BondPak 7102 Adhesive Material Safety Data Sheet 1 of 12
MANUFACTURER:
BondPro Corporation Transportation Emergency
650 Brakke Drive Chemtrec: 800-424-9300
Hudson, WI 54016
Phone: 715-386-6206
Fax: 715-386-1462
ISSUSED: March 10, 2003
TRADE NAME:
BondPak 7102 Adhesive
This product is a kit which contains both the Part A and Part B
independently packaged in a duel cartridge syringe. An MSDS for each
of these components is included. Please do not separate the component
MSDSs from this cover page.
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. BONDPRO CORPORATION MAKES
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY
IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE
OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for
determining whether the BondPro Corporation product is fit for a
particular purpose and suitable for user鈥檚 methods of use or
application. Given the variety of factors that can affect the use and
application of a BondPro Corporation product, some of which are
uniquely within the user鈥檚 knowledge and control, it is essential that
the user evaluate the BondPro Corporation product to determine whether
it is fit for a particular purpose and suitable for user鈥檚 method of
use or application.
BondPro Corporation provides information in electronic form as a
service to its customers. Due to the remote possibility that
electronic transfer may have resulted in errors, omissions or
alterations in this information, BondPro Corporation makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from BondPro Corporation.
BondPak 7102 Adhesive Material Safety Data Sheet 2 of 12
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Page 1 of 5
MANUFACTURER:
BondPro Corporation Transportation Emergency
650 Brakke Drive Chemtrec: 800-424-9300
Hudson, WI 54016
Phone: 715-386-6206
Fax: 715-386-1462
May 30, 2001
TRADE NAME:
BondPro 7513 Adhesive part A
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCE DESCRIPTION CAS# PERCENT
SYNTHETIC RUBBER OLIGOMER TradeSecret 40 - 70
POLYFUNCTIONAL AZIRIDINE 64265-57-2 10 - 30
COMPLEXED AMINE/POLYOL BLEND TradeSecret 1.0 - 5.0
AMORPHOUS SILICA 7631-86-9 1.0 - 5.0
This material is not on EINECS and should be used in Europe only for
research purposes in order to establish its properties. The
components of this product are in compliance with the chemical
notification requirements of TSCA
SECTION 3. PHYSICAL DATA
BOILING POINT: N/A
VAPOR PRESSURE: < 0.1 mmHg
VAPOR DENSITY: N/D
EVAPORATION RATE: N/D
SOLUBILITY IN WATER: slight
SPECIFIC GRAVITY: 1.028 g/cc
PERCENT VOLATILE: 7.9 % by wt ASTM D2369 @110 C
pH: N/A
VISCOSITY: 25000 - 35000 centipoise
MELTING POINT: N/A
APPEARANCE AND ODOR:
Paste, WHITE, MILD ODOR
SECTION 4. FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: 223 F Setaflash
FLAMMABLE LIMITS - LEL: N/D
FLAMMABLE LIMITS - UEL: N/D
AUTOIGNITION TEMPERATURE: N/D
BondPak 7102 Adhesive Material Safety Data Sheet 3 of 12
BondPro 7513 Adhesive part A Page 2 of 5
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Not determined.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 2 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
OSHA FIRE HAZARD CLASS: Class II Combustible Liquid
SECTION 5. REACTIVITY DATA
STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Strong Acids, Heat.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Aldehydes,
Amine Compounds, Toxic Vapors, Gases or Particulates.
SECTION 6. ENVIRONMENTAL INFORMATION
SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Extinguish all ignition sources.
Contain spill. Cover with inorganic absorbent material. Cover with
water. Collect spilled material. Clean up residue. Place in a
closed container. Cloth or paper contaminated with adhesive should be
disposed of in a metal container, covered with water and container
sealed.
RECOMMENDED DISPOSAL:
Incinerate in an industrial or commercial facility. Do not dispose
of in a sanitary landfill.
ENVIRONMENTAL DATA:
Not applicable.
REGULATORY INFORMATION:
Volatile Organic Compounds: 81 gms/liter South Coast Air Quality Mgmt
Dist Method.
BondPak 7102 Adhesive Material Safety Data Sheet 4 of 12
BondPro 7513 Adhesive part A Page 3 of 5
VOC Less H2O & Exempt Solvents: 81 gms/liter South Coast Air Quality
Mgmt Dist Method.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity.
