Safety Data Sheet
according to 91/155/EEC and ISO 11014-1
(see instructions in Annex to 93/112/EC)
Date of printing: 14.06.2005 Page: 1/7
Revised: 14.06.2005 MSDS 283A
Hazardous according to the criteria of Worksafe Australia
1. Identification of the substance/preparation and company
Product
Product name
Sikadur?31/41NZ Part A
Manufacturer/supplier information
Manufacturer/supplier: Sika (NZ) Ltd
Street/postbox: 85-91 Patiki Road, Avondale
Town/City and Post Code: Auckland
Country: New Zealand
Phone: (09) 820 2900
Telefax: (09) 820 4091
General Information Operations Manager
Emergency after hours phone: 0800 734 607
2. Composition/information on ingredients
Chemical characterization
Filled and modified epoxy resin
Hazardous ingredients
Designation according to 67/548/EEC
CAS No. Concentration Danger symbols R phrases
?reaction product: bisphenol A-(epichlorhydrin)
epoxy resin (number average molecular weight <= 700)
25068-38-6 10 - 30 % Xi 36/38,43
?reaction product: bisphenol F-(epichlorhydrin)
epoxy resin (number average molecular weight <= 700)
9003-36-5 10 - 30 % Xi 36/38,43
?silica
14808-60-7 > 60 % Xi 36/37/38
?non-hazardous ingredients to 100 %
3. Hazards identification
Hazards identification
Xi Irritant
Information on hazards to man and to the environment
36/38 Irritating to eyes and skin.
43 May cause sensitization by skin contact.
4. First-aid measures
General instructions
In any case show the physician the Safety Data Sheet
Product name: Sikadur?31/41NZ Part A
Date of printing: 14.06.2005 Page: 2/7
Revised: 14.06.2005 MSDS 283A
4. First-aid measures (continued)
After inhalation
Ensure supply of fresh air.
In the event of symptoms take medical treatment.
After skin contact
Remove soiled or soaked clothing immediately, do not allow to dry.
In case of contact with skin wash off immediately with soap and
water
Consult a doctor if skin irritation persists.
After eye contact
In case of contact with the eyes, rinse immediately for at least
15 minutes with plenty of water.
Summon a doctor immediately.
After ingestion
Do not induce vomiting.
Summon a doctor immediately.
5. Fire-fighting measures
Suitable extinguishing media
foam
dry powder
carbon dioxide
water mist
Unsuitable extinguishing media for safety reasons
Full water jet
Exposure hazard arising from the product, its combustion products or
resulting gases
In the event of fire the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Special protective equipment for fire-fighting
Use breathing apparatus.
Additional information
Cool containers with water spray jet.
Fire residues and contaminated firefighting medium must be disposed
of in accordance with the local regulations.
Product name: Sikadur?31/41NZ Part A
Date of printing: 14.06.2005 Page: 3/7
Revised: 14.06.2005 MSDS 283A
6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Use breathing apparatus if exposed to vapours/dust/aerosol.
Environmental precautions
In case of entry into waterways, soil or drains,
inform the responsible authorities.
Procedures for cleaning up
Pick up with absorbent material.
When picked up, treat material as prescribed under heading "Disposal".
Remove residues with small amount of alcohol-based solvent.
7. Handling and storage
Handling
Instructions for safe handling
See chapter 8 / Personal protective equipment.
Instructions for fire and explosion protection
Keep away from sources of ignition - no smoking.
Storage
Requirements for storage rooms and containers
Keep container tightly closed in a cool, well-ventilated place
Combined storage instructions
Keep away from food, beverages and animal feedstocks.
Additional information regarding storage
Protect from heat and direct sunlight
8. Exposure controls/personal protection
Personal protective equipment
General protective and hygiene measures
Do not inhale vapours
Avoid contact with eyes and skin
Take care for sufficient ventilation or exhaust on the workshop place.
Do not eat, drink or smoke during work time.
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately.
Respiratory protection
In case of insufficient ventilation.
Ori-nasal mask suitable for organic vapours.
Product name: Sikadur?31/41NZ Part A
Date of printing: 14.06.2005 Page: 4/7
Revised: 14.06.2005 MSDS 283A
8. Exposure controls/personal protection (continued)
Class of vapour filter is depending on
pollutant concentration on the scene.
