SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 24/MAY/2005
Date Updated: 13/MAR/2004
Version 1.2
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name TIN(IV) CHLORIDE, 99.995%
Product Number 217913
Company Sigma-Aldrich Pty, Ltd
Unit 2, 14 Anella Avenue
Castle Hill NSW 1765
Australia
Technical Phone # +61 2 9841 0555
Fax +61 2 9841 0500
Emergency Phone # +61 2 9841 0566
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
STANNIC CHLORIDE 7646-78-8 231-588-9 050-001-00-5
Formula SnCl4
Molecular Weight 260.5 AMU
Synonyms Etain (tetrachlorure d') (French) * Libavius
fuming spirit * Stagno (tetracloruro di)
(Italian) * Stannane, tetrachloro- * Stannic
chloride * Tin perchloride * Tin tetrachloride *
Tintetrachloride (Dutch) * Zinntetrachlorid
(German)
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Causes burns. Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of contact with skin, wipe off excess material with a
dry cloth. Wash remaining material off with copious amounts of
water for at least 15 minutes.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
Do not induce vomiting.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed
container, and hold for waste disposal. Ventilate area and wash
spill site after material pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store under nitrogen.
SPECIAL REQUIREMENTS: Handle and store under inert gas. Air and
moisture sensitive.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Discard contaminated
shoes. Wash thoroughly after handling.
EXPOSURE LIMITS - DENMARK
Source Type Value
OEL TWA 2 mg/m3
EXPOSURE LIMITS - UNITED KINGDOM
Source Type Value
OEL TWA 2MG(SN)/M3
OEL STEL 4 mg(Sn)/m3
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PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
Special Protective Measures: Faceshield (8-inch minimum).
9 - Physical and Chemical Properties
Appearance Physical State: Liquid
Color: Colorless
Property Value At Temperature or Pressure
pH 0.2 20 掳C Concentration: 60
g/l
BP/BP Range 114 掳C 760 mmHg
MP/MP Range -33 掳C
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure 20 mmHg 22 掳C
SG/Density 2.226 g/cm3
Partition Coefficient N/A
Viscosity < 0.001 Pas 25 掳C
Vapor Density 9 g/l
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Conditions of Instability: May decompose on exposure to moist air
or water.
Materials to Avoid: Strong bases, Alcohols.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Tin/tin oxides, Hydrogen
chloride gas.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: XP8750000
ACUTE TOXICITY
LC50
Inhalation
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Rat
2,300 mg/m3
10M
LD50
Intraperitoneal
Mouse
99 MG/KG
SIGNS AND SYMPTOMS OF EXPOSURE
Inorganic tin salts are poorly absorbed into the body. When
parenterally administered tin salts are highly toxic. Tin oxide
inhaled as a dust or fume leads to a benign pneumoconiosis with
no sign of interference with pulmonary function. Deposited dust
appears nodular with the particles being mostly extracelluar. No
necrosis, foreign-body giant-cell reaction, or collagen
formation has been seen. Tin salts that have gained access to
the blood stream are highly toxic and produce neurologic damage
and paralysis. With most common tin salts, the toxicity profile
is complicated by hydrolysis in body fluids producing
unphysiologic pH values. The reported symptoms of hyperemia,
vascular changes with bleeding in the central nervous system,
liver, heart, and other organs may be due to tin itself or to
the unphysiological pH changes. Ingestion produces vomiting due
to the gastric irritation from the activity and astringency of
tin compounds. Injection of inorganic tin salts produces
diarrhea, muscle paralysis, and twitching. Material is extremely
destructive to tissue of the mucous membranes and upper
respiratory tract, eyes, and skin. Inhalation may result in
spasm, inflammation and edema of the larynxand bronchi, chemical
pneumonitis, and pulmonary edema. Symptoms of exposure may
include burning sensation, coughing, wheezing, laryngitis,
shortness of breath, headache, nausea, and vomiting. To the best
of our knowledge, the chemical, physical, and toxicological
properties have not been
ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes burns.
Inhalation: Toxic if inhaled. Material is extremely destructive
to the tissue of the mucous membranes and upper respiratory
tract.
Ingestion: May be harmful if swallowed.
CHRONIC EXPOSURE - MUTAGEN
Human
4 MG/L
Cell Type: leukocyte
Cytogenetic analysis
12 - Ecological Information
ECOTOXICOLOGICAL EFFECTS
Test Type: EC50 Algae
Time: 4 h
Value: > 50 mg/l
Test Type: EC50 Daphnia
Species: Daphnia magna
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Time: 48 h
Value: 32.9 mg/l
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 1827
Class: 8
PG: II
Proper Shipping Name: Stannic chloride, anhydrous
IMDG
UN#: 1827
Class: 8
PG: II
Proper Shipping Name: Stannic chloride, anhydrous
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 1827
Class: 8
PG: II
Proper Shipping Name: Stannic chloride, anhydrous
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 050-001-00-5
INDICATION OF DANGER: C
Corrosive.
R-PHRASES: 34 52/53
Causes burns. Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-PHRASES: 7/8 26 45 61
Keep container tightly closed and dry. In case of contact with
eyes, rinse immediately with plenty of water and seek medical
advice. In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible). Avoid
release to the environment. Refer to special
instructions/safety data sheets.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 1
SWITZERLAND
SWISS POISON CLASS: 2
16 - Other Information
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WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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