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Gazette
Australian Government
No. C 03, Tuesday 6 March 2007
CHEMICAL
Published by the National Industrial Chemicals
Notification and Assessment Scheme - NICNAS




?Commonwealth of Australia 2007

ISBN 1035-9877

This work is copyright. Apart from any use as permitted under the Copyright Act 1968, no part may be reproduced by any
process without prior written permission from the Commonwealth available from the Attorney-General's Department.
Requests and inquiries concerning reproduction and rights should be addressed to:
Commonwealth Copyright Administration
Copyright Law Branch
Attorney-General's Department
Robert Garran Offices
National Circuit
Canberra ACT 2600
email: Commonwealth.Copyright@ag.gov.au
web:

The Industrial Chemicals (Notification and Assessment) Act 1989 (the Act) commenced on
17 July 1990. As required by Section 5 of the Act, a Chemical Gazette is published on the
first Tuesday in any month or on any days prescribed by the regulations.

CONTENTS

SPECIAL NOTICES

1 IMMEDIATE PROHIBITION OF MANUFACTURE AND IMPORT 5
OF PENTABROMODIPHENYL ETHER

2 DATA COLLECTED BY NICNAS ON USES OF 7
PERFLUOROOCTANE SULFONATE (PFOS),
PERFLUOROALKYL SULFONATE (PFAS),
PERFLUOROOCTANOIC ACID (PFOA) AND THEIR RELATED
SUBSTANCES, AND PRODUCTS/MIXTURES CONTAINING
THESE SUBSTANCES

3 SECONDARY NOTIFICATION OF NOTIFIED CHEMICAL ? 8
ARACHIDYL GLUCOSIDE (LTD/1183)

4 VOLUNTARY CALL FOR INFORMATION ?METHYLDIBROMO 9
GLUTARONITRILE (MDBGN)

5 RECENTLY PUBLISHED OECD CHEMICAL REPORTS 10

NEW CHEMICALS

SUMMARY REPORTS

6 LTD/1278 TEGO WET 500 13

7 LTD/1281 CHEMICAL IN EFKA-5071 16

8 STD/1227 HITEC 055 19

9 PLC/671 FLUOROSURFACTANT POLYMER #2 IN HP 21
INKJET INKS

23
10 PLC/674 SILOXANES AND SILICONES, DI-ME, 3-
HYDROXYPROPYL ME, ETHERS WITH
POLYETHYLENE-POLYPROPYLENE GLYCOL
MONOBENZOATE

11 PLC/675 FLUOROSURFACTANT #1 IN HP INKJET INKS 25

12 PLC/679 POLYMER IN HYJET IV-A PLUS AND HYJET V 27

13 SAPLC/51 MODAFLOW ?9200 29

14 ACCESS TO FULL PUBLIC REPORT 32

PERMITS ISSUED

15 LOW VOLUME CHEMICAL PERMITS 33

16 COMMERCIAL EVALUATION CATEGORY PERMITS 34

17 EARLY INTRODUCTION PERMITS 35

18 CONTROLLED USE PERMITS 36

AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES

37
19 NOTICE OF CHEMICALS ELIGIBLE FOR LISTING ON THE
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES FIVE
YEARS AFTER ISSUING OF ASSESSMENT CERTIFICATES

20 NOTICE OF AMENDMENTS TO THE AUSTRALIAN INVENTORY 38
OF CHEMICAL SUBSTANCES

39
21 NOTICE OF CHEMICALS ELIGIBLE FOR IMMEDIATE LISTING
ON THE AUSTRALIAN INVENTORY OF CHEMICAL
SUBSTANCES AFTER ISSUING OF ASSESSMENT
CERTIFICATES

1 IMMEDIATE PROHIBITION OF MANUFACTURE AND IMPORT
OF PENTABROMODIPHENYL ETHER

In accordance with section 61 of the Industrial Chemicals (Notification and
Assessment) Act 1989, (the Act) as amended, the manufacture and import of
pentabromodiphenyl ether (pentaBDE, CAS No. 32534-81-9) is prohibited by the
Minister for Health and Ageing while it remains a Priority Existing Chemical (PEC).
The prohibition also applies to mixtures containing the chemical. The prohibition of
the import and manufacture of the chemical is effective from the date of publication
of this notice, 6 March 2007.

While the full NICNAS risk assessment is not completed, studies commissioned by
the Australian Government Department of the Environment and Water Resources
(DEW) released today indicate that the highest levels of polybrominated diphenyl
ethers (PBDEs) in Australia were detected in the blood of young children and lower
levels in women of child bearing age. The report can be accessed at

http://www.environment.gov.au/settlements/publications/chemicals/bfr/blood.html

The blood levels of PBDEs detected in women of childbearing age do not pose a risk
to the women per se. However, these levels may pose a potential risk of
developmental effects in the unborn child based on extrapolation from results in
laboratory rats.

There is no evidence of any adverse health effects in newborns or in children from
exposure to PBDEs. However, given that these chemicals have the potential to cause
developmental effects in the offspring of treated laboratory rats, the potential for these
effects to occur in humans cannot be ruled out. Therefore, it is prudent to adopt a
precautionary approach by immediately prohibiting the import and/or manufacture of
pentabromodiphenyl ether in Australia. The NICNAS interim public health risk
assessment report on PBDE congeners is available at
http://www.nicnas.gov.au/publications/CAR/PBDE.asp.

PentaBDE is not manufactured in Australia and available information indicates that
no import has occurred since mid 2005. The regulatory action will ensure that future
importation of pentaBDE will not occur while it remains a PEC.

