Material Safety Data Sheet
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : A-513-12 1K SELF ETCH PRIMER
Product Use Description : Solvent-borne coatings, Primers
Company : PRO-SPRAY
An Alco Industries Company
600 Nova Drive SE
Massillon, Ohio 44646
Phone : 330-830-6000
Fax : 330-830-6005
For Chemical Emergency : CHEMTREC: 1-800-424-9300
CANUTEC: 1-613-996-6666 (For Canada Call Collect)
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Regulatory status : This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
Signal Word : DANGER
Form : aerosol
Odour : characteristic
Odour - Control parameters : no data available
Hazard Summary : Flammable Aerosol
Pressurized container. Protect from sunlight
and do not expose to temperatures exceeding
50?/ 122 ?br>
C F.
Sensitizer
May cause fire. Irritant
Potential Health Effects
Eyes : Causes eye irritation.
Skin : May cause skin irritation.
May cause allergic skin reaction.
Inhalation : Causes respiratory tract irritation.
Target Organs : Skin
Central nervous system
Eyes
Carcinogenicity:
ACGIH : propan-1-ol; n-propanol (CAS-No.: 71-23-8)
ethylbenzene (CAS-No.: 100-41-4)
NTP : No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
IARC : Titanium oxide (TiO2) (CAS-No.: 13463-67-7)
Talc (Mg3H2(SiO3)4) (CAS-No.: 14807-96-6)
ethylbenzene (CAS-No.: 100-41-4)
OSHA : No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
CA Prop 65 : WARNING! This product contains a chemical known in the
State of California to cause cancer.
ethylbenzene (CAS-No.: 100-41-4)
Carbon black (CAS-No.: 1333-86-4)
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No. Weight %
acetone; propan-2-one; propanone 67-64-1 >= 25 - < 35
propan-1-ol; n-propanol 71-23-8 >= 12.5 - < 15
propane 74-98-6 >= 10 - < 12.5
2-methylpropan-1-ol; iso-butanol 78-83-1 >= 7 - < 10
Titanium oxide (TiO2) 13463-67-7 >= 7 - < 10
butane 106-97-8 >= 7 - < 10
Talc (Mg3H2(SiO3)4) 14807-96-6 >= 3 - < 5
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number 25068-38-6 >= 2 - < 3
average molecularweight 700-1200)
2-methoxy-1-methylethyl acetate 108-65-6 >= 1.5 - < 2
1-methoxy-2-propanol; monopropylene glycol methyl ether 107-98-2 >= 1 - < 1.5
xylene 1330-20-7 >= 0.5 - < 0.75
ethylbenzene 100-41-4 >= 0.1 - < 0.2
SECTION 4. FIRST AID
MEASURES
General advice Move: out of dangerous area. Never give anything by mouth to
an unconscious person. In the case of accident or if you feel
unwell, seek medical advice immediately (show the label where
possible). When symptoms persist or in all cases of doubt seek
medical advice. Take off all contaminated clothing immediately.
Inhalation :
Remove to fresh air. Keep patient warm and at rest. If
breathing is irregular or stopped, administer artificial
respiration. If symptoms persist, call a physician.
Skin contact :
Wash off immediately with soap and plenty of water. Do NOT
use solvents or thinners.
Eye contact :
Remove contact lenses. In the case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Irrigate
copiously with clean, fresh water for at least 10 minutes, holding the
eyelids apart.
Ingestion :
If a person vomits when lying on his back, place him in the
recovery position. Clean mouth with water and drink afterwards
plenty of water. Ingest activated charcoal. If swallowed, seek
medical advice immediately and show this container or label.
SECTION 5. FIRE-FIGHTING MEASURES
Form aerosol
:
Flash point : < 0 ?(< 32 ?br>
C F)
Ignition temperature : 365 ?(689 ?br>
C F)
Lower explosion limit : 1.4 %(V)
Upper explosion limit : 8.5 %(V)
Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or
media carbon dioxide.
Extinguishing media which : High volume water jet
must not be used for safety
reasons
Specific hazards during fire : Fire will produce dense black smoke containing hazardous
fighting combustion products (see heading 10).
Do not use a solid water stream as it may
scatter and spread fire.
Use personal protective equipment.
Special protective :
Wear self contained breathing apparatus for fire
equipment for fire-
fighting if necessary.
fighters
Use water spray to cool unopened containers.
