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Polybrominated Flame Retardants








Gazette
Commonwealth
of Australia
No. C 10, Tuesday, 5 October 2004
CHEMICAL
Published by the Commonwealth of Australia




ISSN 1035-9877

The Industrial Chemicals (Notification and Assessment) Act 1989 (the Act) commenced on
17 July 1990. As required by Section 5 of the Act, a Chemical Gazette is published on the
first Tuesday in any month or on any days prescribed by the regulations.

CONTENTS

SPECIAL NOTICES

1 ADDENDUM-SPECIAL GAZETTE PUBLISHED 16 AUGUST 2004- 5
LRCC

2 INFORMATION TO IMPORTERS OF INDUSTRIAL CHEMICALS 6

3 CHANGES TO THE NICNAS HANDBOOK FOR NOTIFIERS 8

4 POLYBROMINATED FLAME RETARDANTS - CALL FOR 9
INFORMATION

NEW CHEMICALS

SUMMARY REPORTS

15
5 STD/1067 POLY(OXY-1-2-ETHANEDIYL), ALPHA,
ALPHA',-[1,4-DIMETHYL-1,4-BIS (3-
METHYLBUTYL)-2-BUTYNE-1,4-
DIYL]BIS[OMEGA-HYDROXY-

6 STD/1099 PROMIDIUM IS 18

7 STD/1112 W-663 20

8 LTD/1129 SODIUM PEG-7 OLIVE OIL CARBOXYLATE 22

9 LTD/1135 POLYMER IN PLIOGRIP 24

10 LTD/1152 POLYMER IN DISPERBYK-2001 27

11 LTD/1154 B-21825 29

12 LTD/1156 DOW CORNING 7-6030 QUATERNARY 31
AMMONIUM FUNCTIONAL SILICONE

13 EX/58 POLYMER IN DOW CORNING 9040 SILICONE 34
ELASTOMER BLEND

14 PLC/324 POLYESTER ALKYD-25 37

15 PLC/423 RESIN COMPONENTS OF LEXAN SLX 39
GRADES

16 PLC/448 POLYMER IN NALCO 98 AUS047 41

17 PLC/473 ARISTOFLEX AVC 43

18 PLC/474 POLYMER IN POLYURETHANE DISPERSION 45
145049

19 PLC/490 POLYMER IN OPTIFLO M2600/M2600VF 47

20 PLC/493 TOPAS 50

21 PLC/495 S-9974 52

22 ACCESS TO FULL PUBLIC REPORT 54

PERMITS ISSUED

23 LOW VOLUME CHEMICAL PERMITS 55

24 COMMERCIAL EVALUATION CATEGORY PERMITS 56

25 EARLY INTRODUCTION PERMITS 57

AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES

58
26 NOTICE OF CHEMICALS ELIGIBLE FOR LISTING ON THE
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES FIVE
YEARS AFTER ISSUING OF ASSESSMENT CERTIFICATES

27 NOTICE OF AMENDMENTS TO THE AUSTRALIAN INVENTORY 60
OF CHEMICAL SUBSTANCES

61
28 NOTICE OF CHEMICALS ELIGIBLE FOR IMMEDIATE LISTING
ON THE AUSTRALIAN INVENTORY OF CHEMICAL
SUBSTANCES AFTER ISSUING OF ASSESSMENT
CERTIFICATES

5

1 ADDENDUM-SPECIAL GAZETTE PUBLISHED 16 AUGUST
2004-LRCC
There was an error on page 7 of the above Gazette. Correct text is included below:

Non-cosmetic chemical (amended)
The volume restriction for the exemption of non-cosmetic chemicals which pose no
unreasonable risk to occupational health, public health or environment, has increased
from 10 to 100kg/annum [subpara. 21(4)(b)(ii)]. Advice to NICNAS prior to
introduction is optional and introducers of chemicals in this category wishing to
advise NICNAS should fill out Form 21-4a and return it to NICNAS.

There is a new requirement for the introducer to keep records relating to occupational
health and safety, public health matters and the environmental effects of the chemical
for five years. Annual reporting requirements for this exemption category commence
for the registration year 1 September 2004, with the first report required by 28
September 2005. [s.21AA of the Act].

Cosmetic chemical <10kg (amended)
Introducers of cosmetic chemicals which pose no unreasonable risk to occupational
health, public health or environment, in quantities of less than 10kg/annum, are no
longer required to notify NICNAS prior to introduction.

The criteria for the cosmetic chemical and the five-year record keeping requirement
remain unchanged. Annual reporting requirements for this exemption category
commence for the registration year 1 September 2004, with the first report required by
28 September 2005. [s.21AA of the Act].

Cosmetic chemical >10kg but <100kg (amended)
The volume restriction for the exemption of cosmetic chemicals which pose no
unreasonable risk to occupational health, public health or environment, has increased
from 10 to 100kg/annum [subpara. 21(4)(b)(i)]. Introducers of the chemical must
notify NICNAS of the introduction in writing (Form 15) and provide the Material
Safety Data Sheet (MSDS) relevant to the chemical or product containing the
chemical and a copy of the label attached to the packaging of the chemical or product
containing the chemical.

The criteria for the cosmetic chemical and the five-year record keeping requirement
remain unchanged. Annual reporting requirements for this exemption category
commence for the registration year 1 September 2004, with the first report required by
28 September 2005. [s.21AA of the Act].




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

6

2 INFORMATION TO IMPORTERS OF INDUSTRIAL CHEMICALS
NICNAS has received a number of enquiries from importers and Customs Brokers
about relevant tariff classifications to goods containing industrial chemicals. The
Table below shows a typical list of tariff classifications that may fall within the scope
of the NICNAS Registration requirements. Importers should note that they should not
limit themselves to these import classifications as some industrial chemicals are
imported under chapters not listed below:

For more information on these chapters see the Australian Customs Service website at
http://www.customs.gov.au/site/page.cfm?u=4273.



