MSDS: Acid Stain (All Colors) Code: 2900-FS000
Material Safety Data Sheet
Section 1: Product Information
Manufacturer's Name / Address: Trade Name: Acid Stain (All Colors)
Floric Polytech
Chemical
10280 Indiana Court Acid Solution, Hydrochloric / Phosphoric
Family:
Rancho Cucamonga, CA 91730
Info. Phone:
Intended Use: Concrete Colorant, Stain
(909) 483-1870
Emergency Phone:
1-800-424-9300 CHEMTREC 24 Hours
Section 2: Hazards Identification
Likely Routes of Exposure: Eye Inhalation Skin Contact Ingestion
Overexposure Effects (organs or systems targeted or affected): Eyes, Skin, Larynx, Respiratory Tract; Possible liver
damage and pulmonary edema, Gastro-Intestinal Tract
POTENTIAL HEALTH EFFECTS:
Chronic: Burns to eyes and skin, larynx spasm, coughing or choking, pulmonary edema, dermatitis
Acute:
? Exposure to eyes causes severe irritation, redness, swelling and tearing
? Skin exposure will cause irritation, redness, burns and / or rash
? Inhalation may cause irritation of nose, throat and respiratory tract
? Ingestion may result in severe gastric distress, destruction of tissue
Section 3: Hazardous Ingredients
No. Hazardous Component CAS # % of Total
1 Phosphoric Acid 7664-38-2 < 10%
7647-01-0
2 Hydrochloric Acid < 15%
7447-39-4
3 Cupric Chloride < 30%
10588-01-9
4 Sodium Dichromate > 5%
7773-01-5
5 Manganese Chloride > 5%
7758-94-3
6 Ferrous Chloride > 20%
7 Chromic Chloride 10025-73-7 > 6%
8 Ferric Chloride 7439-89-6 > 15%
9
NA = Not Applicable ND = No Data NE = Not Established NL = Not Listed NR = Not Required
Release Date: December 17, 2007 Supersedes Date: N/A (New Release) Page 1 of 5
MSDS: Acid Stain (All Colors) Code: 2900-FS000
Section 4: First Aid Measures
General: Move person to an area free from further exposure. If unconscious seek emergency medical assistance
immediately. Treat symptomatically. NEVER ATTEMPT TO GIVE ANYTHING BY MOUTH TO A PERSON WHO IS
UNCONSCIOUS.
Eyes: Flush with running water for 15 minutes while holding eyes open. Flush under eyelids to clear any trapped debris.
Seek medical attention immediately.
Skin: Remove contaminated clothing immediately. Wash affected areas thoroughly with soap and water removing all
material. Do not use clothing again until properly laundered. Dispose of if required. Seek medical attention if symptoms
arise or persist.
Inhalation: Remove affected person from further risk of exposure and seek medical assistance immediately. Administer
oxygen or artificial respiration as needed.
Ingestion: DO NOT INDUCE VOMITING! Seek medical attention immediately. Never induce vomiting or give liquid to
an unconscious person.
Section 5: Fire Fighting Measures
Hazardous Combustion Products: Product is not combustible, extreme heat may yield noxious or toxic fumes
Extinguishing Media: Any suitable media for surrounding fire
Special Firefighting Procedures: Full protective equipment with self contained breathing apparatus
Unusual Fire and Explosion Hazards: Extreme conditions may produce phosphorous compound
Section 6: Accidental Release Measures
General: Clear all non-essential personnel from spill area. If indoors ventilate the area. Remove all sources of ignition.
Provide cleanup personnel with proper protective equipment such as gloves, eyewear, protective clothing and breathing
equipment as required.
Cleanup of Small Spills: Dike or impound material to prevent spreading and prevent further spillage if possible. Cover
spill with appropriate absorbent material. Collect material in appropriate container or vessel. Remove containers to safe
area and cover to await reclamation or disposal. Area may be rinsed with water but do not allow it to be flushed into
sewers or natural waterways.
Cleanup of Large Spills: Contain material as above and contact local fire or police department for immediate
emergency response.
Section 7: Handling and Storage
Safe Storage Considerations: Store in cool, dry, ventilated conditions. Do not allow material to freeze. Keep away
from points of ignition and avoid excessive heat. Keep containers tightly sealed when not in use.
Safe Handling Considerations: Use proper workplace hygiene practices. Keep work areas clear and uncluttered. Use
personal protective equipment when required as specified in Section 8.
NA = Not Applicable ND = No Data NE = Not Established NL = Not Listed NR = Not Required
Release Date: December 17, 2007 Supersedes Date: N/A (New Release) Page 2 of 5
MSDS: Acid Stain (All Colors) Code: 2900-FS000
Section 8: Exposure Controls/Personal Protection
No. Hazardous Component OSHA PEL (TWA) ACGIH TLV (TWA)
3
1 mg/m3
1 Phosphoric Acid 1 mg/m
2 ppm
5 ppm
2 Hydrochloric Acid
3
1 mg/m3
3 Cupric Chloride (Limits for Copper mist & dust) 1 mg/m
3
0.05 mg/m3
4 Sodium Dichromate 0.1 mg/m
3
0.2 mg/m3
5 Manganese Chloride 5 mg/m
3
1 mg/m3
6 Ferrous Chloride 1 mg/m
3
0.5 mg/m3
7 Chromic Chloride 0.5 mg/m
8 Ferric Chloride NE NE
9
Respiratory Protection: If necessary use a NIOSH approved air purifying respirator appropriate to keep breathing air
below the acknowledged exposure limits.
Skin Protection: Wear chemical resistant clothing such as gloves, apron, boots or full coverage suits as appropriate.
Eye Protection: Full coverage safety glasses; chemical goggles or full-face shield may be substituted. Contact lenses
should not be worn.