Further information :
Exposure to decomposition products may be a
hazard to
health.
Standard procedure for chemical fires.
Use extinguishing measures that are appropriate to
local circumstances and the surrounding environment.
Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local
regulations.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions Ventilate the area.
:
Remove all sources of ignition.
Avoid inhalation of vapour or mist.
Refer to protective measures listed in sections 7 and 8.
Environmental Should not be released into the environment. Avoid
precautions :
subsoil penetration. If the product contaminates
rivers and lakes or drains inform respective
authorities.
Methods for cleaning up Contain and collect spillage with non-combustible
:
absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and place in container for disposal
according to local / national regulations.
67-64-1 5,000 lbs final RQ
CERCLA Hazardous :
substances and
corresponding RQs
71-23-8 100 lbs final RQ
74-98-6 100 lbs final RQ
78-83-1 5,000 lbs final RQ
106-97-8 100 lbs final RQ
107-98-2 100 lbs final RQ
1330-20-7 100 lbs final RQ
100-41-4 1,000 lbs final RQ
SECTION 7. HANDLING AND STORAGE
Handling
Handling :
Do not breathe vapours or spray mist.
Advice on protection :
Avoid contact with skin and eyes.
against fire and
Take precautionary measures against static discharges.
explosion
Prevent the creation of flammable or explosive
concentrations of vapour in air and avoid vapour
concentration higher than the occupational exposure
limits.
Limit the stocks at work place.
Do not spray on a naked flame or any other
Dust explosion class :
incandescent material.
Use only in well-ventilated areas.
For personal protection see section 8.
Storage
Keep away from heat and sources of
Requirements for
ignition. Do not smoke.
storage :
Vapours may form explosive mixtures with air.
areas and containers
Vapours are heavier than air and may spread along
floors.
Advice on common
Electrical equipment should be protected to the
storage :
appropriate
standard.
not applicable
Storage period :
BEWARE: Aerosol is pressurized. Keep away from
Storage temperature :
direct sun exposure and temperatures over 50 ?/ 122
C
?Do not open by force or throw into fire even after
F. :
Other data
use. Do not spray on
flames or red-hot objects.
Please observe the storage instructions for aerosols
Keep away from food, drink and animal feeding stuffs.
Keep away from oxidising agents and strongly acid or
alkaline materials.
24 Months
5 - 30 ?(41 - 86 ?br>
C F)
No decomposition if stored and applied as directed.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Components CAS-No. List Type: Value
acetone; propan-2-one; 67-64-1 ACGIH TWA 500 ppm
propanone
ACGIH STEL 750 ppm
NIOSH REL 250 ppm 590 mg/m3
OSHA Z1 PEL 1,000 ppm 2,400 mg/m3
OSHA Z1A TWA 750 ppm 1,800 mg/m3
OSHA Z1A STEL 1,000 ppm 2,400 mg/m3
US CA OEL TWA PEL 750 ppm 1,780 mg/m3
US CA OEL Ceiling 3,000 ppm
US CA OEL STEL 1,000 ppm 2,400 mg/m3
propan-1-ol; n-propanol 71-23-8 ACGIH TWA 200 ppm
ACGIH STEL 400 ppm
ACGIH NIC TWA 100 ppm
NIOSH REL 200 ppm 500 mg/m3
NIOSH STEL 250 ppm 625 mg/m3
OSHA Z1 PEL 200 ppm 500 mg/m3
OSHA Z1A TWA 200 ppm 500 mg/m3
OSHA Z1A STEL 250 ppm 625 mg/m3
US CA OEL TWA PEL 200 ppm 500 mg/m3
US CA OEL STEL 250 ppm 625 mg/m3
propane 74-98-6 ACGIH TWA 1,000 ppm
NIOSH REL 1,000 ppm 1,800 mg/m3
OSHA Z1 PEL 1,000 ppm 1,800 mg/m3
