E.E. Zimmerman Company/Elroy Turpentine Company Prepared: 1/06
P.O. Box 111254
Pittsburgh, PA 15238
(412) 963-0949 www.eezimmermanco.com
MATERIAL SAFETY DATA SHEET
E-Z LACQUER THINNER
EMERGENCY CONTACT: FOR CHEMICAL EMERGENCY - SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT,
CALL CHEMTREC AT 1-(800)-424-9300, DAY OR NIGHT.
HMIS NFPA
INDEX
4 - Severe Health *2 Health Not Determined
3 - Serious Flammability 3 Flammability Not Determined
2 - Moderate Physical Hazard 1 Reactivity Not Determined
1 - Slight
0 - Insignificant * denotes chronic hazard
Section 2. COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT(S) CAS Number % (by volume)
TOLUENE 108-88-3 43.0
ACETONE 67-64-1 23.0- 27.0
ALIPHATIC PETROLEUM DISTILLATES 64742-89-8 18.0- 22.0
METHYL ALCOHOL 67-56-1 11.0
ISOBUTYL ISOBUTYRATE 97-85-8 1.0- 3.0
Section 3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS:
EYE:
Can cause eye irritation. Symptoms include stinging, tearing, redness and swelling of eyes.
SKIN:
May cause mild skin irritation. Prolonged or repeated contact may dry the skin. Symptoms
may include redness, burning, drying and cracking of skin, and skin burns. Passage of this material
into the body through the skin is possible, and may add to toxic effects from breathing or swallowing.
SWALLOWING:
Swallowing this material may be harmful. This material can get into the lungs during swallowing
or vomiting. This results in lung inflammation and other lung injury.
INHALATION:
Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not
likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms usually occur at air
concentrations higher than the recommended exposure limits. (See Section 8).
SYMPTOMS OF EXPOSURE:
Signs and symptoms of exposure to this material through breathing, swallowing, and /or passage of the material
through the skin may include: metallic taste, mouth and throat irritation (soreness, dry or scratchy feeling, cough),
stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), cough, central nervous
system excitation (giddiness, liveliness, light-headed feeling) followed by central nervous system depression (dizziness,
drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects,
temporary changes in mood and behavior, leg cramps, muscle weakness, pain in the abdomen and lower back, blurred
vision, shortness of breath, loss of coordination, confusion, irregular heartbeat, cyanosis(causes blue coloring of the
skin and nails from lack of oxygen), high blood sugar, visual impairment (including blindness), coma, and death.
TARGET ORGAN EFFECTS:
This material (or a component) shortens the time of onset or worsens the liver and kidney damage induced by other
chemicals. Exposure to lethal concentrations of methanol has been shown to cause damage to organs including liver,
kidneys, pancreas, heart, lungs and brain. Although this rarely occurs, survivors of severe intoxication may suffer from
permanent neurological damage. Prolonged intentional toluene abuse may lead to damage to many organ systems
having effects on: central and peripheral nervous systems, vision, hearing, liver, kidneys, heart and blood. Such abuse
has been associated with brain damage characterized by disturbances in gait, personality changes and loss of memory.
Comparable central nervous system effects have not been shown to result from occupational exposure to toluene.
Prolonged intentional toluene abuse may lead to hearing loss progressing to deafness. In addition, while noise is known
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to cause hearing loss in humans, it has been suggested that workers exposed to organic solvents, including toluene,
along with noise may suffer greater hearing loss than would be expected from exposure to noise alone. Overexposure
to this material (or its components) has been suggested as a cause of the following effects in laboratory animals: mild,
reversible liver effects, mild, reversible kidney effects, cardiac sensitization, liver abnormalities, respiratory tract damage
(nose, throat, and airways), effects on hearing, central nervous system damage. Overexposure to this material (or its
components) has been suggested as a cause of the following effects in humans: cardiac sensitization, visual impairment.
kidney damage.
DEVELOPMENTAL INFORMATION:
Toluene may be harmful to the human fetus based on positive test results with laboratory animals. Case studies
show that prolonged intentional abuse of toluene during pregnancy can cause birth defects in humans. Methanol
has caused birth defects in laboratory animals, but only when inhaled at extremely high vapor concentrations. The
relevance of this finding to humans is uncertain.
