Monday, January 08, 2007
Page 1 of 7
MSDS - Material Safety Data Sheet
Product Name: Genova PURPLE PRIMER
MSDS No.: GE379560
Part Numbers Covered:
13010
13011
13015
13020
13110
13111
13115
13120
1. Basic Information:
Manufacturer: Genova Products
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Address: 7034 East Court Street
City, ST Zip: Davison, MI 48423
2 1
Emergency Contact: INFOTRAC
Emergency Telephone Number: 800-535-5053
Contact: Information Telephone Number
Information Telephone Number: 800-521-7488
2
4
Last Update: 01/08/2007 Expiration Date:
1
X Liquid Gas Solid
Chemical State:
G
Pure Mixture
Chemical Type: X
2. Ingredients:
Trade Secret
EHS IARC SARA
313 OSHA ACGIH Other
% Range NTP SUB Z PEL TLV Limits
CAS No. Chemical Name
108-94-1 CYCLOHEXANONE 13 - 21 25 PPM 20 PPM NI
78-93-3 METHYL ETHYL KETONE 65 - 75 200 PPM 200 PPM NI
109-99-9 TETRAHYDROFURAN 7 - 15 200 PPM 50 PPM NI
3. Hazardous Identification:
Hazard Category:
X Acute X Chronic X Fire Pressure Reactive
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MSDS - Material Safety Data Sheet
Product Name: Genova PURPLE PRIMER
MSDS No.: GE379560
Hazardous Identification Information:
Hazards Overview:
Purple liquid with a distinct and penetrating odor.
Extremely flammable liquid and vapor. Vapors may cause flash fire.
May cause eye and skin irritation.
Inhalation of vapors or mists may cause respiratory irritation and central nervous system effects.
Ingestion may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May be fatal if swallowed.
Aspiration hazard.
Symptoms may be delayed.
4. First Aid Measures:
Route(s) of Entry:
EYES: Liquid causes severe irritation. Vapors cause slight to moderate irritation.
SKIN: Liquid or vapors may cause severe irritation.
INHALATION: May cause nose and throat irritation, headache, nausea, vomiting, drowsiness and incoordination.
INGESTION: Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney and liver disorders. May be fatal if
swallowed.
TARGET ORGANS: Eyes, Skin, Lungs, Kidney, Liver, Central Nervous System.
Health Hazards (Acute and Chronic):
ACUTE:
Severe skin irritant. Fast skin penetrant. Not expected to be a sensitizer. Eye irritant. Inhalation hazard. Overexposure may
cause coughing, shortness of breath, dizziness, vomiting, central nervous system depression, intoxication, and collapse.
Ingestion hazard. May produce symptoms of nervous system depression including headache, dizziness, nausea, loss of sense
of balance, drowsiness, and visual disturbances.
CHRONIC:
Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause defatting and
dermatitis. May cause liver and kidney damage. May cause reproductive and fetal effects May cause lung damage. Narcotic in
high concentrations.
Signs and Symptoms:
See HEALTH HAZARDS above.
Medical Conditions Generally Aggravated by Exposure:
AGGRAVATION OF EXISTING CONDITIONS:
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the
effects of the substance.
Emergency and First Aid Procedures:
Monday, January 08, 2007
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MSDS - Material Safety Data Sheet
Product Name: Genova PURPLE PRIMER
MSDS No.: GE379560
FOR EMERGENCY FIRST AID HELP CALL 1-303-623-5716 COLLECT.
SKIN CONTACT:
Immediately wash skin with soap and water while removing contaminated clothing and shoes. Launder clothing before reuse.
Seek medical attention if irritation persists.
EYES:
Liquid: Immediately flush with plenty of water for 5 minutes. Remove contacts if present and continue flushing with water while
holding eyelids open with thumb and index finger for 15 minutes. Seek medical attention if irritation develops or persists.
Vapors: If vapors cause irritation, move to fresh air and flush eyes as above. Seek medical attention if irritation develops or
persists.
INHALATION:
Move to fresh air. Give oxygen if breathing is difficult. Give artificial respiration if required. Call a physician or poison control
center (1-303-623-5716 collect) immediately.
INGESTION:
DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or
drowsy. Get immediate medical attention by calling a Poison Control Center (1-303-623-5716 Collect), or hospital emergency
room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment
center or hospital.
Other Health Warnings:
NI
5. Fire Fighting Measures:
Flash Point: 25 - 30 潞F Lower Explosive Limit: 2.4 % Vol. Upper Explosive Limit: 12.7 % Vol.
F.P. Method: TCC
Fire Extinguishing Media: Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container with water. Water may be ineffective
as an extinguishing agent.
Special Fire Fighting Procedures:
Firefighters should wear positive pressure self contained breathing apparatus and full protective clothing for fires in areas where
chemicals are used or stored.
