Page 1 of 7
MATERIAL SAFETY DATA SHEET CND- N-118
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
1. PRODUCT IDENTIFICATION
1.1 Product Name:
METRO METAL POWDERS
1.2 Chemical Name:
METHACRYLATE COPOLYMER BLEND
1.3 Synonyms:
NA
1.4 Trade Names:
METRO POWDERS: CITY OF ANGELS (COPPER), CITY OF LIGHTS (SILVER), CITY OF PEACE (WHITE), SIN CITY (BLACK), GOLDEN CITY (GOLD),
MELTING POT (BROWN)
1.5 Product Use:
PROFESSIONAL USE ONLY
1.6 Distributor鈥檚 Name:
CREATIVE NAIL DESIGN, INC.
1.7 Distributor鈥檚 Address:
1125 JOSHUA WAY VISTA, CA USA 92081
1.8 Emergency Phone:
CHEMTREC: 800-424-9300 / 703-527-3887
1.9 Business Phone:
800-833-NAIL (6245), 760-599-2900
2. HAZARD IDENTIFICATION
2.1 Hazard Identification:
NA
2.2 Routes of Entry: Inhalation: YES Absorption: NO Ingestion: YES
2.3 Effects of Exposure:
EYES: Possible irritation from dust.
SKIN: Irritation. Allergic contact dermatitis is possible with prolonged or repeated contact.
INGESTION: No exposure effects are reported.
INHALATION: Considered a nuisance dust. May cause irritation of the mouth, nose, throat, and lungs.
2.4 Symptoms of Overexposure:
EYES: Redness & watering.
SKIN: Redness, itching, drying of skin.
INGESTION: No symptoms are expected.
INHALATION: Upper respiratory irritation, including coughing & sneezing.
2.5 Acute Health Effects:
EYES: Possible irritation from dust.
SKIN: Irritation. Allergic contact dermatitis is possible with prolonged or repeated contact.
INGESTION: No exposure effects are reported.
INHALATION: Considered a nuisance dust. May cause irritation of the mouth, nose, throat, and lungs.
2.6 Chronic Health Effects:
None known.
2.7 Target Organs:
Eyes, skin and respiratory system.
NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2004 format.
Page 2 of 7
MATERIAL SAFETY DATA SHEET CND-N-118
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
3. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH OSHA OTHER
TLV STEL PEL STEL IDLH
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. % ppm ppm ppm ppm ppm
POLYETHYLMETHACRYLATE 9003-42-3 NA NA 鈮? 45.0 NE NE NE NE NE
METHACRYLATE COPOLYMER NA NA NA 鈮? 45.0 NE NE NE NE NE
BENZOYL PEROXIDE 94-36-0 DM8575000 202-327-6 鈮? 1.0 (5) NE (5) NE NE
ADDITIONAL INGREDIENTS:
CITY OF ANGELS (COPPER):
POLYETHYLENE TEREPHTHALATE 25038-59-9 TR2725000 NA 鈮? 15.0 NE NE NE NE NE (5) AEI*
CITY OF LIGHTS (SILVER):
POLYETHYLENE TEREPHTHALATE 25038-59-9 TR2725000 NA 鈮? 15.0 NE NE NE NE NE (5) AEI*
CITY OF PEACE (WHITE):
MICA 12001-26-2 NA 310-127-6 鈮? 15.0 (3) NA (3) NA NA DUST
TITANIUM DIOXIDE 13463-67-7 XR2275000 236-675-5 鈮? 2.0 (10) NA (15) NA NA DUST
BORON NITRIDE 10043-11-5 ED7800000 233-136-6 鈮? 2.0 (5) NA (10) NA NA DUST
THE GOLDEN CITY (GOLD)
POLYETHYLENE TEREPHTHALATE 25038-59-9 TR2725000 NA 鈮? 15.0 NE NE NE NE NE (5) AEI*
SIN CITY (BLACK):
POLYETHYLENE TEREPHTHALATE 25038-59-9 TR2725000 NA 鈮? 10.0 NE NE NE NE NE (5) AEI*
COLORANT CI 77499 1309-74-1 NA 215-168-2 鈮? 10.0 NE NE NE NE NE
THE MELTING POT (BROWN):
POLYETHYLENE TEREPHTHALATE 25038-59-9 TR2725000 NA 鈮? 10.0 NE NE NE NE NE (5) AEI*
MICA 12001-26-2 NA 310-127-6 鈮? 10.0 (3) NA (3) NA NA DUST
COLORANT CI 77499 1309-37-1 NA 215-168-2 鈮? 5.0 NE NE NE NE NE
OTHER COMPONENTS PRESENT IN LESS THAN 1% CONCENTRATION BAL THE REMAINING COMPONENTS DO NOT CONTRIBUTE
ANY SIGNIFICANT ADDITIONAL HAZARDS
* DuPont Chemical Company
4. FIRST AID MEASURES
4.1 First Aid:
EYES: Flush eyes thoroughly with copious amounts of water for at least 15 minutes, holding eyelid(s) open to ensure complete
flushing. If irritation persists, seek immediate medical attention.