OSHA Z1A TWA 1,000 ppm 1,800 mg/m3
US CA OEL TWA PEL 1,000 ppm 1,800 mg/m3
2-methylpropan-1-ol; iso- 78-83-1 ACGIH TWA 50 ppm
butanol
NIOSH REL 50 ppm 150 mg/m3
OSHA Z1 PEL 100 ppm 300 mg/m3
OSHA Z1A TWA 50 ppm 150 mg/m3
US CA OEL TWA PEL 50 ppm 150 mg/m3
butane 106-97-8 NIOSH REL 800 ppm 1,900 mg/m3
OSHA Z1A TWA 800 ppm 1,900 mg/m3
US CA OEL TWA PEL 800 ppm 1,900 mg/m3
Talc (Mg3H2(SiO3)4) 14807-96-6 ACGIH TWA 2 mg/m3
NIOSH REL 2 mg/m3
OSHA Z1A TWA 2 mg/m3
Z3 TWA 20
Z3 TWA 2.4
Z3 TWA 0.1 mg/m3
Z3 TWA 0.3 mg/m3
US CA OEL TWA PEL 2 mg/m3
2-methoxy-1-methylethyl 108-65-6 WEEL TWA 50 ppm
acetate
US CA OEL TWA PEL 100 ppm 541 mg/m3
US CA OEL STEL 150 ppm 811 mg/m3
1-methoxy-2-propanol; 107-98-2 ACGIH TWA 100 ppm
monopropylene glycol methyl
ether
ACGIH STEL 150 ppm
NIOSH REL 100 ppm 360 mg/m3
NIOSH STEL 150 ppm 540 mg/m3
OSHA Z1A TWA 100 ppm 360 mg/m3
OSHA Z1A STEL 150 ppm 540 mg/m3
US CA OEL TWA PEL 100 ppm 360 mg/m3
US CA OEL STEL 150 ppm 540 mg/m3
xylene 1330-20-7 ACGIH TWA 100 ppm
ACGIH STEL 150 ppm
OSHA Z1 PEL 100 ppm 435 mg/m3
OSHA Z1A TWA 100 ppm 435 mg/m3
OSHA Z1A STEL 150 ppm 655 mg/m3
US CA OEL TWA PEL 100 ppm 435 mg/m3
US CA OEL Ceiling 300 ppm
US CA OEL STEL 150 ppm 655 mg/m3
ethylbenzene 100-41-4 ACGIH TWA 100 ppm
ACGIH STEL 125 ppm
NIOSH REL 100 ppm 435 mg/m3
NIOSH STEL 125 ppm 545 mg/m3
OSHA Z1 PEL 100 ppm 435 mg/m3
OSHA Z1A TWA 100 ppm 435 mg/m3
OSHA Z1A STEL 125 ppm 545 mg/m3
US CA OEL TWA PEL 100 ppm 435 mg/m3
US CA OEL STEL 125 ppm 545 mg/m3
Engineering measures : Provide adequate ventilation.
Eye protection : Safety glasses
Hand protection : Choose gloves to protect hands against chemicals depending
on the concentration and quantity of the hazardous substance
and specific to place of work.
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective gloves
with the glove manufacturer.
Skin and body protection : impervious clothing
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment.
respirator with ABEK filter
Hygiene measures : Do not inhale aerosol.
When using do not eat, drink or smoke.
Avoid contact with skin, eyes and clothing.
Wash hands before breaks and at the end of workday.
Wash contaminated clothing before re-use.
Handle in accordance with good industrial hygiene and safety
practice. General industrial hygiene practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : aerosol
Odour : characteristic
Flash point : < 0 ?(< 32 ?br>
C F)
Ignition temperature : 365 ?(689 ?br>
C F)
Thermal decomposition : Heating can release hazardous gases., Fire or intense heat
may cause violent rupture of packages.
Lower explosion limit : 1.4 %(V)
Upper explosion limit : 8.5 %(V)
Vapour pressure : 3.6 hPa
at 20 ?(68 ?br>
C F)
Density : 0.85 g/cm3
at ca.20 ?(68 ?br>
C F)
Volatile organic compounds : 32.06 %
(VOC) content
SECTION 10. STABILITY AND REACTIVITY
Conditions to avoid : Heat, flames and sparks.
Materials to avoid : Strong acids and strong bases
Oxidizing agents
Hazardous : Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx),
decomposition dense black smoke.
products
: Heating can release hazardous gases. Fire or intense heat
Thermal decomposition may cause violent rupture of packages.
Hazardous reactions : Vapours may form explosive mixture with air.
Note: No decomposition if used as directed.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute inhalation toxicity: Irritating to respiratory system.
