KERR
Material Safety Data Sheet
in accordance with Community Regulation 2006/1907/EC (R.E.A.Ch.)
Revision Date: 14th April 2009
SECTION 1
Product & Company identification
1.1 Product name
SUPER SEP
1.2 Uses/Application:
Dental stone separating agent.
1.3 Company (Name, address and info phone number)
KERR ITALIA S.r.l.
Via Passanti, 332
84018 Scafati (SA) - Italy
Free phone: 00-800-41-050-505
1.4 Emergency phone (according to communitarian directive 99/45/EC, article 17)
+39.081.8508.325 (08.00-17.00, European time, GMT+1)
E-mail address: safety@kerrhawe.com
SECTION 2
Hazard identification
2.1 Hazard classification (according to communitarian directives 67/548/EEC & 99/45/EC)
Highly flammable; Harmful; Irritating.
2.2 Other hazard
None.
SECTION 3
Composition/Information on Ingredients
(according to communitarian directives 67/548/EEC, 99/45/EC & 2001/58/EC)
3.1 Hazardous ingredients
HAZARDOUS % HAZARD RISK CAS N. EINECS
INGREDIENTS SYMBOLS PHRASES N.
Naphtha (petroleum), 25-35 Xn 65 64742-48-9 265-150-3
hydrotreated heavy (*)
Isopropyl alcohol (Isopropanol) 35-45 F; Xi 11-36-67 67-63-0 200-661-7
Isobutylic alcohol (Isobutanol) 4,5-6,5 Xi 10-37/38-41-67 78-83-1 201-148-0
1,2 dichloropropane 3,5-4,5 F; Xn 11-20/22 78-87-5 201-152-2
1-phenilazo, 2-naphthol < 0,01 Xn 40-68-43-53 842-07-9 212-668-2
(*) This substance is not considered toxic according to Directive 2008/58/EC, Annexes 1A and 1C.
3.2 Other non-hazardous ingredients
Octadecanoic acid (TLV).
Material Safety Data Sheet for: SUPER SEP
KERR
SECTION 4
First aid measures
4.1 Treatment for eye contact: Flush with plenty of water also under eyelids for at least 15 minutes.
4.2 Treatment for skin contact: Wash with soap and water. If irritation occurs, consult a physician.
4.3 Treatment for inhalation (breathing): Move to fresh air, and if necessary, make a mouth to mouth
insufflation.
4.4 Treatment for ingestion (swallowing): Do not induce vomiting. Give a few sips of water or milk. Consult
immediately a physician.
SECTION 5
Fire-fighting Measures
5.1 Suitable extinguishing media: Carbon dioxide, alcohol foam, dry chemicals.
5.2 Forbidden extinguishing media: Direct water flow.
5.3 Special fire fighting measures: None.
5.4 Unusual fire and explosion hazards: None.
5.5 Special protection equipment: Sealed overall for liquid and gases; self contained breathing apparatus.
SECTION 6
Accidental Release Measures
6.1 Personal Precautions: Impervious gloves, safety glasses, lab coat or apron, in case of a dangerous high
concentration use a respirator with filter.
6.2 Environmental Precautions: Avoid product spillage in sewage or drainage and in case inform the
concerned authorities. Limit leakage and keep away from ignition source.
6.3 Reclaiming Methods: Avoid any ignition source, absorb with paper or allow to evaporate in a hooded
area. Flush the area with water. Evaporation residues are non-hazardous and may
be disposed of with ordinary waste.
Material Safety Data Sheet for: SUPER SEP
KERR
SECTION 7
Handling and Storage (according to article 5 of communitarian directive 98/24/EC)
7.1 Handling Precautions: Keep away from ignition source. May attack forms of plastics, rubber and
castings. Do not store or handle in aluminum equipment at temperature above 49癈 (120癋).
7.2 Precautions in case of Fire and Explosion: None.
7.3 Storage Conditions: Keep product in a normal container. The product can charge electrostatically; use
grounded equipment.
7.4 Suggested container(s): Original sealed containers provided by manufacturer.
7.5 Indication for Combined Storage: Strong oxidizing agents. Do not store or handle in aluminum
equipment at temperature above 49癈 (120癋).
7.6 Environmental precautions: Do not allow product to reach sewers and rivers.
7.7 Other Precautions: Use according to directions.
SECTION 8
Exposure controls/personal protection
(Isopropanol): TWA: 200 ppm (491,5 mg/m3); STEL: 400 ppm (983 mg/m3);
8.1 Exposure Limits:
(Isobutanol): TWA: 50 ppm (152 mg/m3);
(1,2-dichloropropane): TWA: 10 ppm (46 mg/m3).
