Material Safety Data Sheet Page 1 of 5
Material Name: DuraFormTM 316 L (Stainless Steel Powder)
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Hazardous Materials
Identification System
Product/Trade Name: DuraFormTM 316 L (Stainless Steel Powder)
(HMIS):
Chemical Family: Metal Powder
(Degree of hazard: 0 = low, 4 =
For use with the SinterstationTM DM100 and DM250
Product Use: extreme);
Systems Health 0*
Flammability 0
Physical Hazards 0
Personal Protection:
Skin, eye protection
Manufacturer:
Manufacturer Contact 3D Systems, Inc.
333 Three D Systems Circle
Rock Hill, SC 29730 U.S.A.
For Information Phone: 803.326.3900
Emergency 800.424.9300 - Chemtrec
II. COMPOSITION INFORMATION
CAS # Component Percent
7440-47-3 Chromium 7 ?12
7440-50-8 Copper 3?
7440-21-3 Silicon 1?
7440-02-0 Nickle 1?
7439-98-7 Molybdenum 1?
7439-96-5 Manganese 1?
7429-90-5 Aluminum powder (pyrophoric) 0.5 ?1.5
OSHA Classification: Irritant, Sensitizer (29 CFR 1910.1200 Appendix A)
III. HAZARDS IDENTIFICATION
Emergency Overview
Can cause sensitization by skin contact. Limited evidence of a carcinogenic effect.
Potential Health Effects:
Eyes: Can cause irritation consisting of redness, swelling and pain.
Skin: Can cause irritation or other allergic reactions, including redness and/or swelling.
Inhalation: Can cause respiratory irritation.
Ingestion: Not an expected route of entry.
Chronic: Can cause an allergic skin reaction with repeated or prolonged exposure consisting of redness, swelling and/or rash
(urticaria).
MSDS ?DuraFormTM 316L (Stainless Steel Powder) ?P/N 150603-S02-00-A ?ENGLISH ?US
Material Safety Data Sheet Page 2 of 5
Material Name: DuraFormTM 316 L (Stainless Steel Powder)
Medical Conditions Aggravated by Exposure
Could irritate an existing dermatitis or respiratory condition.
IV. FIRST AID MEASURES
Skin contact: Immediately flush skin with plenty of soap and water. Remove contaminated clothing and shoes. Get medical
attention if symptoms occur. Wash clothing before reuse.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists.
Inhalation: Move affected person to fresh air. In case of asphyxia, initiate artificial respiration immediately. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion: Ingestion is unlikely. However, if large quantities are swallowed, get medical attention.
V. FIRE FIGHTING MEASURES NFPA Ratings
0 0 = Minimal
Flash Point: NA Method Used: NA
1 = Slight
0
0
Upper Flammable Limit (UFL): NA Lower Flammable Limit (LFL): NA 2 = Moderate
Auto Ignition: Not self-igniting Rate of Burning: NA 3 = Serious
4 = Severe
General Fire Hazards: .
Hazardous Combustion Products: Thermal decomposition products can include CO, CO2, organometalic compounds, and smoke.
Extinguishing Media: Use water mist, dry chemical, carbon dioxide, or chemical foam. Avoid the use of a stream of
water to control fire since dusting can occur.
Fire Fighting Equipment/Instructions: Wear full protective clothing, including helmet, self-contained positive-pressure or pressure-
demand breathing apparatus, protective clothing and facemask. Move container from area if it
can be done without risk. Do not use high-volume water jet or high-pressure inert gas since
pressure may cause dusting. Avoid inhalation of material or combustion by-products.
VI. ACCIDENTAL RELEASE MEASURES
Containment Procedures: Ensure adequate ventilation. Avoid formation of dust. Do not release material or contaminated water into
drains, soil or surface waters.
Clean-Up Procedures: Wear appropriate protective equipment and clothing. Avoid the generation of dusts during clean up. Clean
mechanically with non-sparking tools. Place material in an appropriate container for disposal.
Evacuation Procedures: Keep unnecessary personnel away.
Special Procedures: A slipping hazard exists when small particles are spilled.
VII. HANDLING AND STORAGE
Handling Procedures: Avoid spilling powders to prevent slip hazards. Avoid dust accumulation of this material.
Storage Procedures: Keep this material in a cool, dry place. Eliminate all sources of ignition.