Chapter Reference Number Description

Animal or vegetable fats and oils and their cleavage
1505, 1518 to 1522
15
products; prepared edible fats; animal or vegetable waxes
inclusive

Salt; sulphur; earths and stone; plastering materials; lime
All
25
and cement

All Ores, slag and ash
26

Mineral fuels, mineral oils and products of their
All except 2701,
27
distillation; bituminous substances; mineral waxes
2702, 2703, 2709

Inorganic chemicals; organic or inorganic compounds of
All except 2844,
28
precious metals, of rare-earth metals, of radioactive
2845
elements or of isotopes

All except 2935,
29
Organic chemicals
2936, 2937, 2940,
2941

Tanning or dyeing extracts; tannins and their derivatives;
All
32
dyes, pigments and other colouring matter; paints and
varnishes; putty and other mastics; inks

Essential oils and resinoids; perfumery, cosmetic or toilet
All
33
preparations

Soap, organic surface-active agents, washing
All except 3406
34
preparations, lubricating preparations, artificial waxes,
prepared waxes, polishing or scouring preparations,
candles and similar articles, modelling pastes, "dental
waxes" and dental preparations with a basis of plaster

Albuminoidal substances; modified starches; glues;
All
35
enzymes


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

7


Explosives; pyrotechnic products; matches; pyrophoric
All except 3603
36
alloys; certain combustible preparations

Photographic or cinematographic goods
3707 only
37
3707- Chemical preparations for photographic uses
(other than varnishes, glues, adhesives and similar
preparations), unmixed products for photographic uses,
put in measured portions or put up for retail sale in a
form ready for use

All Miscellaneous chemical products
38

3901 to 3914
39
Plastics and articles thereof
inclusive

4001 and 4002 only Rubber and articles thereof
40

Pulp of wood or of other fibrous cellulosic material;
47
All except 4707
recovered (waste and scrap) paper or paperboard

Miscellaneous manufactured articles
9608, 9612, 9613
96
only




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

8

3 CHANGES TO THE NICNAS HANDBOOK FOR NOTIFIERS
The Handbook for Notifiers has been updated on the NICNAS website to reflect the
new arrangements following the introduction of the Industrial Chemicals (Notification
and Assessment) Amendment (Low Regulatory Concern Chemicals ) Act 2004
(LRCC Amendment Act).

The Handbook is a guide to importers, manufacturers and exporters of industrial
chemicals in Australia. It outlines their obligations under the Industrial Chemicals
(Notification and Assessment) Act 1989, as well as the assessment and notification
procedures and other information relevant to industrial chemicals regulation.

For further enquiries about the Handbook for Notifiers contact Hana Hamdan (Team
Leader, Innovation and Compliance) on 02 8577 8855 or email to
comply@nicnas.gov.au.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

9



4 POLYBROMINATED FLAME RETARDANTS - CALL FOR
INFORMATION
The Director of the National Industrial Chemicals Notification and Assessment
Scheme (NICNAS) is seeking information under section 48 of the Industrial
Chemicals (Notification and Assessment) Act 1989 (the Act) on polybrominated flame
retardants (PBFRs).

The information sought on these chemicals is:

? Quantities imported and/or manufactured;
? Products imported containing the chemical and quantities of chemical in the
products;
? Uses of the chemical or the products containing the chemical; and
? Alternatives or substitutes currently being used

The notice is directed to all persons who have manufactured or imported one or more
of the PBFRs or products containing PBFRs in the last 12 months. Any other persons
with information on these chemicals including users, past importers or manufacturers
are also encouraged to provide information on the uses of and alternatives available
for these chemicals to the Director.

The data provided will be used to update the information currently held by NICNAS
and determine further regulatory activity.

While the table below may not cover all the PBFRs in use in Australia it can be
used as a guide.

Polybrominated Flame Retardants CAS No

1,2-bis(2,4,6-tribromophenoxy)ethane 37853-59-1

1,4-Bis(pentabromophenoxy)tetrabromobenzene 58965-66-5

59447-57-3
2-propenoic acid (pentabromophenyl)methyl ester,
homopolymer

3,4,5,6-Tetrabromophthalic anhydride, ethylene 77098-07-8 /
glycol, propylene oxide reaction products 20566-35-2

Bis(2,3-dibromopropyl) phosphate 5412-25-9

Decabromodiphenyl ether 1163-19-5

Disodium tetrabromophthalate 25357-79-3

Hexabromocyclododecane 25637-99-4

Hexabromodiphenyl ether 36483-60-0


Chemical Gazette Commonwealth of Australia Gazette
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Nonabromodiphenyl ether 63936-56-1

Octabromodiphenyl ether 32536-52-0

Pentabromodiphenyl ether 32534-81-9

71342-77-3
Phosgene-tetrabromobisphenol A polymer bis(2,4,6-
tribromophenyl) ester

125997-20-8
Phosphoric acid, mixed 3-bromo-2,2-dimethyl propyl
and 2-chloroethyl esters

Polymer of tetrabromobisphenol A, phosgene, phenol 94334-64-2

Polystyrene, brominated 88497-56-7

Tetrabromobisphenol A 79-94-7

Tetrabromobisphenol A bis(2,3-dibromopropyl) ether 21850-44-2

68928-70-1
Tetrabromobisphenol A, 2,2-bis[4-(2,3-
epoxypropyloxy)dibromophenyl]propane polymer

Tetrabromodiphenyl ether 40088-47-9

Tribromodiphenyl ether 49690-94-0

Tris(tribromoneopentyl) phosphate 19186-97-1


Responses on the chemicals are required on the attached form. A separate form should
be completed for each chemical. The due date for responses is 17 November 2004.