SKIN: Remove contaminated clothing and wash affected areas with soap and water. Wash all contaminated clothing
thoroughly before reuse. If irritation persists, seek medical attention.
INGESTION: Contact ChemTrec at 703-527-3887 or the nearest Poison Control Center or local emergency telephone number for
assistance and instructions. If vomiting occurs spontaneously, keep victim's head lowered (forward) to reduce the risk
of aspiration.
INHALATION: Remove victim to fresh air at once. Under extreme conditions, if breathing stops, perform artificial respiration and seek
medical attention.
4.2 Medical Conditions Aggravated by Exposure:
Pre-existing dermatitis, asthma or bronchitis.
Page 3 of 7
MATERIAL SAFETY DATA SHEET CND-N-118
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
579 掳F (304 掳C) TCC
5.2 Autoignition Temperature:
NA
5.3 Flammability Limits: Lower Explosive Limit (LEL): NA Upper Explosive Limit (UEL): NA
5.4 Fire & Explosion Hazards:
NA
5.5 Extinguishing Methods:
Carbon dioxide, dry chemical & water spray.
5.6 Firefighting Procedures:
Keep containers cool until well after the fire is out. Prevent runoff from fire control or dilution from
entering sewers, drains, drinking water supply, or any natural waterway. Firefighters should wear full
face, self-contained breathing apparatus (MSHA/NIOSH approved or the equivalent) and impervious
protective clothing.
6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., <1 gallon) wear appropriate personal protective equipment (e.g., goggles, gloves). Spilled product should be
swept or vacuumed up immediately to prevent falls. Dispose of properly in accordance with local, state and federal regulations.
Wash all affected areas and outside of container with plenty of warm water and soap. Remove any contaminated clothing and wash
thoroughly before reuse.
For spills 鈮? 1 gallon, deny entry to all unprotected individuals. Spilled product should be swept or vacuumed up immediately to
prevent falls. Transfer to containers for proper disposal. Wash all affected areas and outside of container with plenty of warm water
and soap. Remove any contaminated clothing and wash thoroughly before reuse. Keep spills and cleaning runoffs out of municipal
sewers and open bodies of water.
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Use eye protection when using this product. Wash hands thoroughly after using this product and before eating, drinking, or smoking.
7.2 Storage & Handling:
Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans). Keep away from excessive heat. Do not
store in damaged or unmarked containers or storage devices. Keep containers securely closed when not in use.
7.3 Special Precautions:
Empty containers may retain residual amounts of product. Therefore, empty containers should be handled with care. The product is
a fine powder, and may cause a slipping and falling hazard if spilled. Spilled product should be swept or vacuumed up immediately
to prevent falls.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
General mechanical ventilation (e.g., fans) and local exhaust ventilation is recommended for use with this product.
8.2 Respiratory Protection:
Respirators are not required for use with this product. However, this product is a nuisance dust hazard. Product may cause irritation of
the mouth, nose, throat, and lungs. Accordingly, when working with large quantities (> gallon) a dust mask is suggested. A
respiratory protection program that meets OSHA鈥檚 29 CFR 搂1910.134 and ANSI Z88.2 requirements must be followed whenever a
respirator is used.
8.3 Eye Protection:
Safety glasses with side shields should be used when using this product.
8.4 Hand Protection:
None required under normal conditions of use. May cause skin irritation in some sensitive individuals.
When handling large quantities (e.g., 鈮? 1 gallon), wear rubber or impervious plastic gloves.
Page 4 of 7
MATERIAL SAFETY DATA SHEET CND-N-118
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
HEALTH 1
8.5 Body Protection:
No apron required when handling small quantities.
