CONSOLIDATED ENERGY COMPANY LLC
901 Main Street
Jesup, Iowa 50648
MATERIAL SAFETY DATA SHEET
1 CHEMICAL PRODU-CT & COMPANY IDENTIFICATION
FUEL OIL #1
TRADE NAME
CAS NUMBER 8008-20-06
MSDS NUMBER 5439
PRODUCT CODE ND
SYNONYM(S) NO. 1 FUEL OIL (LOW SULFUR); #1 FO; K-1 KEROSENE; JET
FUEL; JP-8; NO. 1 HEATING OIL, JET A, #1 LOW SULFUR,
DYED; K-I KEROSENE, DYED; APPICABLE TO ALL GRADES
MANUFACTURE/ Flint Hills Resources, LP P.O. Box 2917, Wichita, KS 67201
SUPPLIERS Frontier Oil and Refining Company, 4610 S. Ulster, Suite 200; Denver
CO. 80237
Cenex, A division of CHS Cooperatives, P.O. Box 64089, Mail Station
525, St Paul, MN 55164
Citgo Petroleum Corporation, P.O. Box 3758. Tulsa, OK 74102
Exxommoblie Oil Corp., 3225 Gallows Road, Fairfax VA. 22037
Gary-Williams Energy Corp., 1207 Soverign Row. OKC, OK 73108
Lion Oil Co., 1000 McHenry St., ElDorado, AK 71730
Marathon Ashland Petroleum LLC., 539 South Main St., Findlay, OH 45840
Conoco/Phillips, Bartlesville, OK 74004
Valero Marketing and Supply Co., P.O. Box 500, San Antonio, TX 78292
F.C. Stone Trading, 10330 NW Prairieview RD., Kansas City, MO 64153
SRP, 8101 E. Prentice Ave., Suite 704, Greenwood Village, CO 80111
Western Petroleum Company, 9531 West 78th St., Eden Prairie, MN 55344
TransMontaigne Product Services, Inc, 370 S17th Street, Suite 2750, Denver, Co.
80202
Premcor Refining Group Inc., 8182 Maryland Ave. Clayton, MO 63105
Center Marketing Company, 600 Mason Ridge Center Drive, St. Louis, Mo. 63141
Apex Oil Co., 8235 Forsyth, 4th Floor, St Louis, Mo 63105
TELEPHONE NUMBERS-24 HOUR EMERGENCY ASSISTANCE
Chemtrec 800-633-8253
Consolidated Energy Company 800-399-1562
2 COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Name CAS Number Concentration* Exposure limits/Health Hazards
A COMPLEX COMBINATION
OF C9-C16 HYDROCARBONS
PRODUCED BY THE 08-20-6 9-100% ND
DISTILLATION OF CRUDE OIL `
1,2,4,-TRIMETHYLBENZENE 95-63-6 0-6% 25 ppm 8-hour TWA (ACGIH)
ETHYLBENZENE 100-41-4 0-4% 100 ppm 8 Hour TWA (OSHA)
100 ppm 8-Hour TWA (ACGIH)
125 ppm 15-Min STEL (ACGIH)
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Trade Name FUEL OIL NO.1 (LOW SULFUR)
TOLUENE 108-88-3 0-2% 200 PPM 8-Hour TWA (OSHA)
300 ppm CEILING (OSHA)
50 ppm 8-Hour TWA (ACGIH)
XYLENES 1330-20-7 0-1% 100 ppm 8-Hour TWA (OSHA)
100 PPN 8-Hour TWA (ACGIH)
150 ppm 15-Min STEL (ACGIH)
NAPHTHALENE 91-20-3 0-0.5% 10- ppm 8-Hour TWA (OSHA)
10- ppm 8-Hour TWA (ACGIH)
15- ppm 15-Min STEL (ACGIH)
BIPHENYL 95-52-4 0-0.5% 0.2 ppm 8-Hour TWA (OSHA)
0.2 ppm 8-Hour TWA (ACGIH)
CUMENE 98-82-8 0-0.3% 50 ppm 8-Hour YWA (OSHA)
50 ppm 8-Hour TWA (ACGIH)
BENZENE 71-43-2 0-0.1% 1- ppm. 8-Hour TWA (OSHA)
5- ppm. 15-min STEL (OSHA)
0.5 ppm 8-Hour TWA (ACGIH)
2.5 ppm 15-min STEL (ACGIH)
*Values do not reflect absolute minimums and maximums; these values are typical which may vary
from time to time.