When components B & A are mixed at a 10:1 ratio, the specific gravity
of the mixture is 1.006 . The VOC content (less water and exempt
solvent) for the mixture is 218 g/l
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: No
SECTION 7. SUGGESTED FIRST AID
EYE CONTACT:
Immediately flush eyes with large amounts of water for at least 15
minutes. Get immediate medical attention.
SKIN CONTACT:
Immediately flush skin with large amounts of water. Remove
contaminated clothing. If irritation persists, call a physician. Wash
contaminated clothing before reuse.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
SECTION 8. PRECAUTIONARY INFORMATION
EYE PROTECTION:
Avoid eye contact. Wear safety glasses with side shields.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: butyl rubber, nitrile rubber, polyethylene, polyvinyl
alcohol.
RECOMMENDED VENTILATION:
Do not use in a confined area or areas with little or no air
movement. Provide appropriate local exhaust when product is heated.
Use in a well-ventilated area. If exhaust ventilation is not
adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors. half-mask organic vapor respirator, full-
face organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Wash hands after handling and before eating. Do not ingest.
BondPak 7102 Adhesive Material Safety Data Sheet 5 of 12
BondPro 7513 Adhesive part A Page 4 of 5
RECOMMENDED STORAGE:
Store away from acids. Store away from heat. Keep container dry.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed. Keep away from heat, sparks, open
flame, and other sources of ignition. Combustible liquid and vapor.
OTHER PRECAUTIONARY INFORMATION:
Not intended for consumer sale or use.
When equalizing plungers, prior to use, dispense unmixed adhesive
onto a clean, solvent-free, non-porous surface such as aluminum foil,
glass or a metal can. Do not dispense unmixed adhesive onto paper or
cloth towels or rags.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
SYNTHETIC RUBBER OLIGOMER NONE NONE NONE NONE
POLYFUNCTIONAL AZIRIDINE NONE NONE NONE NONE
COMPLEXED AMINE/POLYOL BLEND NONE NONE NONE NONE
AMORPHOUS SILICA 3 MG/M3 TWA CMRG
AS RESPIRABLE DUST
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer
to the potential contribution to the overall exposure by the cutaneous
route including mucous membrane and eye, either by airborne or, more
particularly, by direct contact with the substance. Vehicles can alter
skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- NONE: None Established
SECTION 9. HEALTH HAZARD DATA
EYE CONTACT:
Chemical Related Eye Burns (chemical corrosivity): signs/symptoms can
include cloudy appearance of the cornea, chemical burns, pain,
tearing, ulcers, impaired vision or loss of vision.
SKIN CONTACT:
Allergic Skin Reaction: signs/symptoms can include redness, swelling,
blistering, and itching.
Severe Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, itching, dryness,
cracking, blistering, and pain. May be absorbed through the skin and
produce effects similiar to those caused by inhalation and/or
ingestion.
INHALATION:
Health effects from inhalation are not expected unless product is
heated.
BondPak 7102 Adhesive Material Safety Data Sheet 6 of 12
BondPro 7513 Adhesive part A Page 5 of 5
Allergic Respiratory Reaction: signs/symptoms can include difficulty
breathing, wheezing, tightness of chest, and respiratory failure.
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin(jaundice) and
tenderness of upper abdomen.
IF SWALLOWED:
Illness may occur after a single swallowing of relatively large
quantities of this material.
Irritation of Gastrointestinal Tissues: signs/symptoms can include
pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and
blood in feces.
Liver Effects: signs/symptoms can include yellow skin(jaundice) and
tenderness of upper abdomen.
Abbreviations: N/D - Not Determined N/A - Not Applicable CA -
Approximately
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. BONDPRO CORPORATION MAKES
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY
IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE
OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for
determining whether the BondPro Corporation product is fit for a
particular purpose and suitable for user鈥檚 methods of use or
application. Given the variety of factors that can affect the use and
application of a BondPro
Corporation product, some of which are uniquely within the user鈥檚
knowledge and control, it is essential that the user evaluate the
BondPro Corporation product to determine whether it is fit for a
particular purpose and suitable for user鈥檚 method of use or
application.
