M104-F224 FLAT BLACK LACQUER ENAMEL
MATERIAL SAFETY DATA SHEET
RPM Wood Finishes Group
3194 Hickory Boulevard
Hudson, North Carolina 28638
828-728-8266
EMERGENCY PHONE (CHEM TREC): . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-800-424-9300
FOR ALL INTERNATIONAL TRANSPORTATION ACCIDENTS. . . . . . . . . . . . . . . . .1-703-527-3887 (collect)
Health: 2 Flammability: 4 Reactivity 0
PRODUCT NAME: M104-F224 FLAT BLACK LACQUER ENAMEL
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 30/07/04
SUPERCEDES: 08/07/04
MSDS NO. M104-F224
OSHA HAZ. CLASS: Eye irritant. Neurotoxin - may cause nervous system damage.
Mucous membrane (respiratory tract) irritant.
II. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME % CAS # PEL
acetone 11-20 67-64-1 1000 ppm TWA; 2400 mg/m3 TWA
ethyl acetate 11-20 141-78-6 400 ppm TWA; 1400 mg/m3 TWA
propane 11-20 74-98-6 1000 ppm TWA; 1800 mg/m3 TWA
n-butyl acetate 11-20 123-86-4 150 ppm TWA; 710 mg/m3 TWA
toluene 1-10 108-88-3 200 ppm TWA; C 300 ppm
isobutane 1-10 75-28-5 No PEL established
isopropanol 1-10 67-63-0 400 ppm TWA; 980 mg/m3 TWA
Cellulose Nitrate, Cellulose Ester 1-10 9004-70-0 No PEL established
isobutyl isobutyrate 1-10 97-85-8 No PEL established
rosin ester 1-10 8050-31-5 No PEL established
diisononyl phthalate 1-10 68515-48-0 No PEL established
carbon black <1 1333-86-4 3.5 mg/m3 TWA
butanol <1 78-92-2 150 ppm TWA; 450 mg/m3 TWA
III. HAZARDS IDENTIFICATION
Absorption., Inhalation, ingestion, skin, eyes.
Routes of Entry:
Skin disease including eczema and sensitization. Respiratory disease including
Medical Conditions Aggravated:
asthma and bronchitis. Eye disease. Kidney disease. Liver disease.
Immediate (Acute) Health Effects
Irritation may be delayed for several hours. Can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
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Substance causes moderate skin irritation. Continued or prolonged contact may
Skin Contact:
irritate the skin and cause a skin rash (dermatitis). Can cause minor skin irritation,
defatting, and dermatitis.
Can cause irritation. Can cause moderate irritation, tearing and reddening, but not
Eye Contact:
likely to permanently injure eye tissue. Contact with the eyes may cause moderate to
severe eye injury. Eye contact may result in tearing and reddening, but not likely to
permanently injure eye tissue. Temporary vision impairment (cloudy or blurred
vision) is possible.
Can be absorbed through the skin but exposure must be extensive before adverse
Skin Absorption:
health effects occur. Harmful if absorbed through the skin. May cause severe
irritation and systemic damage. No absorption hazard in normal industrial use.
Harmful if swallowed. Aspiration of material into the lungs can cause chemical
Ingestion:
pneumonitis which can be fatal. Minimal toxicity Irritating to mouth, throat, and
stomach. Can cause abdominal discomfort, nausea, vomiting and diarrhea.
Target Organ Acute Toxicity:
Acetone respiratory system, skin, eyes, CNS
Ethylacetate eyes, skin, respiratory system
Propane CNS
n-Butyl acetate eyes, skin, respiratory system, CNS
Toluene CNS, liver, kidneys, skin, eyes, respiratory system
Isobutane CNS
Isopropyl alcohol eyes, skin, respiratory system
Carbon black respiratory system, eyes, lymphatic cancer
n-Butyl alcohol eyes, CNS, skin, respiratory system
Long-Term (Chronic) Health Effects:
ACGIH. IARC. NIOSH. NTP. OSHA. Contains a substance that is a probable cancer
Carcinogenicity:
hazard based on human studies.