COMPOSITION COMMENTS
This Material Data Sheet is intended to communicate potential health hazards and potential physical
hazards associated with the product(s) covered by this sheet, and is not intended to communicate
product specific information. For product specific information, contact your Pawnee Petroleum
Products representative.
3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING!
HEALTH HAZARDS
MAY CAUSE CARDIAC SENSITATIZATION
MAY BE IRRITATING TO THE SKIN, EYES AND RESPIRATORY TRACT
OVEREXPOSURE MAY CAUSE CNS DEPRESSION
ASPIRATION HAZARD IF SWALLOWED-CAN ENTER LUNGS AND CAUSE DAMAGE
CONTAINS MATERIAL WHICH MAY CAUSE REPRODUCTIVE EFFECTS BASED ON
ANIMAL DATA
SKIN CANCER HAZARD BASED ON TESTS WITH LABORATORY ANIMALS
DANGER-CONTAINS BENZENE-CANCER HAZARD
MAY CAUSE BLOOD DISORDERS
SEE "TOXICOLOGICAL INFORMATION" (SECTION 11) FOR MORE INFORMATION
FLAMMABILITY HAZARDS
COMBUSTIBLE
PER OSHA GUIDELINES, 29 CFR 1910.1200(c)
REACTIVITY HAZARDS
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STABLE
POTENTIAL HEALTH EFFECTS, SKIN
MODERATELY IRRITATING. Contact may cause reddening, itching and inflammation.
Repeated or prolonged skin contact may cause drying, reddening, itching and cracking. Defatting
agent.
No significant effects are expected to occur following short term exposure. Repeated or prolonged
contact with large amounts of this material may result in absorption through the skin to produce toxic
effects.
POTENTIAL HEALTH EFFECTS, EYE
SLIGHTLY IRRITATING. Exposure to vapors, fumes or mists may cause irritation. May cause
slight transient irritation, lacrimation (tears) and a burning sensation in the eyes. Prolonged or
repeated exposure may cause irritation and conjunctivitis.
POTENTIAL HEALTH EFFECTS, INHALATION
MODERATLEY TOXIC. Breathing of mists, vapors, or fumes may irritate the nose, throat and
lungs. Symptoms may include sore throat, coughing, labored breathing, sneezing, and burning
sensation, depending on the concentration and duration of exposure.
May cause central nervous system depression or effects. Symptoms may include headache,
excitation, euphoria, dizziness, incoordination, drowsiness, light-headedness, blurred vision, fatigue,
tremors, convulsions, loss of consciousness, coma, respiratory arrest and death, depending on the
concentration and duration of exposure.
May cause cardiac sensitization, including arrhythmia (irregular heart beat) and death due to cardiac
arrest.
Overexposure to this material may cause systemic damage including target organ effects listed under
"Toxicological Information" (Section 11).
Other specific symptoms of exposure are listed under "Toxicological Information" (Section 11).
4 FIRST AID MEASURES
SKIN
Immediately wash skin with plenty of soap and water while removing contaminated clothing and
shoes. GET IMMEDIATE MEDICAL ATTENTION.
Place contaminated clothing in closed container for storage until laundered or discarded. If clothing
is to be laundered, inform person performing operation of contaminant's hazardous properties.
Discard contaminated leather goods.
EYE
Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away
from the eyeball to ensure thorough rinsing. GET IMMEDIATE MEDICAL ATTENTION.