BondPro Corporation provides information in electronic form as a
service to its customers. Due to the remote possibility that
electronic transfer may have resulted in errors, omissions or
alterations in this information, BondPro Corporation makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from BondPro
Corporation.
BondPak 7102 Adhesive Material Safety Data Sheet 7 of 12
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Page 1 of 6
MANUFACTURER:
BondPro Corporation Transportation Emergency
650 Brakke Drive Chemtrec: 800-424-9300
Hudson, WI 54016
Phone: 715-386-6206
Fax: 715-386-1462
ISSUED: May 16, 2001
TRADE NAME:
BondPak 7102 Adhesive part B Acrylic
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCE DESCRIPTION CAS# PERCENT
METHYL METHACRYLATE 80-62-6 40.0 - 60.0
synthetic polymer - Vendor
Trade Secret (V.T.S.) ++ TradeSecret 10.0 - 30.0
acrylic polymer - Vendor Trade
Secret (V.T.S.) ++ TradeSecret 5.0 - 10.0
METHACRYLIC ACID 79-41-4 5.0 - 10.0
++ Material is a trade secret of our supplier and the CAS number is
unknown to 3M.
This product contains the following toxic chemical or chemicals subject
to the reporting requirements of Section 313 of Title III of the
Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR
Part 372:
METHYL METHACRYLATE
SECTION 3. PHYSICAL DATA
BOILING POINT: 214.00 F
VAPOR PRESSURE: 29.0000 mmHg
@ 68F
VAPOR DENSITY: > 1.00 Air=1
EVAPORATION RATE: 3.0 BuOAc=1
SOLUBILITY IN WATER: moderate
SPECIFIC GRAVITY: 1.030 Water=1
PERCENT VOLATILE: 30.00 - 60.00 % by wt
pH: N/A
VISCOSITY: 40000 - 60000 centipoise
MELTING POINT -54 F
APPEARANCE & ODOR:
Paste, Off-white, pungent acrylic odor
BondPak 7102 Adhesive Material Safety Data Sheet 8 of 12
BondPak 7102 Adhesive part B Page 2 of 6
SECTION 4. FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: 51.00 F
FLAMMABLE LIMITS - LEL: 2.00 % by vol
FLAMMABLE LIMITS - UEL: 12.50 % by vol
AUTOIGNITION TEMPERATURE: N/D
EXTINGUISHING MEDIA:
Water, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
See Hazardous Decomposition section for products of combustion.
Vapors may travel long distances along the ground or floor to an
ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 3 REACTIVITY: 2
UNUSUAL REACTION HAZARD: none
SECTION 5. REACTIVITY DATA
STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Amines, Reducing Agents, Heat, Reactive Metals, Sparks and/or Flames.
Heat is generated during cure. Do not cure a mass larger than 50
grams in a confined space to prevent a premature reaction (exotherm)
with production of intense heat and smoke.
HAZARDOUS POLYMERIZATION: Hazardous polymerization may occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Toxic Vapors,
Gases or Particulates
SECTION 6. ENVIRONMENTAL INFORMATION
SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Collect spilled material. Place in an approved
metal container.
BondPak 7102 Adhesive Material Safety Data Sheet 9 of 12
BondPak 7102 Adhesive part B Page 3 of 6
RECOMMENDED DISPOSAL:
Incinerate in an industrial or commercial facility in the presence of
a combustible material. Dispose of completely cured (or polymerized)
material in a sanitary landfill.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 0.00 gms/liter.
VOC Less H2O & Exempt Solvents: 0.0 gms/liter.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity.
CERCLA/RCRA HAZARDOUS WASTE CODES: U162(METHYL METHACRYLATE).
CERCLA REPORTABLE QUANTITY: 100 POUNDS
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
SECTION 7. SUGGESTED FIRST AID
EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Wash affected area with soap and water.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If signs/symptoms
continue, call a physician.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
SECTION 8. PRECAUTIONARY INFORMATION
EYE PROTECTION:
Avoid eye contact. Wear ventilated goggles. Where safety Glasses with
side shields.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: butyl rubber, polyvinyl alcohol, fluoroelastomer
(Viton).
BondPak 7102 Adhesive Material Safety Data Sheet 10 of 12
BondPak 7102 Adhesive part B Page 4 of 6
RECOMMENDED VENTILATION:
Curing ovens must be exhausted to outdoors or to a suitable emission
control device. If exhaust ventilation is not adequate, use
appropriate respiratory protection. Provide ventilation adequate to
control vapor concentrations below recommended exposure limits and/or
control spray or mist.