Possible reproductive hazard.
Reproductive and Developmental
Toxicity:
No data available to indicate product or any components present at greater than 0.1%
Mutagenicity:
is mutagenic or genotoxic.
Upon prolonged and/or repeated exposure, can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
Prolonged or repeated contact may cause irritation. Upon prolonged or repeated
Skin Contact:
contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to
cause permanent damage.
Upon prolonged or repeated contact, can cause moderate to severe eye injury. Eye
Eye Contact:
contact may result in tearing and reddening, but not likely to permanently injure eye
tissue. Temporary vision impairment (cloudy or blurred vision) is possible.
Upon prolonged or repeated exposure, harmful if absorbed through the skin. May
Skin Absorption:
cause severe irritation and systemic damage.
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Respiratory Tract. Skin. Skin. Eyes. Nervous System. Respiratory Tract. Nervous
Target Organ Chronic Toxicity:
System. Eyes. Kidneys. Liver.
No additional health information available.
Supplemental Health Hazard
Information:
IV. FIRST AID
Remove to fresh air. If breathing is difficult, have a trained individual administer
Inhalation:
oxygen. If not breathing, give artificial respiration and have a trained individual
administer oxygen. Get medical attention immediately.
Immediately flush eyes with plenty of water. Get medical attention, if irritation
Eyes:
persists. Immediately flush eyes with plenty of water for at least 20 minutes retracting
eyelids often. Tilt the head to prevent chemical from transferring to the
uncontaminated eye. Get immediate medical attention and monitor the eye daily as
advised by your physician.
Wash with soap and water. Get medical attention if irritation develops or persists.
Skin Contact:
Wash with soap and water. Get medical attention if irritation develops or persists.
First aid is normally not required. No hazard in normal industrial use. Do not induce
Ingestion:
vomiting. Seek medical attention if symptoms develop. Provide medical care provider
with this MSDS.
No additional first aid information available.
Notes to MD:
V. FIRE FIGHTING MEASURES
Flammability Summary:
o
-144 (CALC.) F
Flash Point:
12.8 @ 77?F
Upper Flammable/Explosive
Limit, % in air:
1.4 @ 77?F
Lower Flammable/Explosive
Limit, % in air:
Flammable Liquid. Can release vapors that form explosive mixtures at temperatures at
Fire Hazards:
or above the flash point. Vapors may be ignited by heat, sparks, flames or other
sources of ignition at or above the low flash point giving rise to a Class B fire. Vapors
are heavier than air and may travel to a source of ignition and flash back.
Use alcohol resistant spray, Carbon Dioxide, water spray or dry chemical to
Extinguishing Media:
extinguish a fire involving this chemical. Flammable component(s) of this material
may be lighter than water and burn while floating on the surface. H2O, CO2, dry
chemical, foam. Carbon dioxide Alcohol foam Use alcohol resistant foam, carbon
dioxide, or dry chemical extinguishing agents. Water spray or fog may also be
effective for extinguishing if swept across the base of the fire. Water can also be used
to absorb heat and keep exposed material from being damaged by fire.
Flammable component(s) of this material may be lighter than water and burn while
Fire Fighting Instructions:
floating on the surface.Do not enter fire area without proper protection including self-
contained toxic breathing apparatus and full protective equipment. Fight fire from a
safe distance and a protected location due to the potential of hazardous vapors and
decomposition products. Flammable component(s) of this material may be lighter than
water and burn while floating on the surface. Use water spray/fog for cooling.
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Hazardous Combustion Products: Carbon dioxide, Carbon monoxide Hydrogen cyanide Nitrogen containing gases
Toxic gases
VI. ACCIDENTAL RELEASE MEASURES
Exposure to the spilled material may be irritating or harmful. Follow personal
Health Consideration for Spill
Response: protective equipment recommendations found in Section VIII of this MSDS.