The penalty for non-compliance with this notice is up to $33,000. In accordance with
Section 50 of the Act, the information may be accompanied by an application that
some or all of the information provided should be treated as `exempt information'.
Application forms may be obtained from Ms Virginia Parish on 02 8577 8893 or via
the NICNAS website at http://www.nicnas.gov.au/forms/files/form3.doc.

Polybrominated Flame Retardants (PBFRs) have attracted much interest
internationally and nationally given the human health and environmental concerns of
some chemicals within this group. NICNAS conducted a preliminary assessment on
polybrominated flame retardants as a group and published a report (Priority Existing
Chemical Assessment Report No. 20) in 2001. The report can be accessed at
http://www.nicnas.gov.au/publications/CAR/PEC/PEC20/PEC20index.asp. Recent
information on some of these chemicals has lead to regulatory activities overseas and
considerable interest nationally.

Polybrominated flame retardants have widespread use in numerous household and
industrial items such as printed circuit boards, polystyrene and other plastics. This


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

11


large number of dispersive uses provides many ways for PBFRs to enter the
environment. Some polybrominated flame retardants are persistent, lipophilic and
bioaccumulative, therefore, adversely impact the environment. Some PBFRs cause
carcinogenicity, endocrine disruption and reproductive effects. Hence, current
Australian use information is required to put the hazard data on PBFRs in perspective.

Further information can be obtained from Dr Janith Wickramaratna (Tel: 02 8577
8846; email: janith.wickramaratna@nicnas.gov.au).

Completed forms should be sent to Ms Virginia Parish
Existing Chemicals
NICNAS
GPO Box 58
Sydney NSW 2001




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

12


RESPONSE TO SECTION 48 NOTICE ?POLYBROMINATED FLAME
RETARDANTS

Please use a separate form for each chemical.


Company Name:

Address:



Contact name:

Phone Number: Fax Number:


Details of Chemical
Chemical Name:

Product or Trade Name:

Chemical Abstract Services Number (CAS No.):


1. Do you manufacture the above chemical (Please circle) Y/N

If yes, please provide an estimate of the quantity you manufacture (tonnes/year)

Tonnes/year:


2. Do you import the chemical? Y/N

If yes, please provide an estimate of the quantities of chemical you import (tonnes/year)

Tonnes/year:


3. Do you import products (mixtures) containing this chemical? Y/N

Please indicate the product(s) you import containing the chemical and the total tonnage of chemical in
each product:

Name of Product Tonnes chemical/year
(Description of Product)




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

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4. What are the uses of the chemical/products?




5. Do you manufacture or formulate products containing this chemical? Y/N

Please indicate the product(s) you manufacture or formulate containing the chemical and the total
tonnage of chemical in each product:


Name of Product Tonnes chemical/year
(Description of Product)




6. Do you use this chemical other than for manufacturing products
(eg. manufacturing articles)? Y/N

If yes, what types of articles are they used in?




7. What are the uses of the products manufactured/formulated by you?




8. Is this chemical available to members of the public? Y/N




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

14

Do you manufacture/import any chemicals that are used as an alternative/substitute for
9.
PBFRs? Y/N

If yes please provide

Name of Chemical Quantities




Information collected by NICNAS may be provided to State, Territory or Commonwealth regulatory
agencies for the purposes of monitoring compliance under relevant legislation. All information
collected is treated in accordance with strict confidentiality guidelines and in compliance with the
Privacy Act 1988.

Further information can be obtained from Dr Janith Wickramaratna (Tel: 02 8577 8846; email:
janith.wickramaratna@nicnas.gov.au).

Is your company a small business with less than 20 employees? YES NO
If yes, please provide an estimate of the time taken to complete this form:
hrs mins



Thank-you. Please send the completed form to: Ms Virginia Parish
Existing Chemicals
NICNAS
GPO Box 58
Sydney NSW 2001




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

15

5 PUBLICATION SUMMARY REPORT
Poly(oxy-1,2-ethanediyl), alpha, alpha', -[1,4-dimethyl-1,4-bis (3-
methylbutyl)-2-butyne-1,4-diyl]bis[omega-hydroxy-
Summary Report
Reference No: STD/1067
Swift and Company Ltd (ABN 44 000 005 578), of Level 1, 372 Wellington Rd,
Mulgrave, Victoria, 3170 and 3M Australia Pty Ltd (ABN 90 000 100 096), of 2-74
Dunheved Circuit, St Marys, 2760 have submitted a standard notification statement in
support of their application for an assessment certificate for Poly(oxy-1,2-ethanediyl),
, ', -[1,4-dimethyl-1,4-bis (3-methylbutyl)-2-butyne-1,4-diyl]bis[-hydroxy-. The
notified polymer is intended to be used as a non-ionic wetting agent for high
performance waterborne applications such as coatings, inks and adhesives. One to
three tonnes of the notified polymer will be imported per annum for each of the first
five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the assumption that analogue data are acceptable and indicative of toxicity
of the notified polymer, the notified polymer is classified as hazardous under the
NOHSC Approved Criteria for Classifying Hazardous Substances. The classification
and labelling details are:

R41 Risk of Serious Damage to Eyes

Occupational Health and Safety

Use as a clear coat component
There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Use as fountain solution concentrate component and other potential uses
There is Moderate Concern to occupational health and safety under the conditions of
the occupational settings described.

Public Health

Use as a clear coat component and Use as fountain solution concentrate component
There is Negligible Concern to public health based on its reported use pattern.