While articles containing pentaBDEs may continue to be imported into Australia, the
quantity of the chemical in imported articles is expected to decline given international
regulatory and voluntary activity. To date the actual sources of PBDEs detected in
the Australian studies have not been identified.

The immediate regulatory action is based on a precautionary approach to the
regulation of this chemical. The full risk assessment of pentaBDE will include an
examination of their potential sources in homes. This prohibition will be reviewed on
completion of the final risk assessments of pentaBDE and further regulatory action
taken, as appropriate,

As per the notice in the Chemical Gazette of 6 February 2007 octaBDE is no longer a
PEC as it was removed from the Australian Inventory of Chemical Substances
(AICS). This means that manufacture and/or importation of octaBDE into Australia
will require notification to and assessment of the chemical by NICNAS. Manufacture
and importation of octaBDE is also not permitted under the NICNAS exemption
categories except as laboratory standards for analytical determination. Persons
importing octaBDE for analytical purposes must comply with annual reporting
obligations as required under the Act.

Penalties apply under the Act if pentaBDE and octaBDE or mixtures containing these
chemicals are manufactured or imported after 6 March 2007 (pentaBDE) and 6
February 2007 (octaBDE).

If you would like further information or wish to discuss any aspect of this activity
please, contact Sneha Satya - Team Leader, Review & Treaties on (02) 8577 8880 or
email: sneha.satya@nicnas.gov.au.

7

2 DATA COLLECTED BY NICNAS ON USES OF PERFLUOROOCTANE
SULFONATE (PFOS), PERFLUOROALKYL SULFONATE (PFAS),
PERFLUOROOCTANOIC ACID (PFOA) AND THEIR RELATED SUBSTANCES,
AND PRODUCTS/MIXTURES CONTAINING THESE SUBSTANCES
The Director of NICNAS sought information under section 48 of the Industrial Chemicals
(Notification and Assessment) Act 1989 (the Act) on the manufacture, importation and use of
perfluorooctane sulfonate (PFOS), perfluoroalkyl sulfonate (PFAS), perfluorooctanoic acid
(PFOA) and their related substances, and products/mixtures containing these substances. A
notice calling for information was published in the Chemical Gazette of 7 March 2006.

Sixty-one associations and companies responded to the call for information. It was reported
that no manufacture of these chemicals occurs in Australia. Ten importers and two
formulators provided responses indicating import or formulation activities with PFAS, PFOA
and/or PFCA (perfluorocarboxylic acid) related substances, while majority of the responses
indicated that neither importation nor use of PFOS or PFOA had occurred since the last
NICNAS call for information in 2003. In accordance with section 50A of the Act, summaries
of the information collected are published in NICNAS Alerts 5 and 6, which can be accessed
on the NICNAS website.

Alert 5: PFOS and PFAS

Alert 6: PFOA and PFCA




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

8

3 SECONDARY NOTIFICATION OF NOTIFIED CHEMICAL
ARACHIDYL GLUCOSIDE
(LTD/1183)
Under subsection 65(2) of the Industrial Chemical (Notification and Assessment) Act 1989
(the Act), the Director requires the secondary notification of Arachidyl glucoside by:

Johnson & Johnson Pacific Pty Ltd
45 Jones St
Ultimo NSW 2007

The data required, referring to the relevant sections of the schedule to the Act, are as follows:

Part C Toxicity

Human Health
(a) the chemical's toxic effects after a single oral administration;
(b) the chemical's toxic effects after a single dermal exposure;
(d) the extent of dermal irritation caused by the chemical
(e) the extent of eye irritation caused by the chemical;
(g) the toxic effects of the chemical on administration for a period of 10 to 14 days;
(k) any production by the chemical of chromosome damage in mammalian cells grown
in vitro.

Any additional data available on toxicological and/or ecotoxicological effects of the
chemical.

The information required should be provided to the Director within 28 days of the publication
of this notice.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

9

4 VOLUNTARY CALL FOR INFORMATION
NICNAS is seeking information on uses and exposure to methyldibromo glutaronitrile
(CAS No: 35691-65-7) (in raw form or in products), due to potential health concerns
(particularly skin sensitisation).
The chemical identity of methyldibromo glutaronitrile is listed below:
Chemical Name: Pentanedinitrile, 2-bromo-2-(bromomethyl)-

Other Names/Trade Names: MDBGN
1,2-Dibromo-2,4-Dicyanobutane (DBDCB)
Tektamer or Tektamer 38
Tuopai DM 01
Bromothalonil

The following specific information is sought for this chemical:
Estimate of the total quantity (tonnes/year) of MDBGN imported to Australia (in raw
?br> form or in products);
Estimate of the total quantity (tonnes/year) of MDBGN manufactured in Australia (in
?br> raw form or in products);
Uses of MDBGN or the products containing the chemical; and
?br>
The types of products, concentration of MDBGN in the products and whether any
?br> products are available to the public.
NICNAS encourages all persons who have relevant information to provide this to NICNAS
by 6 April 2007.


Information should be sent to Lorma Gutierrez
Rapid Risk Assessment
NICNAS
GPO Box 58
Sydney NSW 2001

If you would like any further information or wish to discuss any aspect of this activity please
contact Lorma Gutierrez by phone: (02) 8577 8863, fax: (02) 8577 8888 or email:
lorma.gutierrez@nicnas.gov.au.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

10

5 RECENTLY PUBLISHED OECD CHEMICAL REPORTS
A number of Screening Information Data Set initial assessment reports (SIARs), conducted
under the OECD's High Production Volume (HPV) Programme, have recently been
published. The table below lists the chemicals.