FLAMMABILITY 0
When handling large quantities (e.g., 鈮? 1 gallon), eye wash stations and deluge
showers should be available. Upon completion of work activities involving large
REACTIVITY 2
quantities of this product, wash any exposed areas thoroughly with soap and water.
PROTECTIVE EQUIPMENT A
EYES
9. PHYSICAL & CHEMICAL PROPERTIES
9.1 Density: NA
9.2 Boiling Point: NA
9.3 Melting Point: Approximately 200掳C
9.4 Evaporation Rate: NA
9.5 Vapor Pressure: NA
9.6 Molecular Weight: NA
9.7 Appearance & Color: Metallic colored powders with faint bland odor.
9.8 Odor Threshold: ND
9.9 Solubility: Insoluble
9.10 pH NA
9.11 Viscosity: NA
9.12 Other Information: NA
10. STABILITY & REACTIVITY
10.1 Stability: Stable under normal conditions of use (see section 7).
10.2 Hazardous Decomposition Products: Oxides of carbon and nitrogen.
10.3 Hazardous Polymerization: Highly unlikely, but will occur if large quantity of product comes in contact with an equally large
quantity of monomer.
10.4 Conditions to Avoid: High heat (120掳F) and proximity to monomers. (Large quantities only, e.g. > 1 gallon).
10.5 Incompatible Substances: Monomer. (Large quantities only, e.g. > 1 gallon).
11. TOXICOLOGICAL INFORMATION
11.1 Toxicity Data: This product has not been tested on animals to obtain toxicological data. There are toxicology data
for the components of this product, which are found in the scientific literature. These data have not
been presented in this document.
See section 3.5
11.2 Acute Toxicity:
11.3 Chronic Toxicity: See section 3.6
11.4 Suspected Carcinogen: NE
11.5 Reproductive Toxicity: This product is not reported to produce reproductive toxicity in humans
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
This product is not reported to produce embryotoxic effects in humans.
Embryotoxicity:
Teratogenicity: This product is not reported to produce teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to produce reproductive effects in humans.
11.6 Irritancy of Product: See Section 3.3
NE
11.7 Biological Exposure Indices:
11.8 Physician Recommendations: Treat symptomatically.
12. ECOLOGICAL INFORMATION
12.1 Environmental Stability: This product will slowly volatilize from soil. Components of this product will slowly decompose into
organic compounds.
12.2 Effects on Plants & Animals: There is no specific data available for this product.
There is no specific data available for this product.
12.3 Effects on Aquatic Life:
Page 5 of 7
MATERIAL SAFETY DATA SHEET CND-N-118
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose of in accordance with all federal, state, and local regulations.
13.2 Special Considerations:
NA
14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
NOT REGULATED
14.2 IATA (AIR):
NOT REGULATED
14.3 IMDG (OCN):
NOT REGULATED
14.4 TDGR (Canadian GND):
NOT REGULATED
14.5 ADR/RID (EU):
NOT REGULATED
15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
This product does not contain any substances with SARA reporting requirements.
15.2 SARA Threshold Planning Quantity:
This product does not contain any substances with a SARA threshold planning quantity.
15.3 TSCA Inventory Status:
All chemical substances of this product are listed on the TSCA inventory or are otherwise exempt from inventory status.
15.4 CERCLA Reportable Quantity (RQ):
This product does not contain any substances with a CERCLA reportable quantity.
15.5 Other Federal Requirements:
This product complies with the appropriate sections of the Food and Drug Administration鈥檚 21 CFR Subchapter G, (Cosmetics).
15.6 Other Canadian Regulations
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR. The components of this product are listed on the DSL/NDSL. None
of the components of this product are listed on the Priorities Substances List.
15.7 State Regulatory Information:
No component of this mixture is listed in the California Proposition 65 Lists.
15.8 67/548/EEC (European Union) Requirements:
The primary component of this product is not listed in Annex I of EU Directive 67/548/EEC.
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MATERIAL SAFETY DATA SHEET CND-N-118
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
16. OTHER INFORMATION
16.1 Other Information:
WARNING: Precisely follow directions and MSDS (available through your supplier) for use. Avoid skin and eye contact. Keep out of
reach of children. If redness or other signs of adverse reaction occur, discontinue use immediately and thoroughly rinse affected
area.
