Material Safety Data Sheet
according to 91/155/EEC
Product name : Eurothane Varnish Satin
Revision : 23.06.2006 Version : 3.0.0
Print date : 25.07.2006
01. Identification of substance, product and company
Product name:
Eurothane Varnish Satin
Use of the substance / product
Eurothane Varnish Satin is an advanced polyurethane varnish suitable for interior use on floors, furniture, paneling and other
woodwork requiring an abrasion, scratch, water and alcohol resistant finish.
Manufacturer/Supplier
Wijzonol Bouwverven International B.V.
Street/P.O.Box
Russenweg 14
Country code/Postal code/Town/City
8041 AL ZWOLLE
Telephone / Telefax (weekdays 8-5 C.E.T.)
+31 (0)38-4291100 / +31 (0)38-4291149
Emergency information
No additional information available.
02. Composition/information on ingredients
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances Directive 67/548//EEC.
Hazardous components
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY ; EC-No. : 265-150-3 ; CAS-No. : 64742-48-9
Percentage : 40 - 45 %
Classification : R 10 Xn ; R 65 R 66
NAPHTHA (PETROLEUM), HYDRODESULFURIZED HEAVY ; EC-No. : 265-185-4 ; CAS-No. : 64742-82-1
Percentage : 2,5 - 5 %
Classification : N ; R 51/53 Xn ; R 65 R 67 R 66
2-BUTANONE OXIME ; EC-No. : 202-496-6 ; CAS-No. : 96-29-7
Percentage : < 0,5 %
Classification : Carc. Cat.3 ; R 40 R 43 Xi ; R 41 Xn ; R 21
1,2,4-TRIMETHYLBENZENE ; EC-No. : 202-436-9 ; CAS-No. : 95-63-6
Percentage : < 0,5 %
Classification : R 10 N ; R 51/53 Xn ; R 20 Xi ; R 36/37/38
For the wording of the listed risk phrases refer to section 16.
03. Hazards identification
Hazard designation according to 91/155/ECC.
Flammable ?Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. ?Repeated
exposure may cause skin dryness or cracking.
Classification : R 10 ?R 52/53 ?R 66
04. First-aid measures
General
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious
person.
After inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, administer artificial respiration. Give
nothing by mouth. If unconsciousness, place in recovery position and seek medical attention.
After skin contact
Remove contaminated clothing. Wash skin thoroughly with soap and water or use recognised skin cleaner. Do NOT use solvents
or thinners.
After eye contact
Remove contact lenses, irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek
medical attention.
After ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
05. Fire-fighting measures
Suitable extinguishing media
Alcohol resistant foam, CO2, powders, water spray.
Unsuitable extinguishing media
Page : 1 / 5
Material Safety Data Sheet
according to 91/155/EEC
Product name : Eurothane Varnish Satin
Revision : 23.06.2006 Version : 3.0.0
Print date : 25.07.2006
Waterjet.
Special risk posed by the substance or by the actual product, its combustion products or gases discharged
Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Special protective equipment
Appropriate breathing apparatus may be required. For fighting fires in buildings and confined spaces, firefighters must use self-
contained breathing apparatus and should wear full fire-fighting turn-out gear.
Additional information
Cool closed containers exposed to fire with water. Do not allow run-off from the fire fighting to enter drains of waterways.
06. Accidental release measures
Personal precautions
Eliminate sources of ignition and ventilate the area. Avoid breathing vapors. Refer to protective measures listed in sections 7
and 8.
Environmental precautions
Do not empty into drains. If the product is accidentally released into lakes, rivers or sewages, inform appropriate authorities in
accordance with local regulations.
Methods for cleaning up/collecting
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and
place in container for disposal according to local regulations (see section 13). Clean preferably with a detergent; avoid use of
solvents.
07. Handling and storage
Information for safe handling
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of
flammable or explosive concentrations of vapor in air and avoid vapor concentrations higher than the OEL (Occupational
Exposure Limit). Additionally, the product should only be used in areas from which all naked lights and other sources of ignition
have been eliminated. Electrical equipment should be protected to the appropriate standard. Floors should be of the conducting
type. Product may charge electrostatically: always ground containers when transferring from one container to another.
Operators should wear antistatic footwear and clothing. No sparking tools should be used. Keep the container tightly closed.
Isolate from sources of heat, sparks and open flame. No sparking tools should be used. Avoid contact with skin and eyes. Avoid
the inhalation of dust, particulates and spray mist arising from the application of this product. Avoid inhalation of dust from
sanding.
