3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Instant Adhesive CA-100 08/03/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Scotch-Weld(TM) Instant Adhesive CA-100
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 08/03/2004
Supercedes Date: 05/29/2001
Document Group: 11-2664-8
Product Use:
Intended Use: Structural Strength Instant Adhesive.
Specific Use: Cyanoacrylate Adhesive.
Formerly know as 3M(TM) Pronto(TM) Instant Adhesive CA-100
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
ETHYL CYANOACRYLATE 7085-85-0 60 - 100
POLY(METHYL METHACRYLATE) 9011-14-7 10 - 30
HYDROQUINONE 123-31-9 0.1 - 0.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Viscous Liquid
Odor, Color, Grade: Clear, colorless, sharp irritating odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Combustible liquid and
vapor. Hazardous polymerization may occur. May cause severe eye irritation. May cause allergic skin reaction. May bond
tissue rapidly.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Instant Adhesive CA-100 08/03/2004
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Bonds eyelids rapidly.
Skin Contact:
Bonds skin rapidly.
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. DO
NOT force eyelids open.
Skin Contact: FOR SKIN BONDS: Quickly soak in warm water and avoid use of excessive force to free bonded area. If
unable to free bonded area, or if lips or mouth are bonded, get medical attention. If irritation persists, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Instant Adhesive CA-100 08/03/2004
No Data Available
Autoignition temperature
185 潞F [Test Method: Tagliabue Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Vapors may
travel long distances along the ground or floor to an ignition source and flash back. Combustible liquid and vapor.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by
qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Collect as much of the spilled material as
possible using non-sparking tools. Collect as much of the spilled material as possible. Place in a closed container approved for
transportation by appropriate authorities. DO NOT wipe spill or residue with cleanup materials containing cotton.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this
product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources
of ignition. Avoid contact with oxidizing agents. Keep out of the reach of children.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Store away from
flammable and combustible materials. Keep container tightly closed.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Do not use in a confined area or areas with little or no air movement. Use general
dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Instant Adhesive CA-100 08/03/2004
control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Butyl Rubber, Polyvinyl Alcohol (PVA), Polyethylene/Ethylene
Vinyl Alcohol. The following protective clothing material(s) are recommended: Apron - Polyethylene ethylene vinyl alcohol. DO
NOT wear cotton gloves.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece air-purifying respirator with organic vapor cartridges and N95 particulate prefilters. Consult the
current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ETHYL CYANOACRYLATE ACGIH TWA 0.2 ppm
HYDROQUINONE ACGIH TWA 2 mg/m3 Table A3
HYDROQUINONE CMRG STEL 4 mg/m3
HYDROQUINONE OSHA TWA 2 mg/m3 Table Z-1
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Viscous Liquid
Specific Physical Form:
Clear, colorless, sharp irritating odor
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
185 潞F [Test Method: Tagliabue Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
149.00 潞F [@ 6 mmHg]
Boiling point
1.05 g/ml
Density
No Data Available
Vapor Density
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Instant Adhesive CA-100 08/03/2004
1.0 mmHg [@ 20 潞C]
Vapor Pressure
1.05 [Ref Std: WATER=1]
Specific Gravity
Nil
Solubility in Water
Negligible
Evaporation rate
No Data Available
Kow - Oct/Water partition coef
0.0 % weight
Percent volatile
No Data Available
VOC Less H2O & Exempt Solvents
2500 - 4500 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong bases; Amines
Hazardous Polymerization: Hazardous polymerization may occur. Additional Information: May occur in large quantities only.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Oxides of Nitrogen During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Reclaim if feasible. Dispose of completely cured (or polymerized) wastes in a sanitary landfill.
Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to accept
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Instant Adhesive CA-100 08/03/2004
chemical waste.
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
62-3873-0330-8, 62-3873-0335-7, 62-3873-3830-4
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Instant Adhesive CA-100 08/03/2004
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 2 Reactivity: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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