Eye Wash & Shower Station Requirements: Should be locally accessible and properly maintained.
Other Protective Equipment (glove box, ventilation, etc.): Sufficient local exhaust and ventilation as required to keep
airborne concentrations safely below the acknowledged exposure limits.
Section 9: Physical and Chemical Characteristics
NE Specific Gravity: 1.27-1.33
Boiling Point (癈):
NE
Vapor Pressure: Melting Point: NE
Evaporation Rate:(Butyl
NE
Vapor Density:(Air = 1) <1
Acetate=1)
Soluble
Solubility in Water: pH: 2-3
-12 癈
Freezing Point NA
Flash Point (癈):
Coefficient of Oil/ Water
Conditions of Flammability:
NE None
Distribution:
Odor Threshold: NE NA
Autoignition Temperature (癈):
LEL: NA
Physical State: Explosion Limits: vol.% in air
Liquid
UEL: NA
Appearance: Various colors, sharp
VOC Content (g/l): ND
(odor, color, etc.) pungent (acidic) odor
Section 10: Stability/Reactivity
Chemical Stability: Stable under normal conditions Unstable
Conditions to Avoid:
Incompatibility (materials to avoid): Strong alkalis, reactive metals
Hazardous Decomposition Products: May evolve extremely toxic chloride fumes; extreme thermal decomposition may
form phosphorous compounds
Hazardous Polymerization (reactivity): Will Occur Will Not Occur
NA = Not Applicable ND = No Data NE = Not Established NL = Not Listed NR = Not Required
Release Date: December 17, 2007 Supersedes Date: N/A (New Release) Page 3 of 5
MSDS: Acid Stain (All Colors) Code: 2900-FS000
Section 11: Toxicological Information
Acute and Chronic Toxicity: Data may exist for ingredients previously listed but may or may not apply to this product for
amounts contained as a percentage of weight or volume. It is advised that information sources for individual ingredients
be consulted for accurate and precise data.
Listed as Carcinogen/Potential Carcinogen: This product is not known to be carcinogenic, however some ingredients
may be listed by one or more of the agencies below as shown.
NTP (National Toxicology Program): Not listed
OSHA (Occupational Health & Safety Administration): Not listed
IARC (International Agency for Research on Cancer): Not reviewed
Reproductive Effects: None known
Developmental Effects: None known
Section 12: Ecological Information
Ecotoxicity (effects on plants and animals): No specific data exists for this product. Based on data for some
ingredients this material it should be considered to be toxic to land and aquatic organisms.
Environmental Fate of Material: No specific data exists for this product, however based on data for some ingredients
this material should be considered not to be completely biodegradable and at least partially persistent in the environment.
Section 13: Disposal Considerations
Appropriate Waste Disposal Methods: Consult your local, state or provincial and federal regulations before disposing
of any chemicals. Dispose of in accordance with all applicable regulations with regard to precedence.
Section 14: Transport Information
U.S. Department of Transportation (US DOT)
?Proper Shipping Name: Hydrochloric / Phosphoric Acid Solution
?Hazard Class: 8
?UN Number: UN1789 / UN1805
?Packing Group: III
TDG (Canadian Ground): See US DOT
IMDG (Water): See US DOT
ICAO (Air): See US DOT
Section 15: Regulatory Information
GLOBAL INVENTORIES
TSCA (USA; Toxic Substance Control Act): All ingredients are listed or exempt from listing
DSL (Canada; Domestic Substance List): All ingredients are listed
ECL (Korea; Established Chemicals List): All ingredients are listed
PICCS (Philippines): No information currently available
ENCS (Japan; Established and New Chemicals List): All ingredients are listed
IECS (China): No information currently available
EINECS (European Inventory of Existing Commercial Chemical Products): All ingredients are listed: 231-633-2,
231-595-7, 231-210-2, 234-190-3, 231-869-6, 231-843-4, 256-852-0, 231-096-4
SARA Title III (Superfund Amendments & Reauthorization Act)
??13: Considered a Toxic Chemical: Hydrochloric Acid 7647-01-0 -7
?Ё311/312: Health Hazard: Acute and chronic for all ingredients except 7664-38-2 (Acute only)
??02: Extremely Hazardous: Hydrochloric Acid 7647-01-0 RQ=5000; Chromic Chloride RQ=1 as 10025-73-7
California Proposition 65 (Known to the State of California to cause cancer, birth defects, or other reproductive harm):
Sodium Dichromate 10588-01-9
WHMIS (Canadian Workplace Hazardous Material Information System): Class E3 (Corrosive) 7664-38-2, 7647-01-0
NA = Not Applicable ND = No Data NE = Not Established NL = Not Listed NR = Not Required
Release Date: December 17, 2007 Supersedes Date: N/A (New Release) Page 4 of 5
MSDS: Acid Stain (All Colors) Code: 2900-FS000
Section 16: Supplemental Information
NFPA (National Fire Protection Agency) 704: 0 = Minimal Hazard 3 = Severe Hazard
1 ?Slight Hazard 4 = Extreme Hazard
2 = Moderate Hazard
Health: 3 Fire: 0 Reactivity: 0
Disclaimer
The information and recommendations contained herein are based upon data believed to be correct; however, no
guarantee or warranty of any kind, express or implied, is made with respect to the accuracy of the information contained
herein. We accept no responsibility and disclaim all liability for any harmful effects, which may be caused by exposure to
our products. Customers and users of this product must comply with all applicable health and safety laws, regulations and
orders.
NA = Not Applicable ND = No Data NE = Not Established NL = Not Listed NR = Not Required
Release Date: December 17, 2007 Supersedes Date: N/A (New Release) Page 5 of 5
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