Unusual Fire and Explosion:
Extremely flammable liquid. Keep away from heat and all sources of ignition including sparks, flames, lighted cigarettes and pilot
lights. containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ingition
source and flash back. This product contains Tetrahydrofuran that may form explosive organic peroxides when exposed to air or
light or with age. Combustion will produce toxic and irritating vapors including carbon monoxide and carbon dioxide.
6. Accidental Release Measures:
Steps to be Taken in Case Material is Released or Spilled:
Remove all sources of ignition and ventilate area. Stop leak if it can be done without risk. Prevent liquid from entering
watercourses, natural waterways, drainage collection areas or sewers.
Personnel cleaning up the spill should wear appropriate Personal Protective Equipment, including respirators if vapor
concentrations are high. Soak up spill with an inert absorbent such as sand, earth or other non-combusting material. Put spent
absorbent material in covered, labeled metal containers. See Section 13 for disposal information.
Report releases to proper authorities as required.
7. Handling and Storage:
Precautions to be Taken:
Monday, January 08, 2007
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MSDS - Material Safety Data Sheet
Product Name: Genova PURPLE PRIMER
MSDS No.: GE379560
HANDLING:
Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to
outdoors). Wash thoroughly after handling. do not eat, drink or smoke in the work area. Keep product away from heat, sparks,
flames and all other sources of ignition. No smoking in use or storage areas. Keep containers closed when not in use.
STORAGE:
Store in a cool, dry, well ventilated area away from incompatable materials. Keep containers closed when not in use.
Other Precautions:
"Empty" containers can retain product residue and can be hazardous. Follow all MSDS precations in handling empty containers.
Do not cut or weld on or near empty or full containers.
Prevent prolonged or repeated breathing of vapors released during application process. Reports have associated repeated and
prolonged overexposure to solvents with permanent brain damage and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents may be harmful or fatal.
8. Exposure Controls/Personal Protection:
Ventilation Requirements:
GENERAL MECHANICAL: Exhaust ventilation capable of maintaining emissions at the point of use below OSHA PEL.
LOCAL EXHAUST: Open doors & windows. If used in an enclosed area, use exhaust fans.
Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of vapors are not exposed to electrical
fixtures or hot surfaces.
Personal Protective Equipment:
RESPIRATORY PROTECTION:
For operations where the exposure limits may be exceeded, a NIOSH approved organic vapor resiprator or supplied air respirator
is recommended. Equipment selection depends on the contaminant type and concentration. Select in accordance with 29 CFR
1910.134 and good industrial hygiene practice.
For firefighting, use self-contained breathing apparatus.
EYE PROTECTION:
Safety glasses with side shields or safety goggles.
SKIN PROTECTION:
Rubber gloves are adequate for normal use of the product. For long exposures to the substance, chemical resistant gloves may
be required to avoid prolonged exposure.
OTHER PROTECTION:
An eye wash and safety shower should be available in the work area.
9. Physical and Chemical Properties:
Boiling Point: 133 潞F Melting Point: NI
Evaporation Rate (Butyl Acetate = 1): 5.5 Vapor Pressure (mm Hg.): 179.6
Specific Gravity (H20 = 1): 0.83800 Vapor Density (AIR = 1): 2.0
Solubility In Water: Almost Complete @ 68 潞 F Appearance and Odor: Purple Liquid / Ether-like odor
Other Information: Specific Gravity: ~.838
10. Stability and Reactivity:
Stability:
Stable.
Incompatibility (Materials to Avoid):
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MSDS - Material Safety Data Sheet
Product Name: Genova PURPLE PRIMER
MSDS No.: GE379560
Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds, chlorinated inorganics (potassium, calcium and sodium
hypochlorite) and hydrogen peroxides. May attack plastic and rubber compounds.
Decomposition/By Products:
Burning can produce carbon monoxide, carbon dioxide, water, cyanide, hydrogen cyanide, and vapors of chemicals listed in
Section II.
Hazardous Polymerization:
Will not occur.
11. Toxicological Information:
CHRONIC TOXICITY: Prolonged or reapeated overexposure can cause dermatitis and damage to the kidney, liver, lungs and
central nervous system.
TOXICITY DATA
Cyclohexanone:
Oral rat LD50: 1,620 mg/kg.
Inhalation rat LC50: 8,000 ppm/4 hours
Skin rabbit: 1 mL/kg
Methyl Ethyl Ketone:
Oral rat LD50: 2,737 mg/kg.
Inhalation rat LC50: 23,500 mg/m3/8 hours
Skin rabbit: 6480 mg/kg
Tetrahydrofuran:
Oral rat LD50: 1,650 mg/kg
Inhalation rat LC50: 21,000 ppm/ 3 hours
SENSITIZATION:
None of the components are known to cause sensitization.
