MATERIAL SAFETY DATA SHEET
Control Solutions, Inc.
5903 Genoa-Red Bluff
Pasadena, TX 77507-1041
Phone: 281-892-2500 (8:00am-5:00pm, M-F) Issue Date: 06/27/07
Chemtrec: (800) 424-9300
Section 1 Name & Hazard Summary
Material name: Cyonara 9.7 Insecticide
Hazard summary (as defined by OSHA Hazard Comm. Std., 29 CFR 1910.1200):
Physical hazards: None.
Health hazards: Irritant (eye, skin, respiratory passages, skin sensitizer).
Read the entire MSDS for a more thorough evaluation of the hazards.
Section 2
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INGREDIENTS ACGIH TLV
***Lambda-cyhalothrin (PP321 Technical) (CAS 91465-08-6) 9.7 Not listed
Other ingredients 90.3
Ingredients not precisely identified are proprietary or non-hazardous. Values are not product
specifications.
Section 3 PHYSICAL DATA
Appearance and odor: White viscous liquid mild odor
pH: 5.31
Specific gravity/Bulk Density: 1.048 g/ml
Viscosity: 162.702 (20掳 C) and 78.676 (40掳 C) centistokes
Section 4 FIRE AND EXPLOSION HAZARD DATA
Flash point: Not applicable
Autoignition temperature: No data
Flammable limits (STP): Not applicable
Extinguishing media:
Water fog, foam, carbon dioxide, dry chemical, halogenated agents.
Special fire fighting protective equipment:
Self-contained breathing apparatus with full facepiece and protective clothing.
Unusual fire and explosion hazards:
Possible toxic smoke, vapors, fallout and runoff water can result from fires depending on
extent of combustion and presence of other combustible materials. Contaminated
buildings, areas, and equipment must be properly decontaminated before reuse.
Section 5 REACTIVITY DATA
Stability: Stable under normal conditions.
Incompatibility: Oxidizing agents, alkalies, calcium hypochlorite.
Hazardous decomposition products: Combustion products: Carbon dioxide, carbon monoxide. Nitrogen oxides,
ammonia, cyanuric acid, biuret. Halogen, halogen acids, possible trace amounts of carbonyl halide.
Hazardous polymerization: Will not occur.
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Section 6 HEALTH HAZARD ASSESSMENT
General:
Toxicity data are available on this specific product; this health hazard assessment is
based on the results of screening tests.
Ingestion:
The acute oral toxicity in rat is greater than 300 mg/kg. This material is classified as
鈥渕oderately toxic鈥? by ingestion.
Eye contact:
A 2% v/v spray strength dilution was tested using three rabbits. No corneal or iridial
effects. Mild irritation may occur following exposure to this material.
Skin Contact:
This material is moderately irritating in rabbit dermal irritation studies. Short contact
periods with human skin will probably not produce irritation. This material was determined not to
be a skin sensitizer.
Skin absorption:
The acute dermal toxicity is >5000 mg/kg for this material. Systemically toxic
concentrations of this product will not be absorbed through human skin.
Inhalation:
The inhalation toxicity in rat is >2.02 mg/1. Particulates of this material will probably
irritate respiratory passages.
Other effects of overexposure:
Studies using laboratory animals exposed to high levels of the active ingredient
lambda-cyhalothrin have shown that lambda-cyhalothrin may induce neurotoxic effects
such as staggering gait, muscle tremors and convulsions.
First aid procedures:
FIRST AID
Have the product container or label with you when calling a poison control center or doctor, or
going for treatment. You may also contact SafetyCall庐 International (866) 897-8050 for emergency
medical treatment information.
鈥?
If swallowed Call poison control center or doctor immediately for treatment advice.
鈥? Have person sip a glass of water if able to swallow.
鈥? Do not induce vomiting unless directed to do so by a poison control
center or doctor.
鈥? Do not give anything by mouth to an unconscious person.
鈥?
If on skin or Take off contaminated clothing.
鈥?
clothing Rinse skin immediately with plenty of water for 15-20 minutes.
鈥? Call a poison control center or doctor for treatment advice.
鈥?
If inhaled Move person to fresh air.
鈥? If person is not breathing, give artificial respiration, preferably mouth to
mouth if possible.
鈥? Call a poison control center or doctor for further treatment advice.
鈥?
If in eyes Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Remove contact lenses, if present, after the first 5 minutes, then continue
rinsing eye.
鈥? Call a poison control center or doctor for treatment advice.
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Section 7 SPILL OR LEAK PROCEDURES
Steps to be taken in case material is released or spilled:
This material is harmful to aquatic organisms. Releases to natural waters should be
reported to appropriate water pollution control authorities. Releases of untreated
effluent to the sewer should be immediately reported to the public treatment works.
Make sure all personnel involved in the spill cleanup follow good industrial hygiene
practices. A small spill can be handled routinely. Use adequate ventilation to prevent
inhalation. Wear suitable protective clothing and eye protection to prevent skin and eye contact. Use the
following procedures:
1. Do not allow material to enter streams, sewers or other waterways.
2. Spread absorbent on the liquid such as clay, sand, sawdust, or dirt. Sweep up and place in a suitable container
for disposal and label the contents.
