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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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CHEMICAL PRODUCT IDENTIFICATION:
PRODUCT ID . . . . . . . . . . : TLP4700
PRODUCT CLASS . . . . . . . . . : CELLULOSE LACQUER, SOLVENT BASED
TRADE NAME . . . . . . . . . . : WHITE/LIGHT TINT BASE LACQUER - GLOSS
MSDS PREPARATION DATE . . . . . . : 09/20/2007
MANUFACTURER IDENTIFICATION:
NAME . . . . . . . . . . . . . : INSL-X PRODUCTS CORPORATION
ADDRESS . . . . . . . . . . . . : 50 HOLT DRIVE
STONY POINT, NY 10980
TELEPHONE . . . . . . . . . . . : (800) 225-5554
EMERGENCY CONTACT . . . . . . . : CHEMTREC
EMERGENCY TELEPHONE . . . . . . : (800) 424-9300
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SECTION 2 - COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
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1
CAS# 1330-20-7
XYLENE (MIXED ISOMERS)
PCT BY WT: 9.3250 VAPOR PRESSURE: 5.100 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 100 ppm TWA
ACGIH TLV/STEL: 150 ppm STEL
OSHA PEL/TWA: 100 ppm TWA
LC50: Inhalation (Rat) - 6700 ppm/4H
LD50: Oral (Rat) - 4.3 g/kg
CA PROPOSITION 65: NO
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2
CAS# 108-88-3
TOLUENE
PCT BY WT: 17.1680 VAPOR PRESSURE: 22.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 50 ppm - TWA (Skin)
ACGIH TLV/STEL: 150 ppm - STEL (Skin)
OSHA PEL/TWA: 200 ppm - TWA
OSHA STEL: 150 ppm
OSHA CEILING: 300 ppm
LD50: Oral (Rat) - 636 mg/kg
CA PROPOSITION 65: Yes
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3
CAS# 67-63-0
ISOPROPYL ALCOHOL
PCT BY WT: .5 - 5 VAPOR PRESSURE: 33.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 200 ppm - TWA
ACGIH TLV/STEL: 400 ppm - STEL
OSHA PEL/TWA: 400 ppm - TWA
OSHA STEL: 500 ppm
LC50: Rat (8 Hrs) - > 12,000 ppm
LD50: Oral (Rat) - 5000 mg/kg
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4
CAS# 71-36-3
BUTANOL
PCT BY WT: 1.1340 VAPOR PRESSURE: 4.400 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 20 ppm ?TWA
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TLP4700 PAGE 2
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OSHA PEL/TWA: 100 ppm - TWA
OSHA CEILING: PEL: 50 ppm (Skin)
LC50: Inhalation (Rat, 4 Hr.)- > 8000 ppm
LD50: Oral (Rat)- 2500 mg/kg
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5 METHANOL
CAS# 67-56-1
METHYL ALCOHOL
PCT BY WT: 3.9340 VAPOR PRESSURE: 98.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 200 ppm - TWA (Skin)
ACGIH TLV/STEL: 250 ppm - STEL (Skin)
OSHA PEL/TWA: 200 ppm - TWA
OSHA STEL: 250 ppm - STEL(Skin)
LC50: Inhalation (Rat) - 64,000 ppm/4H
LD50: Oral (Rat) - 5628 mg/kg
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6 2-PENTANONE, 4-METHYL
CAS# 108-10-1
METHYL ISOBUTYL KETONE
PCT BY WT: 1.6620 VAPOR PRESSURE: 16.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 50 ppm - TWA
ACGIH TLV/STEL: 75 ppm - STEL
OSHA PEL/TWA: 100 ppm - TWA
OSHA STEL: 75 ppm
LC50: Inhalation (Rat): 2000-4000 ppm/4H
LD50: Oral (Rat)- 2080 mg/kg
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7 n-BUTYL ACETATE
CAS# 123-86-4
ACETIC ACID BUTYL ESTER
PCT BY WT: 5 - 10 VAPOR PRESSURE: 15.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: TWA 150 ppm
ACGIH TLV/STEL: STEL 200 ppm
OSHA PEL/TWA: TWA 150 ppm
OSHA STEL: 200 ppm
LC50: Inhalation (Rat) - > 1800 ppm/6 Hrs
LD50: Oral (Rat)- 14,130 mg/kg
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8 ISOBUTYL ISOBUTYRATE
CAS# 97-85-8
2-METHYLPROPYL 2-METHYLPROPANOATE
PCT BY WT: .5 - 5 VAPOR PRESSURE: 3.000 MMHG @ 68F
EXPOSURE LIMIT:
