Information
DOT PSN Cd: LFJ
Symbols:
DOT Proper Shipping Name: PAINT RELATED MATERIAL
DOT PSN Modifier: INCLUDING PAINT THINNING, DRYING, REMOVING, OR REDUCING COMPOUND
Hazard Class: 3
UN ID Num: UN1263
DOT Packaging Group: II
Label: FLAMMABLE LIQUID
Special Provision: B52,T7,T30
Packaging Exception: 150
Non Bulk Pack: 173
Bulk Pack: 242
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
Water/Ship/Other Req:
Detail IMO Information
IMO PSN Cd: LCP
IMO Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL
IMO PSN Modifier: (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDING PAINT THINNING
OR REDUCING COMPOUND) o
> IMDG Page Num: 3268
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UN Num: 1263
UN Hazard Class: 3.2
IMO Packaging Group: I/II *
Subsidiary Risk Label: -
EMS Num: 3-05
Med First Aid Guide Num: 310
Detail IATA Information
IATA PSN Cd: SXL
IATA UN ID Num: 1263
IATA Proper Shipping Name: PAINT RELATED MATERIAL
IATA PSN Modifier: (INCLUDING PAINT THINNING OR REDUCING COMPOUNDS)
IATA UN Class: 3
Subsidiary Risk Class:
IATA Label: FLAMMABLE LIQUID
UN Packing Group: II
Packing Note Passenger: 305
Max Qty Pass: 5L
Packaging Note Cargo: 307
Max Qty Cargo: 60L
Exceptions: A7,A72
Detail AFI Information
AFI PSN Cd: XXX
AFI Symbols:
AFI Proper Shipping Name: SEE ADDITIONAL DATA FIELD IN HMIS FOR FURTHER INFORMATION
AFI PSN Modifier:
AFI Hazard Class: N/A
AFI UN ID Num: N/A
AFI Packing Group: N/A
AFI Label:
Special Provisions: N/A
Back Pack Reference: N/A
HAZCOM Label
Product ID: PAINT, THINNER
CAGE: 34897
Assigned Ind: N
Company Name: ASHLAND CHEMICAL CO
Street:
PO Box: 2219
City: COLUMBUS State: OH ZIP: 43216 Country: US
Health Emergency Phone: 00-274-5263/800-ASHLAND
Label Required Ind: Y
Date of Label Review: 12/16/1998
Status Cd: C
Mfg Label Num:
Label Date: 12/16/1998
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Year Procured: N/K
Origination Cd: G
Chronic Hazard Ind: N/P
Eye Protection Ind: N/P
Skin Protection Ind: N/P
Signal Word: N/P
Respiratory Protection Ind: N/P
Health Hazard:
Contact Hazard:
Fire Hazard:
Reactivity Hazard:
Hazard And Precautions EYES: CAUSES IRRITATION, SKIN: PROLONGED OR REPEATED CONTACT
CAN CAUSE MODERATE IRRITATION, BREATHING: EXCESSIVE INHALATION OF VAPORS CAN
CAUSE NASAL, AND RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS, DEATH.
SWALLOWING: CCAN CAUSE GASTROINTESTINA IRRITATION. EYES: REDNESS, TEARING. SKIN:
(CNS) DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS
AND EVEN DEATH. SWALLOWING: NAUSEA, VOMITING, DI ARRHEA.
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