Other potential uses
There is No Significant Concern to public health based on its reported use pattern.

Environmental Effects

The chemical is not considered to pose a risk to the environment based on its
PEC/PNEC ratio and reported use pattern.


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

16




RECOMMENDATIONS

Regulatory Controls
Hazard Classification and Labelling

? Use the following risk phrases for products/mixtures containing the notified
polymer:
- > 10%: R41
- 5% < concentration < 10%: R36

Control Measures
Occupational Health and Safety

? Employers should implement the following safe work practices to minimise
occupational exposure during handling of the notified polymer as introduced.
- Avoid contact with eyes
- Avoid splashes and spills

? Employers should ensure that the following personal protective equipment is
used by workers to minimise occupational exposure to the notified polymer as
introduced:
- Splash-proof goggles, chemical resistant industrial clothing and
impermeable gloves;

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified polymer are classified as
hazardous to health in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances, workplace practices and control
procedures consistent with provisions of State and Territory hazardous
substances legislation must be in operation.

Environment

? The following control measures should be implemented by end users to
minimise environmental exposure during use of the notified polymer:
- Do not allow material or contaminated packaging to enter drains, sewers or
water courses.

Disposal

? The notified polymer should be disposed of in a landfill in compliance with
federal, state and local authorities. Waste product may also be incinerated in


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

17


an approved combustion system. Careful measures should be undertaken to
avoid release of the notified polymer to the sewer system and watercourses.

Emergency procedures

? Spills/release of the notified polymer should be handled by stopping the
leak/spill if possible, reducing vapour spreading with a water spray and
constructing a dike to prevent water flow. If recovery is not feasible admix
with dry soil, sand or non-reactive adsorbent and place in an appropriate
chemical waste container. Transfer to containers by suction, preparatory for
later disposal. Flush area with water spray. For large spills, recover spilled
material with a vacuum truck.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under subsection 64(1) of the Act; if
- the notified polymer is included in products at a percentage >5%
or

Under subsection 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

18

6 PUBLICATION SUMMARY REPORT
Promidium IS
Summary Report
Reference No: STD/1099
Uniqema Australia Pty Ltd (ABN 00018084) of Level 37, 101 Collins St Melbourne
VIC 3000 and Symex Holding Pty Ltd (ABN 29 091 035 353) of 14 Woodruff St Port
Melbourne VIC 3207 have submitted a standard notification statement in support of
their application for an assessment certificate for Promidium IS. The notified
chemical is intended to be used as a cleansing agent, solubiliser, consistency agent
and foam booster in personal care products and industrial cleaning agents. Personal
care products will be either imported preformulated or formulated in Australia by
batch processes. Less than 10 tonnes of the notified chemical will be imported per
annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data, the notified chemical is classified as a hazardous
substance in accordance with the NOHSC Approved Criteria for Classifying
Hazardous Substances in terms of skin and eye irritation.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is Negligible Concern to public health when used as described.

Environmental Effects

On the basis of the PEC/PNEC ratio, the notified chemical is not considered to pose a
risk to the environment based on its reported use pattern and estimated volumes.

RECOMMENDATIONS

Regulatory Controls
Hazard Classification and Labelling

? The NOHSC Chemicals Standards Sub-committee should consider the
following [health, environmental and physico-chemical] hazard classification
for the notified chemical:

? R36 Irritating to eyes
? R38 Irritating to skin


Chemical Gazette Commonwealth of Australia Gazette
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? Use the following risk phrases for products/mixtures containing the notified
chemical:
? 20%: R36 Irritating to eyes
? 20%: R38 Irritating to skin

Control Measures
Occupational Health and Safety

? Employers should ensure that the following personal protective equipment is
used by workers to minimise occupational exposure to the notified chemical as
introduced:
- Impervious gloves

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified chemical are classified as
hazardous to health in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances, workplace practices and control
procedures consistent with provisions of State and Territory hazardous
substances legislation must be in operation.

Environment

? The following control measures should be implemented by reformulator to
minimise environmental exposure during reformulation of the notified
chemical:
- Process areas should be bunded with all drains leading to a treatment plant
or collection point

Disposal

? The notified chemical should be disposed of to landfill.

Emergency procedures

? Spills/release of the notified chemical should be contained, collected and
placed in sealable labelled container. The material should be reused if not
contaminated. If contaminated then it should be disposed of to landfill.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.


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No. C 10, 5 October 2004

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The Director will then decide whether secondary notification is required.

No additional secondary notification conditions are stipulated.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

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7 PUBLICATION SUMMARY REPORT
W-663
Summary Report
Reference No: STD/1112
Brother International (Aust.) Pty Ltd (ACN 17 001 393 835) of 7 Khartoum Road
North Ryde NSW 2113 has submitted a standard notification statement in support of
their application for an assessment certificate for W-663. The notified chemical is
intended to be used as an additive in toner used for printing. The toner containing the
notified chemical will be imported in toner cartridges for electrophotocopying
machines or electrophotographic printers. Cartridges are replaced by removal of
sealing tape and insertion into the machine or printer. Less than three tonnes of the
notified chemical will be imported per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data, the notified chemical is not classified as a hazardous
substance in accordance with the NOHSC Approved Criteria for Classifying
Hazardous Substances.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is Negligible Concern to public health when used as described.

Environmental Effects

The chemical is not considered to pose a risk to the environment based on its reported
use pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety

No special precautions are required for the notified chemical when used at low
quantities in a toner in cartridges in electrophotocopying machines or
electrophotographic printers. However, in the interests of good occupational health
and safety, the following guidelines and precautions should be observed for use of
toners containing the notified chemical:

? Avoid contact with skin and eyes.
? Avoid breathing dust


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No. C 10, 5 October 2004

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? Avoid generation of dust. Photocopiers and printers should be located in well
ventilated areas. The NOHSC Exposure Standard of 10 mg/m3 TWA for
nuisance dust should be maintained in the workplace.

