SAFETY DATA SHEET
Sikadur 52 Part A
Date of issue - 26/04/2002. SKD52A
PRODUCT AND COMPANY IDENTIFICATION
Product Code SKD52A
Product Name Sikadur 52 Part A
2-component epoxy resin for crack injection and stabilising.
Product Description
Sika Limited
Manufacturer/Supplier
Watchmead
Welwyn Garden City
Hertfordshire.
AL7 1BQ
tel. 01707 394444
Fax. 01707 329129
COMPOSITION/INFORMATION ON THE COMPONENTS
Preparation - Hazardous ingredients ( Europe )
Component Concentration Classification Risk Phrases
1) Epoxy resin ( No.Av. mol.wt. < 700) 25068-38-6 50.00% - 100.00% Xi, N R36/38, R43, R51/53
2) Aliphatic glycidyl ether 68609-97-2 2.50% - 10.00% Xi, N R38, R43, R51/53
3) Solvent Naptha (petroleum) heavy aromatic. 64742-94-5 2.50% - 100.00% Xn, N R51/53, R65, R66
HAZARD IDENTIFICATION
Irritating to eyes and skin.
Main Hazards
May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
FIRST AID MEASURES
Immediately flood the eye with plenty of water for at least 15 minutes,
Eye Contact
holding the eye open.
Obtain medical attention urgently.
Wipe off as much as possible with a clean dry cloth. Wash skin
Skin Contact
thoroughly with soap and water.
Solvents should not be used to clean skin because they may increase
the penetration of the material.
Wash out mouth with water. Obtain medical attention.
Ingestion
Remove from exposure. In cases of possible respiratory irritation or if
Inhalation
feeling unwell in cases of prolonged exposure,obtain medical attention.
FIRE FIGHTING MEASURES
Not readily combustible.
Extinguishing Media
Use foam, dry chemical or carbon dioxide.
Do not use water jet.
Extinguishing Media - Not suitable
Combustion will produce smoke,carbon dioxide and carbon monoxide.
Special Hazards of Product
Wear full protective clothing and self-contained breathing apparatus.
Protective Equipment for Fire-Fighting
CM Version - 2 Page: 1/4
SAFETY DATA SHEET
Sikadur 52 Part A
Date of issue - 26/04/2002. SKD52A
ACCIDENTAL RELEASE MEASURES
Wear appropriate protective clothing.
Personal Precautions
Try to prevent the material from entering drains or water courses.
Environmental Precautions and
Clean-up Methods
Contain and absorb using earth, sand or other inert material.
Spillages
Transfer into suitable containers for recovery or disposal.
HANDLING AND STORAGE
Use in well ventilated area.
Handling
Avoid contact with eyes, skin and clothing.
Storage area should be: cool. dry.
Storage
Storage temperature should be controlled to between 5 and 25 癈.
Store in the original container securely closed . Keep away from
foodstuffs
EXPOSURE CONTROLS/PERSONAL PROTECTION
Use of the basic principles of Industrial Hygiene will enable this
Engineering Control Measures
material to be used safely.
Respiratory protection not normally required.
Respiratory Protection
Wear suitable impervious gloves. (butyl / nitrile type)
Hand Protection
The insides of gloves must be kept scrupulously clean.
Chemical goggles.
Eye Protection
PHYSICAL AND CHEMICAL PROPERTIES
Liquid.
Physical State
Straw - Colourless.
Color
Faint. Characteristic.
Odor
7.7 at 10% w/w in water.
pH
112
Flash Point 癈
Insoluble.
Solubility - Water
Negligible vapour pressure at ambient conditions.
Vapor Pressure ( kPa )
Approx. 1150 at 20 癈.
Density (kg/m3)
Above 500.
Autoignition Temperature 癈
Approx. 1900 at 20 癈. (measured as mPa.s)
Viscosity ( at 20癈 )
STABILITY AND REACTIVITY
Stable under normal conditions.
Stability
Heating may produce: oxides of carbon acrid smoke and irritating
Hazardous Decomposition Products
fumes.
TOXICOLOGICAL INFORMATION
Low order of acute toxicity.
Acute toxicity
Irritating to the eyes.
Eye irritation
Frequent or prolonged skin contact may cause some local short term
Skin irritation
skin irritation.
The low molecular weight epoxy resin is a potential skin sensitiser.
Sensitization - Skin
CM Version - 2 Page: 2/4
SAFETY DATA SHEET
Sikadur 52 Part A
Date of issue - 26/04/2002. SKD52A
ECOLOGICAL INFORMATION
The product is insoluble in water.
Mobility
The product is expected to be not readily biodegradable.
Persistence/degradability
This material is harmful to aquatic organisms.
Ecotoxicity
DISPOSAL
Dispose of as Special Waste.
Product Disposal
Arrange for disposal via a licensed waste contractor.
Dispose of containers with care.
Container Disposal
Empty containers may contain hazardous residues.
Empty packaging should be removed by a licensed waste contractor.
