Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SUPERTOX SL188,5 4X5L JUG GB 1/8
Version 2 / GB Revision Date: 05.04.2006
102000001997 Print Date: 24.04.2006
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name SUPERTOX SL188,5 4X5L JUG GB
Product code (UVP) 05928397
Usage herbicide
Company Bayer Environmental Science
230 Cambridge Science Park
Milton Road
Cambridge
Cambridgeshire CB4 0WB
Great Britain
Telephone +44(0)1223 226500
Telefax +44(0)1223 426240
Emergency telephone number 0800-220876 (UK 24 hr)
+44(0)1603-242424 (Overseas 24 hr)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Soluble concentrate (SL)
CMPP-P/2,4-D 95:93.5 g/l
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Mecoprop-P-diethanolamine Xn, N R22, R38, 13.00
salt R41, R50/53
2,4-D diethanolamine salt 5742-19-8 Xn, N R22, R41, 12.80
R43, R51/53
Diethanolamine 111-42-2 Xn R22, R38, > 1.00 - < 5.00
203-868-0 R41, R48/22
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Harmful if swallowed.
Risk of serious damage to eyes.
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice
Remove contaminated clothing immediately and dispose of safely.
Inhalation
Move to fresh air. Keep patient warm and at rest. If symptoms persist, call a physician.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SUPERTOX SL188,5 4X5L JUG GB 2/8
Version 2 / GB Revision Date: 05.04.2006
102000001997 Print Date: 24.04.2006
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact
In case of contact with eyes rinse thoroughly with water. Get medical attention if irritation
develops and persists.
Ingestion
Do not induce vomiting. Keep at rest. Rinse mouth. Obtain medical attention.
Notes to Physician
Symptoms
Local:, The product causes irritation of eyes, skin and mucous membranes.
Symptoms
Systemic:, To date no symptoms are known.
Treatment
Local treatment:
Initial treatment should be symptomatic and supportive.
Treatment
Systemic treatment:
In the event of a mouthful or more being ingested, the following measures should be
considered:
Gastric lavage with charcoal, if necessary further treatment.
Observe specific parameters: blood pressure, levels of 2,4-D in plasma and urine, pH in urine.
Observe specific parameters: blood pressure, levels of mecoprop in plasma and urine, pH in
urine.
Elimination by dialysis (forced alkaline diuresis).
There is no specific antidote.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media which must not be used for safety reasons
high volume water jet
Specific hazards during fire fighting
In case of fire the evolution of dangerous gases is possible.
Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Remove product from areas of fire, or otherwise cool containers with water in order to avoid
pressure being built up due to heat.
Whenever possible, contain fire-fighting water by diking area with sand or earth.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Keep people away from and upwind of spill/leak.
Avoid contact with spilled product or contaminated surfaces.
When dealing with a spillage do not eat, drink or smoke.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SUPERTOX SL188,5 4X5L JUG GB 3/8
Version 2 / GB Revision Date: 05.04.2006
102000001997 Print Date: 24.04.2006
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
If spillage enters drains leading to sewage works inform local water company immediately.
If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone
number 0800 807060).
Methods for Cleaning Up
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material).
Keep in suitable, closed containers for disposal.
Clean floors and contaminated objects with plenty of water.
Additional Advice
Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
Check also for any local site procedures.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
No specific precautions required when handling unopened packs/containers; follow relevant
manual handling advice.
Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion
No special precautions required.
Storage
Requirements for storage areas and containers
Keep containers tightly closed in a cool, well-ventilated place.
Store in a place accessible by authorized persons only.
Keep away from direct sunlight.
Protect against frost.
Storage stability
Storage temperature 0 - 30 掳C
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment)
Regulations 2004). Engineering controls should be used in preference to personal
protective equipment wherever practicable. Refer also to COSHH Essentials.
Personal protective equipment
Respiratory Protection No personal respiratory protective equipment normally required.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SUPERTOX SL188,5 4X5L JUG GB 4/8
Version 2 / GB Revision Date: 05.04.2006
102000001997 Print Date: 24.04.2006
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
Skin and body protection Wear standard coverall and type 3 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
Hygiene measures
When using, do not eat, drink or smoke.
Remove soaked protective clothing immediately.
Remove soiled clothing immediately.
Clean hands and face at work intervals and after work.
Work in an adequately ventilated room.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Colour orange to brown
Odour characteristic
Safety data
pH 8.0 - 9.0
Determined in the undiluted form.
