3M Canada Company
1840 Oxford Street East, Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
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Material Safety Data Sheet
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Document id : 27-2162-9 Issue date : 2009/11/16
Version : 1.00 Supersedes date : ---
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Corporate Regulatory Services, 3M Canada Company
Telephone: (800) 364-3577, Fax: (800) 603-7758, Web Site: www.3M.ca
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1 Chemical Product and Company Identification
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Tradename:
SOLUPREP ANTISEPTIC SPONGES (10% POVIDONE IODINE)
Product ID:
CH-0000-1582-6
Intended Use of Product:
Sanitizer
Division:
ZD - 3M Canada Company
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2 Hazards Identification
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Critical Hazards:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Moderate Skin Irritation: Signs/symptoms can include localized
redness, swelling, itching, and dryness.
May be absorbed following inhalation and cause target organ effects.
May be absorbed following ingestion and cause target organ effects.
See Sections 7 and 11 for further information.
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3 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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WATER 7732-18-5 70 - 80
POLY(VINYLPYRROLIDINONE)IODIDE 25655-41-8 15 - 20
P-NONYLPHENOL POLYETHYLENE GLYCOL 26027-38-3 1 - 5
ETHER
ISOPROPYL ALCOHOL 67-63-0 1 - 5
DISODIUM PHOSPHATE 7558-79-4 1 - 5
NONYLPHENOXYPOLY(OXYETHYLENE)ETHANOL 9016-45-9 0.1 - 1
CITRIC ACID 77-92-9 0.1 - 1
POLYETHYLENE GLYCOL 25322-68-3 0.1 - 1
NOTE:
Each percentage is expressed as the ratio of the weight of the
ingredient to the weight of the controlled product.
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4 First Aid Measures
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Instructions for Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms persist,
get medical attention.
Instructions for Skin Contact:
Remove contaminated clothing and shoes. Wash affected area with
soap and water. If signs/symptoms develop, get medical attention.
Wash contaminated clothing and clean shoes before reuse.
Instructions for Inhalation:
If signs/symptoms develop, remove person to fresh air. If
signs/symptoms persist, get medical attention.
Instructions for Ingestion:
Do not induce vomiting unless instructed to do so by medical
personnel. Give victim two glasses of water. Never give anything
by mouth to an unconscious person. Get medical attention.
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5 Fire Fighting Measures
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Flash point: > 93.33 C CC
Lower Explosive Limit (%): Not Available
Upper Explosive Limit (%): Not Available
Autoignition temperature: Not Available
Suitable Extinguishing Media:
Ordinary combustible material. Use fire extinguishers with class A
extinguishing agents (e.g., water, foam).
Exposure Hazards during Fire:
Vapours may travel long distances along the ground or floor to an
ignition source and flash back.
SOLUPREP ANTISEPTIC SPONGES (10% POVIDONE IODINE) Page 3 of 9
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Combustion Products from Fire:
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Hydrogen Gas - During Combustion;
Unusual Fire and Explosion Hazards
None known.
Fire Fighting Procedures:
Water may not effectively extinguish fire; however, it should be
used to keep fire-exposed containers and surfaces cool and prevent
explosive rupture. Wear full protective equipment (Bunker Gear) and
a self-contained breathing apparatus (SCBA).
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6 Accidental Release Measures
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Personal Precautions:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation,
and personal protective equipment. Call 3M-HELPS line
(1-800-364-3577) for more information on handling and managing the
spill.
Environmental Procedures
No data available.
Methods for cleaning up
No data available.
Spill Response:
Evacuate unprotected and untrained personnel from hazard area. The
spill should be cleaned up by qualified personnel. Ventilate the
area with fresh air. For large spill, or spills in confined spaces,
provide mechanical ventilation to disperse or exhaust vapors, in
accordance with good industrial hygiene practice. Warning! A motor
could be an ignition source and could cause flammable gases or
vapors in the spill area to burn or explode. Contain spill. For
larger spills, cover drains and build dikes to prevent entry into
sewer systems or bodies of water. For large spills, if necessary,
get assistance from professional spill clean up team. For small
spills, carefully cover the spill with soda ash (sodium carbonate)
or sodium bicarbonate. Work from around the perimeter inward. Avoid
splashing. Add enough water to ease mixing and stir. Continue
stirring and adding water and neutralizing agent until the reaction
stops. Let cool before collecting. Or use a commercially available
'Acid spill' clean-up kit. Follow the kit directions exactly, as
specified. Working from around the edges of the spill inward, cover
with bentonite, vermiculite, or commercially available inorganic
absorbent material. Mix in sufficient absorbent until it appears
dry. Remember, adding an absorbent material does not remove a toxic,
corrosivity or flammability hazard. Collect as much of the spilled
material as possible. Clean up residue with a dilute solution
(approximately 1 to 5%) of soda ash (sodium carbonate) or baking
soda (sodium bicarbonate) in water. Collect the resulting residue
SOLUPREP ANTISEPTIC SPONGES (10% POVIDONE IODINE) Page 4 of 9
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containing solution. Place in a metal container approved for use in
transportation by appropriate authorities. The container must be
lined with polyethylene plastic or contain a plastic drum liner
made of polyethylene. Cover, but do not seal for 48 hours. Dispose
of collected material as soon as possible.
