MATERIAL SAFETY DATA SHEET
NURELLE-D 505
1. COMPANY IDENTIFICATION
DE-NOCIL CROP PROTECTION PVT. LIMITED EHS Delivery Leader ,
Contact Person In
Reg. Office : Ist Floor, Unit No. 1, Corporate Park, Lote Plant
Emergency
V.N. Purav Marg, Chembur, Mumbai 400 071.
The District Collector
Local Bodies Involved
PET bottles in CFB box.
Standard Packing
Phone : 91-22-55985700, Fax : 91-22-55985790
PLANT : A-1, Lote-Parshuram Industrial Area, Lote, Relevant DE-NOCIL Tremcard
Tremcard Details / Ref.
Taluka - Khed, Dist.- Ratnagiri. 415 722. ---
Others
Tel. (02356) 72046 , Fax - (02356) 72310 ; (02356) 72042
2. CHEMICAL IDENTITY
Nurelle-D 505
[(RS)-伪-Cyano-3-phenoxybenzyl- (1-RS)-
Chemical Name Trade Name
cis, trans-3-(2,2-dichlorovinyl)- 2,2- Mixture of
Chemical
dimethyl cyclopropane carboxylate] +
organophosphate &
Classification
{0,0-Diethyl 0-(3,5,6-trichloro 2-pyridyl)
Synthetic Pyrethroid
Phosphorothioate
Pesticide.
2921-88-2
Synonyms CAS Number
52315-07-8
Mixture 6.1 , 3
Chemical Formula U. N. Hazard Class
DNA 663
U.N. Number ADR H.I.N.
DNA
HAZCHEM code (E.A.C.)
HAZARDOUS INGREDIENTS
REGULATED IDENTIFICATION CAS No.
Poison 1. Cypermethrin 52315-07-8
Shipping Name
6.1 , 3 2. Chlorpyrifos 2921-88-2
Shipping Code/ Label
Hazardous Waste ID No. 15 3. O-Xylene 1330-20-7
Uses : - Photostable Pyrethroid insecticide.
3. PHYSICAL AND CHEMICAL DATA
Boiling Point/Range oC Yellowish clear
DNA Liquid
Physical State Appearance
Melting/Freezing Point oC < -5 DNA Xylene like
Vapour Pressure Odour
at 20 oC , N/m2
3.7 Forms Other Information : -
Vapour Density (Air=1) Solubility in water
at 30 oC emulsion
Specific Gravity at 20 oC 1.1 Not
pH
Pertinent
Water = 1
4. FIRE AND EXPLOSION HAZARD DATA
Flash Point oC 34 Flammability LEL % v DNA TDG Flammability 3
CC
--
OC UEL % v
No Explosion Sensitivity to Yes DNA
Explosion sensitivity Auto ignition Temp.
to impact Static Electricity
Yes No No
Combustible Material Explosive Material Hazardous Polymerization
No No No
Flammable Material Oxidizer Corrosive Material
No No Other Information :- Decomposes at 220 oC
Pyrophoric Material Organic Peroxide
Toxic fumes of CN-, Cl- , SOx and NOX
Hazardous Combustion Products
5. REACTIVITY DATA
Stable under normal conditions
Chemical Stability
Strong Oxidizers such as nitrates, perchlorates, conc. H2SO4
Incompatibility With Other Material
None.
Reactivity
None.
Hazardous Reaction Products
DOW RESTRICTED - For internal use only
Prepared By :- Madhav Paranjape DE-NOCIL CONFIDENTIAL Revision 00
Date :- 01st November 1999
Checked By :- EHS Delivery Leader Page 1 of 3
NURELLE-D 505
6. HEALTH HAZARD DATA
1. Absorption through Skin 2. Inhalation 3. Ingestion
Route Of Entry
High vapour concentration may cause irritation of eyes, skin & mucous membrane.
Effects Of Exposure / Symptoms
Headache, nausea & narcosis. Ingestion may be fatal.
Refer section 8 for first aid. Obtain medical attention immediately.
Emergency Treatment
0.2 mg/m 3 for CHP DNA
TLV-TWA(ACGIH) STEL(ACGIH)
Permissible Exposure Limits
435 mg/m 3for
xylene.
