No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 1 of 9
COMPANY DETAILS
Name : First National Battery Emergency telephone no/ (043) 731-1111
Address : P.O. Box 182 POISON CENTRE: 0800 333 444 / 021 931 6129
East London, 5200 JHB METROPOLITAN EMERGENCY SERVICE: (011) 375 5911
Tel. : (043) 731-1111 Website : http://www.battery.co.za
Fax : (043) 731-2007
CONTACT: Dr. L. DENNER
MATERIAL SAFETY DATA SHEET
MINING ACCUMULATOR (OMF CAP LAMPS)
1. PRODUCTION IDENTIFICATION
TRADE NAME : Battery, wet, contains acid
: Mining Accumulator (OMF Cap Lamps)
PRODUCT FAMILY : Electric Storage Battery
UN NO. : 2794
CONTACT : Benoni / East London
Mr. Justin Ward
TELEPHONE NUMBER : 043 731 1111
POISON INFORMATION CENTRE : 0800 333 444 / 0219316129
JHB METROPOLITAN
EMERGENCY SERVICE : 011 375 5911
____________________________________________________________________________
2. COMPOSITION
AIR EXP LIMITS MG/M3
CHEMICAL TRADE HAZARDOUS CAS NO. % WT
NAME OSHA ACGIH NIOSH
Inorganic compounds of the negative grid:
Pb Lead Yes 7439-92-1 95% 0.05 0.15 0.1
Sb Antimony No 7440-36-0 5% 0.5 0.5 -
Inorganic compounds of the positive grid:
Pb Lead Yes 7439-92-1 95% 0.05 0.15 0.1
Sb Antimony Yes 7440-36-0 3.2% 0.5 0.5 -
Electrolyte:
H2SO4 Sulphuric Acid Yes 7664-93-9 *36% 1 1 1
*% of acid in electrolyte
Case Material:
Polycarbonate No 100% None listed
Lid Material:
ABS Acrylonitrite No 9003-56-9 100% None listed
Butadiene
Styrene
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No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 2 of 9
3. HAZARD IDENTIFICATION
MAIN HAZARD : Explosion / Corrosion
EXPLOSION HAZARDS : Hydrogen gas is liberated during the
operation of batteries. Keep other sources of
ignition away from batteries. Do not allow
metallic contact between terminals of opposite
polarity. Follow manufacturer鈥檚 instruction on
installation and service.
ROUTES OF ENTRY : Sulphuric Acid: Harmful by all routes of entry
Lead compounds: Hazardous exposure can
only occur only when product is heated, oxidised
or otherwise processed or damaged to create
dust, vapour or fume.
HEALTH EFFECTS
EYES : Sulphuric Acid: severe irritation, burns,
Cornea damage and blindness.
Lead Compounds: May cause eye irritation.
SKIN : Sulphuric Acid: Severe irritation, burns and
ulceration.
Lead compounds: Not absorbed through the
skin.
INGESTION : Sulphuric Acid: May cause severe irritation of
mouth, throat, oesophagus and stomach.
Lead Compounds: Acute ingestion may cause
abdominal pain, nausea, vomiting, diarrhoea and
severe cramping. This may lead to rapidly
systematic toxicity and must be treated by a
physician.
INHALATION : Sulphuric Acid: Breathing of sulphuric acid vapours
or mists may cause severe respiratory irritation.
Lead Compounds: Inhalation of lead dust or fumes
may cause irritation of upper respiratory tract and
lungs.
CARCINOGENICITY : Sulphuric Acid: The International Agency of
Research on Cancer (IARC) has classified 鈥渟trong
inorganic acid mist containing sulphuric acid鈥? as a
Category 1 carcinogen, a substance that is
carcinogenic to humans. This classification does not
apply to liquid forms of sulphuric acid solution
contained within a battery. Inorganic acid mist
(sulphuric acid mist) is not generated under normal
use of this product. Misuse of the product, such as
overcharging, may result in the generation of
sulphuric acid mist.
Lead Compounds: Lead is listed as a 2B
carcinogen, likely in animals at extreme doses.
Proof carcinogenicity in humans is lacking at
present.
No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 3 of 9
EFFECTS OF OVEREXPOSURE 鈥? ACUTE
Sulphuric Acid: Severe skin irritation, damage to
cornea upper respiratory function.
