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MATERIAL SAFETY DATA SHEET
1- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MANUFACTURER PIGMENT SANAYI A.脼.
ADDRESS and PHONE NUMBERS IN Kemalpa镁a Asfalt媒 No:44 Kemalpa镁a Izmir/TURKEY
CASE OF EMERGENCY Tel:+902328770400 Fax:+902328770401
PRODUCT NAME Zinc Tetroxy Chromate Pigment
TRADE NAMES/SYNONYMS CHROMIC ACID, ZINC SALT; ZINC CHROME; ZINC
YELLOW; ZINC CHROME YELLOW; BASIC ZINC
CHROMATE; CHROMIUM ZINC OXIDE; ZINC
CHROMATE(VI) HYDROXIDE; ZINC
HYDROXYCHROMATE; ZINC TETRAOXYCHROMATE;
ZINC TETROXYCHROMATE; PRIMROSE YELLOW;
BUTTERCUP YELLOW; CRO4ZN; OHS25370; RTECS
GB3290000
PRODUCT CODE ZTC-19
CHEMICAL CLASS Inorganic Zinc compound, metal salt
CHEMICAL FORMULA 4Zn(OH)2ZnCrO4
COMPOSITION AND INFORMATION ON INGREDIENTS
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Cas Number EC (EINECS) Chemical Name Formula % Zinc Tetroxy
Number Chromate
15930-94-6 Basic zinc Chromate 4Zn(OH)2ZnCrO4 100
236-878-9
3- HAZARDS IDENTIFICATION
HAZARD DESCRIPTION T Toxic
N Dangerous for the environment
INFORMATION PERTAINING TO PARTICULAR R 45 May cause cancer.
DANGERS FOR MAN AND ENVIRONMENT R 22 Harmful if swallowed.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
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FIRST AID
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LIMITS OF EXPOSURE
LONG TIME EXPOSURE ACUTE, CHRONIC
FIRST AID
EYE CONTACT : Harmful. In case of contact, immediately flush eyes with water for
at least 15 min. Call a physician.
SKIN CONTACT : Harmful. Flush skin with water and soap, Wash clothes before
reuse.
INGESTION : -- Call a physician.
INHALATION : Harmful. If not breathing perform artificial respiration, if breathing
give fresh oxygen. Remove to fresh air and call a
physician.
TOXIC TYPE : -
OTHER ADVISES : As ANTIDOTE : calcium disodium edetate/dextrose,
intravenous; calcium disodium edetate/procaine,
intramuscular. dimercaprol, intramuscular.
FIRE FIGHTING MEASURES
5-
SUITABLE EXTINGUISHING AGENTS CO2, extinguishing powder or water spray. Fight larger
fires with water spray.
SPECIAL HAZARDS CAUSED BY THE In case of fire, the following can be released:
MATERIAL, ITS PRODUCTS OF COMBUSTION Toxic metal oxide fume
OR RESULTING GASES Corrosive gases/vapours.
PROTECTIVE EQUIPMENT Wear self-contained respirator.
Wear fully protective impervious suit.
6- ACCIDENTAL RELEASE MEASURES
PERSON RELATED SAFETY PRECAUTIONS Wear protective equipment. Keep unprotected persons
away.
Ensure adequate ventilation
MEASURES FOR ENVIRONMENTAL Do not allow material to be released to the environment
without proper governmental permits.
PROTECTION
MEASURES FOR CLEANING / COLLECTING Dispose the material according to item 13.
OTHER PROCEDURES See Section 7 for information on safe handling
See Section 8 for information on personal protection
equipment.
See Section 13 for disposal information.
HANDLING AND STORAGE
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STORING and LOADING PRECAUTIONS Keep away from eye and skin contact. Place in closed
containers. Keep away from food. If contacted wash
thoroughly.
HANDLING Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
OTHERS Do not inhale and protect from flammable media.
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EXPOSURE CONTROLS AND PERSONAL PROTECTION
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Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at
least 0.5 m per second.
LD50 : > 5,000 mg/kg.
ZINC CHROMATES:
0.1 mg(CRO3)/m3 OSHA ceiling
0.01 mg(Cr)/m3 ACGIH TWA
0.001 mg(Cr(VI))/m3 NIOSH recommended TWA 10 hour(s)
MEASUREMENT METHOD: Particulate filter; Reagent; Visible spectrophotometry; NIOSH III # 7600,
Hexavalent Chromium.