DNA DNA
IDLH Odour threshold
LD50 Oral Rat : 230 mg/Kg
LD50 Rabbit : >2000 mg/Kg
Health - (2) Flammability - (3) Reactivity - (0) Special - (--)
NFPA Hazard Signals
7. PREVENTIVE MEASURES
Use PVC or Rubber gloves, apron, gum-boots, goggles / face shield and overalls. Use
PERSONAL PROTECTIVE
breathing apparatus if required.
EQUIPMENTS
Store in cool, clean, ventilated, fireproof storage area. Keep away from heat, spark, open
HANDLING AND
flame and incompatible materials. (Strong oxidizing agents ). Protect containers against
STORAGE PRECAUTIONS
physical damage.
8. EMERGENCY AND FIRST AID MEASURES
FIRE (Class Of Fire : B )
Alcohol resistant foam or dry agent (CO2, Dry chemical powder). Spray water to cool
Fire Extinguishing Media
adjacent containers.
Prevent any contaminated water runoff to sewers or water sources.
Special Procedures
None.
Unusual Hazard
EXPOSURE
Eyes : Flush with plenty of water for at-least 15 min.
First Aid
Skin : Remove contaminated clothing and wash affected part with Soap and water
Measures Inhalation : Remove victim to fresh air. If not breathing, give artificial respiration.
Ingestion : If conscious have victim drink water or milk. DO NOT induce vomiting.
Obtain Medical Attention Immediately
Inject atropine IV or IM (0.4-2.0 mg/Kg.) every 15 min. until atropinised or universal antidote (A
Antidotes / Dosage
mixture containing 2 parts activated charcoal, 1 part MgO and 1 part tannic acid in 300 ml warm water.
No specific antidote for pyrethroids. Treat symptomatically
SPILLS
Stop leak if safe to do so. Contain spillage. Absorb in earth or sand for disposal. Eliminate all sources
Steps To Be
of ignition. Cordon off area. Stay upwind. Use personal protective equipment.
Taken
Incinerate. Detoxify the contaminated area.
Waste Disposal
Method
9. ADDITIONAL INFORMATION / REFERENCES
ECOLOGICAL INFORMATION
Avian oral toxicity : Mallard duck 76.6 mg/Kg. Toxic to bees.
Ecotoxicity
Aquatic Toxicity : 3.0 ppm / Rainbow trout /TLm/fresh water.
Cypermethrin : Slowly hydrolyses in water. Hydrolyses rapidly in alkaline media.
Persistence
Chlorpyriphos : Half life period in natural water at 25掳C & pH=8.0 is 1.5 days.
OTHER INFORMATION It is highly toxic substance.
REFERENCES (For Obtaining More Information)
1. Hazardous Chemical Data Book: G. Weiss : Noyes data corp. USA 4. Handbook of Environmental Data : Keren Verschueren :
2. Dangerous properties of Industrial Materials : Van Nostrand Reinhold Co. , USA
N.I. Sax : Van Nostrand Reinhold Co. , USA 5. Toxic & hazardous Industrial Chemical Safety Manual : The
3. The Sigma Aldrich Library of Chemical Safety Data : international technical institute , Tokyo, JAPAN
Sigma Aldrich Corporation , USA 6. Occupational Safety And Health Guidelines For Chemical
Hazards: NIOSH/OSHA: U.S. Dept. Of health & Human
Services And U.S. Dept. Of labour , USA.
10. DISCLAIMER
Information in this Material Safety Data Sheet is believed to be reliable but no representation, guarantee or warranties of any kind are
made as to its accuracy, suitability for a particular application or results to be obtained from them. It is upto the User/Distributor to
ensure that the information contained in the Material Safety Data Sheet is relevant to the product manufactured / handled or sold by
DOW RESTRICTED - For internal use only
Prepared By :- Madhav Paranjape DE-NOCIL CONFIDENTIAL Revision 00
Date :- 01st November 1999
Checked By :- EHS Delivery Leader Page 2 of 3
him as the case may be. DE-NOCIL makes no warranties, expressed or implied, in respect of the accuracy of this document for any
particular purpose.
DOW RESTRICTED - For internal use only
Prepared By :- Madhav Paranjape DE-NOCIL CONFIDENTIAL Revision 00
Date :- 01st November 1999
Checked By :- EHS Delivery Leader Page 3 of 3
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