? Service personnel should wear cotton or disposable gloves when replenishing
toner and servicing copying machines and printers.

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

Environment

Disposal

? Empty toner cartridges containing the notified chemical should be disposed of
to landfill.

? Do not dispose the notified chemical into sewers or water bodies.

Emergency procedures

? Spills/release of the notified chemical should be handled by sweeping up and
discarding in to a waste container.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.

No additional secondary notification conditions are stipulated.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

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8 PUBLICATION SUMMARY REPORT
Sodium PEG-7 Olive Oil Carboxylate
Summary Report
Reference No: LTD/1129
Unilever Australia Limited (ABN 66 004 050 828) of 219 North Rocks Road North
Rocks NSW 2151 has submitted a limited notification statement in support of their
application for an assessment certificate for the chemical "sodium PEG-7 olive oil
carboxylate". The notified chemical is intended for use as an anionic surfactant at
1.2% in a facial toner product. About 300 kg of the notified chemical will be imported
per annum for each of the first five years, initially in final consumer packages and
then as a 35% aqueous solution (Olivem 400) for local formulation.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data there is insufficient information to substantiate that the
notified chemical is not a hazardous substance. However, Olivem 400 (35% notified
chemical) is not likely to be classified as hazardous under the NOHSC Approved
Criteria for Classifying Hazardous Substances.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is No Significant Concern to public health when used in the proposed manner.

Environmental Effects

On the basis of the widespread and low use level, the chemical is not considered to
pose a risk to the environment at the proposed import volume.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety

? Employers should implement the following engineering controls to minimise
occupational exposure to the notified chemical as introduced in a 35%
solution:
- Enclosed and automated processes at the blending and packaging sites;
- Adequate ventilation for the plant operators and local exhaust ventilation
for quality control personnel.




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? Employers should implement the following safe work practices to minimise
occupational exposure during handling of the notified chemical as introduced
in the lubricant additive package:
- Adequate training for staff in handling surfactant components;
- Implementation of general health surveillance and monitoring programs as
required.

? Employers should ensure that the following personal protective equipment is
used by workers to minimise occupational exposure to the notified chemical as
introduced in the lubricant additive package:
- Industrial standard protective clothing and gloves;
- Safety glasses with side-shields/chemical goggles;
- Vapour respirators if required.

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified chemical are classified as
hazardous to health in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances, workplace practices and control
procedures consistent with provisions of State and Territory hazardous
substances legislation must be in operation.

Disposal

? The notified chemical should be disposed of by recovering the product if
possible and disposing to landfill.

Emergency procedures

? Spills/release of the notified chemical should be prevented from spreading or
entering into drains, ditches or rivers by using sand, earth or other appropriate
barriers. Small spills may be diluted with water, whilst larger spills should be
adsorbed with inert material (sand or vermiculate) and disposed of in
accordance with local, state and federal authorities.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.

No additional secondary notification conditions are stipulated.


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

25




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

26

9 PUBLICATION SUMMARY REPORT
Polymer in Pliogrip Adhesives
Summary Report
Reference No: LTD/1135
Ashland Pacific Pty Ltd (ACN 000 075 641) of Sir Thomas Mitchell Road, Chester
Hill NSW 2162 has submitted a limited notification statement in support of their
application for an assessment certificate for Polymer in Pliogrip Adhesives. The
notified polymer is intended to be used as a component of an adhesive for heavy
vehicles. The adhesive will be imported in cartridges containing two variants of the
notified polymer, isocyanate-rich and polyol-rich, which are mixed before being
extruded onto the substrate. Less than 10 tonnes of the notified polymer will be
imported per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data the notified polymer is not classified as hazardous under
the NOHSC Approved Criteria for Classifying Hazardous Substances. However, the
isocyanate-rich component of the adhesive is classified as hazardous. The
classification and labelling details are:

R20 - Harmful by inhalation,
R36/37/38 - Irritating to eyes, respiratory system and skin and
R42/43 - May cause sensitisation by inhalation and skin contact.

Occupational Health and Safety

There is Moderate Concern to occupational health and safety under the conditions of
the occupational settings described.

Public Health

There is Negligible Concern to public health when used as indicated.

Environmental Effects

The chemical is not considered to pose a risk to the environment based on its reported
use pattern.

RECOMMENDATIONS

The following recommendations relate to the isocyanate-rich notified polymer
containing approximately 50% excess isocyanate. Although the adhesive contains the
notified polymer at a low level (7%), in the absence of certain knowledge of likely
atmospheric concentrations of isocyanate in the workplace and in view of the serious
consequences of isocyanate-induced respiratory sensitisation, a conservative approach
to risk management should be taken.


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

27




Control Measures
Occupational Health and Safety

? Employers should implement the following engineering controls to
minimise occupational exposure to the notified polymer in Pliogrip
adhesives:
- Good general ventilation and local exhaust ventilation where
practicable.

? Employers should ensure that the following personal protective
equipment is used by workers to minimise occupational exposure to the
notified polymer in Pliogrip adhesives:
- Supplied air respiratory protection and protective clothing, gloves
and footwear impervious to isocyanate-containing compounds. The open
points at the interface between different forms of protective clothing
should be sealed.

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? Atmospheric or biological monitoring should be conducted by qualified
professionals to guage potential workplace atmospheric concentrations of
isocyanate during use of the notified polymer.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified chemical are classified
as hazardous to health in accordance with the NOHSC Approved Criteria
for Classifying Hazardous Substances, workplace practices and control
procedures consistent with provisions of State and Territory hazardous
substances legislation must be in operation.