CANCER INFORMATION:
Based on the available information, this material cannot be classified with regard to carcinogenicity. This material is not
listed as a carcinogen by the International Agency for Research on Cancer, the National Toxicology Program, or the
Occupational Safety and Health Administration.
OTHER HEALTH EFFECTS:
No Data
PRIMARY ROUTE(S) OF ENTRY:
Inhalation, skin absorption, skin contact, eye contact, ingestion.
Section 4. FIRST AID MEASURES
EYES:
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently
with water for at least 15 minutes while holding eyelids apart. Seek immediate medical attention. If symptoms persist
or there is any visual difficulty, seek medical attention.
SKIN:
Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention.
Launder clothing before reuse.
SWALLOWING:
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the
left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to
induce vomiting. If possible, do not leave individual unattended.
INHALATION:
If symptoms develop, immediately move individual away from exposure and into fresh air. If symptoms persist, seek
immediate medical attention. keep person warm and quiet. If person is not breathing, begin artificial respiration. If
breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
NOTE TO PHYSICIANS:
Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate abuse, may
be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed
to this material. This product contains methanol which can cause intoxication and central nervous system depression.
Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual
disturbances and blindness. Since metabolism is required for these toxic symptoms, their onset may be delayed from 6
to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent
methanol metabolism. Ethanol administration is indicated in symptomatic patients or at blood methanol concentrations
above 20 ug/dl. Methanol is effectively removed by hemodialysis. Fomepizole (4-methylpyrazole) is an effective
antagonist of alcohol dehydrogenase, and as such, may be used as an antidote in the treatment of ethylene glycol,
diethylene glycol and methanol poisoning. This material is an aspiration hazard. Potential danger from aspiration must
be weighed against possible oral toxicity (See Section 3 - Swallowing) when deciding whether to induce vomiting. This
material (or a component) has produced hyperglycemia and ketosis following substantial ingestion. Pre-existing
disorders of the following organs (or organ systems) may be aggravated by exposure to this material: respiratory tract,
skin, lung (for example, asthma-like conditions), liver, kidney, central nervous system, pancreas, heart. auditory system.
Exposure to this material may aggravate any preexisting condition sensitive to a decrease in available oxygen,
such as chronic lung disease, coronary artery disease or anemias. Individuals with preexisting heart disorders may
be more susceptible to arrhythmias (irregular heartbeats) if exposed to high concentrations of this material.
Section 5. FIRE FIGHTING MEASURES
FLASH POINT:
<-1.0 F (-18.3 C) TCC
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EXPLOSIVE LIMIT:
(for component) Lower 1.2%
AUTOIGNITION TEMPERATURE:
No Data
HAZARDOUS PRODUCTS OF COMBUSTION:
May form: carbon dioxide and carbon monoxide, various hydrocarbons.
FIRE AND EXPLOSION HAZARDS:
Material is volatile and readily gives off vapors which may travel along the ground or be moved by ventilation
and ignited by pilot lights, flames, sparks, heaters, smoking, electric motors, static discharge, or other ignition
sources at locations near the material handling point. Never use welding or cutting torch on or near drum (even
empty) because product (even just residue) can ignite explosively. May form explosive peroxides.
EXTINGUISHING MEDIA:
Regular foam (such as AFFF), water fog, carbon dioxide, dry chemical.
FIRE FIGHTING INSTRUCTIONS:
Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).
Section 6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL:
Eliminate all sources of ignition such as flares, flames (including pilot lights), and electrical sparks. Absorb liquid on
vermiculite, floor absorbent or other absorbent material. Persons not wearing proper personal protective equipment
should be excluded from area of spill.
LARGE SPILL:
Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing
protective equipment should be excluded from area of spill until clean-up has been completed. Stop
spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading.
If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers
for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials
to containers for disposal. Prevent run-off to sewers, streams or other bodies of water. If run-off occurs,
notify proper authorities as required, that a spill has occurred.