CARCINOGENICITY:
None of the components are listed as a carcinogen or suspect cacinogen by NTP, IARC or OSHA. The NTP has reported that
exposure of mice and rats to Tetrahydrofuran vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their lifetime caused an
increased incidence of kidney tumors in male rats and liver tumors in female mice. The significance of these findings for human
health is unclear at this time, and may be related to "species specific" effects. Elevated incidences of tumors in humans have not
been reported for Tetrahydrofuran. ACGIH has classified Cyclohexanone and Tetrahydrofuran as "A3", Confirmed Animal
Carcinogen with Unknown Relevance to Humans.
MUTAGENICITY:
Cyclohexanone has been positive in bacterial and mammalian assays. Methyl Ethyl Ketone and Tetrahydrofuran are generally
thought not to be mutagenic.
REPRODUCTIVE TOXICITY:
Methyl Ethyl Ketone and Cyclohexanone have been shown to cause embryofetal toxicity and birth defects in laboratory animals.
Tetrahydrofuran have been found to cause adverse developmental effects only when exposure levels cause othe toxic effects to
the mother.
12. Ecological Information:
THIS PRODUCT IS NOT EXPECTED TO BE TOXIC TO AQUATIC ORGANISMS.
Cyclohexanone: 96 hour LC50 values for fish is over 100mg/L.
Methyl Ethyl Ketone: 96 hour LC50 values for fish is over 100mg/L.
Tetrahydrofuran: 96 hour LC50 for fathead minnow: 2160 mg/L.
13. Disposal Considerations:
Monday, January 08, 2007
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MSDS - Material Safety Data Sheet
Product Name: Genova PURPLE PRIMER
MSDS No.: GE379560
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
RCRA Hazardous Waste Number: U057 (Cyclohexanone, U159 (MEK), U213 (Tetrahydrofuran)
EPA Hazardous Waste ID Number: D001, D035, F005
EPA Hazardous Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)
14. Transport Information:
DOT (DEPARTMENT OF TRANSPORTATION) U.S.:
Proper Shipping Name: Less than 1 Liter = Consumer Commodity
Hazard Class/Packing Group: Less than 1 Liter = ORM-D
UN/NA Number: Less than 1 Liter = None
Hazard Labels: Less than 1 Liter = Consumer Commodity, ORM-D
INTERNATIONAL MARITIME DANGEROUS GOODS:
Proper Shipping Name: Flammable Liquid, N.O.S.), Limited Quantity
Hazard Class/Packing Group: 3, II
UN Number: UN1993
Label: Flammable Liquid N.O.S.
2004 NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128
15. Regulatory Information:
SARA, Section 311 / 312, Hazard Category:
Acute Health
Chronic Health
Flammable
SARA, Section 302, Extremely Hazardous Substances:
This product does not contain chemical regulated under SARA Section 302.
SARA, Section 313, Toxic Chemical:
This product does not contain any chemcials subject to reporting under SARA Section313.
CERCLA 103, Reportable Quantity:
Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center; The RQ for the
product, based on the RQ for Methyl Ethyl Ketone (100% maximum) of 5,000 lbs. is 5,000 lbs. Many states have more stringent
release reporting requirements. Report spills required under federal, state and local regulations.
CALIFORNIA PROPOSITON 65:
This product does not contain any chemical subject to California Proposition 65 regulation.
TSCA INVENTORY:
All of the components of this product are listed on the TSCA inventory.
16. Other Information:
KEEP AWAY FROM HEAT SPARK AND FLAMES AT ALL TIMES.
STORE IN A COOL DRY PLACE.
Monday, January 08, 2007
Page 7 of 7
MSDS - Material Safety Data Sheet
Product Name: Genova PURPLE PRIMER
MSDS No.: GE379560
ABBREVIATIONS:
~= Approximately
<= Less Than
>= Greater Than
ACGIH = American Conference of Governmental Industrial Hygienists
AIHA = American Industrial Hygiene Association
C= Degrees Celcius
Deg = Degrees
EPA = Environmental Protection Agency
F= Degrees Farenheit
HMIS = Hazardous Materials Information System
IARC = International Agency for Research on Cancer
NA = Not Applicable
NDA = No Data Available
NE = Not Established
NFPA = National Fire Protection Association
NI = Not Indicated
NIOSH = National Institure of Occupational Safety and Health
NTP= National Toxicology Program
OSHA = Occupational Safety and Health Administration
DISCLAIMER: The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the
best of our knowledge. However, Genova Products, Inc. cannot give any guarantees regarding information from other sources, and
expressly does not make warranties, nor assumes any liability for its uses.
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