Under the HPV programme, OECD member countries co-operatively undertake an initial
assessment of HPV chemicals, to screen them and agree on the need for further work.

HPV chemicals include all chemicals manufactured or imported at levels greater than 1,000
tonnes per year in at least one Member country or in the European Union region.

Australia takes an active role in reviewing draft SIARS and participating in the forums where
the conclusions and recommendations of the reports are discussed and agreed.

The SIARS are a useful source of chemical hazard information for both industry and the
public.

The SIDS Initial Assessment Reports for these chemicals are available from the following
website: http://www.chem.unep.ch/irptc/sids/OECDSIDS/INDEXCHEMIC.htm


Chemicals CAS N? SIAM*
C10-13 Alkylbenzene sulfonic acid, sodium salt 68411-30-3 20
C10-13 Alkyl deriv benzene sulfonic acid, sodium 90194-45-9 20
salt
4-C10-13-sec Alkyl deriv. benzene sulfonic acid, 127184-52-5 20
sodium salt
C10-14 Alkyl deriv benzene sulfonic acid, sodium 69669-44-9 20
salt
Ammonium chloride 12125-02-9 17
Ammonium persulfate 7727-54-0 20
Barium carbonate 513-77-9 20
Calcium Gluconate 299-28-5 18
-Caprolactone 502-44-3 19
1-Chloro-1,2,2,2-tetrafluoroethane 2837-89-0 16
p-Chlorotoluene 106-43-4 20
Copper monochloride 7758-89-6 21
Decylbenzene sulfonic acid, sodium salt 1322-98-1 20
Diallyl phthalate 131-17-9 19
N, N-Dicyclohexyl-2-benzothiazolesulfenamide 4979-32-2 18
Diethylmalonate 105-53-3 20
Dimethylmalonate 108-59-8 20
Dimethyl phosphonate 868-85-9 18
Diphenyl carbonate 102-09-0 19
Dodecylbenzene sulfonic acid, sodium salt 25155-30-0 19


Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

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Ethanol, 2-tert-butoxy- 7580-85-0 19
Ethylene Glycol Phenyl Ether 122-99-6 18
Ethyltriacetoxysilane 17689-77-9 21
2-Furanmethanol, tetrahydro 97-99-4 20
Gluconic acid 526-95-4 18
Glucono-Delta-Lactone 90-89-2 18
Hydroxyethyl acrylate 818-61-1 20
Hydroxypropyl acrylate 25584-83-2 20
-Ionome [(E)-4-(2,6,6-trimethyl-1-cyclohexen-1- 79-77-6 18
yl)buten-2-one]
Iron dichloride 7758-94-3 19
Isobutyl isobutyrate 97-85-8 20
Isophytol 505-32-8 16
DL-Lactone 79-50-5 21
2-Methyl-2-butene 513-35-9 19
Methyltriacetoxysilane 4253-34-3 21
C10-14 Monoalkylbenzene sulfonic acid, sodium salt 85117-50-6 20
C10-16 Monoalkylbenzene sulfonic acid, sodium salt 68081-81-2 20
2-Naphthol 135-19-3 15
1,1,1,2,2-Pentafluoroethane 354-33-6 20
Phosphoryl trichloride 10025-87-3 19
Potassium gluconate 299-27-4 18
Propylene Glycol Phenyl Ether (minor isomer - 4169-04-4 18
primary alcohol)
Propylene Glucol Phenyl Ether (commercial mixed 41593-38-3 18
isomer product)
Propylene Glucol Phenyl Ether (major isomer - 770-35-4 18
secondary alcohol)
Potassium persulfate 7727-21-1 20
Silane, trimethoxy[3-(oxiranylmethoxy)propyl] 2530-83-3 19
Silicic acid, aluminum sodium salt 1344-00-9 19
Silicic acid, calcium salt 1344-95-2 19
Silicon dioxide 7631-86-9 19
Silicon dioxide (synthetic amorphous silica) 112945-52-5 19
Silicon dioxide (synthetic amorphous silica) 112926-00-8 19
Sodium gluconate 527-07-1 18
Sodium persulfate 7775-27-1 20
Tetraethylene glycol butyl ether 1559-34-8 15
Tetraethylene glycol methyl ether 23783-42-8 15
1,2,3,4-Tetrahydronaphthalene 119-64-2 19
Tetrahydrothiophene-1,1-dioxide 126-33-0 19
Thiodiglycol 111-48-8 19


Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

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o-Toluidine 95-53-4 19
2,4,6-Tribromophenol 118-79-6 17
Tridecylbenzene sulfonic acid, sodium salt 26248-24-8 20
Tris(2-ethylhexyl)benzene-1,2,4-tricarboxylate 3319-31-1 14
Triethylene glycol butyl ether 143-22-6 15
Triphenyl phosphate 115-86-6 15
Tungsten Carbide 12070-12-1 21
Undecylbenzene sulfonic acid, sodium salt 27636-75-5 20
Sodium gluconate 527-07-1 18
* SIDS Initial Assessment Meeting at which the report was discussed.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

13

6 PUBLICATION SUMMARY REPORT
Tego Wet 500
Summary Report
Reference No: LTD/1278
International Sales & Marketing Pty Ltd (ABN 36 467 259 314) of 260 - 262 Highett Road
Highett VIC 3190 has submitted a limited notification statement in support of their
application for an assessment certificate for Tego Wet 500. The notified polymer is intended
to be used as a low foam wetting agent in coatings, paints, and printing inks. One tonne of the
notified polymer will be imported per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data the notified polymer can not be classified under the NOHSC
Approved Criteria for Classifying Hazardous Substances.