Smoking, eating and drinking should be prohibited in application area.
For personal protection see Section 8.
Never use pressure to empty: container is not a pressure vessel.
Always keep in containers of same material as the original one.
Comply with the health and safety at work laws.
Further information about storage conditions
Storage in accordance with CPR 15-1 or CPR 15-2. Observe label precautions. Store between 0 and 35 degrees C. (32 and 95
degrees F.) in a dry, well ventilated place away from sources of heat and direct sunlight.
Keep away from oxidizing agents, strongly alkaline and strongly acidic materials. No smoking. Prevent unauthorized access.
Containers which are opened must be carefully resealed and kept upright to prevent leakage. Do not allow to enter drains.
08. Exposure controls and personal protection
Additional information about engineering measures
Provide adequate ventilation. Where reasonably practical this should be achieved by the use of local exhaust ventilation and
good general extraction. If these are not sufficient to maintain concentrations below the OEL (Occupational Exposure Limit),
suitable respiratory protection must be worn.
Components with critical values that require monitoring at the workplace (exposure limits)
1,2,4-TRIMETHYLBENZENE ; CAS-No. : 95-63-6
Specification : NIOSH REL TWA ( USA )
Value : 25 ppm
Version date : 01.01.2003
Personal protective equipment
Respiratory protection
If workers are exposed to concentrations above the exposure limit, they must use a NIOSH-approved respirator.
Hand protection
Solvent-resistant gloves may be appropriate gloves.
Eye protection
Safety glasses or goggles may be appropriate.
Body protection
Page : 2 / 5
Material Safety Data Sheet
according to 91/155/EEC
Product name : Eurothane Varnish Satin
Revision : 23.06.2006 Version : 3.0.0
Print date : 25.07.2006
Personnel should wear anti-static clothing made of natural fiber or of high temperature resistant synthetic fiber.
09. Physical and chemical properties
Relevant safety data
Physical state : liquid
homogeneous viscous
Appearance :
liquid
Boiling point / range : ( 1013 hPa ) 140 - 200 癈
Boiling point hPa (Fahrenheit) : ( 1013 hPa ) 284 - 392 癋
Flashpoint : ca. 38 癈 Closed cup
Flashpoint [Fahrenheit] : ca. 100,4 癋 Closed cup
Ignition temperature : 210 - 260 癈
Ignition temperature
410 - 500 癋
[Fahrenheit]
Lower explosion limit : 0,6 % b.v.
Upper explosion limit : 8 % b.v.
Vapor pressure : ( 50 癈 / 122 癋 ) < 3 hPa
g/cm3
Specific gravity : ( 20 癈 / 68 癋 ) 0,9 - 0,94
Solvent-separation test : ( 20 癈 / 68 癋 ) < 3 %
Solubility in water : ( 20 癈 / 68 癋 ) < 0,1 % b.w.
Flow time : ( 20 癈 / 68 癋 ) > 90 s DIN-cup 4 mm
Viscosity KU : ( 20 癈 / 68 癋 ) 85 - 90 KU
10. Stability and reactivity
Conditions to avoid
Stable under recommended storage and handling conditions (See section 7).
Materials to avoid
Keep away from oxidizing agents, strongly alkaline and strongly acidic materials to avoid exothermic reactions.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide,
smoke, oxides of nitrogen.
11. Toxicological information
There are no data available on the product itself. The product has been assessed following the conventional method of the
Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See sections 2 and 15 for
details.
Health effects from exposure:
Inhalation: May irritate mucous membranes, produce a narcotic effect, impair reaction time or coordination.
Eye Contact: May cause irritation.
Skin contact: May cause irritation and be absorbed through skin.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the product
may cause defatting of the skin, resulting in non-allergic contact dermatitis and absorption through the skin.
Liquid splashed in the eyes may cause irritation and reversible damage.
12. Ecological information
There are no data available on the product itself.
The product should not be allowed to enter drains or waterways.
13. Disposal considerations
Do not empty into waters or drains.
14. Transport information
Land transport ADR/RID
Classification
Class : 3 Kemlercode : 30
Substance number : 1263 Classification-Code : F1
ADR : - (<= 450 l) ?Special provisions : 640E ?LQ 7 See Section 16.