? Preplacement and periodic medical surveillance programs should be
conducted for all workers potentially exposed to isocyanates. Emphasis
should be placed on pre-existing respiratory and/or allergic conditions
and lung function tests.

Environment

Disposal

? The notified chemical should be disposed of by landfill or incineration

Emergency procedures

? Absorb with an inert material and put the spilled material in an


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

28


appropriate waste disposal. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sewer system.



Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.

No additional secondary notification conditions are stipulated.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

29

10 PUBLICATION SUMMARY REPORT
Polymer in Disperbyk-2001
Summary Report
Reference No: LTD/1152
Nuplex Industries (Aust) Pty Ltd (ABN: 25 000 045 572) of 49-61 Stephen Road,
Botany NSW 2019 and PPG Industries Australia Pty Ltd (ABN: 82 055 500 939) of
McNaughton Road, Clayton, VIC 3168 have submitted a limited notification
statement in support of their application for an assessment certificate for Polymer in
Disperbyk-2001. The notified polymer is intended to be used as a wetting and
dispersing additive for solvent based coatings and pigment concentrates. It will be
used at below 6% in paint formulations, mostly for automotive use. Up to five tonnes
of the notified polymer will be imported per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data, the notified polymer is not classified as hazardous under
the NOHSC Approved Criteria for Classifying Hazardous Substances.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is Negligible Concern to public health when used as described in the
notification.

Environmental Effects

The notified polymer is not considered to pose a risk to the environment based on its
reported use pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety

? Employers should implement the following engineering controls to minimise
occupational exposure to the notified polymer:
- Enclosed spray paint application system for industrial use.

? Employers should ensure that the following personal protective equipment is
used by workers to minimise occupational exposure to the notified chemical as
introduced and as diluted for use in the products:
- Protective gloves,


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

30


- safety glasses or goggles,
- half-facepiece respirator and
- industrial clothing

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified polymer are classified as
hazardous to health in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances, workplace practices and control
procedures consistent with provisions of State and Territory hazardous
substances legislation must be in operation.

Environment

? The following control measures should be implemented by end users to
minimise environmental exposure during use of the notified polymer:
- Do not pour leftover paint or cleaning solvent down the drain.

Disposal

? Wastes generated during industrial application should be disposed of through a
licensed waste contractor.
? Keep unwanted paint in sealed containers for disposal via special chemical
waste collections. Empty paint containers should be left open in a well-
ventilated area to dry out. When dry, recycle steel containers via steel can
recycling programs.

Emergency procedures

? Spills/release of the notified chemical should be soaked up with inert
absorbent material and disposed of in accordance with State regulations. Do
not allow spills to enter drains.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

If the use pattern changes leading to a significant increase in the potential for aquatic
exposure, then ecotoxicity data for fish, daphnia and algae should to be submitted for
assessment.

The Director will then decide whether secondary notification is required.


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

31

11 PUBLICATION SUMMARY REPORT
B-21825
Summary Report
Reference No: LTD/1154
Kodak Australasia Pty Ltd (ABN 49 004 057 621) of 173 Elizabeth Street, Coburg,
VIC 3058 has submitted a limited notification statement in support of their application
for an assessment certificate for B-21825. The notified chemical is intended to be
used as a component of photographic paper. The chemical will be imported and used
in the manufacture of photographic paper at the notifier's plant. Less than one tonne
of the notified chemical will be imported per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data the notified chemical is not classified as hazardous under
the NOHSC Approved Criteria for Classifying Hazardous Substances.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is Negligible Concern to public health when used in the proposed manner.

Environmental Effects

The chemical is not considered to pose a risk to the environment based on its reported
use pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety

? Employers should implement the following engineering controls to minimise
occupational exposure to the notified chemical:
- For formulation, local exhaust ventilation should be used when handling
the notified chemical in powder form.

? Employers should implement the following safe work practices to minimise
occupational exposure during handling of the notified chemical as introduced
and in the emulsion formulation and application processes:
- In handling the notified chemical, avoid spills and dust generation.
- In handling the notified chemical, minimise the potential for ingestion
through good personal hygiene.

Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

32


- In handling the emulsion formulation, avoid spills, splashes or aerosol
generation that would increase exposure.

? Employers should ensure that the following personal protective equipment is
used by workers to minimise occupational exposure to the notified chemical as
introduced and in the emulsion formulation and application processes:
- Respiratory protection if exposure to dust is likely.
- Gloves
- Protective clothing
- Safety eye protection

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified chemical are classified as
hazardous to health in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances, workplace practices and control
procedures consistent with provisions of State and Territory hazardous
substances legislation must be in operation.

Disposal

? Dispose of wastes containing the notified chemical according to local
jurisdiction waste disposal regulations. Residual chemical retained in emptied
containers and in dust collection filters should be treated as prescribed waste
and disposed of to secure landfill. Follow label warnings even after container
is emptied.