The notified polymer contains ethylene glycol ethers that constitute a structural alert
associated with a variety of adverse health effects.

Occupational Health and Safety

There is no significant concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is Negligible Concern to public health when used in the proposed manner.

Environmental Effects

The polymer is not considered to pose a risk to the environment based on its reported use
pattern.

RECOMMENDATIONS

Control Measures
Health Surveillance

? As the notified polymer may be of health concern, employers should carry out health
surveillance for workers involved in handling of the notified polymer.

Occupational Health and Safety

? Employers should implement the following engineering controls to minimise
occupational exposure to the notified polymer:
- Local exhaust ventilation during reformulation and packaging.
- Ventilation during paints and coating operations.
- Local exhaust ventilation should be in place during all spraying operations.

Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

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? Employers should implement the following safe work practices to minimise
occupational exposure during handling of the notified polymer:
- Avoid skin, eye and inhalation exposure.

? Employers should ensure that the following personal protective equipment is used by
workers to minimise occupational exposure to the notified polymer:
- Safety glasses, gloves and protective industrial clothing during reformulation and
when products are applied using roller
- Respiratory protection, safety glasses, gloves, and protective industrial clothing
during spraying operations.

Guidance in selection of personal protective equipment can be obtained from Australian,
Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? The notified polymer should be handled in accordance with provisions of State and
Territory legislation regarding the Handling of Combustible and Flammable Liquids.

? If products and mixtures containing the notified polymer are classified as hazardous to
health in accordance with the NOHSC Approved Criteria for Classifying Hazardous
Substances, workplace practices and control procedures consistent with provisions of
State and Territory hazardous substances legislation must be in operation.

Environment

Disposal

? The notified polymer should be disposed of by authorised incineration or landfill.

Storage

? The notified polymer should be stored in accordance with provisions of State and
Territory legislation regarding the Storage of Combustible and Flammable Liquids.

Emergency procedures

? Spills or accidental release of the notified polymer should be handled by physical
containment, whilst preventing entry to drains and waterways. Do not discharge to
soil or subsoil. Collect spill with adsorbent material (eg sand, vermiculite or universal
binder) and place in suitable containers for disposal.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing within 28
days by the notifier, other importer or manufacturer:

Under Section 64(1) of the Act; if
- the importation volume exceeds one tonne per annum notified polymer; or
- if the concentration of the notified polymer in final products exceeds 2%.

Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

15

- repeat dose toxicity and/or developmental/reproductive toxicity data becomes
available; or
- reporting of adverse health effects becomes available.

or

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

16

7 PUBLICATION SUMMARY REPORT
Chemical in EFKA-5071
Summary Report
Reference No: LTD/1281
Ciba Specialty Chemicals Pty Ltd (ABN 97 005 061 469) of 235 Settlement Road,
Thomastown Vic 3074 has submitted a limited notification statement in support of their
application for an assessment certificate for Chemical in EFKA-5071. The notified chemical
is intended to be used as a wetting and dispersing agent in solvent based automotive paints
for use in crash repair shops. Up to 1 tonnes of the notified chemical will be imported per
annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

No toxicological data have been provided for the notified chemical and therefore the
substance cannot be classified in accordance with the NOHSC Approved Criteria for
Classifying Hazardous Substances (NOHSC, 2004)

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is Negligible Concern to public health when used as described.

Environmental Effects

The chemical is not considered to pose a risk to the environment based on its reported use
pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety

? Employers should implement the following safe work practices to minimise
occupational exposure during handling of the notified chemical as introduced and in
reformulated paint products:
- Avoid contact with skin and eyes
- Avoid splashes and spills
- Do not breathe spray
- Spray application of paint containing the notified chemical should be in accordance
with the NOHSC National Guidance Material for Spray Painting (NOHSC, 1999b)




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

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? Employers should ensure that the following personal protective equipment is used by
workers to minimise occupational exposure to the notified chemical as introduced and
in reformulated paint products:
- Suitable protective clothing
- Eye/face protection
- Suitable gloves
- Suitable respirators where inhalation exposure is possible

? Employers should implement the following engineering controls to minimise
occupational exposure to the notified chemical as introduced and in the formulated
paint product:
- Avoid generation of aerosols during paint formulation and preparation
- Spray application should be carried out in an enclosed automated spray booth where
possible

Guidance in selection of personal protective equipment can be obtained from Australian,
Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified chemical are classified as hazardous
to health in accordance with the NOHSC Approved Criteria for Classifying
Hazardous Substances, workplace practices and control procedures consistent with
provisions of State and Territory hazardous substances legislation must be in
operation.

Disposal

? The notified chemical should be disposed of by incineration or to landfill

Emergency procedures

? Spills or accidental release of the notified chemical should be handled by physical
containment, collection and subsequent safe disposal.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing within 28
days by the notifier, other importer or manufacturer:

Under Section 64(1) of the Act; if
- the importation volume exceeds one tonne per annum notified chemical; or
- the notified chemical is formulated in paints at a concentration of 1%; or
- if any toxicological data on the notified chemical becomes available

or

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.


Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

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The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

19

8 PUBLICATION SUMMARY REPORT
HiTEC 055
Summary Report
Reference No: STD/1227
Afton Chemical Asia Pacific LLC (ABN: 99 109 644 288) of Level 9, Berry Street, North
Sydney NSW 2059 has submitted a standard notification statement in support of their
application for an assessment certificate for HiTEC 055. The notified chemical is intended to
be used as an additive in end-use lubricant products such as gear lubricant or vehicle
transmission oil at concentration of 0.05-0.10%. Reformulation and use of the end-use
lubricant products will take place throughout Australia. Up to two tonnes of the notified
chemical will be imported per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

Based on the available data the notified chemical is classified as hazardous under the NOHSC
Approved Criteria for Classifying Hazardous Substances. The classification and labelling
details are:
?R38 Irritating to skin

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is No Significant Concern to public health when used in the proposed manner.

Environmental Effects

On the basis of the PEC/PNEC ratio:
?The chemical is not considered to pose a risk to the environment based on its reported
use pattern.

RECOMMENDATIONS

Regulatory Controls
Hazard Classification and Labelling

? The Office of the ASCC, Department of Employment and Workplace Relations
(DEWR), should consider the following health hazard classification for the notified
chemical:
- R38 Irritating to skin

? Use the following risk phrases for products/mixtures containing the notified chemical:
- Conc >20%: (Xi) R38 Irritating to skin


Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

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Control Measures
Occupational Health and Safety

? Employers should implement the following safe work practices to minimise
occupational exposure during handling of the notified chemical as introduced and in
blended oil products:
- Avoid skin and eye contact

? Employers should ensure that the following personal protective equipment is used as a
precauion by workers to minimise occupational exposure to the notified chemical as
introduced and in blended oil products:
- Eye protection
- Impervious gloves

Guidance in selection of personal protective equipment can be obtained from Australian,
Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified chemical are classified as hazardous
to health in accordance with the NOHSC Approved Criteria for Classifying
Hazardous Substances, workplace practices and control procedures consistent with
provisions of State and Territory hazardous substances legislation must be in
operation.

Disposal

? The notified chemical should be disposed of by landfill or incineration.

Emergency procedures

? For small spills, add absorbent (soil may be used in the absence of other suitable
materials) and use a non-sparking or explosion-proof means to transfer material to a
sealable, appropriate container for disposal. For large spills, dike spilled material or
otherwise contain material to ensure run-off does not reach a waterway. Placed spilled
material in an appropriate container for disposal. Minimize contact of spilled material
with soils to prevent run-off to surface waterways.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing within 28
days by the notifier, other importer or manufacturer:

Under Section 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.

No additional secondary notification conditions are stipulated.



Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

21

9 PUBLICATION SUMMARY REPORT
Fluorosurfactant Polymer #2 in HP inkjet inks
Summary Report
Reference No: PLC/671
Hewlett Packard Australia Pty Ltd (ABN 74 004 394 763) of 3 Richardson Place, North
Ryde, NSW, has submitted a polymer of low concern (PLC) notification statement in support
of their application for an assessment certificate for "Fluorosurfactant Polymer #2 in HP
inkjet inks". The notified polymer is intended to be used as a component of inkjet printing
inks, Australia wide. Up to 50 kg of the notified polymer will be imported per annum for
each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Occupational Health and Safety

The notified polymer does not pose a significant risk to occupational health and safety under
the conditions of the occupational settings described.

Public Health

There is No Significant Concern to public health when used in the proposed manner.

Environmental Effects

Based on the notified polymer's reported use pattern and the PEC/PNEC ratio, it is not
considered to pose a risk to the environment.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety
? No specific engineering controls, work practices or personal protective equipment are
required for the safe use of the notified polymer itself, however, these should be
selected on the basis of all ingredients in the formulation.

Guidance in selection of personal protective equipment can be obtained from Australian,
Australian/New Zealand or other approved standards.

? Service personnel should wear cotton or disposable gloves and ensure adequate
ventilation is present when removing spent printer cartridges containing the notified
polymer and during routine maintenance and repairs.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified polymer are classified as hazardous to
health in accordance with the NOHSC Approved Criteria for Classifying Hazardous
Substances, workplace practices and control procedures consistent with provisions of
State and Territory hazardous substances legislation must be in operation.



Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

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Disposal

? The notified polymer should be disposed of by incineration or landfill.

Emergency procedures

No special precautions necessary (cartridges).
?br>
Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing within 28
days by the notifier, other importer or manufacturer:

Under subsection 64(1) of the Act; if
- the notified polymer is introduced in a chemical form that does not meet the PLC
criteria.
- other uses are proposed.
- further information becomes available regarding transformations and degradation
of the notified polymer including any adverse health and environmental effects of
the breakdown products. This information is to be provided to NICNAS as soon as
practicable in order to determine if additional recommendations, if relevant, are
required.
or

Under subsection 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

23

10 PUBLICATION SUMMARY REPORT
Siloxanes and Silicones, di-Me, 3-hydroxypropyl Me, ethers with polyethylene-
polypropylene glycol monobenzoate
Summary Report
Reference No: PLC/674
A.S. Harrison & Co. Pty Ltd (ABN 89 000 030 437) of 75 Old Pittwater Road, Brookvale
NSW 2100 has submitted a polymer of low concern (PLC) notification statement in support
of their application for an assessment certificate for Siloxanes and Silicones, di-Me, 3-
hydroxypropyl Me, ethers with polyethylene-polypropylene glycol monobenzoate. The
notified polymer is intended to be used at ~0.1% by weight to improve skin feel in a shaving
cream formulation. Up to 3 tonnes of the notified polymer will be imported per annum for
each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

The notified polymer meets the PLC criteria and can therefore be considered to be of low
hazard. This is supported by toxicological endpoints observed in testing conducted on the
notified polymer.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is No Significant Concern to public health when used in the proposed manner.