Hand protection
Nitrile rubber gloves
Eye protection
Tightly fitting safety glasses
Body protection
protective clothing
9. Physical and chemical properties
Appearance
Physical state: Pasty
Colour: whitish
Odour: slight, product specific
Data relevant to safety Method
Flash point 170 癈 DIN 51758
Auto-ignition temperature 370 癈
Vapour pressure at 20癈 0.1 hPa
Density at 20癈 1.7 g/cm3 approx
Solubility in water 2%
at 20癈
pH value at 20癈 6
10. Stability and reactivity
Conditions to avoid
Not any known.
Materials to avoid/dangerous reactions
Hazardous reactions possible with:
Amines
Phenols
Acids
Alkalis
Thermal decomposition and hazardous decomposition products
No decomposition if used as prescribed.
Product name: Sikadur?31/41NZ Part A
Date of printing: 14.06.2005 Page: 5/7
Revised: 14.06.2005 MSDS 283A
11. Toxicological information
Sensitization
When skin contact:
Sensitization/allergic reaction possible.
Allergic reaction can may be observed in sensitive persons, even
on very low concentrations.
Experience on humans
When skin contact:
Irritation.
When eyes contact:
Irritation.
When inhalation:
Irritation.
When swallowed:
Small amount may cause considerable health disorders.
Further toxicological information
For more-component products see also the safety-data-sheets of the
other components.
12. Ecological information
Additional information
Product is water polluting.
Do not allow to enter waste water drain, waterways or soil.
From current information concerning hazardous substances, environmen-
tal effects cannot be claimed at this time.
13. Disposal considerations
Product
Recommendations
Must be disposed of in a special waste disposal unit in accordance
with the corresponding regulations.
See chapter 15, national regulations.
On 1.1.02 the European Waste Code Numbers will be in force. They are
based on the origin of the waste and not on its chemical composition.
At the actual status of knowledge the different kind of waste cannot
be unambiguously related to the European Waste Code Numbers. Please
contact the corresponding authority.
Packaging
Recommendations
Completely emptied packaging can be given for recycling.
Packaging that cannot be cleaned should be disposed of as product
waste
Product name: Sikadur?31/41NZ Part A
Date of printing: 14.06.2005 Page: 6/7
Revised: 14.06.2005 MSDS 283A
14. Transport information
ADG
UN No.: None Class: None Packing group: N/A
Proper shipping name
N/A
Label No.: N/A
IMO/IMDG
UN No.: 3082 Class: 9 Packing group: III
Proper shipping name
Environmentally hazardous substance, liquid, n.o.s.
contains: Epoxide resin
Label No.: 9
IATA/ICAO
Further information
No dangerous goods.
15. Regulatory information
Labeling according to EEC Directive
The product is classified and labeled in accordance with
EC directives/the relevant national laws.
Relevant hazardous ingredients for labeling
Contains: reaction product: bisphenol A-(epichlorhydrin)
epoxy resin (number average molecular weight <= 700)
Danger symbols
Xi Irritant
R phrases
36/38 Irritating to eyes and skin.
43 May cause sensitization by skin contact.
S phrases
24 Avoid contact with skin.
37 Wear suitable gloves.
Special labeling for certain preparations
Contains epoxy-containing compounds.
Observe manufacturer's instructions.
National regulations
SUSDP (AUS) S5
Toxicity class 4 SFOPH T No.: 615084
Product name: Sikadur?31/41NZ Part A
Date of printing: 14.06.2005 Page: 7/7
Revised: 14.06.2005 MSDS 283A
15. Regulatory information (continued)
Water hazardous class (WGK)
WGK 2
Brandklasse (CH)
4
Abfallcode und Abfallbezeichnung (CH)
DISPOSE AS SPECIAL WASTE: PAINT HAVING AN ORGANIC PHASE
(BASIS EPOXY RESIN).
16. Other information
The information contained in this Safety Data Sheet corresponds to our
level of knowledge at the time of publication. All warranties are excluded.
Our most current General Sales Conditions shall apply. Please
consult the Technical Data Sheet prior to any use and processing.