Emergency procedures

? Spills/release of the notified chemical should be collected by shovelling into
suitable containers for disposal. Avoid dust formation. Clean surface
thoroughly to remove residual contamination.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under Subsection 64(1) of the Act; if
- the importation volume exceeds one tonne per annum notified chemical.
or

Under Subsection 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

33

12 PUBLICATION SUMMARY REPORT
Dow Corning 7-6030 Quaternary Ammonium Functional Silicone
Summary Report
Reference No: LTD/1156
Dow Corning Australia Pty Ltd (ABN 36 008 444 166) of 3 Innovation Road
Macquarie University Research Park North Ryde NSW 2113 has submitted a limited
notification statement in support of their application for an assessment certificate for
Dow Corning 7-6030 Quaternary Ammonium Functional Silicone. The notified
polymer is intended to be used as a component of hair care products. The notified
polymer will be imported as a polymer concentrate at >90% and will be stored at the
notifier's warehouse prior to distribution to local hair care product formulators.
Alternatively, the notified polymer will be imported as formulated hair care products
containing <1% notified polymer. Up to 10 tonnes of the notified polymer will be
imported per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data, the notified polymer is classified as a hazardous
substance in accordance with the NOHSC Approved Criteria for Classifying
Hazardous Substances. The classification and labelling details are:
R36/38 ?Irritating to eyes and skin; and
R43 ?May cause sensitisation by skin contact.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is No Significant Concern to public health when used as a component of hair
care products.

Environmental Effects

On the basis of the PEC/PNEC ratio, the polymer is not considered to pose a risk to
the environment based on its reported use pattern.

RECOMMENDATIONS

Regulatory Controls
Hazard Classification and Labelling

? The NOHSC Chemicals Standards Sub-committee should consider the
following health hazard classification for the notified polymer:
- R36/38 ?Irritating to eyes and skin; and


Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

34


- R43 ?May cause sensitisation by skin contact.
? Use the following risk phrases for products/mixtures containing the notified
polymer:
- 20%: R36/38 - Irritating to eyes and skin.
- 1%: R43 - May cause sensitisation by skin contact.

Control Measures
Occupational Health and Safety
? Employers should implement the following engineering controls to minimise
occupational exposure to the notified polymer as introduced:
- Local exhaust ventilation during transfer and mixing operations

? Employers should implement the following safe work practices to minimise
occupational exposure during handling of the notified polymer as introduced:
- During transfer operations and cleaning equipment, avoid spills and
splashing.

? Employers should ensure that the following personal protective equipment is
used by workers to minimise occupational exposure to the notified polymer as
introduced:
- Chemical resistant gloves, safety glasses, protective clothing or equivalent
when handling the notified polymer

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified polymer are classified as
hazardous to health in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances, workplace practices and control
procedures consistent with provisions of State and Territory hazardous
substances legislation must be in operation.

Disposal

? Dispose of wastes containing the notified polymer in accordance with local
jurisdiction waste management regulations.

? Do not dispose of the notified polymer to drains or natural waterways.

? Spilled notified polymer (including saturated absorbent or cleaning material)
may be hazardous as spontaneous heating may occur. Such wastes should be
disposed of to landfill or incinerated.

? Emptied finished product containers with residues of the notified chemical
should be cleaned and recycled or sent to landfill for disposal.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

35


? Small quantities of waste/spilled formulation containing the notified chemical
should be disposed of to landfill or sewer.

Emergency procedures

? Spills/release of the notified polymer should be prevented from spreading or
entering into drains, ditches or rivers by using sand, earth or other appropriate
barriers. Inform local authorities if this cannot be prevented.

? Clean up spilled quantities of notified polymer by pumping into labelled,
sealable containers. Clean up remaining materials from spill with suitable
absorbent. Final clean using steam, solvents or detergents and collect
washwaters for treatment and appropriate disposal

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.

No additional secondary notification conditions are stipulated.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

36

13 PUBLICATION SUMMARY REPORT
Polymer in Dow Corning 9040 Silicone Elastomer Blend
Summary Report
Reference No: EX/58
An Assessment Certificate for the notified polymer known by the name Polymer in
DOW CORNING 9040 Silicone Elastomer Blend was granted to Dow Corning
Australia Pty Ltd (ABN 91 008 396 245) of Macquarie University Research Park; 3
Innovation Rd, North Ryde NSW 2113.

The Assessment Report for Polymer in DOW CORNING 9040 Silicone Elastomer
Blend is identified by the sequence number PLC/189 (Synthetic Polymer of Low
Concern Notification).

Since granting of the abovementioned Assessment Certificate, Unilever Australia Ltd
(ABN 66 004 050 828) of 219 North Rocks Road North Rocks NSW 2151 has
submitted a notification statement in support of their application for an extension of
the original Assessment Certificate for Polymer in DOW CORNING 9040 Silicone
Elastomer Blend. Dow Corning Australia Pty Ltd. has agreed to this extension.

Information submitted by Unilever Australia Pty Ltd pertains to the introduction of
the notified polymer for use in as a viscosity increasing and suspending agent in
moisturizing lotions. Introduction volumes will be up to 400 kg per year, imported as
the finished product. The concentration of the chemical in final products is 7.8%.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

The notified polymer is of very low acute oral toxicity and low dermal toxicity. It is
not a skin irritant or a skin sensitiser, and a very slight ocular irritant. No evidence of
mutagenicity was observed in a bacterial assay. The notified polymer is not classified
as a hazardous substance in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances

Occupational Health and Safety

There is little potential for significant occupational exposure to the notified polymer
in the transport and storage of the polymer solution or the personal care products
containing this polymer, or during retail sale of the products. There will be exposure
during production of the personal care products.

During the reformulation and packaging processes, the main exposure route for the
notified polymer will be dermal. The polymer solution and final products will be
viscous, and ready formation of aerosols is not expected. The polymer is not expected
to be hazardous by dermal exposure as the high molecular weight will preclude
absorption through the skin. The engineering controls and personal protective
equipment specified in the notification (local exhaust ventilation and protective



Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

37


eyewear) will provide protection against the notified polymer. No significant OHS
risks are expected due to the low toxicity of the notified polymer.
Public Health

An analogous chemical to the notified polymer showed some evidence of effects on
reproduction in rats, following subcutaneous administration (Kennedy, 1976). The use of the
notified polymer at 0.1%-1.7% in personal care products means that a small amount will be
applied to the skin for each use. Likely skin application sites, such as underarms, possess
large numbers of sweat glands, and consequently there is potential for increased dermal
absorption at these sites. This is not of concern in this case, as the notified polymer is of high
molecular weight (NAMW > 15500) and is unlikely to penetrate biological membranes,
suggesting limited systemic absorption following normal use.