LC50: Inhalation, Rat: 5000 ppm/6H
LD50: Oral (Rat): 6400 - 12800 mg/kg
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9 ISOBUTYL ACETATE
CAS# 110-19-0
2-METHYLPROPYL ACETATE
PCT BY WT: 5 - 10 VAPOR PRESSURE: 18.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: TWA 150 ppm
OSHA PEL/TWA: TWA 150 ppm
LC50: Inhalation (Rat, 4Hr.): 3500-3800 ppm
LD50: Oral (Rat)- > 4350 mg/kg
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TLP4700 PAGE 3
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10
CAS# 141-78-6
ETHYL ACETATE
PCT BY WT: .5 - 5 VAPOR PRESSURE: 93.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 400 ppm - TWA
OSHA PEL/TWA: 400 ppm - TWA
LC50: Inhalation (Rat) - 1600 ppm/8H
LD50: Oral (Rat) - >5620 mg/kg
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11 ETHYLBENZENE
CAS# 100-41-4
PCT BY WT: 2.3310 VAPOR PRESSURE: 7.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: TWA 100 ppm
ACGIH TLV/STEL: STEL 25 ppm
OSHA PEL/TWA: TWA 100 ppm
OSHA STEL: 125 ppm
LD50: Oral, Rat - 3500 mg/kg
CA PROPOSITION 65: Yes
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12
CAS# 13463-67-7
TITANIUM DIOXIDE
PCT BY WT: 15 - 20
EXPOSURE LIMIT:
ACGIH TLV/TWA: 10 mg/cu m(Total Dust) - TWA
OSHA PEL/TWA: 10 mg/cu m(Total Dust) - TWA
LD50: Oral (Rat)- >7500 mg/kg (TiO2)
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This product contains one or more reported carcinogens or suspected
carcinogens which are noted in Section 3, Hazards Identification,
CARCINOGENICITY.
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This product contains one or more Hazardous Air Pollutants.
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This product contains pigments, which may become a dust nuisance when
removed by abrasive blasting, sanding, or grinding.
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This product contains one or more reported or suspected reproductive
toxins.
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SECTION 3 - HAZARDS IDENTIFICATION
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POTENTIAL HEALTH EFFECTS
EYES: Causes eye irritation.
SKIN: Prolonged or repeated skin contact may cause drying, cracking
or irritation.
INHALATION: High vapor concentrations may cause drowsiness and
irritation of the eyes or respiratory tract.
INGESTION: Swallowing small amounts of this product during normal
handling is not likely to cause harmful effects, but
swallowing large amounts may be harmful.
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TLP4700 PAGE 4
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MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Any pre-existing respiratory or eye/skin conditions.
POSSIBLE ROUTES OF ENTRY
Inhalation, ingestion, skin absorption.
CARCINOGENICITY
If applicable, refer to the message(s) below.
HEALTH HAZARDS SPECIFIC TO PRODUCT COMPONENTS:
EFFECTS OF CHRONIC OVEREXPOSURE TO:
XYLENE: Studies have shown a possible association with exposure to
xylene and respiratory tract irritation, liver & kidney damage,
nausea, and vomiting in humans. Ethylbenzene has been shown
to cause cancer in laboratory animals. The relevance of this
finding to humans is uncertain. IARC has classified ethyl-
benzene as a possible human carcinogen (Group 2B).
TOLUENE: Intentional abuse, misuse or other massive exposure to toluene
may cause multiple organ (liver, kidney, brain cell) damage
and/or death. Comparable CNS effects have not been shown to
result from occupational exposure to toluene. Prolonged
intentional toluene abuse may lead to hearing loss progressing
to deafness.