INHALATION
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Trade Name FUEL OIL NO.1 (LOW SULFUR)
Remove to fresh air. If not breathing, institute rescue breathing. If breathing is difficult, ensure
airway is clear and give oxygen.
Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION
INGESTION
Do not induce vomiting because of danger or aspirating liquid into lungs, causing serious damage and
chemical pneumonia. If spontaneous vomiting occurs, keep head below hips to prevent aspiration
and monitor for breathing difficulty. Gastric lavage should be preformed only by qualified medical
personnel.
Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION.
NOTES TO PHYSICAN
Gastric lavage may be indicated if ingested. If spontaneous vomiting has occurred after ingestion, the
patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungs may
be delayed up to 48 hours.
In cases of acute poisoning, artificial respiration with administration of oxygen may be useful for support. DO
NOT GIVE EPINEHRINE, EPHEDRINE OR SIMLAR ADRENERGIC DRUGS. THEY MAY INDUCE
FATAL VENTRICULAR FIBRILLATION. Electrocardiographic monitoring should be carried out with
severely ill patients to anticipate cardiac arrest.
Anemia may require the usual supportive measures. Medical evaluation of acute overexposure should include
hematological determinations until stable. In severe acute and chronic poisoning, both renal and hepatic
damage may occur and should be anticipated in such cases. Respiratory and pulmonary problems may require
special attention. After severe acute symptoms have bee alleviated, it may be advisable to consider periodic
monitoring of the patient until such time as the likelihood of other adverse effects can be discounted.
5 FIRE FIGHTING MEASURES
HAZARDOUS COMBUSTION PRODUCTS
Combustion may produce COx, NOx, SOx, reactive hydrocarbons, irritating vapors and hydrogen
sulfide.
EXTINGUISHING MEDIA
Use water spray, dry chemical, alcohol foam, all purpose AFFF or carbon dioxide to extinguish fire.
BASIC FIRE FIGHTING PROCEDURES
Evacuate area and fight fire from safe distance.
If leak or spill has not ignited, ventilate area and use water spray to disperse gas or vapor and to
protect personnel attempting to stop leak.
Use water to cool adjacent structures and to protect personnel. Shut off source flow if possible. Stay
away from storage tank ends. Withdraw immediately in case of rising sound from venting safety
device or any discoloration of storage tank due to fire.
Firefighters must wear NIOSH approved positive pressure breathing apparatus (SCBA) with full face
mask and full protective equipment.
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Trade Name FUEL OIL NO.1 (LOW SULFUR)
UNUSUAL FIRE & EXPLOSIN HAZARDS
Vapors may form explosive mixture with air. Vapors can travel to a source of ignition and flash
back.
Explosion hazard if exposed to extreme heat or to physical or thermal shock.
Flash Point > 100 *F (>38*C) PENSKY-MARTENS
CLOSED CUP
Autoignition Temperature 400*F (>204 *C)
Flammability Limits in Air, Lower, % by Volume 0.7%
Flammability Limits in Air, Upper, % by Volume 5%
6 ACCIDENTAL RELEASE MEASURES
EMERGENCY ACTION
Eliminate and/or shut off ignition sources and keep ignition sources out of the area. Keep
unnecessary people away; isolate hazard area and deny entry. Stay upwind. Isolate for ?mile in all
directions if tank, railcar or tank truck is involved in fire. Evacuate area endangered by release as
required. (See Exposure Control/Personal Protection ?Section 8).
ENVIRONMENTAL PRECAUTIONS
Eliminate all sources of ignition. Isolate hazard areas and deny entry.
If material is released to the environment, take immediate steps to stop and contain release. Caution
should be exercised regarding personnel safety and exposure to the released material. Notify local
authorities and the National Response Center, if required.
SPILL OR LEAK PROCEDURE
Keep unnecessary people away. Isolate area for at least 25-50 meters (80-160 feet) to preserve public
safety. For large spills, consider initial evacuation for at least 300 meters (1000 feet).
