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MSDS Material Safety Data Sheet
CAS

57-13-6 7447-40-7 7778-80-5 7722-76-1 7783-28-0 7783-20-2 471-34-1 7704-34-9 1309-37-1 7720-78-7 1317-35-7 7487-88-9 9011-05-6 14977-37-8 39409-82-0

File Name: 57-13-6_7447-40-7_7778-80-5_7722-76-1_7783-28-0_7783-20-2_471-34-1.asp

                                                                        MATERIAL SAFETY
DATA SHEET #1015
1301 East 9th Street, Suite 1300, Cleveland, OH 44114-1849 DATE ISSUED: 6/25/01
Emergency Phone: LESCO: (800) 321-5325 SUPERSEDES: 11/29/00
CHEMTREC: (800) 424-9300
I. PRODUCT IDENTIFICATION
Product: LESCO Granular Fertilizer-All Analyses Chemical Family: Fertilizer Mixture
Chemical Name/Synonyms: Granular fertilizers including all chemical, partially sulfur coated, 100 percent sulfur
coated nutrients with and without micronutrients.
II. PRODUCT INFORMATION: INGREDIENTS
Chemical Name TLV/TWA %(by wt.) CAS#
Formulated with one or more of the following ingredients. Check specific product label.
3
Urea 10 mg/M (dust) 0-98 57-13-6
3
5 mg/M (resp)
3
Potassium Chloride 10 mg/M 0-95 7447-40-7
3
Potassium Sulfate 10 mg/M 0-95 7778-80-5
3
Monoammonium Phosphate 15 mg/M (dust) 0-95 7722-76-1
3
5 mg/M TLV
3
Diammonium Phosphate 15 mg/M (dust) 0-95 7783-28-0
3
5 mg/M (resp)
3
Ammonium Sulfate 15 mg/M (dust) 0-95 7783-20-2
Calcium Carbonate ND 0-95 471-34-1
Sulfur 5 ppm (SO2) 0-20 7704-34-9
3
Iron (Ferric) Oxide 15 mg/M (dust) 0-10 1309-37-1
3
Iron (Ferrous) Sulfate 15 mg/M (dust) 0-10 7720-78-7
3
Manganese Oxide 15 mg/M (dust) 0-10 1317-35-7
3
Magnesium Sulfate 15 mg/M (dust) 0-10 7487-88-9
Urea Formaldehyde 0-10 9011-05-6
Sulfate of Potash-Magnesia 0-10 14977-37-8
Magnesium Carbonate 0-10 39409-82-0
Biosolids 0-10 ND
3 3 3
TLV of all chemicals and mixtures is 15 mg/M ; TWA is 10 mg/M ; Respirable dust TLV of 5 mg/M , unless otherwise
indicated.

III. PHYSICAL AND CHEMICAL CHARACTERISTICS
Boiling Point: NA Specific Gravity (water=1): NA
Melting Point: NA Bulk Density (lbs./cu. ft.): 45-65
Vapor Pressure (mm Hg): NA Evaporation Rate: NA
Vapor Density (air = 1) NA Percent Volatile: NA
Solubility in Water: Moderate Appearance and Odor: Multicolored granules-
pH: ND slight pungent odor.

IV. FIRE AND EXPLOSION HAZARD DATA

Flash Point (method Used): NA (non combustible) Auto Ignition Temperature: NA
Lower Explosion Limits: NA Upper Explosion Limits: NA
NFPA/HMIS RATING: HEALTH 1 FIRE 1 REACTIVITY 0
Extinguishing Media: [] Foam [] Alcohol Foam [ ] Dry Chemical
[X] Water Spray [] Other [] CO2
Special Fire-Fighting Procedures: Wear NIOSH approved positive pressure, self-contained breathing apparatus. Do not
breathe fumes. Remove from area of fire at first opportunity. Prevent water runoff from entering drains, sewers or water
sources. Fertilizer will become slippery when wet. Guard against falls.
Unusual Fire and Explosion Hazards: If heated to decomposition, will give off toxic fumes of ammonia and formaldehyde.
Under fire conditions, urea may decompose to cyanuric acid, biuret or ammonia. Dispersion of fine dust in the air may form
an explosive mixture.
V. HEALTH HAZARDS