Environmental Effects

The polymer is not considered to pose a risk to the environment based on its reported use
pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety

? No specific engineering controls, work practices or personal protective equipment are
required for the safe use of the notified polymer itself, however, these should be
selected on the basis of all ingredients in the formulation.

Guidance in selection of personal protective equipment can be obtained from Australian,
Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.



Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

24

? If products and mixtures containing the notified polymer are classified as hazardous to
health in accordance with the NOHSC Approved Criteria for Classifying Hazardous
Substances, workplace practices and control procedures consistent with provisions of
State and Territory hazardous substances legislation must be in operation.

Disposal

? The notified polymer should be disposed of by authorised landfill.

Emergency procedures

? Spills and/or accidental release of the notified polymer should be handled by physical
containment with subsequent adsorption with compatible material (sand, vermiculite
etc). Transfer to suitable containers for disposal or reclamation.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing within 28
days by the notifier, other importer or manufacturer:

Under subsection 64(1) of the Act; if
- the notified polymer is introduced in a chemical form that does not meet the PLC
criteria.
or

Under subsection 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

25

11 PUBLICATION SUMMARY REPORT
Fluorosurfactant #1 in HP inkjet inks
Summary Report
Reference No: PLC/675
Hewlett Packard (ABN: 74 004 394 763) of 3 Richardson Place, North Ryde NSW 2113 has
submitted a polymer of low concern (PLC) notification statement in support of their
application for an assessment certificate for Fluorosurfactant #1 in HP inkjet inks. The
notified polymer is intended to be used as a component of inkjet printing inks in pre-packed
cartridges. Up to 0.05 tonnes of the notified polymer will be imported per annum for each of
the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

The notified polymer meets the PLC criteria and can therefore be considered to be of low
hazard. This is supported by toxicological endpoints observed in testing conducted on a
product containing up to 85% notified polymer.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is No Significant Concern to public health when used in the proposed manner.

Environmental Effects

The polymer is not considered to pose a risk to the environment based on its reported use
pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety
? No specific engineering controls, work practices or personal protective equipment are
required for the safe use of the notified polymer itself, however, these should be
selected on the basis of all ingredients in the formulation.

Guidance in selection of personal protective equipment can be obtained from Australian,
Australian/New Zealand or other approved standards.

? Service personnel should wear cotton or disposable gloves and ensure adequate
ventilation is present when removing spent printer cartridges containing the notified
polymer and during routine maintenance and repairs.

? A copy of the MSDS should be easily accessible to employees.

Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

26


? If products and mixtures containing the notified polymer are classified as hazardous to
health in accordance with the NOHSC Approved Criteria for Classifying Hazardous
Substances, workplace practices and control procedures consistent with provisions of
State and Territory hazardous substances legislation must be in operation.

Disposal

? The notified polymer should be disposed of by incineration or landfill.

Emergency procedures

? No special precautions necessary (cartridges).

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing within 28
days by the notifier, other importer or manufacturer:

Under subsection 64(1) of the Act; if
- the notified polymer is introduced in a chemical form that does not meet the PLC
criteria.
- other uses are proposed.
- further information becomes available regarding transformations and degradation
of the notified polymer including any adverse health and environmental effects of
the breakdown products. This information is to be provided to NICNAS as soon as
practicable in order to determine if additional recommendations, if relevant, are
required.
or

Under subsection 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

27

12 PUBLICATION SUMMARY REPORT
Polymer in HyJet IV-A Plus and HyJet V
Summary Report
Reference No: PLC/679
Mobil Oil Australia Pty Ltd (ABN 88 004 052 984) of 12 Riverside Quay South Bank VIC
3006 has submitted a polymer of low concern (PLC) notification statement in support of their
application for an assessment certificate for Polymer in HyJet IV-A Plus and HyJet V. The
notified polymer is intended to be used as a viscosity index improver in aviation hydraulic
fluids. Up to 4 tonnes of the notified polymer will be imported per annum for each of the first
five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

The notified polymer meets the PLC criteria and can therefore be considered to be of low
hazard.

Occupational Health and Safety

There is No Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is Negligible Concern to public health when used in the proposed manner.

Environmental Effects

The polymer is not considered to pose a risk to the environment based on its reported use
pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety
? No specific engineering controls, work practices or personal protective equipment are
required for the safe use of the notified polymer itself, however, these should be
selected on the basis of all ingredients in the formulation.

Guidance in selection of personal protective equipment can be obtained from Australian,
Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified polymer are classified as hazardous to
health in accordance with the NOHSC Approved Criteria for Classifying Hazardous
Substances, workplace practices and control procedures consistent with provisions of
State and Territory hazardous substances legislation must be in operation.

Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

28


Environment

Disposal

? The notified polymer should be disposed of by authorised incineration.

Emergency procedures

? Spills and/or accidental release of the notified polymer should be handled by physical
containment such as diking. Adsorb with inert material (diatomaceous earth, fire
retardant treated saw dust, etc) and collect for disposal.