Keep ignition sources out of the area and shout off all ignition sources. Absorb spill with inert
material (e.g. dry sand, or earth) then place in chemical waste container. Large spills: Dike far
ahead of liquid spill for later disposal. Stop leak when safe to do so.
See Exposure Control/Personal Protection (Section 8).
7 HANDLING AND STORAGE
HANDLING
Ground lines and equipment used during transfer to reduce the possibility of static spark-initiated fire
or explosion. Use non-sparking tools. Do not cut, grind, drill, weld, or reuse containers unless
adequate precautions are taken against these hazards.
Do not eat, drink, or smoke in areas of use or storage.
STORAGE
Store in tightly closed containers in a cool, dry, isolated, well-ventilated area away from heat, sources
of ignition and incompatibles. Avoid contact with strong oxidizers.
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Empty containers may contain product residue. Do not reuse without adequate precautions.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
Ventilation and other forms of engineering controls are the preferred means of controlling exposures.
EYE PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
Wear chemical safety goggles and face shield. Have eye wash facilities readily available where eye
contact can occur.
SKIN PROTECTION: PERSONAL PROTECTIVE EQUIPMENT (PPE)
Avoid skin contact with this material. Use appropriate chemical protective gloves when handling.
Use good personal hygiene.
RESPIRATORY PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
A NIOSH approved air purifying respirator with an appropriate cartridge or canister, such as full face
piece air purifying respirator equipped with an organic vapor cartridge, may be used in circumstances
where airborne concentrations may exceed exposure limits. The use of air purifying respirators is not
recommended where hydrogen sulfide levels may exceed exposure limits.
Air purifying respirators are limited by the oxygen levels in the work environment. Use a positive
pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels
are not known, or any other circumstances where air purifying respirators may not provide adequate
protection.
9 PHYSICAL & CHEMICAL PROPERITES
ODOR AND APPEARANCE
CRYSTAL CLEAR LIQUID WITH KEROSENE-LIKE ODOR; FOR TAX EXEMPT PURPOSES,
THIS FUEL MAY CONTAIN RED DYE
Boiling Point 280 ?572 *F (138-300 *C)
Specific Gravity 0.77 ?.84 at 60/60 *F
Melting Point -53 TO 0 *F ?7 TO -18 *C)
Percent Volatile 100%
Vapor Pressure 22 mmHg AT 158 *F (70 *C)
Vapor Density 4.5 (AIR=1)
Bulk Density ND
Solubility in Water NEGLIGIBLE
Octanol/Water Partn ND
Volatile Organic ND
Pour Point ND
pH Value ESSENTIALLY NEUTRAL
Freezing Point ND
Viscosity 8 cSt AT ? *F (-20 *C)
Evaporation Rate VERY SLOW
Molecular Formula NA
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Trade Name FUEL OIL NO.1 (LOW SULFUR)
Molecular Weight ND
Chemical Family PETROLEUM HYDROCARBON
Odor Threshold ND
10 STABILITY & REACTIVITY
STABILITY/INCOMPABILITY
Incompatible with oxidizing agents. See precautions under handling & Storage (Section 7).
HAZARDOUS REACTIONS/DECOMPOSITON PRODUCTS
Combustion may produce COx, NOx, SOx, reactive hydrocarbons, irritating vapors and hydrogen
sulfide.
11 TOXICOLOGICAL INFORMATION
ROUTES OF EXPOSURE
Inhalation, ingestion, skin and eye contact
LD50
LD50; Fuel Oil No.1, Rat, Oral, >5g/kg
TOXICOLOGICAL DATA
Acute or chronic overexposure to this material or its components may cause systemic toxicity, including
adverse effects to the following: liver and kidney, bone marrow, blood, adrenals, thymus, pituitary, thyroid,
respiratory and central nervous systems.
Exposure to components of this material may cause the following specific symptoms, depending on the
concentration and duration of exposure: anemia, burning sensation in chest, insomnia, pallor, loss of appetite
and anxiety.
Exposure to high concentrations of petroleum mists or vapors may lead to oil chemical pneumonia.