Density ca. 1.077 g/cm鲁 at 20 掳C
Water Solubility miscible
10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.
Materials to avoid None.
Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) > 200 - < 2,000 mg/kg
Acute Inhalation Toxicity LC50 (rat) > 20 mg/l
Exposure time: 4 h
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SUPERTOX SL188,5 4X5L JUG GB 5/8
Version 2 / GB Revision Date: 05.04.2006
102000001997 Print Date: 24.04.2006
Acute Dermal Toxicity LD50 (rat) > 2,000 mg/kg
Skin Irritation No skin irritation. (rabbit)
Eye Irritation Risk of serious damage to eyes. (rabbit)
Sensitization sensitizing (guinea pig)
Further information
Information given is based on data on the components and the toxicology of similar products.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects
Toxicity to Fish LC50 (Lepomis macrochirus (Bluegill sunfish)) > 100 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient mecoprop.
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) > 100 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient 2,4-D.
Toxicity to daphnia EC50 (Daphnia) > 100 mg/l
Exposure time: 48 h
The value mentioned relates to the active ingredient mecoprop.
Toxicity to algae EC50 (Pseudokirchneriella subcapitata) > 270 mg/l
Exposure time: 72 h
The value mentioned relates to the active ingredient mecoprop.
Toxicity to algae EC50 (Selenastrum capricornutum) 33.2 mg/l
Exposure time: 120 h
The value mentioned relates to the active ingredient 2,4-D.
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Advice may be obtained from the local waste regulation authority (part of the Environment
Agency in the UK).
Contaminated packaging
Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using an integrated pressure
rinsing device, or, by manually rinsing three times.
Add washings to sprayer at time of filling.
Dispose of empty and cleaned packaging safely.
Large containers (> 25 l or > 25 kg) should not be rinsed or re-used for any other purpose.
Return large containers to supplier.
Follow advice on product label and/or leaflet.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SUPERTOX SL188,5 4X5L JUG GB 6/8
Version 2 / GB Revision Date: 05.04.2006
102000001997 Print Date: 24.04.2006
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
3082
UN-No
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(MECOPROP-P-DIETHANOLAMINE SOLUTION)
IMDG
3082
UN-No
Class 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(MECOPROP-P-DIETHANOLAMINE SOLUTION )
IATA
3082
UN-No
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(MECOPROP-P-DIETHANOLAMINE SOLUTION )
UK 'Carriage' Regulations
3082
UN-No
Labels 9
Packaging group III
Hazard no. 90
Emergency action code 3Z
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(MECOPROP-P-DIETHANOLAMINE SOLUTION)
15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information and
Packaging for Supply) Regulations 2002: CHIP 3 and any subsequent amendments.
Classification:
Labelling according to EEC Directive
Hazardous components which must be listed on the label:
鈥? Mecoprop
鈥? 2,4-D
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SUPERTOX SL188,5 4X5L JUG GB 7/8
Version 2 / GB Revision Date: 05.04.2006
102000001997 Print Date: 24.04.2006
Symbol(s)
Xn Harmful
N Dangerous for the environment
R-phrase(s)
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S35 This material and its container must be disposed of in a safe way.
S37/39 Wear suitable gloves and eye/face protection.
S57 Use appropriate container to avoid environmental contamination.
CLASSIFICATION ACCORDING TO SPECIFIC UK REGULATIONS:
The labelling information below is that which has been approved under 'The Control of Pesticides
Regulations 1986' and/or 'Part III of the Food and Environment Protection Act 1985' and/or 'Plant
Protection Product Regulations 1999' and any subsequent amendments and may differ from that
indicated by any toxicological and/or other testing otherwise indicated in this 'Safety Data Sheet'.
Symbol(s)
Xn Harmful
R-phrase(s)
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S35 This material and its container must be disposed of in a safe way.
S37/39 Wear suitable gloves and eye/face protection.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: II (Moderately hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R22 Harmful if swallowed.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
Bayer Environmental Science
SAFETY DATA SHEET according to EC Directive 2001/58/EC
SUPERTOX SL188,5 4X5L JUG GB 8/8
Version 2 / GB Revision Date: 05.04.2006
102000001997 Print Date: 24.04.2006
R48/22 Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or policy in
force or arising from any risk assessment involving the substance or product should take precedence
over any of the guidance contained in this safety data sheet where there is a difference in the
information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account
of information or advice contained in this safety data sheet.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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