Lead Compounds: Symptoms of toxicity include
headaches, fatigue, abdominal pain, loss of appetite,
muscular aches and weakness, sleep disturbances
and irritability.
EFFECTS OF OVEREXPOSURE 鈥? CHRONIC
Sulphuric Acid: Possible erosion of tooth enamel,
inflammation of nose, throat and bronchial tubes.
Lead Compounds: Aneamia neuropathy,
particularly of the motor nerves, with wrist drop,
kidney damage, reproductive changes in males and
females.
MEDICAL CONDITIONS GENERALLY
AGGRAVATED BY EXPOSURE
Overexposure to sulphuric acid mist may cause lung
damage and aggravate pulmonary conditions.
Contact of sulphuric acid with skin may aggravate
skin diseases such as eczema and contact
dermatitis. Lead and its compound and aggravate
some forms of kidney, liver and neurological
diseases.
____________________________________________________________________________
4. FIRST AID MEASURES
PRODUCT IN EYES : Sulphuric Acid and Lead: Flush immediately with
large amounts of water for at least 15 minutes,
consult a physician.
PRODUCT ON SKIN : Sulphuric Acid: Flush with large amounts of water
for at least 15 minutes; remove contaminated
clothing completely including shoes.
Lead: Wash immediately with soap and water.
:
PRODUCT INGESTED Sulphuric Acid: Give large quantities of water; do
not induce vomiting, consult a physician.
Lead: Consult a physician immediately.
PRODUCT INHALED : Sulphuric Acid: Remove to fresh air. If breathing is
difficult give oxygen.
Lead: Remove from exposure, gargle, wash nose
and lips, consult physician.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA : CO2, foam or dry chemical. Flammable limits: LEL
= 4.1% (hydrogen gas) UEL = 74.2%.
No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 4 of 9
SPECIAL HAZARDS : If batteries are in charge, shut off power. Use
positive pressure, self contained breathing
water apparatus. Water applied to electrolyte
generates heat and causes it to splatter. High
flammable hydrogen gas is generated during
charging and operation of batteries. To avoid risk
fire or explosion, keep sparks or other sources of
ignition away from batteries. Do not allow metallic
materials to simultaneously contact negative and
positive terminals of cells and batteries. Follow
manufacturer鈥檚 instruction for installation and
service.
PROTECTIVE CLOTHING : APPARATUS EXTINGUISHING ACTION
MEDIA
Self contained CO2 foam, dry Check if batteries
Breathing apparatus chemical batteries are on
charge. Switch off
Power (in case
batteries are on
charge.
______________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS : Wear acid resistant clothing, boots, face-shield,
gloves. Do not allow discharge of unneutralised acid
to sewer.
ENVIRONMENTAL PRECAUTIONS : Spent batteries: Send to supplier (secondary lead
smelter) for recycling. Place neutralised slurry into
sealed containers and handle as applicable with
state and federal regulations. Large water-diluted
spills, after neutralisation and testing should be
managed in accordance with approved local, state
and federal requirements.
Large and small spills: Stop flow of material
contain/absorb small spills with dry sand, earth and
vermiculite. Do not use combustible materials. If
possible, carefully neutralise electrolyte with soda,
ash, sodium bicarbonate, lime etc.
7. HANDLING AND STORAGE
SUITABLE MATERIAL HANDLING/
STORAGE PRECAUTIONS : Store batteries in cool, dry well-ventilated areas with
impervious surfaces and adequate containment in
the event of spills. Batteries should also be stored
under roof for protection against adverse weather
conditions. Separate from incompatible materials.
Store and handle only in areas with adequate water
supply and spill control. Avoid damage to
containers. Keep away from fire, sparks and heat.
_______________________________________________________________________________
No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 5 of 9
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROL : Store and handle in well-ventilated areas. If
mechanical ventilation is used, components must be
acid resistant.
RESPIRTORY PROTECTION : None required under normal handling and conditions.
When concentrations of sulphuric acid mist are to
known to exceed PEL, use NIOSH or MSHA 鈥?
approved respiratory protection.
PERSONAL PROTECTION 鈥? HAND : Rubber or plastic acid-resistance gloves with elbow-
length gauntlet.
