Material Safety Data Sheet # 337
Hercules Chemical Company Inc.
111 South Street
Passaic NJ 07055-7398
Information Telephone: 1-800 221-9330
Internet: www.herchem.com
NFPA HMIS PPE Transport Symbol
Preparation Date April 27, 2007 Revision Date Aug. 2, 2010 Revision Number 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product Identity: HERCULES ROOF & FLASHING SEALANT
Intended Use: Roof Sealant
Manufacturer: Hercules Chemical Company, Inc. Information Telephone: (800) 221-9330
111 South Street
Passaic, New Jersey 07055-7398 Internet: http://www.herchem.com
Emergency Phone: CHEMTREC: (800) 424-9300
MSDS Date of Preparation: 03/23/2007
2. HAZARDS IDENTIFICATION
Combustible viscous paste with mild petroleum odor.
EMERGENCY OVERVIEW
Fumes from the product can be unpleasant, may cause nausea, headache and irritation to eyes, skin and
respiratory tract.
Potential Health Effects.
Inhalation: Inhalation of high vapor concentration can cause dizziness, headaches, and even loss of
consciousness.
Ingestion: DO NOT INDUCE VOMITING. If vomiting occurs, keep head below hips to prevent aspiration of
liquid into the lungs. Get medical attention.
Eye: May cause eye irritation.
Skin: Prolonged skin contact can lead to dry and irritated skin possibly causing dermatitis.
HMIS Hazard Rating: 2 2 0 C
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS No. Percentag OSHA PEL ACGIH TLV Other limits
e
Asphalt 8052-42-4 30-80 Not Established 5.0 mg/m? 5 mg/m?br>
(NIOSH)
Aliphatic hydrocarbons 8052-41-3 3-40 100 ppm 100 ppm 350
(Stoddard) mg/m?(NIOSH)
Amorphous Alumina 93763-70-3 0-20 15 mg/m 10 mg/m N/A
Silicates
Attapulgite Clay 12174-11-7 0-20 N/A 5 mg/m N/A
Cellulose Fibers 9004-34-6 0-15 5 mg/m 5 mg/m N/A
Polymers 9003-55-8 0-20 N/A N/A N/A
Cationic Salt 28701-67-9 0-3 N/A N/A N/A
4. EMERGENCY AND FIRST AID PROCEDURES.
Eye: Immediately flush victim's eyes with large quantities of water, for 15 minutes, holding the eyelids apart.
Get medical attention if irritation persists.
Skin: Wash with soap and water. Remove contaminated clothing and do not reuse until laundered. If persistent
irritation occurs, get medical attention.
Inhalation: Remove the victim to fresh air, if experiencing problem breathing, give oxygen. Give artificial
respiration if not breathing, Get Medical attention. Never give anything by mouth to an unconscious person.
5. FIRE FIGHTING MEASURES
Flashpoint: 104癋 (40癈) PMCC
Flammable Limits: LEL 1.0, LEL 7.0
Autoignition Temperature: Not applicable
Extinguishing Media: Water fog, Foam, Dry Chemical, Carbon Dioxide
Unusual Fire or Explosion Hazards: When heated above flash point, material will release flammable vapors
which can burn or be explosive in confined spaces if ignited. Do not mix with strong oxidants such as liquid
chlorine or concentrated oxygen.
Special Fire-Fighting Instructions: Firefighters and others, who might be exposed to products of combustion,
should wear positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion Products: Carbon monoxide and Carbon Dioxide.
6. ACCIDENTAL RELEASE MEASURES
Spills/Leak Control: Eliminate all sources of ignition and ventilate the area. Soak up with non-combustible
absorbent material like clay or vermiculite. Place in marked containers for proper disposal.
Keep products out of sewers and waterways.
7. HANDLING AND STORAGE
Handling: Keep away from heat and open flames. Keep containers tightly closed. Use with adequate ventilation
Storage: Store in a cool, dry place with adequate ventilation. Do not store in temperatures above 120 deg. F.
Store large quantities in buildings designed for storage of NFPA combustible liquids.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: None required in well ventilated areas. In confined spaces wear a NIOSH approved
respirator for organic vapors.
Engineering Controls: Use with general or local exhaust ventilation.
Skin Protection: Wear protective gloves where prolonged contact is anticipated.
Eye Protection: Safety glasses.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance And Odor: Black viscous Paste with mild odor. Boiling Point: 300-350癋
Physical State: Liquid Vapor Pressure: 3
Vapor Density (Air=1): 3.9 Evaporation Rate (Butyl Acetate=1)@77F: 0.2
Solubility In Water: insoluble Volatile Components: 300 g/l
Specific Gravity: 0.8 - 1.0 Viscosity: Viscous
Melting Point: N/A pH: N/A
10. STABILITY AND REACTIVITY
Stability: Stable.
Conditions to avoid: Keep away from heat, spark, and open flames.
Incompatibility: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, nitrogen oxides, smoke and fumes.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Product may cause respiratory irritation, headache, dizziness, nausea and vomiting. Prolonged or repeated
contact with skin may cause dermatitis.
Sensitization: None.
Chronic: Possible skin and eye irritant.
Carcinogenicity: NTP: No, IARC: No, OSHA: No.
Mutagenicity: Not mutagenic.
Medical Conditions Aggravated by Exposure: Pre-existing skin disease may be aggravated.
Reproductive Toxicity: None.
Acute Toxicity Values: Not determined.
12. ECOLOGICAL INFORMATION
Product has not been tested for ecotoxicity
13. DISPOSAL CONSIDERATIONS
Dispose in accordance with Federal, State, and Local regulations.
14. TRANSPORT INFORMATION
Not regulated for ground transport. For other modes of transportation, consult 49 CFR
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15. REGULATORY INFORMATION
SARA TITLE III ?EPA Regulation 40 CFR 302 (CERCLA Section 102); CFR 355 (SARA Section 301-304);
CFR 372 (SARA Section 311 ?313) ?NOT APPLICABLE
This product contains the following chemicals subject to the reporting requirements of SARA 313 and 40 CFR
372.
1,2,4 ?Trimethylbenzene CAS # 95-63-6 Weight % 0 - 2
EPA HAZARD CLASSIFICATION CODE:
Acute Hazard: N/A
Chronic Hazard: N/A
Fire Hazard: N/A
Pressure Hazard: N/A
Reactive Hazard: N/A
TSCA Inventory: All the components in this product are listed on the TSCA and DSL inventory list.
16. OTHER INFORMATION
DISCLAIMER:
The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to
the best of our knowledge. However, Hercules cannot give any guarantees regarding information from other
sources, and expressly does not make warranties, nor assumes any liability for its use.
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