Primary Route(s) of Entry: Skin, inhalation, ingestion, eyes.
Signs & Symptoms of Exposure
Acute: May cause mild irritation to skin and eyes. Ingestion of large amounts may cause gastrointestinal disorder,
nausea, vomiting and/or diarrhea.
Emergency First-Aid Procedures
Eyes: Flush with clear water for at least 15 minutes. Get medical attention if irritation persists.
Skin: Remove contaminated clothing and wash affected area with soap and water.
Inhalation: Remove to fresh air.
Ingestion: Drink warm water and induce vomiting by touching back of throat with finger. Consult a physician.
Toxicity Information:
Oral LD50 (acute rat): >10,000 mg/kg
Inhalation LC50: NA; expected to have low or no toxicity. Eye Irritation: Mild
Skin Irritation: Mild


Positive Teratogen or Mutagen Carcinogen(NTP): No Potential Carcinogen (IARC or OSHA): No


VI. REACTIVITY

Stability: [X] Stable [ ] Unstable
Conditions to Avoid: None known
Incompatibility: Strong acids, caustic compounds, humid-wet conditions.
Hazardous Decomposition Products: If heated to decomposition, may give off ammonia and formaldehyde as well as
oxides of sulfur, manganese, magnesium, iron, potassium and phosphorus. Urea can yield cyanuric acid or biuret upon
heating.
Hazardous Polymerization: [X] Will not occur [] Will occur

VII. SPILL, LEAK, AND DISPOSAL PROCEDURES

If material is spilled: If material is not contaminated, scoop into clean container for use. If contaminated, scoop into
containers for disposal.
Waste Disposal Method: Dispose according to Federal EPA procedures as outlined in the Resource Conservation
Recovery act (RCRA) and follow state and local guidelines. Be sure that containers are completely empty before disposal.

VIII. SPECIAL PROTECTION INFORMATION

Protective Equipment Suggested for Outdoor Application:
[X] Impervious Gloves [ ] Dust Mask [ ] Respirator(use NIOSH/MSHA approved)
[X] Impervious Boots [X] Clean Clothing [X] Eye Goggles / Safety Glasses
Protective Equipment Suggested for Confined Areas:
[X] Sufficient Ventilation[ ] Respirator(use NIOSH/MSHA approved) [X] Dust Mask
[X] Splash Goggles/ Safety Glasses
[X] Eyewash Station [X] Emergency Shower [ ] Impervious Apron

IX. STORAGE AND HANDLING

Precautions: Store in a cool, dry place if possible. Separate from pesticides, seed, feed, foodstuffs, and away from drains,
sewers, and water sources. Do not eat, drink or smoke while handling this product.
Other Precautions: Keep out of reach of children. Practice good care and good safety precautions when handling this
product. Avoid contact with eye, skin and clothing. Avoid breathing dust. Do not swallow. Wash thoroughly after handling.
X. FEDERAL REGULATORY INFORMATION:

SARA TITLE III; SEC. 311/312 HAZARD CATEGORIES
Y Immediate (Acute) Health SEC 302: NA
N Delayed (Chronic) Health SEC 304: NA
N Fire SEC 313: NA
N Sudden Release of Pressure CERCLA RQ: NA
N Reactivity CAA RQ: NA
EPA Reg. No.: NA
HM 181 Shipping Name: Not Regulated.
NA = Not Applicable ND = Not Determined
Preparation and distribution of this Material Safety Data Sheet done by LESCO, Inc.,
pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200).
The information contained herein is based on available data. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be
obtained from the use thereof; and you should make your investigation to determine safety for the use you contemplate. LESCO, Inc. makes no warranty of
merchantability of fitness for a particular use, nor is there any other express or implied warranty except as may be specifically provided otherwise on product.

LESCO, Inc. assumes no responsibility or liability for any incidental or consequential damages whether related to personal injury or property
damage, to vendees, users or third parties, caused by the material; and LESCO, Inc.'s responsibility is limited to replacement of, or repayment
of, the purchase price for the material(s) with respect to which any damages are claimed. All vendees or users assume all risk associated with
the use of the material(s).
G:\REGUL\WP\MSDS\MSDS - LESCO Strongsville\1015GRANULAR.doc 11/29/00 wpv

?1301 East 9th Street, Suite 1300 ?Cleveland, OH 44114-1849 or (800) 321-5325.
For further information, contact: LESCO, Inc.,

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