8.2 Exposure control measures
8.2.1 Precautionary Measures:
(according to communitarian directives 89/686/EEC & article 4 of 98/24/EC)
Local Exhaust Ventilation: Appropriate.
Special Ventilation: None.
Ventilation:
Mechanical (General) Ventilation: None.
Other Ventilation: None.
Respiratory Protection: Avoid vapor inhalation. In case of dangerous high concentration use a
respirator with approved filter.
Hands Protection: Impervious gloves, nitrilic type.
Eyes Protection: Safety glasses.
Skin Protection: Handle in accordance with good personal hygiene and safety practices.
Other Protective Equipments: Eyewash. It would be better use a lab coat.
Measures listed in this paragraph are to be considered as indications and NOT prescriptions (89/656/EEC)
8.2.2 Environment exposure control measures
Not Applicable.
Material Safety Data Sheet for: SUPER SEP
KERR
SECTION 9
Physical and Chemical Properties
9.1 General information
Appearance: Colourless liquid. Odour: Petroleum odour.
9.2 Information related to health, safety and environment
pH: Not determined (N/D) Relative density: Not applicable (N/A)
Boiling point: 83癈 Specific gravity: 0,83 g/ml @ 20癈
Flash point: 7,2癈 (TCC) Solubility: Insoluble (in water)
Flammability: Yes. Partition coefficient n-octanol/water: N/A
Lower Explosivity Limit (L.E.L.): 2,0 Viscosity (dynamic): < 2500 cP @ 23癈 (Brookfield)
Viscosity (cinematic): > 700 mm2/s @ 23癈
Upper Explosivity Limit (U.E.L.): 12,7
Oxidizing properties: None Vapour density (air = 1): N/D
Vapour pressure: N/A Evaporation rate (n-butane = 1): N/D
Melting point: N/A
9.3 Other information (according to communitarian directive 94/9/EC):
Miscibility: N/D Conducibility: N/A
Solubility in Lipids: N/D Gases Group: N/A
SECTION 10
Stability and Reactivity
Stability: Stable if stored as directed.
10.1 Conditions to avoid: Heat and ignition sources.
10.2 Materials to avoid (incompatibility): Strong oxidizing agents. Do not store or handle in aluminum
equipment at temperature above 49癈 (120癋).
10.3 Hazardous decomposition products: Carbon oxide and non identified organic components may appear
when the product burns.
Other precautions:
Hazardous Polymerization Products: Not determined.
Safety significance in case of change in physical appearance: None.
Stabilizers: The product does not contain stabilizers.
Material Safety Data Sheet for: SUPER SEP
KERR
SECTION 11
Toxicological Information
CMR effects (Carcinogenicity, Mutagenicity and toxicity for reproduction):
No (See asterisk note in section 3.1 related to Naphta, EC number 265-150-3).
___________________________________________________________________________________________________
Effects and hazards of eye contact: Irritating to the eyes.
Effects and hazards of skin contact: Mildly irritating to the skin.
Effects and hazards of Inhalation (Breathing): May cause mild irritation of the respiratory tract.
Effects and hazards of Ingestion (Swallowing): May cause nausea.
Effects for prolonged Exposure: Unknown.
Toxic-kinetic effects: Unknown.
Effects on metabolism: Unknown.
___________________________________________________________________________________________________
Toxicological data for ingredients:
LD50 (oral rat) 4570 mg/Kg
Isopropyl alcohol
LD50 (skin rabbit) 13400 mg/Kg
LC50 (inhalation rat/4hrs) 30 mg/l
LC50 (oral rat) 2460 mg/m3
Isobutyl alcohol
LD50 (oral rat) 1900 mg/Kg
1,2-dichloropropane
LD50 (skin rabbit) 8750 mg/Kg
LC50 (inhalation rat/8hrs) 3000 ppm
LDLo (oral man) 50 mg/Kg
LCLo (inhalation man/6 hours) 10000 ppm
SECTION 12
Ecological Information
This product has not known ecological hazardous effects.
12.1 Eco-toxicity: Not available
12.2 Mobility: Not available
12.3 Persistence and degradability: Not available
12.4 Bioaccumulative potential: Not available
12.5 Results of PBT (Persistent Bio-Toxicity) assessment: Not available
12.6 Other adverse effects: Not available
________________________________________________________________________________
Material Safety Data Sheet for: SUPER SEP
KERR
Aquatic toxicity data for ingredients:
LC50 (fishes, 48 hours) 8970 mg/l
Isopropyl Alcohol
LC50 (Pimephales putida, 96 hours) 1430 mg/l
Isobutyl Alcohol
EC10 (Pseudomonas putida, 18 hours) 750 mg/l
Easily biodegradable:
EC50 (Daphnia magna, 24 hours) 583 mg/l (DIN 38412)
97% (OCSE 303 A);
EC50 (Scenedesmus subspicatus, 48 hours) 1250 mg/l
99% (OCSE 301 E)
SECTION 13
Disposal considerations
Dispose of in accordance of local regulations.