Section 7. HANDLING AND STORAGE
HANDLING:
Containers of this material may be hazardous when emptied. Since emptied containers retain product
residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
Static ignition hazard can result from handling and use. Electrically bond and ground all containers, personnel and
equipment before transfer or use of material. Special precautions may be necessary to dissipate static electricity for
non-conductive containers. Use proper bonding and grounding during product transfer as described in National Fire
Protection Association document NFPA 77. Precautions during use: avoid prolonged or frequently
repeated skin contact with this material. Skin contact can be minimized by wearing impervious protective gloves.
As with all products of this nature, good personal hygiene is essential. Hands and other exposed areas should be
washed thoroughly with soap and water after contact, especially before eating and/or smoking. Regular laundering
of contaminated clothing is essential to reduce indirect skin contact with this material.
Hydrocarbon solvents are basically non-conductors of electricity and can become electrostatically charged during
mixing, filtering or pumping at high flow rates. If this charge reaches a sufficiently high level, sparks can form that may
ignite the vapors of flammable liquids. WARNING. Sudden release of hot organic chemical vapors or mists from
process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment,
may result in ignitions without the presence of obvious ignition sources. Published "autoignition" or "ignition"
temperature values cannot be treated as safe operating temperatures in chemical processes without analysis
of the actual process conditions. Any use of this product in elevated temperature processes should be thoroughly
evaluated to establish and maintain safe operating conditions.
STORAGE:
Do not store near extreme heat, open flame, or sources of ignition.
Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION:
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations
also permit other type safety glasses. Consult your safety representative.
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SKIN PROTECTION:
Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin
contact, wear impervious clothing and boots.
RESPIRATORY PROTECTIONS:
If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines),
a NIOSH/MSHA approved air supplied respirator is advised in absence of proper environmental control.
OSHA regulations also permit other NIOSH/MSHA respirators (negative pressure type) under specified
conditions (see your industrial hygienist). Engineering or administrative controls should be implemented
to reduce exposure.
ENGINEERING CONTROLS:
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
TLV(s).
EXPOSURE GUIDELINES:
COMPONENT
TOLUENE (108-88-03)
OSHA PEL 200.000 ppm - TWA
OSHA PEL 300.000 ppm - Ceiling
OSHA VPEL 100.000 ppm - TWA
OSHA VPEL 150.000 ppm - STEL
ACGIH TLV 50.000 ppm - TWA (Skin)
ACGIH TLV 150.000 ppm - STEL (Skin)
ACETONE (67-64-1)
OSHA PEL 1000.000 ppm - TWA
OSHA VPEL 750.000 ppm - TWA
OSHA VPEL 1000.000 ppm - STEL
ACGIH TLV 500.000 ppm - TWA
ACGIH TLV 750.000 ppm - STEL
ALIPHATIC PETROLEUM DISTILLATES (64742-89-8)
OSHA VPEL 300.000 ppm - TWA
OSHA VPEL 400.000 ppm - STEL
ACGIH TLV 300.000 ppm - TWA
METHYL ALCOHOL (67-56-1)
OSHA PEL 200.000 ppm - TWA
OSHA VPEL 200.000 ppm - TWA (Skin)
OSHA VPEL 250.000 ppm - STEL (Skin)
ACGIH TLV 200.000 ppm - TWA (Skin)
ACGIH TLV 250.000 ppm - STEL (Skin)
ISOBUTYL ISOBUTYRATE (97-85-8)
No exposure limits established
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: (for component) 133.0 F (56.1 C) @ 760 mmHg
VAPOR PRESSURE: (for component) 185.000 mmHg @ 68.00 F
SPECIFIC VAPOR DENSITY: > 1.000 @ AIR=1
SPECIFIC GRAVITY: .812 @ 77.00 F
LIQUID DENSITY: 6.760 lbs/gal @ 77.00 F .812 kg/l @ 25.00 C
PERCENT VOLATILES: 100.00 %
EVAPORATION RATE: Slower than Ethyl Ether
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APPEARANCE: Clear and particle free
STATE: Liquid
PHYSICAL FORM: Homogeneous solution
COLOR: No data
ODOR: Hydrocarbon
pH: Not applicable
Section 10. STABILITY AND REACTIVITY
HAZARDOUS POLYMERIZATION:
Product will not undergo hazardous polymerization.