3. Rinse with a small amount of water and use absorbent to collect the wash solution. Absorb any excess liquid
as indicated above, and add to the disposal container.
4. Seal drum and dispose of contaminated material in a facility permitted for hazardous waste. Large spills
should be handled according to a spill plan. Otherwise, in case of emergency call, day or night, 800-424-9300
(Chemtrec).
Disposal method:
This material is toxic to fish. Do not contaminate waterways by cleaning of equipment or
by disposal of wastes. Untreated effluent should not be discharged where it will drain
into lakes, streams, or ponds. Discarded product is not a hazardous waste under RCRA,
40 CFR 261.
Container disposal:
Observe all hazard precautions. Do not distribute, make available, furnish or reuse empty containers. Triple rinse
(or equivalent). Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill or
incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke.
Section 8 SPECIAL PROTECTION INFORMATION
TLV庐 or suggested control value:
No ACGIH TLV or OSHA PEL is assigned to this mixture. Control of exposure to
below the PEL for the ingredients (see Section 2) may not be sufficient. Minimize
exposure in accordance with good hygiene practice. The manufacturer of the
solvent recommends an exposure limit of 50 ppm as an 8-hr TWA.
Ventilation:
Manufacturing: Provide general and/or local exhaust ventilation to control airborne
levels below the exposure guidelines.
End Use: Generally not required when treatment dilution is used but local exhaust or
ventilation may be used if necessary.
Respiratory protection: Not normally needed for this product when diluted in
water for end-use application. When needed, use MSHA/NIOSH approved respirator
for pesticides.
Protective clothing:
Chemical resistant gloves, long pants, long-sleeved shit. Remove and wash contaminated clothing before reuse.
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Wash separately from other laundry.
Eye protection:
Eye contact with the material should be avoided through the use of chemical
safety glasses, goggles or a faceshield, selected in regard to exposure potential.
Other protective equipment:
An adequate supply of clean potable water should be available to allow thorough
flushing of skin and eyes in event of contact with this compound.
Section 9 SPECIAL PRECAUTIONS OR OTHER COMMENTS
Special precautions or other comments:
Observe OSHA PEL limitations. Avoid breathing
vapors. A sensitized individual should not be exposed to the product
which caused the sensitization. Do not store near feed, food, or within the
reach of children. Containers should be stored in a cool, dry, well-ventilated
area away from flammable materials and sources of heat or flame. Exercise
due caution to prevent damage to or leakage from the container. Workers
must follow good hygiene practices to avoid accidental ingestion.
Section 10 SHIPPING INFORMATION
DOT Classification for Ground Transport (Domestic)
Non bulk, combination package (6x1 qt): Consumer Commodity ORM-D
Containers greater than 5.0L (1.3 gallons):
Proper Shipping Name: Pyrethroid pesticide, liquid, toxic (Lambda-Cyhalothrin)
Hazard Class or Division: Class 6.1
Identification Number: UN3352
Packing Group: PG III
Transport by air (IATA)
Non bulk, combination package (6x1 qt)
Proper shipping name: Consumer Commodity, (Lambda-Cyhalothrin 9.7%), 9, UN-8000,
Packing Authorization: 910
(Passenger Aircraft)
Containers with max qty 2.0L inner pack or single pack max qty 60L
Proper Shipping Name: Pyrethroid pesticide, liquid, toxic (Lambda-Cyhalothrin 9.7%)
Hazard Class or Division: Class 6.1
Identification Number: UN3352
Packing Group: PG III
Packing Authorization: 611
Containers greater than 60L, restricted to cargo aircraft
Containers greater than 220L, prohibited
Transport by water (IMDG)
Proper Shipping Name: Pyrethroid pesticide, liquid, toxic (Lambda-Cyhalothrin 9.7%), Marine Pollutant
Hazard Class or Division: Class 6.1
Identification Number: UN3352
Packing Group: PG III
IMDG EMS #: F-A, S-A
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Section 11 REGULATORY INFORMATION
TSCA (Toxic Substances Control Act) Regulations, 40CFR 710:
This product is a pesticide and is exempt from TSCA regulation.
CERCLA and SARA Regulations (40 CFR 355, 370, and 372):
This product does not contain any chemicals subject to the reporting requirements of
SARA Section 313.
Other Determined Regulations:
EPA Reg. No.: 53883-145
Other Information:
We assigned NFPA and HMIS ratings to this product based on the hazards of its
ingredient (s). Because the customer is most aware of the application of the product,
he must ensure that the proper personal protective equipment (PPE) is provided
consistent with information contained in the product MSDS.*
NFPA HMIS
1 Health 2 Health
0 Flammability 0 Flammability
0 Reactivity 0 Reactivity
PPE1
Special Hazards
*This information is intended solely for the use of individuals trained in the particular
hazard rating system.
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See appropriate MSDA section
The information herein is given in good faith but no warranty, expressed or implied, is made.
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