SECTION 14
Transport information
14.1 Sea transportation (IMDG)
UN number: 1993 Class: 3 Packing group: II
EMS-No: F-E, S-E Stowage/segregation: Category (B);
Limited Quantity: 1 Lt Proper shipping name: Flammable liquid, n.o.s.
14.2 Air transportation (ICAO/IATA)
UN number: 1993 Class: 3 Packing group: II Label: 3 (Flammable liquid)
Maximum quantities: 5 Lt (Passenger Aircraft); 60 Lt (Cargo Aircraft only)
Limited Quantity: 1 Lt Proper shipping name: Flammable liquid, n.o.s.
14.3 Transportation by Road/Railway (RID/ADR)
UN number: 1993 Class: 3 Packing group: II; Hazard identific. n? 33 Label: 3
Proper shipping name: Flammable liquid, n.o.s.
Limited Quantity LQ4: (3lt/30 Kg for combined, 1lt/20Kg for bandaged trays/pallets).
SECTION 15 (Classification according to communitarian directives 67/548/EEC & 99/45/EC)
Regulatory information
Risk phrases
11 Highly flammable.
65 Harmful: may cause lung damage if swallowed.
36 Irritating to eyes.
67 Vapours may cause drowsiness and dizziness. Xn Xi
Safety phrases
2 Keep out of the reach of children.
16 Keep away from sources of ignition.
23 Do not breathe vapour.
24/25 Avoid contact with skin and eyes.
62 If swallowed, do not induce vomiting; seek medical advice immediately
and show this container or label.
Material Safety Data Sheet for: SUPER SEP
KERR
SECTION 16
Other information
16.1 (Other) Risk phrases
10 Flammable.
41 Risk of serious damage to eyes.
43 May cause sensitisation by skin contact.
37/38 Irritating to respiratory system and skin.
20/22 Harmful by inhalation and if swallowed.
40 Limited evidence of a carcinogenic effect.
68 Possible risk of irreversible effects.
53 May cause long-term adverse effects in the aquatic environment.
16.1.1 (Other) Safety phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
46 If swallowed, seek medical advice immediately and show this container or label.
16.2 Sources of key data used to compile the Safety Data Sheet:
European Chemicals Bureau (ECB ?www.ecb.jrc.it)
European chemical Substances Information System (ESIS - www.ecb.jrc.it/esis)
A.C.G.I.H. (www.acgih.org)
N.I.OS.H. (www.cdc.gov/niosh/)
O.S.H.A. (www.osha.gov/)
U.E. (www.europa.eu/index_it.htm)
I.A.R.C. (www.iarc.fr/)
N.T.P. (www.ntp.niehs.nih.gov)
European Community Directives:
67/548/EEC: Classification, packaging and labelling of dangerous substances.
99/45/EC: Directive concerning the approximation of the laws, regulations and administrative
provisions of the Member States relating to the classification, packaging and labelling of
dangerous preparations.
2001/58/EC: Second amendment of directive 91/155/EEC for the definition of a detailed arrangement
of specific information relating to dangerous preparations (art. 14 of 99/45/EC) and
substances (art. 27 of 67/548/EEC).
89/656/EEC: Directive on the minimum health and safety requirements for the use by workers of
personal protective equipment at the workplace (third individual directive within the
meaning of Article 16 (1) of Directive 89/391/EEC).
89/686/EEC: Approximation of the laws of the Member States relating to personal protective
equipment.
94/9/EC: Approximation of the laws of the Member States concerning equipment and protective
systems intended for use in potentially explosive atmospheres
98/24/EC: Protection of the health and safety of workers from the risks related to chemical agents at
work.
2008/58/EC: Commission Directive 2008/58/EC of 21 August 2008 amending, for the purpose of its
adaptation to technical progress, for the 30th time, Council Directive 67/548/EEC on the
approximation of the laws, regulations and administrative provisions relating to the
classification, packaging and labelling of dangerous substances.
Material Safety Data Sheet for: SUPER SEP
KERR
Document modification history: First version in compliance of Community Regulation 2006/1907/EC
(R.E.A.Ch.)
CAUTION: PRODUCT FOR PROFESSIONAL USE
The information on this Safety Sheet is based on presently available data and to our best knowledge
for the correct handling of the product under normal conditions. Any use of this product in any way
not indicated on this Sheet or the use of this product together with any other process/procedure will be
exclusively under the user's responsibility. This document does not constitute explicit or implicit
warranty of product quality or fitness for a particular purpose.
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