TRANSPORT INFORMATION
3082
UN : UN number
Environmentally hazardous substances, liquid, n.o.s.
UN : Proper shipping name
9
UN : Class
3
UN : Packing Group
3082
ADR/RID :
Substance Identification
Number
Environmentally hazardous substance, liquid, n.o.s.
ADR/RID :
Proper shipping name
contains Epoxy Resin
9
ADR/RID :
Class
11(c)
ADR/RID :
Item Number
90
ADR/RID :
Hazard Identification Number
Environmentally hazardous substance, liquid, N.O.S.
IMDG : Proper shipping name
contains Epoxy Resin
3
IMDG : Packing Group
9
IMDG : Class
Not Classified for Air Transport
IATA : Proper shipping name
REGULATORY INFORMATION
Irritant, Dangerous for the environment
Label Requirements
Irritating to eyes and skin.
Risk Phrases
May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Avoid contact with skin.
Safety Phrases
Wear suitable gloves.
Contains epoxy constituents. See information supplied by the
manufacturer.
CM Version - 2 Page: 3/4
SAFETY DATA SHEET
Sikadur 52 Part A
Date of issue - 26/04/2002. SKD52A
OTHER INFORMATION
04.05.1995
First Issue Date
Hazards Identification
Revisions Highlighted
Regulatory Information
Customers are urged to ensure that the product is entirely suitable for
Uses and Restrictions
their own purpose.It is the customer`s responsibilty to ensure that a
suitable and sufficient assessment of the risks created by the use of
the product is undertaken.
Health and Safety at Work etc Act, 1974, and relevant Statutory
UK Legislation
Provisions.
Chemicals (Hazard Information and Packaging) Regulations, 2002.
SI 1999/437: The Control of Substances Hazardous to Health
Regulations
SI No. 972/1996: The Special Waste Regulations 1996
SI No 2839 1991 Environmental Protection (Duty of Care) Regulations.
Approved Code of Practice - Management of Health and Safety at
UK Guidance Publications
Work, HSE.
HS(G) 97, A Step by Step Guide to COSHH Regulations, HSE.
The information contained in this SDS corresponds to our level of
Footnote
knowledge at the time of publication.All warranties are excluded.Our
most current General Sales Conditions shall apply. Please consult the
Technical Data Sheet prior to use.
SAFETY DATA SHEET
Sikadur 52 Part B
Date of issue - 26/04/2002. SKD52B
PRODUCT AND COMPANY IDENTIFICATION
Product Code SKD52B
Product Name Sikadur 52 Part B
2-component epoxy resin for crack injection and stabilising.
Product Description
Sika Limited
Manufacturer/Supplier
Watchmead
Welwyn Garden City
Hertfordshire.
AL7 1BQ
tel. 01707 394444
Fax. 01707 329129
COMPOSITION/INFORMATION ON THE COMPONENTS
Preparation - Hazardous ingredients ( Europe )
Component Concentration Classification Risk Phrases
1) Benzyl Alcohol 100-51-6 25.00% - 50.00% Xn R20/22
2) Isophoronediamine 2855-13-2 10.00% - 25.00% C R21/22, R34, R43,
R52/53
3) Triethylenetetramine 112-24-3 10.00% - 25.00% C R21, R34, R43,
R52/53
4) Solvent Naptha (petroleum) heavy aromatic. 64742-94-5 10.00% - 25.00% Xn, N R51/53, R65, R66
5) 2,4,6-Tri(dimethylaminomethyl) phenol 90-72-2 2.50% - 10.00% Xn R22, R36/38
HAZARD IDENTIFICATION
Harmful by inhalation, in contact with skin and if swallowed.
Main Hazards
Causes burns.
May cause sensitisation by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
FIRST AID MEASURES
Immediately flood the eye with plenty of water for at least 15 minutes,
Eye Contact
holding the eye open. Eyelids should be held away from the eyeball to
ensure thorough rinsing.
Obtain medical attention urgently.
Wipe off as much as possible with a clean dry cloth. If material proves
Skin Contact
difficult to remove, use suitable skin cleanser (not solvent).
Solvents should not be used to clean skin because they may increase
the penetration of the material. Contaminated clothing should be
washed or dry-cleaned before re-use.
Do not induce vomiting.
Ingestion
Obtain medical attention.
Remove from exposure. In cases of possible respiratory irritation or if
Inhalation
feeling unwell in cases of prolonged exposure,obtain medical attention.
CM Version - 2 Page: 1/4
SAFETY DATA SHEET
Sikadur 52 Part B
Date of issue - 26/04/2002. SKD52B
FIRE FIGHTING MEASURES
Not readily combustible. Use foam, dry chemical or carbon dioxide.
Extinguishing Media
Do not use water jet.
Extinguishing Media - Not suitable
Thermal decomposition or burning may release oxides of carbon,
Special Hazards of Product
nitrogen and other toxic gases and vapours.
Wear full protective clothing and self-contained breathing apparatus.
Protective Equipment for Fire-Fighting
ACCIDENTAL RELEASE MEASURES
Wear appropriate protective clothing.