Toluene may be harmful to the human fetus based on positive
test results with laboratory animals. Case studies show that
prolonged intentional abuse of toluene during pregnancy can
cause birth defects in humans.
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SECTION 4 - FIRST AID MEASURES
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EMERGENCY FIRST AID:
EYE CONTACT: Flush at once with large amounts of lukewarm water for at
least 15 minutes and get medical attention.
SKIN CONTACT: Remove from skin with soap and water. Remove drenched
clothing. If irritation persists, consult a physician.
INHALATION: If affected by inhalation of vapor or spray mist, remove to
fresh air. If necessary, restore breathing; in this case
contact physician at once.
INGESTION: Seek medical advice.
NOTE TO PHYSICIAN:
Not Applicable.
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SECTION 5 - FIRE FIGHTING MEASURES
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FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL:
Flammability Classification . . . . . : OSHA Flammable Liquid - Class 1B
Flashpoint . . . . . . . . . . . . . : 30.0 鳩
Explosion Level . . . . . . . . . . . : Low - 1.0
High - 36.0
EXTINGUISHING MEDIA
Water spray, dry chemical, carbon dioxide (CO2), alcohol foam
SPECIAL FIRE-FIGHTING PROCEDURES
Wear self-contained breathing apparatus and protective clothing. USE
WATER WITH CAUTION. The fire could easily be spread by the use of water
in an area where the water could not be contained. Use water spray to
keep fire-exposed containers cool. Water may be ineffective in fighting
the fire.
HAZARDOUS DECOMPOSITION
May form: carbon dioxide and carbon monoxide.
UNUSUAL FIRE AND EXPLOSION HAZARDS
FLAMMABLE. Vapors may cause a flash fire or ignite explosively.
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TLP4700 PAGE 5
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Vapors may travel considerable distance to a source of ignition and flash
back. Prevent build-up of vapors or gases to explosive concentrations.
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition (flame, hot surfaces and sources of
electrical, static or frictional sparks). Avoid breathing vapors.
Ventilate area. For large spills, use water spray to disperse vapors and
dilute spill to a nonflammable mixture. Prevent runoff from entering
drains, sewers, or streams.
CLEAN-UP
Absorb liquid on vermiculite, floor absorbent or other absorbent
material.
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SECTION 7 - HANDLING AND STORAGE
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HANDLING
Keep away from heat, sparks and open flame. Use only with adequate
ventilation. Keep from contact with oxidizing materials. Comply with
all national, state, and local codes pertaining to the storage, handling
dispensing and disposal of flammable liquids.
STORAGE
Keep container tightly closed. Keep container in a well-ventilated
place.
SPECIAL COMMENTS
Avoid contact with eyes and prolonged or repeated contact with skin.
Avoid breathing high vapor concentrations. Wash thoroughly after handling.
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SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
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VENTILATION
Use exhaust ventilation to keep airborne concentrations below
exposure limits.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor respirator approved by
NIOSH for protection against chemicals in Section 2 &/or 15.
EYE PROTECTION
Use safety eyewear with splashguards and side shields.
SKIN PROTECTION
For operations where prolonged or repeated skin contact may occur,
impervious gloves should be worn.
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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Physical State . . . . . . . . . . . .: LIQUID
Vapor Pressure . . . . . . . . . . . : 98.00
Vapor Density . . . . . . . . . . . . : 10.80
Boiling Point Range . . . . . . . . . : Lower - 147.0 鳩
Higher - 595.0 鳩
Specific Gravity . . . . . . . . . . : 1.079
Weight per Volume . . . . . . . . . . : 8.9790 LB/GL
VOC - Total (lb/gal). . . . . . . . . : 4.986
Evaporation Rate . . . . . . . . . . .: 4.100 (n-Butyl Acetate = 1)
Volatile by Weight . . . . . . . . . : 55.5305
Volatile by Volume . . . . . . . . . : 69.5842
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TLP4700 PAGE 6
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SECTION 10 - STABILITY AND REACTIVITY
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STABILITY
This product is stable.
INCOMPATIBILITIES (Materials to Avoid)
This product can react violently with strong oxidizing agents and
strong acids.
