MATERIAL SAFETY DATA SHEET

       SECTION 1 ?CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Buehler Sampl-Kwick Liquid

IDENTIFICATION NUMBER: 20-3564,20-3564-320,20-3564-640,20-3568,20-3560

PRODUCT USE/CLASS: Acrylic hardener



SUPPLIER:

BUEHLER, a division of Illinois Tool Works Inc.

41 WAUKEGAN ROAD

LAKE BLUFF, IL 60044



EMERGENCY: 800-424-9300

INFORMATION: 847-295-6500

PREPARER: Technical Department, 847-295-6500

PREPARE DATE: 03/23/09, 23 March 2009



            SECTION 2 ?COMPOSITION/INFORMATION ON INGREDIENTS

ITEM      CHEMICAL NAME                           CAS NUMBER            WT/WT%

01        Trimethylolpropane trimethacrylate      3290-92-4             10.0-30.0

          ester

02        Isobutyl methacrylate                   97-86-9               60.0-100.0









ITEM      ACGIH TLV-         ACGIH TLV-           OSHA PEL-      OSHA PEL ?   COMPANY TLV-   SKIN

          TWA                STEL                 TWA            CEILING       TWA

01        N.E.               N.E.                 N.E.           N.E.          N.E.           NO

02        N.E.               N.E.                 N.E.           N.E.          N.E.           NO









(SEE SECTION 16 FOR ABBREVIATION LEGEND)









                                                   Page 1 of 5

MSDS NUMBER: 9101995

                           SECTION 3 ?HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: Harmful if swallowed. Causes skin and eye irritation. May cause allergic skin reaction.

Inhalation of vapors may cause irritation, leading to headache and dizziness. Contents may develop pressure on

prolonged exposure to heat.

ACUTE EFFECTS ?EYE CONTACT: Moderately irritating to the eyes. May cause swelling, tearing, and

redness.

ACUTE EFFECTS - SKIN CONTACT: Frequent or prolonged contact may irritate the skin and cause a skin rash

(dermatitis). Repeated or prolonged contact may cause sensitization.

ACUTE EFFECTS ?INHALATION: Liquid aspirated into lungs may cause serious injury or death. High vapor

concentrations are irritating to the eyes, nose, throat and lungs. Prolonged inhalation may cause central nervous

system depression with headache, nausea, and dizziness leading to confusion and unconsciousness.

ACUTE EFFECTS - INGESTION: May cause nausea and vomiting.

CHRONIC OVEREXPOSURE EFFECTS: *Preexisting pulmonary and dermatological disorders may be aggravated

by exposure to hazardous components.

OTHER INFORMATION: Not Applicable.

PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT









                               SECTION 4 ?FIRST AID MEASURES

EYE CONTACT: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue

flushing for at least 15 minutes. Have eyes immediately examined and tested by medical personnel.

SKIN CONTACT: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical

attention if symptoms occur. Wash clothing before reuse.

INHALATION: If symptoms occur, remove to fresh air. Medical personnel may administer oxygen if breathing is

difficult. Seek medical attention if symptoms persist.

INGESTION: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce

vomiting, but give one or two glasses of water to drink and get medical attention.



NOTES TO PHYSICIAN: Not Applicable.









                           SECTION 5 ?FIRE FIGHTING MEASURES

FLASH POINT: 120 F (SETAFLASH CLOSED CUP)

LOWER EXPLOSIVE LIMIT: N.A.

UPPER EXPLOSIVE LIMIT: N.A.

AUTOIGNITION TEMPERATURE: No data

EXTINGUISHING MEDIA: ALCOHOL FOAM,CO2, DRY CHEMICAL,FOAM, WATER FOG

UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may rupture or explode (due to pressure build-up)

when exposed to extreme heat. Irritating and/or toxic gases or fumes may be generated by thermal decomposition or

combustion. Vapors are heavier than air and may travel along the ground to be ignited at locations distant from the

source; flashback of flame may occur.

