MSDS Sampson 249044
MATERIAL SAFETY DATA SHEET
CAB WHITE PRODUCTION LACQUER SATIN
HMIS Health- 2
HMIS Fire- 3
HMIS Reactivity- 0
1 - CHEMICAL PRODUCT AND COMPANY INFORMATION
PRODUCT NAME: CAB White Production Lacquer Satin
PRODUCT CODE: 249044
MANUFACTURER: Sampson Coatings
ADDRESS: 1900 Ellen Road, Richmond, VA 23230
INQUIRY PHONE NUMBER: 804.359.5070 (all non-emergency)
EMERGENCY PHONE NUMBER: 800.424.9300 (Chemtrec)
DATE PREPARED: 5/6/2009 - this document supercedes all previous material safety data sheets.
VERSION: 4.0
2 - COMPOSITION / HAZARDOUS INGREDIENTS
INGREDIENT CAS NUMBER WT %
Xylenes 1330-20-7 5 - 10
Methyl Ethyl Ketone 78-93-3 0-5
Butyl Cellosolve 111-76-2 0-5
Toluene 108-88-3 20 - 25
Acetone 67-64-1 0-5
Isopropanol 67-63-0 5 - 10
Butyl Acetate 123-86-4 5 - 10
Isobutyl Isobutyrate 97-85-8 5 - 10
Ethylbenzene 100-41-4 0-5
Benzene 71-43-2 < 0.5
Titanium Dioxide 13463-67-7 10 - 20
Diisononyl Phthalate 68515-48-0 0-5
polymer Proprietary 0 - 20
Cellulose Acetate Butyrate 9004-36-8 5 - 10
3 - HAZARDS
EMERGENCY OVERVIEW INSTRUCTIONS
Combustion fumes may be harmful.
May cause skin irritation on prolonged contact.
Vapors irritating to eyes and respiratory tract.
FLAMMABLE
Vapors may spread a long distance to electrical source and ignite.
EYE CONTACT: May cause irritation.
SKIN CONTACT:INHALATION: Harmful if inhaled. Repeated overexposure instances or a single large exposure may
sensitize an individual. Persons sensitized by a previous exposure will show symptoms
when exposed to concentrations much lower than exposure limits or exposure guidelines.
Sensitized individuals may show symptoms when exposed to dust, cold air or other
irritants. This increased sensitivity may last for weeks, months or it may be permanent.
May cause allergic respiratory reaction. Lung damage (including fibrosis and decreased
lung function) and respiratory sensitization may be permanent. Symptoms may occur
hours after exposure and include nausea, lightheadedness, drowsiness, dizziness, loss of
coordination, chest tightness, wheezing, cough, shortness of breath and asthmatic attack.
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MSDS Sampson 249044
INGESTION:CHRONIC HEALTH EFFECTS: Prolonged overexposure to solvent vapors may cause adverse effects to the liver, urinary,
cardiovascular and reproductive systems. Reports have associated repeated and
prolonged overexposure to solvents with permanent brain and nervous system damage.
SIGNS / SYMPTOMS: Overexposure may cause headaches and dizziness.
TARGET ORGANS: No information found.
PRE-EXISTING CONDITIONS: Skin allergies, eczema, asthma and other respiratory disorders may be aggravated by
exposure.
4 - FIRST AID
EYE CONTACT: Flush eyes with large amounts of water for 15 minutes. Get medical attention if symptoms
of overexposure or irritation persists.
SKIN CONTACT: Run a gentle stream of water over the affected area for 15 minutes. A mild soap may be
used if available.
INHALATION: Remove from area to fresh air. If symptomatic, contact a poison control center,
emergency room or physician for treatment information.
INGESTION: Gently wipe or rinse the inside of the mouth with water. Never give anything by mouth to
an unconscious person. Contact a poison control center, emergency room or physician
right away as further treatment may be necessary.
5 - FIRE FIGHTING MEASURES
FLASH POINT: 39癋
EXTINGUISHING MEDIA: Dry chemical, Carbon dioxide, Foam, Water spray for large fires
PROTECTIVE EQUIPMENT: Wear self-contained breathing apparatus and protective clothing to prevent contact with
skin and clothing.
SPECIAL FIREFIGHTING PROCEDURES: None.
UNUSUAL FIRE/EXPLOSION HAZARDS: Vapor may spread long distance to electrical source and ignite.
NFPA Health- 2
NFPA? NFPA Fire- 3
NFPA Reactivity- 0
6 - ACCIDENTAL RELEASE MEASURES
PERSONNEL PRECAUTIONS: Use personal protective equipment.
