Lilly Miller Brands
Health Hazard 1
0
Fire Hazard 0
MATERIAL SAFETY DATA SHEET 0 0
Reactivity 0
Personal Protection B
HMIS RATING NFPA RATING
SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Lilly Miller Blackberry & Brush Killer MSDS Number: LM-020
Lilly Miller Hose 'n Go Blackberry & Brush Killer
Generic Name: Garden herbicide EPA Reg. Number: 802-594
Manufacturer: Lilly Miller Brands Revision Number: New
16201 SE 98th Avenue Date Issued: May 1, 2001
Address:
Clackamas, OR 97015 Manufacturer's Phone Number: 503-650-4400
COMPOSITION/INFORMATION ON INGREDIENTS
SECTION II -
Chemical Name CAS Number % TLV PEL
2 mg/m3(Skin) 2 mg/m3(Skin)
Triclopyr, TEA salt** 57213-69-1 8
Triethylamine** 121-44-8 0.5 1 ppm 25 ppm
Inert ingredients Mixture Variable N/A N/A
Water 7732-18-5 Variable N/A N/A
Key: TLV = ACGIH, 8 hr. time weighted average (TWA); PEL = OSHA permissible exposure limit.
** = Regulated under SARA Title III, Section 313
SECTION III - HAZARDS IDENTIFICATION
Emergency Overview: This product is of moderate toxicity. Primary concern is the potential irritation to the eyes.
Triethylamine can be absorbed through the skin. Wash hands and exposed skin with soap and water after using this
product.
Health: 1 Fire: 0 Reactivity: 0 Personal Protection: B
HMIS Rating:
Potential Health Effects:
Routes of Entry: Inhalation, skin contact, eye contact, ingestion
Inhalation: Overexposure to mists may cause transitory upper respiratory irritation.
Skin Contact: Prolonged or repeated exposure may cause skin irritation.
Eye Contact: Do not wear contact when working with this product. Mists may cause severe irritation with
potential corneal injury. Vapors of the amines may cause swelling of the cornea resulting in visual disturbances
such as blurred, smoky or halo vision.
Ingestion: Ingestion may be harmful and irritating to the G.I. system.
Revised: May 1, 2001 Page 1 of 4
Trade Name Lilly Miller Blackberry & Brush Killer; Lilly Miller Hose 'n Go Blackberry & Brush Killer MSDS Number: LM-020
SECTION III - HAZARDS IDENTIFICATION
Medical Conditions Aggravated by Exposure: May cause upper respiratory irritation, and may aggravate pre-
existing respiratory conditions. Repeated skin contact may aggravate skin allergies.
Carcinogenicity: Not listed by NTP or IARC. Not regulated as a carcinogen by OSHA.
SECTION IV - FIRST AID MEASURES
Inhalation: Move to an area free from risk of further exposure. Treat symptomatically if required. No adverse
effects anticipated by this route of exposure incidental to proper handling.
Eye Contact: Flush with copious quantities of clean, clear, lukewarm water at low pressure water for at least 15
minutes. Seek medical attention if irritation persists.
Skin Contact: Wash affected areas thoroughly with soap and warm water immediately after use of this product.
Ingestion: Call a physician or poison control center immediately. Drink 1 or 2 glasses of water. Do not induce
vomiting. Do not induce vomiting or give anything by mouth to an unconscious person.
SECTION V - FIREFIGHTING MEASURES
Health: 0 Fire: 0 Reactivity: 0 Other: 0
NFPA Rating:
Flash point and Method: This product is non-flammable
Extinguishing Method: Not required.
Fire or Explosion Hazards: This product will not burn.
Special Firefighting Procedures: Not applicable.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Clean-up Procedures: Immediately dam or otherwise contain any spills. Use an absorbent material, such as kitty
litter, to absorb material. Seal waste in a plastic bag for disposal.
Personal Precautions: If misty or vaporous conditions exist, wear a face mask approved for use with dusts and
mists such as 3M 8511 N-95 or equivalent.
Environmental Precautions: Product is an effective and potent herbicide. Do not allow spray mists to drift onto
vegetables, flowers, ornamental shrubs and trees, small fruits, fruit trees, or other desirable plants. Keep major spills
from entering lakes and waterways.
SECTION VII - HANDLING AND STORAGE
Storage Temperature: Store at temperatures above 28掳 F. Not affected by extremes of ambient temperature.
Shelf Life: Prolonged storage may reduce effectiveness.
Special Sensitivity: None.
Handling and Storage Precautions: Avoid eye contact and avoid breathing vapors if generated. Good
housekeeping is recommended to prevent the contamination of clothing and footwear and the mis-application of this
product.
Revised: May 1, 2001 Page 2 of 4
Trade Name Lilly Miller Blackberry & Brush Killer; Lilly Miller Hose 'n Go Blackberry & Brush Killer MSDS Number: LM-020
SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: If atmospheric conditions exceed exposure guidelines, wear a face mask approved for use
with dusts and mists such as 3M 8511 N-95 or equivalent.
Eye Protection: Use safety glasses if there is potential for exposure to mists or vapors which could cause injury to
the eyes.
Skin Protection: Gloves and long sleeved garments are a prudent precaution against excessive skin content.
Engineering Controls: Good general ventilation should be sufficient for most conditions.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Pale pinkish liquid.
Odor: Slight ammonia like odor Specific Gravity: N/D
Vapor density: N/D pH: N/D
Solubility in Water: Soluble % Volatile by Weight (VOC): Nil
SECTION X - REACTIVITY
Stability : This is stable material.
Hazardous Polymerization: Will not occur.
Incompatibilities: None in designed use.
Decomposition Products: Nitrogen oxides and hydrogen chloride may be formed under fire conditions.
SECTION XI - TOXICOLOGICAL/ECOLOGICAL INFORMATION
Ecological Concerns: Lilly Miller Blackberry and Brush Killer is an effective herbicide which will kill or damage
plants, shrubs and trees. Use only as directed and use caution to prevent the drifting of vapors to non-targeted
plants. This product may be harmful to aquatic plant life.
SECTION XII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Securely wrap original container in several layers of newspaper and discard in the trash.
Do not rinse original container and pour waste water into any water system.
SECTION XIII - TRANSPORTATION INFORMATION
DOT Shipping Name: Not regulated DOT Label: None
Technical Shipping Name: None DOT Placard: None
DOT Hazard Class: None UN/NA Number: None
Revised: May 1, 2001 Page 3 of 4
Trade Name Lilly Miller Blackberry & Brush Killer; Lilly Miller Hose 'n Go Blackberry & Brush Killer MSDS Number: LM-020
SECTION XIV - REGULATORY INFORMATION
OSHA Status: This product is regulated under OSHA.
EPA Registration Number: 802-594
TSCA Status: All applicable chemicals are registered under TSCA.
CERCLA Reportable Quantity: RQ = 5,000 pounds (N,N-Diethylethamine.
SARA Title III:
Section 302, Extremely Hazardous: N/A
Section 311/312 Hazard Categories: N/A.
Section 313 Toxic Chemicals: Triclopyr, N,N-Diethylethamine
RCRA Status: Not regulated under RCRA
SECTION XV - APPROVALS
Reason for issue: New MSDS Approval Date: April 6, 2001
Prepared by: Compliance Consulting Group, Inc. Supersedes Date None
303-795-2060
SECTION XVI - DISCLAIMER
As of the date of this document, the foregoing information is believed to be accurate and is provided in good faith to
comply with applicable federal and state laws. However, no warranty or representation of law or fact, with respect
to such information, is intended or given.
Revised: May 1, 2001 Page 4 of 4
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