Additional precautions may be necessary based on special circumstances created by
the spill including; the material spilled, the quantity of the spill, the area in which the
spill occurred. Also consider the expertise of employees in the area responding to the
spill.
Prevent the spread of any spill to minimize harm to human health and the
Spill Mitigation Procedures
General Methods: environment if safe to do so. Wear complete and proper personal protective
equipment following the recommendation of Section VIII at a minimum. Dike with
suitable absorbent material like granulated clay. Gather and store in a sealed container
pending a waste disposal evaluation.
VII. HANDLING AND STORAGE
Use spark-proof tools and explosion-proof equipment. Wash thoroughly after
Handling:
handling. Avoid contact with material. "Empty" containers retain product residue
(liquid and/or vapor) and can be dangerous. Remove contaminated clothing and wash
before reuse. Ground and bond containers when transferring material. Harmful or
irritating material. Avoid contact and avoid breathing the material. Use only in a well
ventilated area.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in
Storage:
a cool place in original container and protect from sunlight. Keep container closed
when not in use. Do not store in direct sunlight. Store in a cool dry ventilated location.
Isolate from incompatible materials and conditions. Keep container(s) closed.
VIII. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
Ventilation should effectively remove and prevent buildup of any vapor/mist/fume
Engineering Controls:
generated from the handling of this product. Explosion proof exhaust ventilation
should be used. Local exhaust ventilation or other engineering controls are normally
required when handling or using this product to avoid overexposure.
Protective Equipment
Respirators should be selected by and used under the direction of a trained health and
Respiratory Tract:
safety professional following requirements found in OSHA's respirator standard (29
CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A
written respiratory protection program, including provisions for medical certification,
training, fit testing, exposure assessments, maintenance, inspection, cleaning, and
convenient, sanitary storage should be implemented.
Wear chemically resistant safety glasses with side shields when handling this product.
Eyes:
Wear additional eye protection such as chemical splash goggles and/or face shield
when the possibility exists for eye contact with splashing or spraying liquid, or
airborne material. Do not wear contact lenses. Have an eye wash station available.
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Avoid skin contact by wearing chemically resistant gloves, an apron and other
Skin:
protective equipment depending upon conditions of use. Inspect gloves for chemical
break-through and replace at regular intervals. Clean protective equipment regularly.
Wash hands and other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
IX. PHYSICAL DATA
COLORED LIQUID
Physical State:
STRONG SOLVENT
Odor:
6.4092
Solids Vol %:
10.2066
Solids Wt %:
4.5305
Material VOC lbs/gal:
544.07
Material VOC gms/l:
5.5758
Coatings VOC lbs/gal:
669.599
Coatings VOC gms/l:
6.4369
Weight per gallon:
X. STABILITY AND REACTIVITY
Stable. Normally stable. Keep away from heat, sparks and flame.
Stability Information:
Avoid: heat, sparks, flame and oxidizing agents. High temperatures. None known.
Conditions to Avoid:
Strong oxidizing agents. Strong acids. Strong alkalies. Amines. Oxidizing materials.
Chemical Incompatibility:
Acids. Acetic anhydride. Peroxides.
Hazardous Polymerization will not occur.