ENVIRONMENTAL PRECAUTIONS: Avoid runoff into ditches, storm sewers and other waterways.
SPILL CLEANUP MEASURES: Absorb spill with inert material and place in a chemical waste container. Provide
ventilation. Clean up spills immediately and observe precautions related to protective
equipment.
7 - HANDLING AND STORAGE
HANDLING: Use with adequate ventilation. Avoid breathing vapor and contact with eyes, skin and
clothing.
STORAGE: Store in a cool dry well ventilated area. Keep away from heat and flame.
HYGIENE: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhaling vapor or
mist.
8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: The level of protection and types of controls necessary will vary depending upon potential
exposure conditions. Select controls based on a risk assessment of local circumstances.
Appropriate measures include: Adequate explosion-proof ventilation to control airborne
concentrations below the exposure guidelines/limits. Eye washes and showers for
emergency use.
EYE / FACE PROTECTION: Wear splash goggles on face to protect eyes.
SKIN PROTECTION: Wear butyl rubber gloves, protective clothing and chemical resistant boots.
RESPIRATORY PROTECTION: If engineering controls do not maintain airborne concentrations to a level which is
adequate to protect worker health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation. Check with respiratory
protective equipment suppliers.
OTHER PROTECTIONS: Facilities that store or utilize this material should be equipped with an eyewash facility and
a safety shower.
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MSDS Sampson 249044
PEL (OSHA) / TLV (ACGIH): Xylenes (1330-20-7)
PEL (OSHA): 100 ppm (TWA)
TLV (ACGIH): 100 ppm (TWA), 150 ppm (STEL)
Methyl Ethyl Ketone (78-93-3)
PEL (OSHA): 200 ppm (TWA)
TLV (ACGIH): 200 ppm (TWA), 300 ppm (STEL)
Butyl Cellosolve (111-76-2)
PEL (OSHA): 50 ppm (TWA)
TLV (ACGIH): 20 ppm (TWA)
Toluene (108-88-3)
PEL (OSHA): 200 ppm (TWA)
TLV (ACGIH): 20 ppm (TWA)
Acetone (67-64-1)
PEL (OSHA): 750 ppm (TWA), 1000 ppm (STEL)
TLV (ACGIH): 500 ppm (TWA), 750 ppm (STEL)
Isopropanol (67-63-0)
PEL (OSHA): 400 ppm (TWA)
TLV (ACGIH): 200 ppm (TWA), 400 ppm (STEL)
Butyl Acetate (123-86-4)
PEL (OSHA): 150 ppm (TWA)
TLV (ACGIH): 150 ppm (TWA); 200 ppm (STEL)
Isobutyl Isobutyrate (97-85-8)
PEL (OSHA): Not Established
TLV (ACGIH): Not Established
Ethylbenzene (100-41-4)
PEL (OSHA): 100 ppm (TWA), 125 ppm (STEL)
TLV (ACGIH): 100 ppm (TWA)
Benzene (71-43-2)
PEL (OSHA): 1 ppm (TWA)
TLV (ACGIH): 0.5 ppm (TWA); 2.5 ppm (STEL)
Titanium Dioxide (13463-67-7)
PEL (OSHA): 15 mg/m3 (TWA)
TLV (ACGIH): 10 mg/m3 (TWA)
Diisononyl Phthalate (68515-48-0)
PEL (OSHA): Not Established
TLV (ACGIH): Not Established
Cellulose Acetate Butyrate (9004-36-8)
PEL (OSHA): Not Established
TLV (ACGIH): Not Established
9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL APPEARANCE: Opaque Liquid
COLOR: White
FLASH POINT: 39癋
BOILING RANGE: 176 - 299 癋
DENSITY: 8.2 - 8.6 lbs/gal
MATERIAL VOC (as supplied): 5.6 lbs/gal 670 g/l
COATING VOC (EPA Method 24): 5.6 lbs/gal 670 g/l
10 - STABILITY AND REACTIVITY
CHEMICAL STABILITY: The risk for chemical reactivity is low to none.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
MATERIALS TO AVOID: None.