Skin irritation : Repeated or prolonged contact with the preparation may cause
removal of natural fat from the skin resulting in
desiccation of the skin.
: The liquid splashed in the eyes may cause irritation and
Eye irritation
reversible damage.
Strong lachrymation can make it difficult to escape
Carcinogenicity : No data is available on the product itself.
Toxicity to : No data is available on the product itself.
reproduction : No data is available on the product itself.
Teratogenicity : Symptoms of overexposure may be headache, dizziness,
Further information tiredness, nausea and vomiting.
Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhoea.
Liver and kidney injuries may occur.
Even the smallest quantities that enter into the lung
due to swallowing or subsequent vomiting can lead to
a pulmonary oedema or pneumonia.
67-64-1 Acute oral toxicity: LD50 rat
Component:
Dose: 5,800 mg/kg
acetone; propan-2-one;
propanone
Acute dermal toxicity: LD50 rabbit
Dose: 20,000 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 70 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Repeated or prolonged contact with the preparation may
cause removal of natural fat from the skin resulting in
desiccation of the skin.
Eye irritation: Classification: Irritating to eyes.
Result: Moderate eye irritation
propan-1-ol; n-propanol 71-23-8 Acute oral toxicity: LD50 rat
Dose: 1,870 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 4,000 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: > 34 mg/l
Exposure time: 4 h
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
propane 74-98-6 Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
2-methylpropan-1-ol; iso-butanol 78-83-1 Acute oral toxicity: LD50 rat
Dose: > 2,830 mg/kg
Acute dermal toxicity: LD50 rat
Dose: > 2,000 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: > 24 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Eye irritation
Titanium oxide (TiO2) 13463-67-7 Acute oral toxicity: LD50 rat
Dose: > 10,000 mg/kg
Talc (Mg3H2(SiO3)4) 14807-96-6 Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
reaction product: bisphenol-A- 25068-38-6 Skin irritation: Classification: Irritating to skin.
(epichlorhydrin) epoxy resin Result: Mild skin irritation
(number average molecularweight Prolonged skin contact may cause skin irritation and/or
700-1200) dermatitis.
Sensitization: May cause sensitization by skin contact.
2-methoxy-1-methylethyl acetate 108-65-6 Acute oral toxicity: LD50 mouse
Dose: 8,532 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 7,500 mg/kg
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
1-methoxy-2-propanol; 107-98-2 Acute oral toxicity: LD50 rat
monopropylene glycol methyl ether Dose: > 5,000 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: 11,000 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 40 mg/l
Exposure time: 4 h
Eye irritation: Classification: Irritating to eyes.
Result: Mild eye irritation
xylene 1330-20-7 Acute oral toxicity: LD50 rat
Dose: 2,840 mg/kg
Acute dermal toxicity: LD50 rabbit
Dose: ca. 4,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 6,350 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to
skin. Result: Mild skin irritation
Repeated or prolonged exposure may
cause skin irritation and dermatitis, due
to degreasing properties of the product.
Eye irritation: Classification: Irritating to
eyes.
Result: Mild eye irritation
ethylbenzene 100-41-4 Acute oral toxicity: LD50 rat
Dose: 3,500 mg/kg
Acute dermal
toxicity: LD50
rabbit Dose:
15,500 mg/kg
Acute inhalation toxicity: LC50 rat
Dose: 18 mg/l
Exposure time: 4 h
Skin irritation: Classification: Irritating to skin.
Result: Mild skin irritation
Eye irritation: Classification: Irritating to eyes.
Result: Risk of serious damage to eyes.
SECTION 12. ECOLOGICAL INFORMATION
Adsorbed organic bound : not included
halogens (AOX)
Volatile organic compounds : 32.06 %
(VOC) content
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
Component:
propan-1-ol; n-propanol 71-23-8 Toxicity to fish :
LC50
Species: Pimephales promelas (fathead minnow)
Dose: 4,480 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 3,642 mg/l
Exposure time: 48 h
2-methylpropan-1-ol; iso-butanol 78-83-1 Toxicity to fish :
LC50
Species: Pimephales promelas (fathead minnow)
Dose: 1,430 mg/l
Exposure time: 96 h
Acute and prolonged toxicity for aquatic invertebrates:
EC50
Species: Daphnia magna (Water flea)
Dose: 1,439 mg/l
Exposure time: 48 h
Titanium oxide (TiO2) 13463-67-7 Toxicity to fish :
1-methoxy-2-propanol; 107-98-2 Toxicity to fish:
monopropylene glycol methyl LC50
ether Species: Pimephales promelas (fathead minnow)
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SECTION 13. DISPOSAL CONSIDERATIONS
Adequate disposal : In accordance with local and national regulations.
