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90-72-2 112945-52-5 107-21-1

File Name: 90-72-2_112945-52-5_107-21-1.asp

                                                                                                   Material Safety Data Sheet




Revision Date: 04/25/2006 Issue date: 05/31/2006

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product name: Hysol 608 HARD Item No. : 83086_AB0608 / IDH No. 702128
Product type: Epoxy Hardener Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: (860) 571-5100
1001 Trout Brook Crossing Emergency telephone: (860) 571-5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com

2. COMPOSITION/INFORMATION ON INGREDIENTS


Hazardous components % ACGIH TLV OSHA PEL OTHER
Polymercaptan hardener 60-100 None None None
Proprietary


Phenol, 2,4,6- 5-10 None None None
tris[(dimethylamino)methyl]
90-72-2
3 3 3
Silica, amorphous, fumed, 5-10 6 mg/m TWA 10 mg/m TWA 3 mg/m TWA respirable dust
crystalline-free
112945-52-5

Ethylene glycol 1-5 100 mg/m?Ceiling None None
107-21-1 aerosol only



3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
HMIS:
Physical state: Paste HEALTH: 2
Color: Translucent Amber FLAMMABILITY: 1
Odor: Slight, Ammoniacal PHYSICAL HAZARD: 1
Personal Protection: See Section 8
MAY CAUSE ALLERGIC SKIN REACTION.
WARNING:
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION
HARMFUL IF SWALLOWED.

Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact

Potential Health Effects

Inhalation: May cause respiratory tract irritation. May cause irritation to nose and throat.
Skin contact: Allergic skin reaction. Moderate skin irritation. Rash. Redness.
Eye contact: Moderate eye irritation. Redness. Tissue damage.
Ingestion: Harmful if swallowed.

Existing conditions aggravated by Skin disorders. Skin allergies. Eye disorders.
exposure:

See Section 11 for additional toxicological information.




Item No. : 83086_AB0608 / IDH No. 702128 Product name: Hysol 608 HARD
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4. FIRST AID MEASURES


Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if
symptoms occur.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Get
medical attention immediately.

Notes to physician: None.

5. FIRE-FIGHTING MEASURES

Flash point: 157.3癈 (315癋) Cleveland open cup

Autoignition temperature: Not available

Flammable/Explosive limits-lower %: Not available

Flammable/Explosive limits-upper %: Not available

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Unusual fire or explosion hazards: In the event of fire, cool tanks with water spray.

Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Irritating organic fragments.

6. ACCIDENTAL RELEASE MEASURES

Environmental precautions: Prevent product from entering drains or open waters.

Clean-up methods: Remove all ignition sources. Immediately contact emergency personnel. Scrape up as much material
as possible. Clean residue with soap and water. Store in a closed container until ready for disposal.

7. HANDLING AND STORAGE

Handling: Do not breathe mist or vapors. Keep container closed. Avoid contact with eyes, skin and clothing.
Wash thoroughly after handling.

Storage: Store in original container until ready to use. Keep in a cool, well ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready for use.

Incompatible products: Refer to Section 10.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits
exists.

Skin protection: Chemical resistant, impermeable gloves. Use chemical resistant, impermeable clothing including
gloves and either an apron or body suit to prevent skin contact.

Eye/face protection: Chemical splash goggles or safety glasses with side shields.

See Section 2 for exposure limits.


Item No. : 83086_AB0608 / IDH No. 702128 Product name: Hysol 608 HARD
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9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Paste
Color: Translucent Amber
Odor: Slight, Ammoniacal
Vapor pressure: Less than 0.1 mm Hg at 20篊 (68篎)
pH: Not applicable
Boiling point/range: Greater than 260.2癈 (500癋)
Melting point/range: Not available
Specific gravity: 1.15
Vapor density: 5
Evaporation rate: <0.01
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available
VOC content: <0.40% (value for resin and hardener together) (estimated)

10. STABILITY AND REACTIVITY

Stability: Stable

Hazardous polymerization: Will not occur.

Hazardous decomposition products: None

Incompatability: Strong acids. Strong oxidizers.

Conditions to avoid: Excessive heat. Storage with incompatible materials.

11. TOXICOLOGICAL INFORMATION


Carcinogen Status

Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Polymercaptan hardener No No No
Proprietary

Phenol, 2,4,6- No No No
tris[(dimethylamino)methyl]
90-72-2
Silica, amorphous, fumed, No No No
crystalline-free
112945-52-5
Ethylene glycol No No No
107-21-1



Literature Referenced Target Organ & Other Health Effects

Hazardous components Health Effects/Target Organs
Polymercaptan hardener No data
Proprietary

Phenol, 2,4,6- Allergen, Irritant
tris[(dimethylamino)methyl]
90-72-2
Silica, amorphous, fumed, Nuisance dust
crystalline-free
112945-52-5
Ethylene glycol Blood, Bone Marrow, Central nervous system, Developmental, Eyes, Irritant, Kidney, Liver, Metabolic
107-21-1


12. ECOLOGICAL INFORMATION

Ecological information: Not available




Item No. : 83086_AB0608 / IDH No. 702128 Product name: Hysol 608 HARD
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13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Dispose according to EPA and local governmental regulations.

EPA hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be
different for bulk packaging.

U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

WaterTransportation (IMO/IMDG):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Marine pollutant: None

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.

CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Immediate Health Hazard
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313
of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Ethylene glycol
(CAS# 107-21-1) .

California Proposition 65: This product contains a chemical known to the State of California to cause cancer and birth defects or
other reproductive harm.



Canada Regulatory Information


CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: D.2.B

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: 9

Prepared by: Regulatory Affairs

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from
sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.



Item No. : 83086_AB0608 / IDH No. 702128 Product name: Hysol 608 HARD
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