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7 Handling and Storage
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Storage Requirements:
Keep container closed when not in use.
Incompatible Materials:
Store away from heat; Sparks and/or Flames; Store out of direct
sunlight. Store away from acids; Store away from oxidizing agents.
Ventilation:
No data available.
Use Instructions:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Avoid breathing of vapours,
mists or spray. Avoid eye contact with vapours, mists, or spray.
For industrial or professional use only. Avoid contact with
oxidizing agents.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact with vapours, mists, or spray. The following
should be worn alone or in combination, as appropriate, to prevent
eye contact: Indirect vented goggles;
Skin Protection:
Avoid prolonged or repeated skin contact.
Respiratory Protection:
Avoid breathing of vapours, mists or spray.
Ingestion (Prevention):
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
Recommended Ventilation:
Use in a well-ventilated area.
Ingredient Exposure Data
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WATER (7732-18-5)
LD50 (rat, oral) > 90 ml/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
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No data available.
POLY(VINYLPYRROLIDINONE)IODIDE (25655-41-8)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
P-NONYLPHENOL POLYETHYLENE GLYCOL ETHER (26027-38-3)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
ISOPROPYL ALCOHOL (67-63-0)
LD50 (rat, oral) 5045 mg/kg
LD50 (dermal, rabbit) 12800 mg/kg
LC50 (rat, inhalation/4 hours) 17000 ppm
Exposure Limits
ACGIH: STEL 400 ppm (Table A4)
ACGIH: TWA 200 ppm (Table A4)
DISODIUM PHOSPHATE (7558-79-4)
LD50 (rat, oral) 17,000 mg/kg 12930 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
NONYLPHENOXYPOLY(OXYETHYLENE)ETHANOL (9016-45-9)
LD50 (rat, oral) 1310 mg/kg
LD50 (dermal, rabbit) 2 ml/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
CITRIC ACID (77-92-9)
LD50 (rat, oral) 3 g/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
POLYETHYLENE GLYCOL (25322-68-3)
LD50 (rat, oral) 600 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
AIHA: TWA 10 mg/m3 as aerosol;
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9 Physical and Chemical Properties
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Physical form,Color,Odour: Liquid; dark brown; iodine
odour;
Odour Threshold: No data available.
pH: 1.5 - 6.5 at 25 C
Boiling point/boiling range: Not Available
Melting point/melting range: Not Available
Vapour pressure: Not Available
Water Solubility: 100 %
Specific gravity: 1.054 - 1.064 g/ml at 25 C
Vapour density: Not Available
Volatile organic compounds: Not Available
Evaporation rate: Not Available
Viscosity: Not Available
Percent Volatile: Not Available
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10 Stability and Reactivity
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Conditions to Avoid:
Store away from heat; Sparks and/or Flames; Store out of direct
sunlight.
Materials to Avoid:
Strong acids; Strong oxidizing agents;
Hazardous Decomposition:
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Hydrogen Gas - During Combustion;
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
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11 Toxicological Information
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Effects from Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Effects from Skin Contact:
Moderate Skin Irritation: Signs/symptoms can include localized
redness, swelling, itching, and dryness.
Effects from Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
May be absorbed following inhalation and cause target organ
effects.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal
SOLUPREP ANTISEPTIC SPONGES (10% POVIDONE IODINE) Page 7 of 9
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pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Sensitization Information:
No data available.
Carcinogenicity:
No data available.
Mutagenicity:
No data available.
Reproductive Effects:
No data available.
Component Based Information:
No data available.
Product Based Information:
No data available.
Other Effects & Information:
Central Nervous System (CNS) Depression: Signs/symptoms may include
headache, dizziness, drowsiness, incoordination, nausea, slowed
reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause: Endocrine Effects:
Signs/symptoms may include disruption of gonadal, thyroid, adrenal,
or pancreatic function; changes in hormone production; alterations
in circulating hormone levels; and/or changes in tissue response to
hormones.
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12 Ecological Information
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Environmental Data:
Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
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13 Disposal Considerations
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Product as Sold:
Dispose of waste product in a permitted hazardous waste facility.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transport Information
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Transportation of Dangerous Goods
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TDG Classification: Non-Regulated Material
Special Information:: Contact 3M for more information.
These transportation classifications are provided as a customer
service. As the shipper YOU remain responsible for complying with
all applicable laws and regulations, including proper
transportation classification and packaging. 3M's transportation
classifications are based on product formulation, packaging, 3M
policies and 3M's understanding of applicable current regulations.
3M does not guarantee the accuracy of this classification
information. This information applies only to transportation
classification and not the packaging, labeling, or marking
requirements. The original 3M package is certified for Canadian
ground shipment only. If you are shipping by air or ocean, the
package may not meet applicable regulatory requirements.
International Dangerous Goods Classification
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15 Regulatory Information
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WHMIS Classification: Exempt (Registered under Food
and Drug Act).
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
AICS - Australian Inventory of Chemical Substances
DSL - Domestic Substances List (Canada)
CICS - Chinese Inventory of Chemical Substances
MITI - Ministry of International Trade and Industry (JAPAN)
KECI - Korean Existing Chemicals Inventory
PICCS - Philippines Inventory of Commercial Chemical Substances
TSCA - Toxic Substances Control Act (USA)
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16 Other Information
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Reason for Reissue:
MSDS initial issue
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or
application.
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