SPECIAL FIREFIGHTING PROCEDURES: Use NIOSH-approved self-contained breathing apparatus and full

protective clothing. Use water to cool exposed containers. Water stream directed into fire may cause frothing with

subsequent spread of flame.









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MSDS NUMBER: 9101995

                     SECTION 6 ?ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove or protect from sources of

ignition such as flames, pilot lights, and heaters. Wear appropriate protective equipment during cleanup. Absorb with

inert material, such as clay. Sweep or shovel into loosely-covered waste container and remove to appropriate waste

area. Dispose of in accordance with federal, state, and local regulations.



                             SECTION 7 ?HANDLING AND STORAGE

HANDLING: Wash thoroughly after handling. Avoid contact with skin and eyes. FOR INDUSTRIAL USE ONLY.

STORAGE: Store in a cool place in original container and protect from sunlight. Refrigeration recommended to

extend to product life. Keep containers closed when not in use. KEEP OUT OF THE REACH OF CHILDREN.









           SECTION 8 ?EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: General ventilation usually adequate. Supplemental ventilation should be approved for

use with combustible vapors.

RESPIRATORY PROTECTION: None normally required under general ventilation. If TLV/PEL is exceeded, if use is

performed in a poorly-ventilated space, or if inhalation effects occur, use NIOSH-approved vapor cartridge respirator in

accordance with applicable health and safety regulations and manufacturer's recommendations.

SKIN PROTECTION: Clean clothing to cover skin. Butyl rubber gloves. PVA gloves. Supported PVA gloves.

EYE PROTECTION: Safety glasses. Chemical splash goggles.

OTHER PROTECTIVE EQUIPMENT: Accessible eye wash and safety shower.

HYGIENIC PRACTICES: Follow good general industrial safety practices during use. Do not smoke or eat during use.

Follow all MSDS/label precautions even after container is emptied.









                  SECTION 9 ?PHYSICAL AND CHEMICAL PROPERTIES

BOILING RANGE:             N.A.                       VAPOR DENSITY:                    Is heavier than air

ODOR:                      Mild acrid                 ODOR THRESHOLD:                   No data

APPEARANCE:                Clear                      EVAPORATION RATE:                 Is slower than Butyl

                                                                                        Acetate

SOLUBILITY IN H2O:    Reacts

FREEZE POINT:         No data                         SPECIFIC GRAVITY:                 0.8914

VAPOR PRESSURE:       No data - low                   pH @ 0.0%:                        N.A.

PHYSICAL STATE:       Liquid                          VISCOSITY:                        Low

COEFFICIENT OF WATER/OIL DISTRIBUTION:                No data

(SEE SECTION 16 FOR ABBREVIATION LEGEND)



                          SECTION 10 ?STABILITY AND REACTIVITY

CONDITIONS TO AVOID: Exposure to heat, sunlight, loss of dissolved air.

INCOMPATIBILITY: Strong Lewis or mineral acids. Strong bases or oxidants. Free radical initiators. Oxygen

scavengers.

HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon. Toxic monomers. Aromatic and aliphatic

hydrocarbons.

HAZARDOUS POLYMERIZATION: May occur if exposed to elevated temperatures or catalysts.

STABILITY: This product is stable under normal storage conditions.









                                                  Page 3 of 5

MSDS NUMBER: 9101995

                        SECTION 11 ?TOXICOLOGICAL PROPERTIES

  COMPONENT TOXICOLOGICAL INFORMATION:

  ----------- CHEMICAL NAME -----------   ------ LD50 ------        ------ LC50 ------

  Trimethylolpropane trimethacrylate es    Not Applicable            Not Applicable

  Isobutyl methacrylate                 Oral-rat 9600mg/kg        ECLo-rat 3600ppm6h







                          SECTION 12 ?ECOLOGICAL INFORMATION

ECOLOGICAL TEST DATA: Not Available







                         SECTION 13 ?DISPOSAL CONSIDERATIONS

DISPOSAL METHOD: Review all current federal, state, and local regulations regarding health and disposal for

appropriate disposal procedures. Product "as sold" may be considered a hazardous waste under Federal RCRA

regulations. When cured, product is inert and non-hazardous, and may be disposed of in landfill if local regulations

permit.