Please ensure aerosol cans are sprayed
completely empty (including propellant)
Containers that have not been emptied in
compliance with regulations are regarded as
hazardous waste.
SECTION 14. TRANSPORT INFORMATION
DOT 49 CFR
Proper shipping name : AEROSOLS
UN-No. : 1950
Class : 2.1
Packing group :
Emergency Response : 126
Guidebook Number
TDGR
Proper shipping name : AEROSOLS
UN-No. : 1950
Class : 2.1
Packing group :
Emergency Response : 126
Guidebook Number
ICAO / IATA-DGR
UN UN-No. : 1950
Description of the goods : AEROSOLS
Class : 2.1
ICAO-Labels : 2.1
Packing instruction (cargo : 203
aircraft)
Packing instruction : 203
(passenger aircraft)
Packing instruction : Y203
(passenger aircraft)
IMDG-Code
UN-No. : UN 1950
Description of the goods : AEROSOLS
Class : 2.1
IMDG-Labels : 2.1
EmS Number : F-D S-U
Marine pollutant : no
SECTION 15. REGULATORY INFORMATION
OSHA Hazards : Flammable Aerosol
Moderate respiratory irritant Skin sensitizer
Moderate skin irritant Severe eye irritant Possible
carcinogen
.
TSCA Status : On TSCA Inventory
DSL Status : All components of this product are on the Canadian DSL list.
SARA 311/312 : Fire Hazard
Hazards Acute Health Hazard
Chronic Health Hazard
Acute Health Hazard
Chronic Health Hazard
CERCLA : 682 lbs
Reportable
Quantity
MASS RTK US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code
of Massachusetts Regulations Section 670.000)
Components CAS-No.
1-methoxy-2-propanol; monopropylene glycol methyl 107-98-2
ether
Talc (Mg3H2(SiO3)4) 14807-96-6
butane 106-97-8
Titanium oxide (TiO2) 13463-67-7
2-methylpropan-1-ol; iso-butanol 78-83-1
propane 74-98-6
propan-1-ol; n-propanol 71-23-8
acetone; propan-2-one; propanone 67-64-1
SARA III US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA
Title III Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification
Required
Components CAS-No.
ethylbenzene 100-41-4
SARA III US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title
III Section 302 Extremely Hazardous Substance (40 CFR355, Appendix A)
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA
Title III, Section 302.
PENN RTK US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap.
301-323)
Components CAS-No.
1-methoxy-2-propanol; monopropylene glycol methyl 107-98-2
ether
Polyvinyl acetale
Talc (Mg3H2(SiO3)4) 14807-96-6
butane 106-97-8
Titanium oxide (TiO2) 13463-67-7
2-methylpropan-1-ol; iso-butanol 78-83-1
propane 74-98-6
propan-1-ol; n-propanol 71-23-8
acetone; propan-2-one; propanone 67-64-1
NJ RTK US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute
Annotated Section 34:5A-5)
Components CAS-No.
1-methoxy-2-propanol; monopropylene glycol methyl 107-98-2
ether
Talc (Mg3H2(SiO3)4) 14807-96-6
butane 106-97-8
Titanium oxide (TiO2) 13463-67-7
2-methylpropan-1-ol; iso-butanol 78-83-1
propane 74-98-6
propan-1-ol; n-propanol 71-23-8
acetone; propan-2-one; propanone 67-64-1
California Prop. 65 : WARNING! This product contains a chemical known in the
State of California to cause cancer.
ethylbenzene 100-41-4
Carbon black 1333-86-4
SECTION 16. OTHER INFORMATION
Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process, unless specified in the
text.
Prepared by : PRO-SPRAY
An Alco Industries Company
600 Nova Drive SE
Massillon, Ohio 44646
Phone: 330-830-6000
Fax: 330-830-6005
Date Revised : November 1, 2007
Date Reviewed : n/a
Revision : New
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