HAZARDOUS DECOMPOSITION:
May form: Carbon dioxide and carbon monoxide, various hydrocarbons.
CHEMICAL STABILITY:
Can form potentially explosive peroxides upon long standing in air.
INCOMPATIBILITY:
Avoid contact with: calcium hypochlorite, sodium, strong acids, strong oxidizing agents, zinc.
Section 11. TOXICOLOGICAL INFORMATION
No Data
Section 12. ECOLOGICAL INFORMATION
No Data
Section 13. DISPOSAL CONSIDERATION
WASTE MANAGEMENT INFORMATION:
Dispose of in accordance with all applicable local, state and federal regulations.
Do not discharge effluent containing this product into lakes, streams, ponds or estruaries, oceans or other waters unless
in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit, and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to
sewer systems without previously notifying the local sewage treatment plant authority.
Section 14. TRANSPORT INFORMATION
DOT INFORMATION - 49 CFR 172.101
DOT DESCRIPTION & [CONTAINER MODE]:
PAINT RELATED MATERIAL, 3, UN1263, II [55 al Drum/5 Gal Pail/Gallon]
CONSUMER COMMODITY, ORM-D [Quart/Pint]
NOS COMPONENT:
None
RQ (Reportable Quantity) - 49 CFR 172.101
Product Quantity (lbs) Component
1646 TOLUENE
20515 ACETONE
34374 METHANOL
OTHER TRANSPORTATION INFORMATION
The DOT Transport Information may vary with the container and mode of shipment.
Section 15. REGULATORY INFORMATION
US FEDERAL REGULATIONS:
TSCA (Toxic Substances Control Act) Status
TSCA (UNITED STATES) The intentional ingredients of this product are listed.
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CERCLA RQ - 40 CFR 302.4(a)
Component RQ (lbs)
TOLUENE 1000
ACETONE 5000
METHYL ALCOHOL 5000
CERCLA RQ - 40 CFR 302.4(b)
Materials without a "listed" RQ may be reportable as an "unlisted hazardous substance".
See 40 CFR 302.5 (b).
SARA 302 Components - 40 CFR 355 Appendix A
None
Section 311/312 Hazard Class - 40 CFR 370.2
Immediate (X) Delayed (X) Fire (X) Reactive ( )
Sudden Release of Pressure ( )
SARA 313 Components - 40 CFR 372.65
Section 313 Component(s) CAS Number %
TOLUENE 108-88-3 57.02
METHANOL 67-56-1 15.00
OSHA PROCESS SAFETY MANAGEMENT 29 CFR 1910
None listed
EPA ACCIDENTAL RELEASE PREVENTION 40 CFR 68
None listed
INTERNATIONAL REGULATIONS:
INVENTORY STATUS:
Not Determined
STATE AND LOCAL REGULATIONS:
CALIFORNIA PROPOSITION 65:
The following statement is made in order to comply with the California Safe Drinking Water
and Toxic Enforcement Act of 1986: This product contains the following substance(s) known
to the state of California to cause cancer.
BENZENE
The following statement is made in order to comply with the California Safe Drinking Water
and Toxic Enforcement Act of 1986: This product contains the following substance(s) known
to the state of California to cause reproductive harm.
TOLUENE
BENZENE
NEW JERSEY RTK LABEL INFORMATION:
TOLUENE 108-88-3
ACETONE 67-64-1
NAPHTHA, SOLVENT 64742-89-8
METHYL ALCOHOL 67-56-1
ISOBUTYL ISOBUTYRATE 97-85-8
PENNSYLVANIA RTK LABEL INFORMATION:
BENZENE, METHYL- 108-88-3
2-PROPANONE 67-64-1
ALIPHATIC PETROLEUM DISTILLATES 64742-89-8
METHANOL 67-56-1
E.E. Zimmerman Company/Elroy Turpentine Company believes that the statements, technical information,
and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind,
express or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential,
arising out of their use.
ASPA 7520494 000 0B
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