RESPIRATORY PROTECTION:
Avoid breathing of vapors created during the cure cycle. Avoid
prolonged breathing of vapors. Avoid breathing of dust created by
cutting, sanding or grinding. Select one of the following NIOSH
approved respirators based on airborne concentration of contaminants
and in accordance with OSHA regulations: half-mask dust respirator,
half-mask organic vapor respirator, full-face organic vapor
respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Wash hands after handling and before eating. Do not ingest.
RECOMMENDED STORAGE:
Store in a cool place. Store away from acids. Store away from heat.
Keep container dry. Keep container in well-ventilated area. Keep
out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed.
Keep container tightly closed. Flammable liquid and vapor. Keep
away from heat, sparks, open flame, and other sources of ignition.
No smoking while handling this material. Do not heat under
confinement.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
METHYL METHACRYLATE 100 PPM TWA OSHA
METHYL METHACRYLATE 50 PPM TWA ACGIH
SENSITIZER
METHYL METHACRYLATE 100 PPM STEL ACGIH
SENSITIZER
synthetic polymer - Vendor
Trade Secret (V.T.S.) ++ NONE NONE NONE NONE
acrylic polymer - Vendor
Trade Secret (V.T.S.) ++ NONE NONE NONE NONE
METHACRYLIC ACID 20 PPM TWA ACGIH
METHACRYLIC ACID 20 PPM TWA OSHA Y
*SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer
to the potential contribution to the overall exposure by the cutaneous
route including mucous membrane and eye, either by airborne or, more
particularly, by direct contact with the substance. Vehicles can alter
skin absorption.
BondPak 7102 Adhesive Material Safety Data Sheet 11 of 12
BondPak 7102 Adhesive part B Page 5 of 6
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- OSHA: Occupational Safety and Health Administration
- NONE: None Established
SECTION 9. HEALTH HAZARD DATA
EYE CONTACT:
Moderate Eye Irritation : signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
Vapors from heated material may cause eye irritation.
Dust created by cutting, grinding, sanding, or machining may cause eye
irritation.
SKIN CONTACT:
Allergic Skin Reaction: signs/symptoms can include redness, swelling,
blistering, and itching.
Mild Skin Irritation: signs/symptoms can include redness, swelling, and
itching.
INHALATION:
Illness may occur after a single overexposure by inhalation to
relatively large quantities of this material.
Nervous System Effects: signs/symptoms can include emotional changes,
lack of coordination, tremors and sensory loss.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
Vapors of heated material may cause respiratory system irritation.
Dust from cutting, grinding, sanding or machining may cause
irritation of the respiratory system.
IF SWALLOWED:
Irritation of Gastrointestinal Tissues: signs/symptoms can include
pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and
blood in feces.
REPRODUCTIVE/DEVELOPMENTAL TOXINS:
METHACRYLIC ACID (79-41-4) is a suspected reproductive hazard causing
birth defects and delayed development to rat embryo's in ex-vivo
exposure studies. Correlation to airborne or ingested doses, in
regard to typical exposures, are inconclusive.
METHYL METHACRYLATE (80-62-6) is not classifiable as to its potential
reproductive effects in humans.
Abbreviations: N/D - Not Determined N/A - Not Applicable CA -
Approximately
BondPak 7102 Adhesive Material Safety Data Sheet 12 of 12
BondPak 7102 Adhesive part B Page 6 of 6
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. BONDPRO CORPORATION MAKES
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY
IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE
OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for
determining whether the BondPro Corporation product is fit for a
particular purpose and suitable for user鈥檚 methods of use or
application. Given the variety of factors that can affect the use and
application of a BondPro
Corporation product, some of which are uniquely within the user鈥檚
knowledge and control, it is essential that the user evaluate the
BondPro Corporation product to determine whether it is fit for a
particular purpose and suitable for user鈥檚 method of use or
application.
BondPro Corporation provides information in electronic form as a
service to its customers. Due to the remote possibility that
electronic transfer may have resulted in errors, omissions or
alterations in this information, BondPro Corporation makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from BondPro Corporation.
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