Material Safety D
Data Sheet
t
Dat of issue
te Revision da
ate Pa
age
044/02/04 07/18/07 1
2640 E 37th Street, Vern
h
non, CA 9005
58 Produ code
uct Pro
oduct name
(323) 581-5
5200
ST
T2012 HA
ARDENER
R
EMERGEN
NCY PHONE : 800-535-50 / 352-323
053 3-3500
1. Product Identificatio
t on
Produ name
uct Soft Feelin Paint - ST
ng T2012 Hardener
Polyisocyaanate resin
Chemical name of solid
f
Isobutyl Isobutyrate / N
N-butyl acetate
e
Chemical name of solvent
f
2. Compos sition of Infor
rmation on IIngredients
Chemical Name EINECS-NNo CAS Num mber CONC.
C
202-612-
-5 97-85-
-8 15-25
Isobut Isobutyra
tyl ate
204-658-
-1 123-86-4 1-10
n-buty Acetate
yl
212-485-
-8 822-06-0 0-1
Hexammethylene di- -isocyanate
28182-81-2 50-80
500-060-
-2
Poly is
socyanate Re esin
3. Hazards Identificatio
s on
Irritation o skin, eyes a respiratory tract. Substance affects
of and y t
Effect of (over) ex
ts xposure:
(central) neervous system
m.
Sympt toms of (over exposure:
r)
Couughing, heada ache, dizzines drowsiness unconsciou
ss, s, usness, nausea &
a
Inhala
ation:
Vommiting
As rresult of abso
orption throug the intact skin, the subst
gh tance may cau
use
Skin :
syst
temic toxic efffects. Dry sk redness.
kin,
Pain redness
n,
Eyes:
Sore throat, stom
e mach-ache, headache, dizzinness, vomitin dullness
ng,
Ingest
tion:
EINECS
Danger Classificati
r ion: Toxic
Risk ph
hrases:
10 Flammmable
23 Tox by inhalati
xic ion
36/37/338 Irrit
tation to eyes, respiratory s
, systems and s
skin
42/43 May cause sensit
y tization by inh
halation and s
skin contact
Safety phrases:
S1/2 Kee locked up a out of the reach of chil
ep and e ldren
S26 In case of contac with eyes, r
ct rinse immediaately with plenty of water and
n
seek medical adv
k vice
S28 Afte contact wit skin, wash immediately with soap and water.
er th
S38 In case of insuffi
icient ventilat
tion, wear suit
table respirato equipmen
ory nt
S45 In case of acciden or if you fe unwell, se medical ad
nt eel eek dvice immediiately
4. First-Ai Measures
id
Move to fres air rest half upright posi
sh f ition, loosen c
clothing. Artif
ficial
Inhalaation:
respiration in case of diffi
n iculty in breat
thing. Seek m medical advic ce
after signific exposure.
cant .
Page | 1
Wash off immediately with plenty of soap and water. Take all
Skin:
contaminated clothing off immediately. Seek medical advice.
Rinse immediately with plenty of water. Eyelids should be held away
Eyes:
from the eyeball to ensure through rinsing. Always seek medical
advice.
Ingestion: DO NOT induces vomiting because of risk of aspiration. Rinse
mouth with water. Seek medical advice.
5. Fire-Fighting Measures
Extinguishing measures
- Suitable: Powder, carbon dioxide, foam, water mist (only large amounts).
- Not to be used: Waterjet
Hazards thermal decomposition and combustion products
- In case of fire toxic fumes might be formed
Protective equipment
- Wear protective clothing and use self-contained breathing apparatus.
6. Accidental Release Measures
Evacuate non-emergency personnel. Isolate the area and prevent access. Remove ignition sources. Notify
management. Put on protective equipment. Control source of the leak. Ventilate. Contain the speed to prevent
it spreading into drains, sewers, water supplies or soils. To minimize vapor, cover the spillage with fire fighting
foam (AFFF). Released material may be pumped into closed but not sealed metal container for disposal . For
minor leak, cover spill area with suitable absorbent material (Kitty litter, oil dry, etc.). Saturate absorbent
material with neutralization solution and mix. Wait 15 minutes. Collect material in open-head metal containers.
Repeat application of decontamination solution with scrubbing, followed by absorben until the surface is
decontaminated. Apply lid loosely and allow containers to vent for 72 hours to let carbon dioxide (CO2) escape.
Neutralization solutions
1. A mixture of 75% water 20% non-ionic surfactant (e.g. Poly-Tergent SL-62), Tergitol TMN-10) and
5% propanol
2. A mixture of 80% water, 20% non-ionic surfactant (e.g. Poly-Tergent SL-62, Tergitol TMN-10)
3. A mixture of 90% water, 3-8% Ammonium hydroxide and 2% liquid detergent
Spills may be reportable to the national Response Center (800)424-8802 and to state and/or local agencies
7. Handling and Storage
Do not breathe vapors, mists or dusts. Use adequate ventilation to keep airborne isocyanate labels below the
exposure limits. Wear respiratory protection if material is heated, sprayed, used in contained space or if the
exposure limit is exceeded. Individual with lung or breathing problems or prior alleged reactions to isocyanates
must not be exposed to vapor or spray mist. Avoid contact with eyes & skin. Store in tightly closed containers
to prevent moisture contamination.
8. Exposure Controls / Personal Protection
Country specific exposure limits have not been established or are not applicable unless listed below
Chemical Name TLV*
EINECS No CAS Number STEL LTEL (PEL)
202-612-5 97-85-8 NE NE
Isobutyl Isobutyrate
204-658-1 123-26-4 200 ppm 150 ppm
n-butyl Acetate
212-485-8 822-06-0 0.02ppm 0.005ppm
Hexamethylene di-isocyanate
Industrial Hygiene/ Ventilation Measures.