Safety Data Sheet
according to 91/155/EEC and ISO 11014-1
(see instructions in Annex to 93/112/EC)
Date of printing: 14.06.2005 Page: 1/7
Revised: 14.06.2005 MSDS No.: 283B
HAZARDOUS ACCORDING TO THE CRITERIA OF WORKSAFE AUSTRALIA
1. Identification of the substance/preparation and company
Product
Product name
Sikadur?31/41 Part B Normal
Manufacturer/supplier information
Manufacturer/supplier: Sika (NZ) Ltd
Street/postbox: 85-91 Patiki Road, Avondale
Town/City and Post Code: Auckland
Country: New Zealand
Phone: (09) 820 2900
Telefax: (09) 820 4091
Emergency after hours phone: 0800 734 607
* 2. Composition/information on ingredients
Chemical characterization
Filled and modified polyamine
Hazardous ingredients
Designation according to 67/548/EEC
CAS No. Concentration Danger symbols R phrases
?Benzyl alcohol
100-51-6 1 - 10 % Xn 20/22/22
?3-aminomethyl-3,5,5-trimethylcyclohexylamine
2855-13-2 1 - 10 % C 21/22,34,41,43
?3,6-diazaoctanethylenediamin
112-24-3 1 - 10 % C 21,34,43,52,53
?2,4,6-tris(dimethylaminomethyl)phenol
90-72-2 1 - 10 % Xi 36/38
?silicon dioxide (quartz)
14808-60-7 > 60 % 36/37/38,20/48
3. Hazards identification
Hazards identification
C Corrosive
Information on hazards to man and to the environment
22 Harmful if swallowed.
34 Causes burns.
43 May cause sensitization by skin contact.
52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Product name: Sikadur?31/41 Part B Normal
Date of printing: 14.06.2005 Page: 2/7
Revised: 14.06.2005 MSDS No.: 283B
* 4. First-aid measures
General instructions
In any case show the physician the Safety Data Sheet
After inhalation
Remove the casualty into fresh air and keep calm.
Summon a doctor immediately.
After skin contact
Remove soiled or soaked clothing immediately, do not allow to dry.
In case of contact with skin wash off immediately with soap and
water
Summon a doctor immediately.
After eye contact
In case of contact with the eyes, rinse immediately for at least
15 minutes with plenty of water.
Transport immediately to hospital.
After ingestion
Do not induce vomiting. Rinse mouth with water. Give a glass of water
or milk to drink.
Summon a doctor immediately.
5. Fire-fighting measures
Suitable extinguishing media
water spray jet
foam
dry powder
carbon dioxide
Unsuitable extinguishing media for safety reasons
Full water jet
Exposure hazard arising from the product, its combustion products or
resulting gases
Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Special protective equipment for fire-fighting
Use breathing apparatus.
Additional information
Cool containers with water spray jet.
Fire residues and contaminated firefighting medium must be disposed
of in accordance with the local regulations.
Product name: Sikadur?31/41 Part B Normal
Date of printing: 14.06.2005 Page: 3/7
Revised: 14.06.2005 MSDS No.: 283B
6. Accidental release measures
Personal precautions
Remove persons to safety.
Ensure adequate ventilation.
Use personal protective clothing.
Use breathing apparatus if exposed to vapour/dust/aerosol.
Environmental precautions
In case of entry into waterways, soil or drains,
inform the responsible authorities.
Procedures for cleaning up
Pick up with absorbent material.
Remove residues with small amount of alcohol-based solvent.
When picked up, treat material as prescribed under heading "Disposal".
7. Handling and storage
Handling
Instructions for safe handling
See chapter 8 / Personal protective equipment.
Instructions for fire and explosion protection
Keep away from sources of ignition - no smoking.
Storage
Requirements for storage rooms and containers
Keep container tightly closed in a cool, well-ventilated place
Combined storage instructions
Keep away from food, beverages and animal feedstocks.
Additional information regarding storage
Protect from heat and direct sunlight
* 8. Exposure controls/personal protection
Exposure Standards
100-51-6 None established Worksafe
2855-13-2 None established Worksafe
112-24-3 None established Worksafe
90-72-2 None established Worksafe
14808-60-7 0.1 mg/m3 TLV TWA (respirable dust) Worksafe
Personal protective equipment
General protective and hygiene measures
Do not inhale vapour
Avoid contact with eyes and skin
Take care for sufficient ventilation or exhaust on the workshop place.
Do not eat, drink or smoke during work time.
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately.
Product name: Sikadur?31/41 Part B Normal
Date of printing: 14.06.2005 Page: 4/7
Revised: 14.06.2005 MSDS No.: 283B
8. Exposure controls/personal protection (continued)
Respiratory protection
In case of insufficient ventilation.
Ori-nasal mask suitable for organic vapour.
Class of vapour filter is depending on
pollutant concentration on the scene.