PERSONAL PROTECTION 鈥? EYE : Chemical goggles or face shield.
PERSONAL PROTECTION - SKIN : Acid resistant apron. Under severe exposure or
emergency conditions, wear acid-resistant clothing]
and boots.
OTHER PROTECTION : In areas where sulphuric acid is handled in
concentrations greater than 1%, emergency eyewash
stations should be provided, with unlimited water
supply. Handle batteries cautiously to avoid spills.
Make certain vent caps are on securely. Avoid
Contact with internal components. Wear protective
clothing when filling or handling batteries.
_______________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
COMPONENT BP SOLUBILITY APPEARANCE SG VAPOUR FLAMMABLE
IN H2O & ODOUR PRESSURE LIMITS
MmHg
H2 -253掳C None LEL=4.1%
UEL=76%
Sulphuric Acid 95-96掳C 100% Clear liquid with 1.245-1.255 10
Sharp pungent
Odour.
Reactivity:
Product : Stable
Storage : Cool, dry place (temp. approx 20掳C)
Testing : Do not exceed charge temperature of 45掳C in service. Normal operational temperature range for PB
acid batteries is 10-30掳C.
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10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID : Prolonged overcharge; sources of ignition.
No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 6 of 9
INCOMPATIBLE MATERIALS : Sulphuric Acid: Contact with combustibles and
organic materials may cause fire and explosion.
Also reacts violently with strong reducing agents,
metals, sulphur trioxide gas, strong oxidisers and
water. Contact with metals may produce toxic
sulphur dioxide fumes and my release flammable
hydrogen gas.
Lead Compounds: Avoid contact with strong acids
bases, halides, halogenates, potassium nitrate,
permanganate, peroxides, nascent hydrogen and
reducing agents.
HAZARDOUS DECOMPOSITION
PRODUCTS : Sulphuric Acid: Sulphur trioxide, carbon monoxide,
sulphuric acid mist, sulphur dioxide and hydrogen.
Lead Compounds: High temperatures likely to
produce toxic metal fume, vapour or dust, contact
with strong acid or bas or presence of nascent
hydrogen may generate highly toxic arsine gas.
CHEMICAL CHEMICAL DECOMPOSITION HAZARDOUS CHEMICAL BIOLOGICAL
H2SO4 Sulphur Trioxide } Combustible toxic fumes Toxic
(Sulphuric Acid) SO2 (Sulphuric Dioxide) } Toxic
Hydrogen (H2) Flammable Toxic
Sulphur Mist Flammable
Hydrogen Highly flammable gas. Fire/explosion hazard.
Sulphur Mist Biologically highly toxic gas.
Metal and vapour May produce other chemical side reactions. Toxic.
Sulphur dioxide Combustible toxic fumes 鈥? biological hazard.
_______________________________________________________________________________
11. TOXOCOLOGICAL INFORMATION
ACUTE TOXICITY : Acute effects of overexposure to lead compounds
are GI (gastrointestinal) upset, loss of appetite,
constipation with cramping, difficulty in sleeping and
fatigue. Exposure and/or contact with battery
electrolyte (acid) may lead to acute irritation of the
skin, corneal damage of the eyes, and irritation of
the mucous membranes of the eyes and upper
respiratory system including the lungs.
SKIN AND EYE CONTACT : Battery electrolyte (acid) may cause contact
dermatitis. Battery electrolyte (acid) will irritate the
eyes upon contact.
No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 7 of 9
CHRONIC TOXICITY : Lead and its compounds may cause chronic
anaemia, damage to the kidneys and nervous
system. Lead may also cause reproductive system
damage and can affect developing foetuses in
pregnant women. Battery electrolyte (acid) may lead
to scarring of the cornea, chronic bronchitis as well
as erosion of tooth enamel in mouth breathers in
repeated exposures.
CARCINOGINICITY : The International Agency for Research on Cancer
(IARC) has classified 鈥渟trong inorganic acid mist
containing sulphuric acid鈥? as a Category 1
carcinogen, a substance that is carcinogenic to
humans. The ACGIH has classified 鈥渟trong
inorganic acid mist containing sulphuric acid鈥? as an
A2 carcinogen (suspected human carcinogen).