Page | 2
Good industrial hygiene is achieved through engineering control such as ventilation. When
that doesn't provide full protection the use of respirators and other personal protective equipment is an
absolute necessity. Exhaust air may be cleaned by scrubbers or filter, curing ovens must be ventilated
to prevent emissions into the workplace.
Respiratory Protection:
When the airborne concentration of HDI monomer and HDI polyisocyanate exceeds the TLV
(Threshold Limit Values) use a supplied air respirator either positive pressure or continuous flow
type). Observe OSHA regulations for respirator use (29 CFR 1910.134). At elevated temperature use
a supplied air (either positive pressure or continuous flow) respirator even in non-spray application.
Hand Protection: Gloves should be worn. Nitrile rubber gloves, Butyl rubber gloves, Neoprene
gloves.
Eye Protection: Chemical safety goggle, with a face shield when there is a greater risk of splash.
Skin and Body Protection: Avoid skin contact. Use appropriate clothing to prevent skin contact.
Gloves, long sleeved shirts and pants.
Medical Surveillance: All applicants who are assigned to an isocyanate work area should undergo a
pre-placement medical evaluation. A history of eczema or respiratory allergies such as hay fever are
possible reasons for medical exclusion from isocyanate areas. People with asthma should be excluded
form isocyanate work area. Once a worker has been diagnosed as sensitized to isocyanate, no further
exposure can be permitted.
Additional Protective Measures: Emergency Showers & Eye Wash Stations should be available.
9. Physical and Chemical Properties
Viscous
Physical Status
82癋
Flash point
0.96-1.06
Specific Gravity
1.7
Lower explosion limit
7.6
Upper explosion limit
Not soluble
Solubility in water
248-304癋
Boiling Range
10. Stability and Reactivity
Stable under normal conditions of use and storage
Water, amines, strong bases, alcohols, copper alloys
Materials to avoid:
Contact with moisture, other materials that react
Hazards Reactions:
with isocyanate , or temperatures above 350癋
(177癈) may cause polymerization.
By fire and high heat: carbon dioxide, carbon
Hazardous decomposition products
monoxide, oxides of nitrogen, dense black smoke,
hydrogen cyanide, isocyanic acid & other
undetermined compounds.
11. Toxicological Information
Acute Oral Toxicity
LD50> 5,000 mg/kg rat
Skin Irritation
Rabbit, exposure time 4 hours, slightly irritating
Eye irritation
Rabbit, slightly irritating
Page | 3
12. Ecological Information
Biodegradation: 1X exposure time: 28d, not readily biodegradable
Acute & Prolonged Toxicity to fish LCO: > 100mg/l (Zebra Fish (Brachydanio reiro),96h)
Acute Toxicity to Aquatic Invertebrates ECO:> 100 mg/l (water flea ( Daphnia magna) , 48h)
Toxicity to Aquatic Plants 100 mg/l (Green algae (scenedesmus subspicatus), 72h)
13. Disposal Considerations
Waste disposal should be in accordance with existing federal, state
Work Disposal Method:
and local environmental control laws. Incineration is the preferred
method.
Do not heat or cut empty container with electric or gas torch. Do not
Empty Container Precautions:
reuse container without through cleaning. Remove all products before
disposal.
14. Transport Information
Other regulated substances, liquid,
Land transport (DOT) proper
N.O.S (Contains Hompolymer of
shipping name:
Hexamethylene Diisocyanate)
Hazard Class 3
US Department of Transportation
Resin Solution
Shipping Name
UN 1866
ID Number
III
Packing Group
Flammable Liquid
Labels
127
Emergency Guide #
15. Regulatory Information
Inventory status Status
Inventory
Y
United States (ISCA)
Y
Canada (DSL)
P
Europe (EINECS/ELINCS)
Y
Australia (AICS)
Y
Japan (MITI)
Y
South Korea (KECL)
Y: All ingredients are on the inventory
E: All ingredients are on the inventory or exempt form listing
P: One or more ingredients fall under the polymer exemption or are on the no longer polymer list. All
other ingredients are on the inventory or exempt from listing
N: Not determined or one or more ingredients are not on the inventory and are not exempt from listing
Federal Regulations
Inventory issues:
All functional components of this product are listed on the TSCA inventory.
SARA Title III Hazard Classes:
Yes
Fire Hazard:
Yes
Reactive Hazard
No
Release of Pressure
Yes
Active Health Hazard
Yes
Chronic Health Hazard
Page | 4
SARA Extremely Hazardous Substance (EHS)/CERCLA Hazardous Substances
CERCLA/SARA RQ
Ingredient
5000 lbs
Butyl acetate
100 lbs
Hexamethylene Diisocyanate (HDI)
State Regulations:
This product does not contain any components that are regulated under California Propositon 65
16. Additional Information
National Fire Protection Association Hazard Ratengs (NEPA (R):
Health 2
Flammability 3
Reactivity 0
PPE
HMIS
Health 2
Flammability 3
Reactivity 1
PPE
Disclaimer:
The information of this MSDS is based on the present state of our knowledge and on current federal
laws. The product is not to be used for other purposes than those specified under Section I without
first obtaining written handling instruction. It is always the responsibility of the user to take all
necessary steps in order to fulfill the demand laid down in the rules and legislation. The information
in this MSDS is meant as a description of the safety measurement of our product; it is not to be
considered as a guarantee of the products' properties.
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