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing within 28
days by the notifier, other importer or manufacturer:

Under subsection 64(1) of the Act; if
- the notified polymer is introduced in a chemical form that does not meet the PLC
criteria.
or

Under subsection 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

29

13 PUBLICATION SUMMARY REPORT
ModaFlow ?9200
Summary Report
Reference No: SAPLC/51
Cytec Australia Holdings Pty Ltd (ABN: 45 081 148 629) of Suite 1 level 1 21 Solent
Circuit Baulkham Hills NSW 2153 has submitted a polymer of low concern (PLC)
notification statement in support of their application for a self-assessed assessment certificate
for MODAFLOW 9200. The notified polymer is intended to be used as a flow and
levelling agent for formulation in industrial spray coatings. MODAFLOW?9200,
containing ~100% notified polymer is imported via Sydney or Melbourne harbour in 25 kg
or 210 kg steel drums. The drums will be transported by road to a warehouse for storage
before being delivered to formulators without further repacking. The notified polymer will
be poured from 25 kg steel containers into 1,000 L capacity stainless steel vats at the
customer's production site. After other batch ingredients have been added, the formulation is
mixed at room temperature. The spray paint (containing <10% notified polymer) is then
piped into 1 or 5 L steel containers, to be sold to paint applicators. The paint is applied
through spray onto substrate parts within a controlled environment.Less than 100 tonnes of
the notified polymer will be imported per annum for each of the first five years.

ASSESSMENT OF PUBLIC, OCCUPATIONAL HEALTH AND SAFETY AND
ENVIRONMENTAL EFFECTS

Hazard Assessment

No toxicological data were submitted. The notified polymer meets the PLC criteria and can
therefore be considered to be of low hazard.

Occupational Health and Safety

There is Low Concern to occupational health and safety under the conditions of the
occupational settings described.

Public Health

There is No Significant Concern to public health when used in the proposed manner.

Environmental Effects

The polymer is not considered to pose a risk to the environment based on its reported use
pattern.

RECOMMENDATIONS

Control Measures
Occupational Health and Safety
? No specific engineering controls, work practices or personal protective equipment are
required for the safe use of the notified polymer itself, however, these should be
selected on the basis of all ingredients in the formulation.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

30

Guidance in selection of personal protective equipment can be obtained from Australian,
Australian/New Zealand or other approved standards.

? A copy of the MSDS should be easily accessible to employees.

? If products and mixtures containing the notified polymer are classified as hazardous to
health in accordance with the NOHSC Approved Criteria for Classifying Hazardous
Substances, workplace practices and control procedures consistent with provisions of
State and Territory hazardous substances legislation must be in operation.

? Spray painting should be in accordance with the NOHSC National Guidance Material
for Spray Painting.

Environment

? The following control measures should be implemented by formulator to minimise
environmental exposure during formulation of the notified polymer:
- Bunding

? The following control measures should be implemented by end users (spray painters)
to minimise environmental exposure during use of the notified polymer:
- Exhaust ventilation with filter

Disposal

? The notified polymer should be disposed of by landfill or incinerated at an approved
waste hander.


Storage

? The following precautions should be taken by the notifier and end-users regarding
storage of the notified polymer.
?Observe the general rules of industrial fire protection
?Keep container tightly closed and dry in a cool, well-ventilated place

Emergency procedures

? Spills/release of the notified polymer should be handled by take up with absorbent
material (eg sand, kieselguhr, universal binder)
? When picked up, treat material as prescribed under heading "Disposal".

Secondary Notification

The Director of Chemicals Notification and Assessment must be notified in writing within 28
days by the notifier, other importer or manufacturer:

Under subsection 64(1) of the Act; if
- the notified polymer is introduced in a chemical form that does not meet the PLC
criteria.

Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

31

or

Under subsection 64(2) of the Act:
- if any of the circumstances listed in the subsection arise.

The Director will then decide whether secondary notification is required.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

32

14 ACCESS TO FULL PUBLIC REPORT
NICNAS publishes a Full Public Report for each new chemical assessed. These reports are
available for public inspection at the library of the National Occupational Health & Safety
Commission at their Canberra office by appointment only. Please call the library on (02)
6279 1161 or (02) 6279 1163 to arrange to view the Full Public Report.
Reports can also be viewed and downloaded free of charge from our website at
www.nicnas.gov.au. Copies of these reports may also be requested, free of charge, by
contacting the Administration Section of NICNAS by phone: (02) 8577 8816 or fax: (02)
8577 8888.




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

33

15 LOW VOLUME CATEGORY PERMITS
The permits listed in Table 1 were issued to import or manufacture the following chemicals
under section 21U of the Industrial Chemicals (Notification and Assessment) Act 1989. Low
Volume Category Permits are approved for 36 months.

Table 1
Low Volume Category Permits


PERMIT COMPANY COMPANY CHEMICAL OR TRADE HAZARDOUS USE DATE
NUMBER NAME POSTCODE NAME SUBSTANCE


La 2018 5-amino-6-chloro-o- Yes Oxidative 31.1.2007
747
Biosthetique cresol dye for hair
Australia Pty dye
(Renewal) Ltd formulations


Epson 2113 MJA-549(N) Yes Ink 8.02.2007
748
Australia Pty colourant
Ltd for ink jet
(Renewal) printer




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

34

16 COMMERCIAL EVALUATION CATEGORY PERMIT
The permits listed in Table 2 were issued to import or manufacture the following chemicals
for commercial evaluation under section 21G of the Industrial Chemicals (Notification and
Assessment) Act 1989.