These classifications do not apply to liquid forms of
sulphuric acid or sulphuric acid solutions contained
within a battery. Inorganic acid mist (Sulphuric acid
mist is not generated under normal use of this
product. Misuse of the product, such as
overcharging, may however, result in the generation
of sulphuric acid mist. The IARC study classified
lead as an A3 carcinogen (animal carcinogen).
While the agent is carcinogenic in experiment
animals at relatively high doses, the agent is unlikely
to cause cancer in humans except under
uncommonly high levels of exposure. For further
information, see
the ACGIH鈥檚 pamphlet, 1996. Threshold Limit
Values and Biological Exposure Indices.
MUTAGENICITY : Not known.
REPRODUCTIVE HAZARDS : Not known
_______________________________________________________________________________
12. ECOLOGICAL INFORMATION
AQUATIC TOXICITY :
Sulphuric Acid: Toxic to fish and algae
Concentrations of 100% sulphuric acid greater than
1.2 mg/L may be lethal to fish.
Lower pH below about 4 would induce fatalities in
aquatic life.
Lead Compounds: No specific data.
_______________________________________________________________________________
13 DISPOSAL INFORMATION
Undamaged and damaged batteries : Store in impervious inert container and return to
supplier for recycling.
_______________________________________________________________________________
No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 8 of 9
14. TRANSPORT INFORMATION
NFPA HAZARD RATING FOR SULPHURIC ACID:
Flammability (red) = 0
Health (blue) =3
Reactivity (yellow) = 2
Sulphuric acid is water reactive if concentrated.
U.S. DOT
The transportation of wet and moist charged (moist active) batteries within the continental United
States is regulated by the U.S. Dot through the Code of Federal Regulations, Title 49 (CFR 49).
These regulations classify these types of batteries as a hazardous material refer to CFR 49, 173.159
For more details pertaining to the transportation of wet and moist batteries.
The shipping information is as follows:
PROPER SHIPPING NAME : Batteries wet, filled with acid.
HAZARDOUS CLASS : 8
UN IDENTIFICATION : UN 2794
PACKAGING GROUP : III
LABEL/PLACARD REQUIRED : Corrosive
IATA
The international transportation of wet and moist charged (moist active) batteries is regulated by the
International Air Transportation Association (ASATA). These regulations also classify these types of
Batteries as a hazardous material. The batteries must be packed according to IATA Packaging
Instruction 800. The shipping information is as follows:
PROPER SHIPPING NAME : Batteries wet, filled with acid.
HAZARDOUS CLASS : 8
UN IDENTIFICATION : UN 2794
PACKAGING GROUP : III
LABEL / PLACARD REQUIRED : Corrosive
IMDG
The international transportation of wet and moist charged (moist active) batteries is regulated by the
International Maritime Goods code (IMDG). These regulations also classify these types of batteries
as a hazardous material. The batteries must be packed according to IMDG code pages 8120 and
8121. The shipping information is as follows :
PROPER SHIPPING NAME : Batteries wet, filled with acid.
HAZARDOUS CLASS : 8
UN IDENTIFICATION : UN 2794
PACKAGING GROUP : III
LABEL / PLACARD REQUIRED : Corrosive
Contact your FNB representative for additional information regarding the classification of batteries.
Spent lead-acid batteries are not regulated as hazardous waste by the EPA when recycled, however,
state and international regulations may vary.
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No: MSDS 04 MINING ACCUMULATOR (OMF CAP LAMP)
Date Issued : 15-02-2008
MATERIAL SAFETY DATA SHEET
Pages : 9 of 9
15. REGULATORY INFORMATION
EEC HAZARD CLASSIFICATION
RISK PHRASES
SAFETY PHRASES
NATIONAL LEGISLATION
_______________________________________________________________________________
16. OTHER INFORMATION
First National Battery provides the information in this MSDS in good faith. However, First National Battery
makes no representations as to its comprehensiveness or accuracy. This MSDS is intended, as a guide, for
the appropriate precautionary handling of the material by a properly trained person using it.
Individuals receiving this information must exercise their independent judgement in determining its
appropriateness for a particular process. First National Battery will not accept responsibility for damages
resulting from use of or reliance upon this information.
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