Components with limit values that require monitoring at the workplace:
Zinc Tetroxy chromate mg/m鲁
TLV 0,05 A2 (as Cr)
USA PEL 0,1 鈥? Ceiling (as CrO3)
Personal Protection
EYES Safety glasses or goggles. Eye-flushing stations.
SKIN Rubber gloves and protective clothes, apron, impervious
gloves.
INHALATION Vomit and call a physician.
LOCAL VENTILATION EXITS Mechenical(General) local ventilation is enough.
OTHER PROTECTIVE EQUIPMENTS The usual precautionary measures for handling chemicals
should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing
immediately. Wash hands before breaks and at the end
of work.
PHYSICAL AND CHEMICAL PROPERTIES
9-
FORM Powder SOLUBILITY IN Insoluble
WATER
MELTING POINT 316掳C COLOUR Yellow
BOILING POINT N/A ODOR Odorless
FREEZING POINT N/A MOLECULAR 578,95
WEIGHT
BULK DENSITY 卤 15 400kg/m3 EVAPORATION N/A
% DENSITY
SPECIFIC GRAVITY 3,4卤0,1 EVAPORATION N/A
RATE
OTHER DATA pH 7,0卤0,1
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STABILITY AND REACTIVITY
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STABILITY Stable under normal conditions
UNSTABILITY REASONS Decomposes at 160掳C.
POLIMERIZATION and ITS DANGERS None.
UNSTABILITY CONDITIONS and MATERIALSDecomposition will not occur if used and stored
according to specifications.
DANGEROUS PRODUCTS OF DECOMPOSITION Toxic metal oxide fume
Corrosive gases/vapors.
TOXICOLOGICAL INFORMATION
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Acute toxicity and primary irritant effect.
ON THE SKIN Irritant to skin and mucous membranes.
ON THE EYE Powder: irritant effect
SENSITIZATION No sensitizing effects known.
EFFECTS OF SHORT TERM Inhalation of dust may cause irritation.
EXPOSURE
EFFECTS OF LONG TERM Repeated or prolonged contact with skin may cause dermatitis. Repeated
EXPOSURE OR REPEATED or prolonged contact may cause skin sensitization. Repeated or prolonged
EXPOSURE inhalation exposure may cause asthma. Repeated or prolonged exposure
may cause nasal ulceration. This substance is carcinogenic to humans. May
cause genetic damage in humans.
CARCINOGEN STATUS NTP: Known Human Carcinogen; IARC: Human Sufficient Evidence,
Animal Sufficient Evidence, Group 1; ACGIH: A1 -Confirmed Human
Carcinogen; EC: Category 1 An excess risk for lung and sinonasal cancer
has been reported in workers in the chromate production, chromate
pigment production and chromium plating industries. Zinc chromate has
been tested in rats by intrabronchial implantation, producing bronchial
carcinomas, by intrapleural administration, producing local tumors, and by
subcutaneous and intramuscular injection, producing local sarcomas.
ECOLOGICAL INFORMATION
12-
Also poisonous for fish and plankton in water bodies.
Do not allow material to be released to the environment without proper governmental permits.
This substance may be hazardous to the environment; special attention should be given to water organisms.
DISPOSAL INFORMATION
13-
Consult state, local or national regulations for proper disposal. Disposal must be made according to official
regulations.
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TRANSPORT INFORMATION
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PROPER SHIPPING NAME : INORGANIC TOXIC SOLID,n.o.s.
HAZARD CLASS : 6.1
U.N. NUMBER : 3288
PACKING GROUP : III
Land transport ADR/RID (cross-border)
ADR/RID CLASS : 6.1
U.N. NUMBER : 3288
ITEM : 65C
Maritime transport IMDG:
IMDG CLASS : 6.1
U.N. NUMBER : 3288
PACKING GROUP : III
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REGULATIONS
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T : Toxic
N : Dangerous for the environment.
EUROPEAN RISK and SAFETY CODES
R 45 May cause cancer.
R 22 Harmful if swallowed.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S 53 Avoid exposure - obtain special instructions before use.
S 45 In case of accident or if you feel unwell, seek medical advice immediately.
OTHER INFORMATION
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Employers should use this information only as a supplement to other information gathered by them, and should
make independent judgement of suitability of this information to ensure proper use and protect the health and safety
of employees. This information is furnished without warranty, and any use of the product not in conformance with
this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the
user.
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