Hand protection
Plastic gloves
Eye protection
Tightly fitting safety glasses
Body protection
protective clothing
9. Physical and chemical properties
Appearance
Physical state: Pasty
Colour: dark grey
Odour: amine-like
Data relevant to safety Method
Flash point 111 癈
Auto-ignition temperature 300 癈
Lower explosion limit 1 % p.b.v.
Upper explosion limit 6 % p.b.v.
Vapour pressure at 20癈 0.3 hPa
Density at 20癈 1.9 g/cm3
Solubility in water 13 %
at 20癈
pH value at 20癈 11
(10g/100ml water)
Viscosity at 20癈 8500 mPas
10. Stability and reactivity
Conditions to avoid
Not any known.
Materials to avoid/dangerous reactions
Hazardous reactions possible with:
Acids
Oxidizers
Product name: Sikadur?31/41 Part B Normal
Date of printing: 14.06.2005 Page: 5/7
Revised: 14.06.2005 MSDS No.: 283B
10. Stability and reactivity (continued)
Thermal decomposition and hazardous decomposition products
No decomposition if used as prescribed.
11. Toxicological information
Sensitization
When skin contact:
Sensitization/allergic reaction possible.
Allergic reaction can may be observed in sensitised persons, even
on very low concentrations.
Experience on humans
When skin contact:
Causes burns.
When eyes contact:
Causes burns.
May cause irreversible damage to eyes.
When inhalation:
Irritation.
When swallowed:
Causes burns.
Smallest amount may cause considerable health disorders.
12. Ecological information
Additional information
Product is water polluting.
Do not allow to enter waste water drain, waterways or soil.
Due to the high pH, aquatic organisms may be harmed.
From current information concerning hazardous substances, environmen-
tal effects cannot be claimed at this time.
13. Disposal considerations
Product
Recommendations
Must be disposed of in a special waste disposal unit in accordance
with the corresponding regulations.
See chapter 15, national regulations.
Product name: Sikadur?31/41 Part B Normal
Date of printing: 14.06.2005 Page: 6/7
Revised: 14.06.2005 MSDS No.: 283B
13. Disposal considerations (continued)
Packaging
Recommendations
Completely emptied packaging can be given for recycling.
Packaging that cannot be cleaned should be disposed of as product
waste
14. Transport information
ADG/ADR/RID
UN No.: 1759 Class: 8 Packing group: III
Proper shipping name
Corrosive solid, N.O.S *
contains: Triethylenetetramine
Label No.:
IMO/IMDG
UN No.: 1759 Class: 8 Packing group: III
EmS: 8-15
Proper shipping name
Corrosive solid, n.o.s.
contains: Triethylenetetramine
Label No.:
IATA/ICAO
UN No.: 1759 Class: 8 Packing group: III
Proper shipping name
Corrosive solid, n.o.s.
contains: Triethylenetetramine
Label No.:
15. Regulatory information
Labelling according to EEC Directive
The product is classified and labelled in accordance with
EC directives/the relevant national laws.
Relevant hazardous ingredients for labelling
Contains: 3-aminomethyl-3,5,5-trimethylcyclohexylamine
3,6-diazaoctanethylenediamin
Danger symbols
C Corrosive
R phrases
22 Harmful if swallowed.
34 Causes burns.
43 May cause sensitization by skin contact.
52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Product name: Sikadur?31/41 Part B Normal
Date of printing: 14.06.2005 Page: 7/7
Revised: 14.06.2005 MSDS No.: 283B
15. Regulatory information (continued)
S phrases
2 Keep out of reach of children
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face
protection.
45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
National regulations
Poisons Schedule (SUSDP)
S5 Poison (contains < 20% amines)
Toxicity law (CH)
Toxicity class 3 SFOPH T No.: 617363
Water hazardous class (WGK)
WGK 2
Brandklasse (CH)
4
Abfallcode und Abfallbezeichnung (CH)
DISPOSE AS SPECIAL WASTE: PAINT HAVING AN ORGANIC PHASE
(BASIS AMINE).
* 16. Other information
This product contains silicon dioxide in the form of quartz. Dust is
unlikely to be generated under normal use, but may be liberated during
operations such as sanding, grinding etc. It is recommended to maintain
exposure to dust as low as practical. Precautions against dust exposure
may need to be observed.
asterisk (*) on left margin marks modification of previous version
The information contained in this Safety Data Sheet corresponds to our
level of knowledge at the time of publication. All warranties are ex-
cluded. Our most current General Sales Conditions shall apply. Please
consult the Technical Data Sheet prior to any use and processing.
|