HAZARDOUS POLYMERIZATION
Will not occur.
CONDITIONS TO AVOID
High temperatures.
HAZARDOUS DECOMPOSITION
May form: carbon dioxide and carbon monoxide.
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SECTION 11 - TOXICOLOGICAL INFORMATION
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No data at this time.
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SECTION 12 - ECOLOGICAL INFORMATION
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No data at this time.
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SECTION 13 - DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL
Discharge, treatment, or disposal may be subject to national,
state or local laws. Mix with compatible chemical, which is less
flammable and incinerate.
Since emptied containers retain product residue, follow label
warnings even after container is emptied. Residual vapors may explode
on ignition; do not cut, drill, grind, or weld on or near this container.
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SECTION 14 - TRANSPORT INFORMATION
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DOT HAZARD CLASS . . . . . . . . : 3
DOT PACKAGING GROUP . . . . . . . : PG II
DOT LABEL . . . . . . . . . . . . : FLAMMABLE LIQUID
DOT SHIPPING NAME . . . . . . . . : PAINT
DOT PLACARD . . . . . . . . . . . : FLAMMABLE LIQUID
UN/NA NUMBER . . . . . . . . . . .: UN1263
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SECTION 15 - REGULATORY INFORMATION
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U.S. FEDERAL REGULATORY INFORMATION
TSCA SECTION 8(b) - INVENTORY STATUS:
All components of this product are either listed on the U.S. Toxic
Substances Control Act (TSCA) inventory of chemicals or are otherwise
compliant with TSCA Regulations.
SARA 313 TOXIC CHEMICALS:
This product contains the following substances subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
XYLENE (MIXED ISOMERS)
CAS# 1330-20-7 PCT BY WT: 9.3250
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TOLUENE
CAS# 108-88-3 PCT BY WT: 17.1680
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TLP4700 PAGE 7
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BUTANOL
CAS# 71-36-3 PCT BY WT: 1.1340
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METHYL ALCOHOL
CAS# 67-56-1 PCT BY WT: 3.9340
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METHYL ISOBUTYL KETONE
CAS# 108-10-1 PCT BY WT: 1.6620
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ETHYLBENZENE
CAS# 100-41-4 PCT BY WT: 2.3310
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SECTION 16 - OTHER INFORMATION
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Prepared by . . . . . . . . . . . . . : INSL-X PRODUCTS CORP.
Date of issue . . . . . . . . . . . . : 09/20/2007
Last Revision Date . . . . . . . . . : 09/18/2007
MSDS Prepared for . . . . . . . . . . :
MSDS Last Prepared . . . . . . . . . : NONE
HMIS Rating: Health- 2 Flammability- 3
Reactivity- 0
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This Material Safety Data Sheet conforms to the Hazard Communication
Standard, 29 CFR 1910.1200(g)(4).
The above information pertains to this product as currently formulated
and is based on the information available, as of this date. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are out-
side our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
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Abbreviations used: int.- interior; ext.- exterior; MSDS - Material Safety
Data Sheet; HMIS - Hazardous Materials Information System; CAS - Chemical
Abstracts Services; pct - percent; wt - weight; mm Hg - millimeters of
mercury; F - Fahrenheit; ACGIH - American Conference of Governmental
Industrial Hygienists; TLV - Threshold Limit Value; OSHA - Occupational
Safety and Health Administration; PEL - Permissible Exposure Limit; TWA -
Time-Weighted Average; STEL- Short Term Exposure Limit; N/A- Not applicable
IARC - International Agency for Research on Cancer; NE - Not established
NTP - National Toxicological Program; CFR - Code of Federal Regulations;
OSHA - Z 29CFR 1910, Subpart Z; VOC - Volatile Organic Compounds; TCC -
Tag Closed Cup; LEL - Lower Explosive Limit; Mg/m3 or Mg/Cu M - milligram
per cubic meter; mppcf - millions of particles per cubic foot; ppm - parts
per million; NIOSH - National Institute of Occupational Safety and Health;
MSHA - Mine Safety and Health Administration; CNS - Central Nervous System.
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