WARNING; The use of any hydrocarbon fuel in an area without adequate ventilation may result in hazardous
levels of combustion products and inadequate oxygen levels.
Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage (sometimes referred to as solvent or painter's syndrome). Intentional misuse by
deliberately concentrating and inhaling this product may be harmful or fatal.
This material may contain benzene. Benzene is carcinogenic to laboratory animals when given by intubation
or by inhalation. There is an association between occupational exposure to benzene and human leukemia.
carcinogenic determination: IARC human positive and Animal suspected carcinogen; NTP known carcinogen;
ACGIH suspected carcinogen; OSHA carcinogen. Acute benzene poisoning causes central nervous system
depression. Chronic exposure affects the hematopoietic system causing blood disorders including anemia and
pancytopenia. Mutagenic and clastogenic in mammalian and non-mammalian test systems. Reproductive or
developmental toxicant only at doses that are maternally toxic, based on tests with animals.
This material may contain naphthalene. Naphthalene can be harmful by any route of exposure. Humans may
be more sensitive to naphthalene than laboratory animals. Naphthalene can cause skin and eye irritation and
acute central nervous system effects. It can also cause blood effects, including hemolytic and aplastic anemia,
cataracts, liver and kidney damage. Following maternal exposure, naphthalene has also been reported to cause
fetal blood system, liver and possible eye damage. In a 2-year lifetime inhalation bioassay, female mice
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showed a significantly increased incidence of pulmonary alveolar and bronchiolar adenomas. On this basis,
NTP has determined that there is some evidence of naphthalene carcinogenicity in female mice. Both male
and female mice showed evidence of chronic inflammation and its associated response in the respiratory
system.
This material has not been tested as a whole for all potential health effects. Use caution in handling to avoid
exposure.
CARCINOGENICITY
In an NTP skin painting study on Fuel Oil No. 1 there was no evidence of carcinogenicity in male of female
mice
Lifetime exposure to whole diesel exhaust has been shown to cause cancer in laboratory animals. NIOSH
recommends that whole diesel exhaust be regarded as a potential occupational carcinogen.
IARC has determined that there is inadequate evidence for the carcinogenicity of light fuel oils in humans and
experimental animals. IARC has determined there is limited evidence for the carcinogenicity of straight run
kerosene in experimental animals and inadequate evidence in humans.
This material may contain ethylbenzene. Ethylbenzene has shown clear evidence of carcinogenicity in male
rats and some evidence of carcinogenicity in female rats and male and female mice.
This material may contain naphthalene. IARC has determined that there is sufficient evidence for the
carcinogenicity of naphthalene in experimental animals (IARC Class 2B).
TERATOGENICITY, MUTAGENICITY, OTHER REPRODUCTIVE EFFECTS
This material contains components wich mayd damage genetic material in some short-term test systems. This
material contains components, which may cause adverse reproductive and/or developmental effects.
Has been shown to be positive in mutagenicity assays. Pregnant women may be at increased risk from
exposure.
PRE-EXISTING CONDITIONS AGGRAVATED BY EXPOSURE
Pre-existing medical conditions which may be aggravated by exposure, include disorders of the kidney, liver
blood, skin, eye, cardiovascular, respiratory system, neurological and hemopoietic systems.
ECOLOGICAL INFORMATION
12
ND
13 DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
This material, as supplied, when discarded or disposed of, is a hazardous waste according to Federal
regulations (40CFR 261) due to its ignitability and benzene content. Under the Resource Conservation and
Recovery Act (RCRA), it is the responsibility of the user of the product to determine, at the time of disposal,
whether the material is a hazardous waste subject RCRA.
The transportation, storage, treatment and disposal of RCRA waste material must be conducted in compliance
with 40 CFR 262, 263, 264, 268, and 270. Disposal can occur only in properly permitted facilities. Check
state and local regulations for any additional requirements as these may be more restrictive than federal laws
and regulations. Chemical additions, processing or otherwise altering this material may make waste
management information presented in this MSDA incomplete, inaccurate or otherwise inappropriate. Disposal
of this material must be conducted in compliance with all federal, state and local regulations.