Hazardous Polymerization:
XI. TOXICOLOGICAL INFORMATION
Chemical Name CAS Number LD50/LC50
Acetone 67-64-1 Inhalation LC50 Rat : 50100 mg/m3/8H; Inhalation LC50 Mouse : 44
gm/m3/4H; Oral LD50 Rat : 5800 mg/kg; Oral LD50 Mouse : 3 gm/kg
Acetic acid, ethyl ester 141-78-6 Inhalation LC50 Rat : 200 gm/m3; Inhalation LC50 Mouse : 45 gm/m3/2H;
Oral LD50 Rat : 5620 mg/kg; Oral LD50 Mouse : 4100 mg/kg; Dermal LD50
Rabbit : >20 mL/kg
Acetic acid, butyl ester 123-86-4 Inhalation LC50 Rat : 2000 ppm/4H; Inhalation LC50 Mouse : 6 gm/m3/2H;
Oral LD50 Rat : 10768 mg/kg; Oral LD50 Mouse : 6 gm/kg; Dermal LD50
Rabbit : >17600 mg/kg
Toluene 108-88-3 Inhalation LC50 Rat : 49 gm/m3/4H; Inhalation LC50 Mouse : 400 ppm/24H;
Oral LD50 Rat : 636 mg/kg; Dermal LD50 Rabbit : 14100 uL/kg
Propane, 2-methyl- 75-28-5 Inhalation LC50 Rat : 57 pph/15M
Isopropyl alcohol 67-63-0 Inhalation LC50 Rat : 16000 ppm/8H; Oral LD50 Rat : 5045 mg/kg; Oral
LD50 Mouse : 3600 mg/kg; Dermal LD50 Rabbit : 12800 mg/kg
Nitrocellulose 9004-70-0 Oral LD50 Rat : >5 gm/kg; Oral LD50 Mouse : >5 gm/kg
Isobutyric acid, isobutyl ester 97-85-8 Inhalation LC50 Rat : 5000 ppm/6H; Oral LD50 Rat : 12800 mg/kg; Dermal
LD50 Rabbit : >8600 mg/kg
Carbon black 1333-86-4 Oral LD50 Rat : >15400 mg/kg; Dermal LD50 Rabbit : >3 gm/kg
sec-Butyl alcohol 78-92-2 Inhalation LC50 Rat : 8000 ppm/4H; Oral LD50 Rat : 790 mg/kg; Oral LD50
Mouse : 2680 mg/kg; Dermal LD50 Rabbit : 3400 mg/kg
XII. ECOLOGICAL INFORMATION
Keep out of waterways. Moderate ecological hazard. This product may be dangerous
Overview (for ingredients):
to plants and/or wildlife.
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XIII. DISPOSAL CONSIDERATIONS
The waste may be a listed and/or characteristic hazardous waste. The waste may be a
Waste Description for Spent
Product: listed hazardous waste. The waste may be a "special" waste. Spent or discarded
material is a hazardous waste.
Comply with all Local, State, Federal, and Provincial Environmental Regulations.
Disposal Methods:
Dispose of by incineration following Federal, State, Local, or Provincial regulations.
If discarded, this product is considered a RCRA ignitable waste, D001.
Potential EPA Waste Codes:
Components Subject to USEPA Land Disposal Restrictions:
Acetone 67-64-1 19.25 %
Ethylacetate 141-78-6 18.8 %
Toluene 108-88-3 7.00 %
n-Butyl alcohol 78-92-2 0.13 %
XIV. TRANSPORTATION INFORMATION
AEROSOLS, FLAMMABLE, 2.1, UN 1950
DOT
See 49CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations.
XV. REGULATORY INFORMATION
Chemical Name Regulation CASRN %
Toluene SARA 313 Reportable: 108-88-3 7.00
Isopropyl alcohol SARA 313 Reportable: 67-63-0 4.69
sec-Butyl alcohol SARA 313 Reportable: 78-92-2 0.13
1333-86-4 0.57
Carbon Black California Proposition 65 Cancer List:
108-88-3 7.00
Toluene California Proposition 65
Developmental Toxicity:
64-17-5 0.57
Ethyl alcohol California Proposition 65
Developmental Toxicity:
67-64-1 19.25
acetone New Jersey Right To Know:
141-78-6 18.8
ethyl acetate New Jersey Right To Know:
74-98-6 14.73
propane New Jersey Right To Know:
123-86-4 14.55
n-butyl acetate New Jersey Right To Know:
108-88-3 7.00
toluene New Jersey Right To Know:
XVI. ADDITIONAL INFORMATION
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION
Other Information:
CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY
FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A
PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES
OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA
OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS
AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND
INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION
OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE
ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
MSDS glossary.
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