FARMLAND INDUSTRIES PETROLEUM DIV -- K-1 KEROSENE - KEROSENE

MATERIAL SAFETY DATA SHEET

NSN: 9140012924460

Manufacturer's CAGE: 6G072

Part No. Indicator: B

Part Number/Trade Name: K-1 KEROSENE

===========================================================================

                             General Information

===========================================================================

Item Name: KEROSENE

Company's Name: FARMLAND INDUSTRIES INC. PETROLEUM DIVISION

Company's P. O. Box: 7305

Company's City: KANSAS CITY

Company's State: MO

Company's Country: US

Company's Zip Code: 64116-0005

Company's Emerg Ph #: 316-251-4000/800-424-9300(CHEMTREC)

Company's Info Ph #: 816-459-4100

Record No. For Safety Entry: 013

Tot Safety Entries This Stk#: 014

Status: FE

Date MSDS Prepared: 22FEB91

Safety Data Review Date: 19JUL94

Supply Item Manager: KY

MSDS Serial Number: BTRYG

Spec Type, Grade, Class: 1-K GRADE

Hazard Characteristic Code: F4

Unit Of Issue: GL

Unit Of Issue Container Qty: BULK

===========================================================================

                      Ingredients/Identity Information

===========================================================================

Proprietary: NO

Ingredient: KEROSENE (ALIPHATIC PETROLEUM SOLVENT/PARAFFINS, NAPHTHENES,

OLEFINS, AROMATIC)

Ingredient Sequence Number: 01

Percent: >95

NIOSH (RTECS) Number: OA5500000

CAS Number: 8008-20-6

OSHA PEL: 100 PPM (MFR)

ACGIH TLV: NOT ESTABLISHED

Other Recommended Limit: NONE SPECIFIED

-------------------------------------

Proprietary: NO

Ingredient: 1,2,4-TRIMETHYLBENZENE (SARA III)

Ingredient Sequence Number: 02

Percent: <2

NIOSH (RTECS) Number: DC3325000

CAS Number: 95-63-6

OSHA PEL: 25 PPM

ACGIH TLV: 25 PPM; 9394

Other Recommended Limit: NONE RECOMMENDED

===========================================================================

                      Physical/Chemical Characteristics

===========================================================================

===========================================================================

Appearance And Odor: PALE YELLOW TO WATER WHITE, OILY LIQUID WITH KEROSENE

ODOR

Boiling Point: >300F,>149C

Vapor Pressure (MM Hg/70 F): <5

Vapor Density (Air=1): 4.5

Specific Gravity: 0.8

Decomposition Temperature: UNKNOWN

Evaporation Rate And Ref: <1 (ETHER=1)

Solubility In Water: NEGLIGIBLE

Percent Volatiles By Volume: 100

Corrosion Rate (IPY): UNKNOWN

===========================================================================

                      Fire and Explosion Hazard Data

===========================================================================

Flash Point: 125F,52C

Flash Point Method: PMCC

Lower Explosive Limit: 0.7

Upper Explosive Limit: 5.0

Extinguishing Media: FOAM, DRY CHEMICAL AND CARBON DIOXIDE. USE WATER

SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY.

Special Fire Fighting Proc: DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE

SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT. THIS MAY INCLUDE SELF-CONTAINED

BREATHING APPARATUS.

Unusual Fire And Expl Hazrds: THIS MATERIAL RELEASES FLAMMABLE VAPORS AT

NORMAL ATMOSPHERIC TEMPERATURES AND PRESSURES; VAPORS WHEN MIXED IN CERTAIN

PROPORTION WITH AIR CAN BURN OR EXPLODE.

===========================================================================

                              Reactivity Data

===========================================================================

Stability: YES

Cond To Avoid (Stability): HIGH HEAT, SPARKS, STATIC ELECTRICITY, OPEN

FLAMES AND OTHER SOURCES OF IGNITION

Materials To Avoid: STRONG OXIDIZING AGENTS

Hazardous Decomp Products: FUMES, SMOKE, CARBON MONOXIDE, CARBON DIOXIDE,

ALDEHYDE AND OTHER DECOMPOSITION PRODUCTS, IN THE CASE OF INCOMPLETE BURN

Hazardous Poly Occur: NO

Conditions To Avoid (Poly): NONE

===========================================================================

                            Health Hazard Data

===========================================================================

LD50-LC50 Mixture: UNKNOWN

Route Of Entry - Inhalation: YES

Route Of Entry - Skin: YES

Route Of Entry - Ingestion: YES

Health Haz Acute And Chronic: ACUTE- INHALATION:CENTRAL NERVOUS SYSTEM

DEPRESSION OR RESPIRATORY IRRITATION. EYES- IRRITATION. INGESTION:HARMFUL,

IRRITATION OF GI TRACT. ASPIRATION INTO THE LUNGS CAN CAUSE SEVERE CHEMICAL

PNEUMONITIS, WHICH CAN BE FATAL. SKIN:PROLONGED OR REPEATED EXPOSURE MAY

CAUSE IRRITATION. CHRONIC:DERMATITIS.

Carcinogenicity - NTP: NO

Carcinogenicity - IARC: NO

Carcinogenicity - OSHA: NO

Signs/Symptoms Of Overexp: HEADACHE, DIZZINESS, NAUSEA, VOMITING & LOSS OF

COORDINATION. EYE CONTACT MAY CAUSE IRRITATION. SKIN:IRRITAION. SWALLOWING

CAN CAUSE VOMITING, DIARRHEA & RESTLESSNESS.

CAN CAUSE VOMITING, DIARRHEA & RESTLESSNESS.

Med Cond Aggravated By Exp: SKIN, CNS, AND IMPAIRED RESPIRATORY FUNCTION.