                      SECTION 14 ?TRANSPORTATION INFORMATION

DOT PROPER SHIPPING NAME: Not regulated in containers <110 gal

DOT TECHNICAL NAME: N.A.

DOT HAZARD CLASS: N.A.                            HAZARD SUBCLASS: N.A.

DOT UN/NA CLASS: N.A.                             PACKAGING GROUP: N.A.

                                                  RESP. GUIDE PAGE:



INTERNATIONAL SHIPPING NAME: Resin Compound

INTERNATIONAL ID NUMBER: UN1866

IMDG CLASS (1? 2?: 3, none                                PACKING GROUP: III

IMDG EMS: 305                                               IATA CLASS (1? 2?: 3, none









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MSDS NUMBER: 9101995

                      SECTION 15 ?REGULATORY INFORMATION

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200)

CERCLA ?SARA HAZARD CATEGORY: THIS PRODUCT HAS BEEN REVIEWED, AND IS CONSIDERED,

UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES: IMMEDIATE HEALTH HAZARD

FIRE HAZARD

SARA SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE

REPORTING REQUIREMENTS OF SECTION 313 AND 40 CFR PART 372:

  ----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN

  No SARA Section 313 components exist in this product.

TOXIC SUBSTANCE CONTROL ACT: THE CHEMICAL SUBSTANCES IN THIS PRODUCT ARE ON THE TSCA

SECTION 8 INVENTORY. THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT

TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:

  ----------- CHEMICAL NAME ----------- CAS NUMBER

  No components found.

NEW JERSEY RIGHT-TO-KNOW: THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG

THE TOP 5 COMPONENTS IN THIS PRODUCT:

  ----------- CHEMICAL NAME ----------- CAS NUMBER

  No non-hazardous materials are among the top five ingredients.

PENNSYLVANIA RIGHT-TO-KNOW: THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN

THE PRODUCT AT GREATER THAN 3%:

  ----------- CHEMICAL NAME ----------- CAS NUMBER

  No non-hazardous ingredients are present at greater than 3%.

CALIFORNIA PROPOSTION 65: No Proposition 65 chemicals known to exist in this product.



CANADIAN WHMIS: THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT

REGULATIONS EXCEPT FOR USE OF THE 16 HEADINGS.

CANADIAN WHMIS CLASS: D2B, B3

COMPONENT RCRA CLASSIFICATIONS: Not regulated

COMPONENT RCRA CODES: Not Applicable.

CERCLA RQ VALUE (MINIMUM): None known









                           SECTION 16 ?OTHER INFORMATION

HMIS RATINGS

HEALTH: 2                       FLAMMABILITY: 2              REACTIVITY: 0

PREVIOUS MSDS REVISION DATE: 11/26/03, 26 Nov 03

REASON FOR REVISION: Administrative change for new format.



VOLATILE ORGANIC COMPOUNDS: 0 grams/ltr (calculated)



LEGEND:

N.A. ?NO INFORMATION         N.E. ?NOT ESTABLISHED        N.D. ?NOT DETERMINED

ABBREVIATIONS: ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS; OSHA

= OCCUPATIONAL HEALTH AND SAFETY ADMINISTRATION; TLV-TWA = THRESHOLD LIMIT VALUE ?TIME

WEIGHTED AVERAGE (8 HOURS); STEL = SHORT-TERM EXPOSURE LIMIT (15 MINUTES); C = CEILING

VALUE; PEL = PERMISSIBLE EXPOSURE LIMIT



DISCLAIMER: TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED IN THIS MSDS IS

ACCURATE OR IS OBTAINED FROM SOURCES BELIEVED TO BE ACCURATE. HOWEVER, NO LIABILITY,

EXPRESSED OR IMPLIED, IS ASSUMED FOR THE ACCURACY OR COMPLETENESS OF THE INFORMATION

CONTAINED HEREIN. BUYER ASSUMES LIABILITY IN ITS USE OF THE MATERIAL.







                                           Page 5 of 5

MSDS NUMBER: 9101995