Personal Precautions
Try to prevent the material from entering drains or water courses.
Environmental Precautions and
Clean-up Methods
Contain and absorb using earth, sand or other inert material. Transfer
Spillages
into suitable containers for recovery or disposal.
HANDLING AND STORAGE
Avoid contact with eyes, skin and clothing. Mix in a well ventilated area.
Handling
Storage area should be: cool. dry.
Storage
Storage temperature should be controlled to between 5 and 25 癈.
Store in the original container securely closed .
Keep away from foodstuffs
EXPOSURE CONTROLS/PERSONAL PROTECTION
Use of the basic principles of Industrial Hygiene will enable this
Engineering Control Measures
material to be used safely.
Respiratory protection not normally required.
Respiratory Protection
Wear suitable impervious gloves. (butyl / nitrile type)
Hand Protection
The insides of gloves must be kept scrupulously clean.
Chemical goggles.
Eye Protection
PHYSICAL AND CHEMICAL PROPERTIES
Liquid.
Physical State
Colourless.
Color
Ammoniacal.
Odor
Approx. 12 at <10% w/w in water.
pH
107
Flash Point 癈
Slightly soluble ( <10%)
Solubility - Water
Negligible vapour pressure at ambient conditions.
Vapor Pressure ( kPa )
Approx. 1000 at 20 癈.
Density (kg/m3)
Approx. 60 at 20 癈. (measured as mPa.s)
Viscosity ( at 20癈 )
> 200
Decomposition temperature 癈
CM Version - 2 Page: 2/4
SAFETY DATA SHEET
Sikadur 52 Part B
Date of issue - 26/04/2002. SKD52B
STABILITY AND REACTIVITY
Stable under normal conditions.
Stability
Heating may produce: ammonia. oxides of carbon. oxides of nitrogen.
Hazardous Decomposition Products
acrid smoke and irritating fumes.
TOXICOLOGICAL INFORMATION
Low order of acute toxicity.
Acute toxicity
This material is corrosive to the eye.
Eye irritation
This material is corrosive to the skin.
Skin irritation
The possibility of allergic sensitisation should be considered
Sensitization - Skin
ECOLOGICAL INFORMATION
The product is sparingly soluble in water.
Mobility
The product is expected to be not readily biodegradable.
Persistence/degradability
This material is harmful to aquatic organisms.
Ecotoxicity
DISPOSAL
Dispose of as Special Waste.
Product Disposal
Arrange for disposal via a licensed waste contractor.
Empty containers may contain hazardous residues.
Container Disposal
Dispose of containers with care.
Empty packaging should be removed by a licensed waste contractor.
TRANSPORT INFORMATION
1760
UN : UN number
Corrosive liquid, n.o.s.
UN : Proper shipping name
contains Triethylenetetramine
8
UN : Class
3
UN : Packing Group
1760
ADR/RID :
Substance Identification
Number
Corrosive Liquid, n.o.s.
ADR/RID :
Proper shipping name
contains Triethylenetetramine
8
ADR/RID :
Class
66(c)
ADR/RID :
Item Number
80
ADR/RID :
Hazard Identification Number
Corrosive liquid, N.O.S.
IMDG : Proper shipping name
contains Triethylenetetramine
3
IMDG : Packing Group
8
IMDG : Class
8-15
IMDG : Ems Number
Corrosive liquid, N.O.S.
IATA : Proper shipping name
contains Triethylenetetramine
3
IATA : Packing Group
8
IATA : Class
CM Version - 2 Page: 3/4
SAFETY DATA SHEET
Sikadur 52 Part B
Date of issue - 26/04/2002. SKD52B
REGULATORY INFORMATION
Corrosive
Label Requirements
Harmful by inhalation, in contact with skin and if swallowed.
Risk Phrases
Causes burns.
May cause sensitisation by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Avoid contact with skin.
Safety Phrases
In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Wear suitable protective clothing, gloves and eye/face protection.
OTHER INFORMATION
04.05.1995
First Issue Date
Hazards Identification
Revisions Highlighted
Regulatory Information
Customers are urged to ensure that the product is entirely suitable for
Uses and Restrictions
their own purpose.It is the customer`s responsibilty to ensure that a
suitable and sufficient assessment of the risks created by the use of
the product is undertaken.
Health and Safety at Work etc Act, 1974, and relevant Statutory
UK Legislation
Provisions.
Chemicals (Hazard Information and Packaging) Regulations, 2002.
SI 1999/437: The Control of Substances Hazardous to Health
Regulations
SI No. 972/1996: The Special Waste Regulations 1996
SI No 2839 1991 Environmental Protection (Duty of Care) Regulations.
Approved Code of Practice - Management of Health and Safety at
UK Guidance Publications
Work, HSE.
General Approved Code of Practice to COSHH Regulations, HSE.
The information contained in this SDS corresponds to our level of
Footnote
knowledge at the time of publication.All warranties are excluded.Our
most current General Sales Conditions shall apply. Please consult the
Technical Data Sheet prior to use.
|