16.2 Terms & Definitions:
See page 7 of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA鈥檚 Hazard Communication Standard, 29 CFR 搂1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & Creative Nail Design's
knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness
are not guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein
relates only to the specific product(s). If this product(s) is combined with other materials, all component properties must be
considered. Data may be changed from time to time. Be sure to consult the latest edition.
16.4 Prepared for:
Creative Nail Design, Inc.
1125 Joshua Way
Vista, CA 92081 USA
800-833-NAIL (6245) phone
760-599-2900
760-599-4005 fax
http://www.creativenaildesign.com/
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Blvd., Suite 201
Torrance, CA 90504
310-370-3600 phone
310-370-5700 fax
http://www.shipmate.com/
Page 7 of 7
MATERIAL SAFETY DATA SHEET CND-N-118
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION:
OTHER STANDARD ABBREVIATIONS:
CAS No. Chemical Abstract Service Number
NA Not Available
EXPOSURE LIMITS IN AIR: NR No Results
NE Not Established
ACGIH American Conference on Governmental Industrial Hygienists
ND Not Determined
TLV Threshold Limit Value
ML Maximum Limit
OSHA U.S. Occupational Safety and Health Administration
SCBA Self-Contained Breathing Apparatus
PEL Permissible Exposure Limit
IDLH Immediately Dangerous to Life and Health NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
FLAMMABILITY
REACTIVITY
HAZARD RATINGS:
FIRST AID MEASURES:
0 Minimal Hazard
Cardiopulmonary resuscitation - method in which a person
1 Slight Hazard
whose heart has stopped receives manual chest compressions
CPR 2 Moderate Hazard
and breathing to circulate blood and provide oxygen to the
3 Severe Hazard
body.
4 Extreme Hazard SPECIAL
HEALTH
HMIS庐
PRECAUTIONS
ACD Acidic
HAZARDOUS MATERIALS IDENTIFICATION
SYSTEM: HMIS ALK Alkaline
COR Corrosive
HEALTH
HEALTH, FLAMMABILITY & REACTIVITY RATINGS: W Use No Water
OX Oxidizer
0 Minimal Hazard
FLAMMABILITY
1 Slight Hazard
TOXICOLOGICAL INFORMATION:
2 Moderate Hazard
REACTIVITY
3 Severe Hazard Lethal Dose (solids & liquids) which kills 50% of the
LD50
4 Extreme Hazard exposed animals s
PERSONAL PROTECTION
Lethal concentration (gases) which kills 50% of the
LC50
NCCHL44T 漏 NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808
PERSONAL PROTECTION RATINGS: exposed animal
Concentration expressed in parts of material per million
ppm
parts
A G
TDlo Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
B H TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or toxic
TC, TCo, LClo, & LCo effects
IARC International Agency for Research on Cancer
C I
NTP National Toxicology Program
RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
D J
TLm Median threshold limit
log KOW or log KOC Coefficient of Oil/Water Distribution
E K
REGULATORY INFORMATION:
Consult your supervisor or S.O.P.
F X WHMIS Canadian Workplace Hazardous Material Information System
for special handling directions.
DOT U.S. Department of Transportation
TC Transport Canada
EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
Face Shield &
NDSL Canadian Non-Domestic Substance List
Safety Glasses Splash Goggles Gloves
Eye Protection
PSL Canadian Priority Substances List
TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
CPR Canada鈥檚 Controlled Product Regulations
Boots Synthetic Apron Full Suit Dust Respirator
EC INFORMATION:
Full Face
Dust & Vapor Airline
Vapor Respirator Respirator
Respirator Hood/Mask or
Note: the dotted circle indicates that this respiratory
protective equipment is required for high concentrations
or for large volume spills or releases of product. C E F N O T+ Xi Xn
Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
FLAMMABILITY LIMITS IN AIR:
WHMIS INFORMATION:
Autoignition Minimum temperature required to initiate combustion in air
Temperature with no other source of ignition
Lower Explosive Limit - lowest percent of vapor in air, by
LEL volume, that will explode or ignite in the presence of an
ignition source
Upper Explosive Limit - highest percent of vapor in air, by
A B C D1 D2 D3 E F
UEL volume, that will explode or ignite in the presence of an
Compressed Flammable Oxidizing Toxic Irritation Infectious Corrosive Reactive
ignition source
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