DECOMPOSITION PRODUCTS (FIRE): carbon monoxide; carbon dioxide; aldehydes; acrylic monomers
11 - TOXICOLOGICAL INFORMATION
LD50, LC50: Xylenes (1330-20-7 )
LD50 (oral rat): 4300 mg/kg
LC50 (inhalation rat): 5000 ppm (4 hr)
Methyl Ethyl Ketone (78-93-3 )
LD50 (oral rat): 2737 mg/kg
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MSDS Sampson 249044
LC50 (inhalation rat): 23,500 mg/m3 (8 hr)
Butyl Cellosolve (111-76-2 )
LD50 (oral rat): 5,890 mg/kg
LC50 (inhalation rat): Not Established
Toluene (108-88-3 )
LD50 (oral rat): 930 mg/kg
LC50 (inhalation rat): 9980 ppm (8 hr)
Acetone (67-64-1 )
LD50 (oral rat): 5,800 mg/kg
LC50 (inhalation rat): 50,100 mg/m3 (8 hr)
Isopropanol (67-63-0 )
LD50 (oral rat): 5,045 mg/kg
LC50 (inhalation rat): 16,000 ppm (8 hr)
Butyl Acetate (123-86-4 )
LD50 (oral rat): 10,768 mg/kg
LC50 (inhalation rat): 390 ppm (4 hr)
Isobutyl Isobutyrate (97-85-8 )
LD50 (oral rat): 12,800 mg/kg
LC50 (inhalation rat): 5,000 ppm (6 hr)
Ethylbenzene (100-41-4 )
LD50 (oral rat): 3,500 mg/kg
LC50 (inhalation rat): Not Established
Benzene (71-43-2 )
LD50 (oral rat): 930 mg/kg
LC50 (inhalation rat): 10,000 ppm (7 hr)
Titanium Dioxide (13463-67-7 )
LD50 (oral rat): Not Established
LC50 (inhalation rat): Not Established
Diisononyl Phthalate (68515-48-0 )
LD50 (oral rat): Not Established
LC50 (inhalation rat): Not Established
Cellulose Acetate Butyrate (9004-36-8 )
LD50 (oral rat): >6,400 mg/kg
LC50 (inhalation rat): Not Established
12 - ECOLOGICAL INFORMATION
No data available.
13 - DISPOSAL CONSIDERATIONS
Waste from this product is hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Dispose of
waste in accordance with Federal, State and Local regulations regarding pollution.
14 - TRANSPORT INFORMATION
DOT UN Number: UN 1263
DOT Hazard Class: Class 3 : Packing Group II
DOT Description/Name: Paint
15 - REGULATORY INFORMATION
TSCA CERTIFICATION: The chemicals in this material are on the TSCA Section 8 Inventory.
SARA 313: This product contains a toxic chemical or chemicals subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR part 372:
Xylenes (1330-20-7); Methyl Ethyl Ketone (78-93-3); Butyl Cellosolve (111-76-2); Toluene
(108-88-3); Isopropanol (67-63-0); Benzene (71-43-2)
California Proposition 65: This product contains a toxic chemical or chemicals listed by California as known to
cause cancer, birth defects or other reproductive harm in compliance with Proposition 65,
the Safe Drinking Water and Toxic Enforcement Act of 1986 (concentration > 0.1% by
weight):
Toluene (108-88-3); Ethylbenzene (100-41-4); Benzene (71-43-2)
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MSDS Sampson 249044
16 - OTHER INFORMATION
HMIS Key
4 = Severe Hazard
3 = Serious Hazard
2 = Moderate Hazard
1 = Slight Hazard
0 = Minimal Hazard
Acronyms and Abbreviations
ACGIH - American Conference of Governmental Industrial Hygiene (http://www.acgih.org)
OSHA - U.S. Occupational Health and Safety Administration (http://www.osha.gov)
IARC - International Agency for Research on Cancer (http://www.iarc.fr)
NTP - National Toxicology Program (http://ntp.niehs.nih.gov)
NIOSH - National Institute for Occupational Safety and Health (http://www.cdc.gov/niosh)
PEL - Permissable Exposure Limit
TLV - Threshold Limit Value
TWA - Time Weighted Average (over 8 hour period)
STEL - Short Term Exposure Limit
NFPA is a registered trademark of the National Fire Protection Association (www.nfpa.org).
HMIS is a registered trademark of the National Paint & Coatings Association (www.paint.org/hmis/).
DISCLAIMER
This document is generated to distribute health, safety and environmental data. It is not a specification sheet nor should any data be construed as a specification. The
information on this MSDS was obtained from sources which we believe are reliable. The information is provided without any warranty, expressed or implied, regarding its
correctness. Some information and conclusions are drawn from sources other than direct tests on the product.
The methods of handling, storage, use and disposal of the product are beyond our control and for this and other reasons we do not assume responsibility. We expressly
disclaim liability for loss, damage, or expense arising out of or in any way connected with the handling, storage, use or disposal of this product.
If the product is used as a component in another product, this MSDS information may not be applicable.
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