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
General Product Information:
CAS # Chemical Name ACGIH TLV OSHA PEL NIOSH REL
0.5 mg/m3 1 mg/m3 0.5 mg/m3
7440-47-3 Chromium
3
1 mg/m3 as Cu (dusts and
7440-50-8 Copper short-term 0.1 mg/m3 as Cu 1 mg/m as Cu (dusts and
long-term 1 mg/m3, as Cu mists) mists)
0.1 mg/m3 as Cu (fume) 0.1 mg/m3 as Cu (fume)
(dusts and mists)
long-term 0.2 mg/m3 as Cu
(fume)
15 mg/m3 total dust 3
7440-21-3 Silicon withdrawn 15 mg/m total dust
5 mg/m3 respirable fraction 3
5 mg/m respirable fraction
3
0.015 mg/m3 as elemental Ni
1.5 I mg/m3 as elemental Ni
7440-02-0 Nickel 1 mg/m
3
3
7439-98-7 Molybdenum 5 mg/m as Mo --
10 I (3 R) mg/m as Mo
(soluble compounds)
(insoluble compounds)
MSDS ?DuraFormTM 316L (Stainless Steel Powder) ?P/N 150603-S02-00-A ?ENGLISH ?US
Material Safety Data Sheet Page 3 of 5
Material Name: DuraFormTM 316 L (Stainless Steel Powder)
0.5 R mg/m3 as Mo (soluble
compounds)
0.2 mg/m3 as Mn, inorganic C 5 mg/m3 short-term 3 mg/m3 short-term
7439-96-5 Manganese
3 mg/m3 long-term
compounds, and fume as Mn, inorganic
compounds, and fume as Mn, inorganic compounds,
and fume
3 3
3
7429-90-5 Aluminum powder 15 mg/m total dust 15 mg/m total dust
(10) NIC-1R mg/m
3
5 mg/m3 respirable fraction
5 mg/m respirable fraction
Metal dust; NIC-A3
Engineering Controls
Ventilation must effectively control dusts.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face: Wear tightly sealed goggles.
Skin: Use impervious gloves, an apron, and closed shoes.
Respiratory: If ventilation cannot effectively keep dust concentrations below established limits, appropriate certified respiratory
protection must be provided.
General: An eye wash fountain and safety shower are recommended.
IX. PHYSICAL AND CHEMICAL PROPERTIES
Appearance .................................. Dark grey Odor .............................................. Oderless
Physical State............................... Powder PH ................................................. NA
Vapour Pressure .......................... NA Flash Point .................................... NA
Melting Point................................. Undetermined Viscosity ........................................ NA
Solubility (H2O) ............................ Insoluble Density .......................................... Undetermined
Percent Volatile ............................ NA Molecular Weight........................... NA
X. CHEMICAL STABILITY AND REACTIVITY
Chemical Stability: Stable under normal conditions of handling, use and transportation.
Incompatibility: None known.
Hazardous Decomposition: Thermal decomposition products can include CO, CO2, organometalic compounds, and smoke.
Hazardous Polymerization: Will not occur.
XI. TOXICOLOGICAL INFORMATION
Acute and Chronic Toxicity
A: General Product Information:
Irritant to skin and mucous membranes.
Sensitization possible through skin contact.
B: Component Analysis:
Carcinogenicity
A: General Product Information: None.
B: Component Carcinogenicity:
Component EPA IARC NTP ACGIH TLV NIOSH OSHA
Chromium 3 A4
Copper D
Nickle 2B R A5 Ca
Manganese D
XII. ECOLOGICAL INFORMATION
Ecotoxicity
MSDS ?DuraFormTM 316L (Stainless Steel Powder) ?P/N 150603-S02-00-A ?ENGLISH ?US
Material Safety Data Sheet Page 4 of 5
Material Name: DuraFormTM 316 L (Stainless Steel Powder)
A: General Product Information: The aquatic toxicity of the product is unknown; however based on components, it is predicted that this
material may be harmful to aquatic organisms or cause long-term adverse effects in the aquatic
environment. Prevent contamination of soil drains and surface waters.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity:
Environmental Fate: No information available for product.
XIII. DISPOSAL CONSIDERATIONS
Waste Disposal Instructions
Do not contaminate drains, soil or surface waters with the material or its container. Avoid disposal. Attempt to utilize product completely.
Dispose of in compliance with all local, state, and federal regulations. Prior to disposal of unused material, 3D Systems Inc.,
recommends consulting and using an approved waste disposal operative to ensure regulatory compliance.