Table 2
Commercial Evaluation Category Permits


PERMIT COMPANY COMPANY CHEMICAL HAZARDOUS QUANTITY USE PERIOD
NUMBER NAME POSTCODE OR TRADE SUBSTANCE APPROVED
NAME



Yes 4000 kg Surface 2 yrs
685 A&I 2577 POLYMER
coating
Coatings IN
UCECOAT
(RENEWAL)
7849




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

35

17 EARLY INTRODUCTION PERMITS FOR NON-HAZARDOUS INDUSTRIAL
CHEMICALS
The permits listed in Table 3 were issued to import or manufacture the following chemicals
prior to the issue of their respective assessment certificates under section 30A of the Act.
Table 3

Early Introduction Permits


PERMIT COMPANY CHEMICAL OR USE
NUMBER NAME TRADE NAME

485 The Valspar Polymer in AK0979P Component of paint formulations
(Australia) for industrial use
Corporation
Pty Limited
486 Cytec Polymer in Crylcoat Tackifier in PVC products
Holdings Pty 9246-0
Ltd
487 Cytec Polymer in GELVA Emulsion adhesive for clear filmic
Holdings Pty GME AX 3312-22 labels
Ltd
488 Cytec Synthacryl 700 Powder coating for application on
Holding Pty consumer articles
Ltd




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

36

18 CONTROLLED USE PERMIT (EXPORT ONLY)
The permits listed in Table 4 were issued to import or manufacture the following chemicals
for export of the entire quantity under section 22F of the Industrial Chemicals (Notification
and Assessment) Act 1989.
Table 4

Controlled Use Permit


PERMIT NUMBER COMPANY NAME CHEMICAL OR USE
TRADE NAME
003 Swift & Company Polyhexamethyl Ingredient in
Ltd biguanide stearate personal deodorants




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

37

19 NOTICE OF CHEMICALS ELIGIBLE FOR LISTING ON THE AUSTRALIAN
INVENTORY OF CHEMICAL SUBSTANCES FIVE YEARS AFTER ISSUING OF
ASSESSMENT CERTIFICATES
Notice is given in accordance with section 14(1) of the Industrial Chemicals (Notification
and Assessment) Act 1989, that the following chemicals have been added to the Australian
Inventory of Chemical Substances.

Table 5

Chemicals Eligible for Listing on the Australian Inventory of Chemical Substances

CHEMICAL NAME MOLECULAR CAS
FORMULA NUMBER
Urea, monohydrochloride CH4N2O.ClH 506-89-8
Fatty acids, C6-24 and C16-18-unsatd., Unspecified 93571-82-5
esters with sucrose
Pyrrolo[3,4-c]pyrrole-1,4-dione, 2,5- C54H84N2O2S2 247089-62-9
dihydro-3,6-bis[4-
(octadecylthio)phenyl]-
1,4-Benzenedicarboxylic acid, polymer (C15H16O2.C9H4O 268557-29-5
with (2E)-2-butenedioic acid, 5.C8H6O4.C8H4O3.
(chloromethyl)oxirane, 1,3-dihydro-1,3- C6H6O.C4H4O4.(C
dioxo-5-isobenzofurancarboxylic acid, 3H6O)n (C3H6O)n
formaldehyde, 1,3-isobenzofurandione, C15H16O2.C3H5Cl
4,4'-(1-methylethylidene)bis[phenol], O.C2H4O.CH2O)x
.alpha.,.alpha.'-[(1-methylethylidene)di-
4,1-phenylene]bis[.omega.-
hydroxypoly[oxy(methyl-1,2-
ethanediyl)]], oxirane and phenol
Fatty acids, C6-10, tetraesters with Unspecified 228573-47-5
sorbitan




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

38

20 NOTICE OF AMENDMENTS TO THE AUSTRALIAN INVENTORY OF
CHEMICAL SUBSTANCES
Notice is given in accordance with section 20 of the Industrial Chemicals (Notification and
Assessment) Act 1989 (the Act) that the following amendment have been made to the
Australian Inventory of Chemical Substances (AICS).

Table 6

In the March 2006 gazette the following chemical was incorrectly listed and the correct
listing is as follows:

Gazetted CAS Gazetted chemical name Correct CAS
number number

156559-12-5 1,3-Benzenedicarboxylic 163183-04-8
acid, polymer with 1,4-
benzenedicarboxylic acid,
hexanedioic acid, 1,6-
hexanediol, 3-hydroxy-2-
(hydroxymethyl)-2-
methylpropanoic acid and
5-isocyanato-1-
(isocyanatomethyl)-1,3,3-
trimethylcyclohexane,
compd. with 1-
(dimethylamino)-2-
propanol




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007

39

21 NOTICE OF CHEMICALS ELIGIBLE FOR IMMEDIATE LISTING ON THE
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES AFTER ISSUING OF
ASSESSMENT CERTIFICATES
Notice is given in accordance with section 13B of the Industrial Chemicals (Notification and
Assessment) Act 1989, that the following chemicals have been added to the Australian
Inventory of Chemical Substances.

Table 7

Chemicals Eligible for Immediate Listing on the Australian Inventory of Chemical
Substances

CHEMICAL NAME MOLECULAR CAS
FORMULA NUMBER
Cyclohexanecarboxylic acid, 2,2-dimethyl-6- C11H18O2 81752-87-6
methylene-, methyl ester
2-Propenoic acid, C18-22-alkyl esters, Unspecified 816417-47-7
polymers with styrene
Siloxanes and Silicones, di-Me, 3- Unspecified 161755-53-9
hydroxypropyl group-terminated,
propoxylated




Chemical Gazette Commonwealth of Australia Gazette
No. C 03, 6 March 2007





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