Proper shipping name
PAINT
Packaging
Packaging group : III
Label : 3
Page : 3 / 5
Material Safety Data Sheet
according to 91/155/EEC
Product name : Eurothane Varnish Satin
Revision : 23.06.2006 Version : 3.0.0
Print date : 25.07.2006
Maritime transport IMDG/GGVSea
Classification
IMDG-Code : 3 EmS number : F-E / S-E
UN number : 1263 Marine Poll. : -
IMDG 2.3.2.5 (<= 30 l) ?LQ 5 l
Proper shipping name
PAINT
Packaging
Packaging group : III
Label : 3
Air transport ICAO-TI and IATA-DGR
Classification
Class : 3
UN number : 1263
Proper shipping name
PAINT
Packaging
Packaging group : III
Label : 3
15. Regulatory information
Classification according to EEC directives
R-phrases
10 Flammable
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
66 Repeated exposure may cause skin dryness or cracking.
S-phrases
57 Use appropriate container to avoid environmental contamination.
61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
35 This material and its container must be disposed of in a safe way
51 Use only in well-ventilated areas.
24 Avoid contact with skin
Special designation for certain products
99 Contains 2-BUTANONE OXIME ;Cobalt-fatty acids, C6-19 ;. May produce an allergic reaction.
International regulatory information
U.S. Federal Regulations
Toxic Substances Control Act (TSCA) status: All ingredients are on the TSCA Inventory or excluded from TSCA.
Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (HCS) Class II Combustible liquid. This
product is considered a hazardous substance as defined by the OSHA HCS.
Listed Carcinogens:
OSHA - none IARC - none NTP - none.
State Regulations:
Contains ingredients listed under state right-to-know laws: New Jersey Worker and Community Right to Know Act,
Massachusetts Hazardous Substances Disclosure by Employers Act, Pennsylvania Worker and Community Right-to-Know Act,
Michigan Natural Resources and Environmental Protection Act, Illinois Toxic Substances Disclosure to Employees Act, Minnesota
Employee Right-to-Know Act.
16. Other information
Further information
The details in this material safety data sheet satisfy the U.S. Occupational Safety and Health Administration Hazard
Communication Standard and legislation in the Netherlands and the European Union. The product is not to be used for other
purposes than those specified under section 1 without first obtaining written handling instructions. It is always the responsibility
of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information
in this SDS is meant as a description of the safety requirements of our product: it is not to be considered as a quarantee of the
products' properties.
Relevant changes
Page : 4 / 5
Material Safety Data Sheet
according to 91/155/EEC
Product name : Eurothane Varnish Satin
Revision : 23.06.2006 Version : 3.0.0
Print date : 25.07.2006
02. Hazardous components ?08. Components with critical values that require monitoring at the workplace (exposure limits) ?br>
14. Land transport ADR/RID and GGVS/GGVE (2003) ?14. Proper shipping name (ADR) ?14. Maritime transport IMDG/GGVSea
?14. Technical name (IMDG) ?14. Technical name (ICAO) ?15. S-phrases ?15. OSHA HCS Class II Combustible liquid.
R-Phrases of components
10 Flammable.
20 Harmful by inhalation.
21 Harmful in contact with skin.
36/37/38 Irritating to eyes, respiratory system and skin.
40 Limited evidence of a carcinogenic effect.
41 Risk of serious damage to eyes.
43 May cause sensitisation by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapors may cause drowsiness and dizziness
Department issuing data sheet
Chemtrec emergency hazardous information (Chemtrec@americanchemistry.com):
Domestic / North America: 800-424-9300
International: 703-527-3887 (call collect)
US Transport
This product has a flash point temperature of between 100 and 141 癋 (38 to 60 癈) which qualifies as a Class 3, flammable liquid.
However, according to 49 CFR 173.150(b) and (c), when shipped in inner packaging with a net capacity of no more than 5 liters (1.3
gallons) and packaged in strong outer packaging (e.g., fiber board box) this product may qualify as a "Limited Quantity" and as a
"Consumer Commodity," and be exempt on that basis from certain U.S. Department of Transportation (DOT) requirements.
Alternatively, according to 49 CFR 173.150(f)(1) and (2), this product may be reclassified as a "Combustible Liquid" and exempted
from all DOT hazardous materials regulations (including marking, labeling, and packaging requirements) when shipped in non-bulk
packaging (maximum capacity of 119 gallons or less). This particular reclassification is not available for product transported via vessel
or aircraft or products which are defined by DOT in 49 CFR 171.8 as "marine pollutants," "hazardous substances," or "hazardous
waste."
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and
shall not establish a legally valid contractual relationship.
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