XIV.TRANSPORT INFORMATION
US DOT RID/ADR IMDG IATA IMO Canada TDG
Shipping Name Not Regulated
XV. REGULATORY INFORMATION
US FEDERAL
TSCA:...........................................................................All materials are listed on the TSCA Inventory or are not subject to TSCA
requirements
SARA 302 EHS List (40 CFR 355 Appendix A): ...........None listed
SARA 313 (40 CFR 372.65): ........................................7440-47-3 Chromium (7 ?12%), 744-50-8 Copper (3 ?7%), 7440-02-0 Nickle (1
?3%), 7439-96-5 Manganese (1 ?3%), 7429-90-5 Aluminum powder
(pyrophoric) (0.5 ?1.5%)
CERCLA (40 CFR 302.4): ............................................Chromium, Copper, Nickle (Stat Code 2) no reporting required if the particles
released are greater than 100 micrometers in diameter.
STATE RIGHT-TO-KNOW STATUS
Component CA Prop. 65 MI NJ PA MA
Nickle X
Component Analysis - Inventory
Component/CAS EC # EEC CAN TSCA NLP
Chromium (CAS#7440-47-3) 231-157-5 EINECS DSL Yes No
Copper (CAS#7440-50-8) 231-159-6 EINECS DSL Yes No
Silicon (CAS#7440-21-3) 231-130-8 EINECS DSL Yes No
Nickle (CAS#7440-02-0) 231-111-4 EINECS DSL Yes No
Molybdenum (CAS#7439-98-7) 231-107-2 EINECS DSL Yes No
Manganese (CAS#7439-96-5) 231-105-1 EINECS DSL Yes No
Aluminum powder (pyrophoric) (CAS#7429-90-5) 231-072-3 EINECS DSL Yes No
MSDS ?DuraFormTM 316L (Stainless Steel Powder) ?P/N 150603-S02-00-A ?ENGLISH ?US
Material Safety Data Sheet Page 5 of 5
Material Name: DuraFormTM 316 L (Stainless Steel Powder)
XVI. ADDITIONAL INFORMATION
MSDS Creation Date: .... July 2, 2008
MSDS Revision #: ......... A
MSDS Revision Date:....
Reason for Revision: ..... Updated
For more information: .... www.3dsystems.com
800.793.3669 (Toll-free in the US GMT-07:00; N. America, Mon ?Fri, 6:00 a.m. to 6 p.m.)
803.326.3900 (Outside the U.S. GMT-07:00; N. America, Mon ?Fri, 6:00 a.m. to 6 p.m.)
+44 144-2282600 (Europe GMT+01:00; Mon ?Fri, 08:00 a.m. - 17:00 p.m. MEZ)
DISCLAIMER OF LIABILITY: The following supersedes any related provision in your company's forms, letters, and agreements from, by or with 3D
Systems Corporation. 3D Systems Corporation makes no warranty, whether expressed or implied, including warranties of merchantability or of fitness
for a particular purpose for this product. No statements or recommendations contained in the product literature are to be construed as inducements to
infringe any relevant patent now or hereafter in existence. Under no circumstances shall 3D Systems Corporation be liable for incidental, consequential,
special, or other damages from alleged negligence, breach of warranty, strict liability or any other theory, arising out of the manufacture, use, sale, or
handling of this product. In no event shall the liability of 3D Systems Corporation for any claims arising out of the manufacture, use, handling, or sale of
its products exceed an amount equal to the buyer's purchase price.
?Copyright 2008 by 3D Systems, Inc. All rights reserved. Subject to change without notice; the 3D logo is a registered trademark of 3D
Systems, Inc.
Key/Legend
ACGIH = American Conference of Governmental Industrial mg/Kg = milligrams per Kilogram
Hygienists mg/L = milligrams per Liter
CAS = Chemical Abstracts Service mg/m3 = milligrams per Cubic Meter
CERCLA = Comprehensive Environmental Response, MSHA = Mine Safety and Health Administration
Compensation, and Liability Act
NA = Not Applicable or Not Available
CFR = Code of Federal Regulations
NIOSH = National Institute for Occupational Safety and Health
CPR = Controlled Products Regulations
NJTSR = New Jersey Trade Secret Registry
DOT = Department of Transportation
NTP = National Toxicology Program
DSL = Domestic Substances List
OSHA = Occupational Safety and Health Administration
EINECS = European Inventory of Existing Commercial Chemical
SARA = Superfund Amendments and Reauthorization Act
Substances
STEL = Short Term Exposure Limit
EPA = Environmental Protection Agency
TDG = Transport Dangerous Goods
IARC = International Agency for Research on Cancer
TSCA = Toxic Substances Control Act
IATA = International Air Transport Association
WHMIS = Workplace Hazardous Materials Information System.
IDL = Ingredients Disclosure List
MSDS ?DuraFormTM 316L (Stainless Steel Powder) ?P/N 150603-S02-00-A ?ENGLISH ?US
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