The low concentration and limited systemic absorption would eliminate any potential toxic
hazard from normal use of the polymer in personal care products. There will be minimal
public exposure during transport, storage and formulation into personal care products.

Based on the above information, it is considered that Polymer in DOW CORNING 9040
Silicone Elastomer Blend is unlikely to pose a significant hazard to public health when used
in the proposed manner.

Environmental Effects

Almost all of the new polymer is expected to be released to the environment as a
consequence of its use in personal care products. Most is expected to be released to the
sewer, although some may be placed directly into landfill with domestic garbage. The
polymer is not biodegradable and that portion released to the sewer (estimated as up to 37.5
tonnes per annum) will become associated with sewer sludge due to its hydrophobic nature.
Although all the polymer is expected to be released, the use pattern is such that the release
will be diffuse and at relatively low levels. For example, if all the annual import of 50
tonnes were to be released to the sewer system, assuming that each individual in Australia
produced 150 L of sewage each day, and taking the national population as 19,000,000 the
Predicted Environmental Concentration (PEC) in the sewage is estimated as 48 礸/L.
However, as indicated previously this will become associated with sludge, and this will
ultimately also be placed into landfill, although some may be incinerated. It is also expected
that around 12.5 tonnes of polymer may be directly released to the soil compartment
through disposal of partly emptied containers in domestic garbage.

Silicone polymers are stable under moist conditions, but it is expected that prolonged
residence in dry landfills would eventually degrade the polymer to landfill gases and silica,
while incineration would destroy the material, also with production of silica.

No ecotoxicity data were supplied, but silicone polymers are not known to be toxic to
aquatic organisms, and in any case the low rate of release and expected association of the
polymer with sediments would mitigate any toxic effects. The polymer is not expected to
bioaccumulate.

RECOMMENDATIONS




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

38


To minimise occupational exposure to Polymer in DOW CORNING 9040 Silicone
Elastomer Blend, the following guidelines and precautions should be observed:

Safety eyewear should be used during occupational use of the products
?br> containing the notified polymer;

Spillage of the notified chemical should be avoided. Spillages should be
?br> cleaned up promptly with absorbents which should then be put into containers
for disposal;

Good personal hygiene should be practised to minimise the potential for
?br> ingestion;

A copy of the MSDS should be easily accessible to employees.
?br>

If products containing the notified chemical are hazardous to health in
?br> accordance with the NOHSC Approved Criteria for Classifying Hazardous
Substances, workplace practices and control procedures consistent with State
and territory hazardous substances regulations must be in operation.

Guidance in selection of goggles may be obtained from Australian Standard (AS)
1336 (Standards Australia, 1994) and Australian/New Zealand Standard (AS/NZS)
1337 (Standards Australia/Standards New Zealand, 1992).

Secondary Notification

Under the Act, the Director of Chemical Notification and Assessment must be
informed if the polymer characteristics cease to satisfy the criteria under which it has
been accepted as a Synthetic Polymer of Low Concern, and secondary notification
may be required under subsection 64(1). The Director must be informed if any of the
circumstances stipulated under subsection 64(2) of the Act arise, and secondary
notification of the notified polymer may be required. No other specific conditions are
prescribed.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

39

14 PUBLICATION SUMMARY REPORT
Polyester Alkyd 25
Summary Report
Reference No: PLC/324
Nuplex Industries (Aust) Pty Ltd (ACN 15 902 254 524) of 49-61 Stephen Road
Botany NSW 2019 has submitted a synthetic polymer of low concern (PLC)
notification statement in support of their application for an assessment certificate for
Polyester Alkyd 25. The notified polymer will be blended with styrene and
performance-enhancing additives to produce a resin binder suitable for use in fibre
reinforced composite materials. 100 tonnes of the notified polymer will be imported
per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

The notified polymer meets the PLC criteria and can therefore be considered to be of
low hazard.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is Negligible Concern to public health based on the use pattern.

Environmental Effects

The polymer is not considered to pose a risk to the environment based on its reported
use pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety

? No specific engineering controls, work practices or personal protective
equipment are required for the safe use of the notified polymer itself, however,
these should be selected on the basis of all ingredients in the formulation.

Guidance in selection of personal protective equipment can be obtained from
Australian, Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004

40


? If products and mixtures containing the notified polymer are classified as
hazardous to health in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances, workplace practices and control
procedures consistent with provisions of State and Territory hazardous
substances legislation must be in operation.

? The use of the product containing the polymer should be in accordance with
the NOHSC National Guidance Material for Spray Painting where
appropriate.

Environment

? The following control measures should be implemented by the manufacturers
to minimise environmental exposure during manufacture and use of the
notified polymer:

- Do not release the resin or polymer products to sewer. Do not allow resin,
polymer products or containers to contaminate drains or waterways.

Disposal

? The notified polymer should be disposed of by release to landfill or
incineration.


Emergency procedures

? Spills/release of the notified polymer should be handled by containment, and
adsorption with material such as sand. Contaminated material (including
sand) should be collected, placed into sealable labelled container and disposed
of to landfill. Do not allow to enter drains or watercourses.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing
within 28 days by the notifier, other importer or manufacturer:

Under subsection 64(1) of the Act; if
- the notified polymer is introduced in a chemical form that does not meet
the PLC criteria.
or

Under subsection 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 10, 5 October 2004





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