LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
3106 UV Curing General Purpose Adhesive
23697
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: 3106 UV Curing General Purpose Adhesive
Item No.: 23697
Product Type: UV Adhesive
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Aliphatic urethane acrylate
oligomer Proprietary 40-45
High boiling acrylate monomer Proprietary 30-35
Modified acrylamide 2680-03-7 15-20
Photoinitiator 24650-42-8 1-3
Photoinitiator Proprietary 1-3
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 112945-52-5 1-3
Substituted silane Proprietary 1-3
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Moderately toxic by ingestion.
Eye, skin, and inhalation irritant. Possible
sensitizer.
Primary Routes of Entry: Dermal, eye contact, skin absorbtion.
Signs and symptoms
of Exposure: Irritation of eyes, skin, or respiratory tract.
This irritation may be delayed up to two days.
Ingestion may cause nausea, abdominal discomfort,
vomiting, or diarrhea.
Existing Conditions
Aggravated by Exposure: Eczema and other skin allergies, asthma and other
respiratory disorders.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: 3106 UV Curing General Purpose Adhesive
Item No.: 23697
3. HAZARDS IDENTIFICATION (continued)
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Aliphatic urethane acrylate
oligomer No Data NO NO NO
High boiling acrylate monomer ALG IRR NO NO NO
Modified acrylamide No Data NO NO NO
Photoinitiator No Data NO NO NO
Photoinitiator No Data NO NO NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
Substituted silane IRR NO NO NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable ALG Allergen
IRR Irritant NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: 172癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Oxides of carbon and nitrogen.
Unusual Fire or
Explosion Hazards: Uncontrolled polymerization may occur at high
temperatures resulting in explosions or
rupturing of storage containers.
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: 3106 UV Curing General Purpose Adhesive
Item No.: 23697
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Spontaneous hazardous polymerization may occur.
Eliminate sources of ignition. Use eye and skin
protection. Maintain adequate ventilation.
Soak up with an inert absorbent. Store in a
half filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store between 50癋 and 90癋.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid eye and skin contact. Avoid breathing
vapors. Keep away from sources of ignition.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Chemical splash safety goggles conforming to
ANSI 287.1 - 1990.
Skin: Neoprene gloves.
Ventilation: Sufficient to maintain vapor concentration
below TLV.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Pale yellow liquid
Odor: Mild
Boiling Point: More than 200癋
pH: Does not apply
Solubility in Water: Low
Specific Gravity 1.071
Volatile Organic Compound
(EPA Method 24) 54.9%; 592 grams per liter
Vapor Pressure: Not available
Vapor Density: More than 1
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Unstable
Hazardous Polymerization: May occur.
Incompatibility: Strong acids, bases, strong oxidizers, peroxides.
copper alloys, carbon steel, rust, iron, and other
polymerization initiators.
Conditions to Avoid: Not available
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: 3106 UV Curing General Purpose Adhesive
Item No.: 23697
10. STABILITY AND REACTIVITY (continued)
Hazardous Decomposition
Products (non-thermal): Dimethylamine
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted (Not more than 450 liters);
Combustible liquids, n.o.s.
(Contains N,N-Dimethylacrylamide)
(More than 450 liters)
Hazard Class or
Division: Unrestricted (Not more than 450 liters)
Combustible liquid (More than 450 liters)
Identification Number: None (Not more than 450 liters);
NA 1993 (More than 450 liters)
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: Not available
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 2
Reactivity Hazard: 1
Specific Hazard: Does not apply
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: 3106 UV Curing General Purpose Adhesive
Item No.: 23697
16. OTHER INFORMATION (continued)
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 2
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0003
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