Emergency/First Aid Proc: GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.

SKIN:WASH WITH WATERLESS CLEANER,THEN WITH SOAP & WATER. EYE:FLUSH WITH

WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. INHALATION:REMOVE TO FRESH AIR

& PROVIDE OXYGEN/CPR IF NEEDED. INGESTION:DO NOT INDUCE VOMITING. IF

VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION. CALL A

PHYSICIAN.

===========================================================================

                    Precautions for Safe Handling and Use

===========================================================================

Steps If Matl Released/Spill: SHUT OFF AND ELIMINATE ALL IGNITION SOURCES.

KEEP PEOPLE AWAY. RECOVER FREE PRODUCT. ADD SUITABLE ABSORBENT TO SPILL

AREA. MINIMIZE BREATHING VAPORS. CONTAIN SPILL BY DIKING OR IMPOUNDING.

PROVIDE ADEQUATE VENTILATION. PROTECT SKIN OR CLOTHING.

Neutralizing Agent: NONE

Waste Disposal Method: DISPOSE BY A LICENSED WASTE DISPOSAL COMPANY IN

ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.

Precautions-Handling/Storing: STORAGE-STORE IN COOL,VENTILATED AREA AWAY

FROM FLAME,SPARKS,STATIC ELECTRICITY.KEEP CONTAINER CLOSED.

Other Precautions: USE ONLY IN WELL VENTILATED AREA. DO NOT WELD, HEAT OR

DRILL CONTAINER. EMPTY CONTAINER STILL CONTAIN HAZARDOUS/EXPLOSIVE VAPOR/

LIQUID. DO NOT USE PRESSURE TO EMPTY DRUM OR EXPLOSION MAY RESULT. TOXIC

FUMES MAY ACCUMULATE AND CAUSE DEATH.

===========================================================================

                              Control Measures

===========================================================================

Respiratory Protection: USE NIOSH-APPROVED EQUIPMENT WHEN AIRBORNE LIMITS

EXCEEDED.

Ventilation: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST)

VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).

Protective Gloves: RUBBER

Eye Protection: CHEMICAL SAFETY GLASSES/GOGGLES

Other Protective Equipment: REMOVE CONTACT LENSES AND WEAR CHEMICAL SAFETY

GLASSES WHERE CONTACT WITH LIQUID MAY OCCUR.

Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING THIS

PRODUCT.

Suppl. Safety & Health Data: USE SPARKS-PROOF TOOLS. THIS LIQUID IS

VOLATILE AND GIVES OFF INVISIBLE VAPORS. EITHER THE LIQUID OR VAPOR MAY

SETTLE IN LOW AREAS AND TRAVEL SOME DISTANCE ALONG THE GROUND OR SURFACE TO

IGNITION SOURCES WHERE THEY MAY IGNITE OR EXPLODE. PROVIDE ADEQUATE

VENTILATION.

===========================================================================

                             Transportation Data

===========================================================================

Trans Data Review Date:    94200

DOT PSN Code: ICS

DOT Proper Shipping Name: KEROSENE

DOT Class: 3

DOT ID Number: UN1223

DOT Pack Group: III

DOT Label: FLAMMABLE LIQUID

IMO PSN Code: IRR

IMO Proper Shipping Name: KEROSENE

IMO Regulations Page Number: 3375

IMO UN Number: 1223

IMO UN Number: 1223

IMO UN Class: 3.3

IMO Subsidiary Risk Label: -

IATA PSN Code: OVO

IATA UN ID Number: 1223

IATA Proper Shipping Name: KEROSENE

IATA UN Class: 3

IATA Label: FLAMMABLE LIQUID

AFI PSN Code: OVO

AFI Prop. Shipping Name: KEROSENE

AFI Class: 3

AFI ID Number: UN1223

AFI Pack Group: III

AFI Basic Pac Ref: 7-7

===========================================================================

                                Disposal Data

===========================================================================

===========================================================================

                                 Label Data

===========================================================================

Label Required: YES

Technical Review Date: 19JUL94

MFR Label Number: UNKNOWN

Label Status: F

Common Name: K-1 KEROSENE

Signal Word: WARNING!

Acute Health Hazard-Moderate: X

Contact Hazard-Moderate: X

Fire Hazard-Moderate: X

Reactivity Hazard-None: X

Special Hazard Precautions: ACUTE-INHALATION OF EXCESSIVE CONCENTRATIONS

OF FUME/MIST CAN BE IRRITATING TO THE RESPIRATORY PASSAGES & CAN CAUSE

HEADACHE,DIZZINESS,NAUSEA,VOMITING & LOSS OF COORDINATION.EYE CONTACT MAY

CAUSE IRRITATION.SKIN CONTACT MAY AGGRAVATE DERMATITIS.SWALLOWING CAN CAUSE

VOMITING,DIARRHEA & RESTLESSNESS.CHRONIC-DERMATITIS.STORAGE-STORE IN COOL,

VENTILATED AREA AWAY FROM IGNITION SOURCES.FIRST AID-GET MEDICAL ATTENTION

IF SYMPTOMS PERSIST.SKIN:WASH WITH WATERLESS CLEANER,THEN WITH SOAP &

REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.ORAL:DO NOT INDUCE

VOMITING.CALL PHYSICIA

Protect Eye: Y

Protect Skin: Y

Protect Respiratory: Y

Label Name: FARMLAND INDUSTRIES INC. PETROLEUM DIVISION

Label P.O. Box: 7305

Label City: KANSAS CITY

Label State: MO

Label Zip Code: 64116-0005

Label Country: US

Label Emergency Number: 316-251-4000/800-424-9300(CHEMTREC)