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14 TRANSPORT INFORMATION
BILL OF LADING ?BULK (U.S. DOT)
Fuel oil (No. 1), Combustible Liquid, NA 1993, PG III
BILL OF LADING ?NON-BULK (U.S. DOT)
Non-Regulated
U.S. Department of Transportation (DOT) Requirements
General Transportation Information for Bulk Shipments
Proper Shipping Name Fuel Oil (No.1)
Hazard Class 3 UN/NA Code NA 1993
Packaging Group PG III
Labels Required None
Placards Required Combustible Liquid, NA 1993
Reportable Quantity See Regulatory Information (Section 15)
General Transportation Information for Non-Bulk Shipments
Proper Shipping Name Non-Regulated
Hazard Class NA UN/NA Code NA
Packaging Group NA
Labels Required NA
Placards Required NA
Reportable Quantity NA
COMMENTS
Non-bulk shipments of this material are non-regulated foe domestic ground transportation when they meet
requirements of 49 CFR 173.150(f).
The above description may not cover shipping in all cases, please consult 49 CFR 100-185 for specific
shipping information.
15 REGULATORY INFORMATION
FEDERAL REGULATIONS
All ingredients are on the TSCA inventory, or are not required to be listed on the TSCA inventory.
Consult OSHA's Benzene standard 29 CFR 1910.1028 for provisions on air monitoring, employee training,
medical monitoring, etc.
A release of this material, as supplied, is exempt from reporting under the Comprehensive Environmental
Response Compensation and Liability Act (CERCLA) by the petroleum exclusion. Releases may be reported
to the National Response center (800-424-8802) under the Clean Water Act, 33 U.S.C. 1321 (b)(3) and (5).
Check state and local regulations for any additional requirements as these may be more restrictive than federal
laws and regulations. Failure to report may result in substantial civil and criminal penalties.
This material contains one or more components designated as hazardous substances or toxic pollutants
pursuant to the Federal Clean Water Act (40 CFR 116.4 Table A; 40 CFR 401.5). Any unpermitted
introduction of this material into a facility stormwater or wastewater discharge may constitute a violation of
the Clear Water Act. Facilities must notify the appropriate permitting agency prior to introducing this material
into the aforementioned discharges.
This material contains one or more substances listed as hazardous, toxic, or flammable air pollutants under
Section 112 of the Clear Air Act.
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There may be specific regulations at the local, regional or state/provincial level that pertain to this material.
STATE REGULATIONS
WARNING: This material contains a chemical known to the State of California to cause cancer and birth
Defects or other reproductive harm.
SARA TITLE III RATINGS
Immediate Hazard: X Delayed Hazard: X Fire hazard: X Pressure Hazard: -
Reactivity Hazard -
NFPA RATINGS
Health 1 Flammability 2 Reactivity 0 Special Hazards
HMIS RATINGS
Health 2* Flammability 2 Reactivity 0
Following ingriedents of this material are listed in SARA 313 above the de minimus concentration
SARA Listed Ingredient Name CAS number Maximum %
1,2,4-TRIMETHYLBENZENE 95-63-6 6.0
ETHYLBENZENE 100-41-4 4.0
TOULENE 108-88-3 2.0
XYLENES 1330-20-7 1.0
BENZENE 71-43-2 0.1
16 OTHER INFORMATION
DISCLAIMER
NOTICE: The information presented herein is based on data considered to be accurate as of the date of the
preparation of this Material Safety Data Sheet. However, an MSDS may not be used as a commercial
specification sheet of manufacture or seller, and no warranty or representation, expressed or implied, is made
as the to accuracy or comprehensiveness of the foregoing data and safety information, nor is any authorization
given or implied to practice any patented invention without a license. In addition, no responsibility can be
assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to
recommended practices, or from any hazards inherent in the nature of the product.
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